Search Documents

By Kyoungkeun Yoo

A citric acid leaching test after heavy medium separation process was performed to remove the heavy metal contaminat such as Pb, Cu, and Zn from contaminated soil. The lead component was removed from soil by heavy medium separation whereas zinc component shows 0 % - 37.9 % removal ratio with particle size. The citric acid leaching was conducted to remove the remained zinc component. The removal ratio of Zn reached to more than 95 % under the conditions; 10 % in pulp density, 200 rpm in agitation speed, 50 °C, 2 mol/L in citric acid concentration at 2 hrs in leaching time. These results suggest that the heavy medium separation method followed by citric acid leaching is effective for treatment of soil contaminated with various chemical forms of heavy metal. Keywords: metal contaminated soil, citrate, heavy medium separation, zinc

Sep 1, 2012

By J. D. Clucas, D. B. Dreisinger

"The Starved Acid Leach Technology (SALT) has been developed by Search Minerals to extract nickel and cobalt VALUES (from nickel laterite ores (saprolites) and Caron plant residues. The technology consists of sulfuric acid atmospheric leaching of the ores or residues followed by neutralization and recovery of nickel and cobalt. The acid addition is carefully controlled to maximize nickel and cobalt extraction while minimizing overall consumption of acid by various gangue reactions. The final recovery processes can be tailored for maximum economic benefit. The use of resin-in-pulp processing is advocated as the most cost effective method for initial recovery of nickel and cobalt from lower grade materials. INTRODUCTIONCommercial processes for laterite ore treatment vary according to laterite type and local conditions. The two general categories of laterite ore are saprolites and limonites.Saprolites are generally treated by pyrometallurgical processes for reduction of nickel to matte or ferro nickel alloys. The high cost of drying, chemical reduction and electric furnace smelting requires that the saprolite grade for economic processing is of the order of 1.8% nickel or higher. There are of course large amounts of saprolite that fall below this “cut-off” grade that are not currently economic.Limonites can be treated by the Caron Process which involves drying of the ore, a reduction roast of the whole ore to reduce nickel and cobalt (and some iron) to the metallic state followed by ammonium – ammonium carbonate solution to leach nickel and cobalt. Nickel and cobalt recovery are low (70-85% for Ni and 20-50% for Co). The Caron plant tailings therefore contain high levels of unrecovered nickel and cobalt. Relatively few plants have used the Caron Process and new installations are not anticipated due to the high energy cost of drying and reduction roasting. Nevertheless, plants in Brazil (Niquelandia), Australia (Yabulu) and Cuba continue to operate.The high pressure acid leach (HPAL) process was pioneered at Moa Bay in Cuba in the 1960’s in the treatment of limonites. In the 1990’s the HPAL process was touted to revolutionize the nickel industry with low capital and operating costs for new installations. Murrin Murrin, Cawse and Bulong in Australia were started and in each case the technical difficulties of operating at extreme temperature and pressure conditions and the challenges in “ramping up” a complex hydrometallurgical facility conspired to cause these plants to fail economically. At present, Cawse and Bulong are closed and Murrin Murrin continues to operate after undergoing a financial restructuring."

Jan 1, 2012

By F. J. Palumbo

An electronic color-sorting machine was tested for recovering colorless glass concentrates from mixed glass products. The tests were made using glass recovered from unincinerated (raw) urban refuse and residues resulting from the incineration of refuse. The results of the study revealed that concentrates analyzing about 86 percent colorless glass could be recovered from mixed unincinerated glass containing 54 percent colorless glass material. Recovery of the colorless glass was about 62 percent. Color sorting the incinerated glass was somewhat more difficult. Multiple-stage processing was required to recover 59 percent of the colorless glass material in a product analyzing 89 percent colorless glass. The feed material analyzed 41 percent colorless glass.

Jan 1, 1971

By A. G. Roach

Introduction The plant described in this paper is located at Coniston, Ontario, the smelting centre of the former Mond Nickel Company. Coniston is situated some eight miles east of Sudbury on the main line of the Canadian Pacific railway and on the Toronto-Capreol branch of the Canadian National-railways. The plant is now under control of the International Nickel Company, as a result of the merger of the two companies in 1929. The smelter proper includes four 50-in. by 240-in. blast furnaces and five 13 ft. by 30 ft. converters, and has a capacity of about 65,000 tons of ore charge per month. As accessories to the smelter there are a mill, where some 10,000 tons per month of low-grade ores are concentrated, and the sintering plant, which is the subject of this paper. The present 6-unit sintering plant replaces a former 4-unit installation. Here, fine ores, concentrates, and flue-dust are sintered on Dwight-Lloyd machines, the sinter produced being charged into the blast furnaces. At the time of writing (1931), only the concentrator is operating at capacity, due to present world conditions.

Jan 1, 1932

By John B. Gayle

During studies of the various methods for determining and specifying the factors that indicate whether a particular coke is better or worse than other cokes for metallurgical uses, questions arose as to the precision of screen-analysis tests on coke. Although the usual index of precision, the standard deviation of the test result, gives a measure of the precision of these data, the experimental determination of the standard deviation for a particular set of conditions requires tests on a large number of duplicate samples. Because this procedure necessaily involves a great deal of labor, an equation for predicting standard deviations from theoretical considerations has been developed. Results predicted with this equation agree satisfactorily with the experimental values and are applicable to tests on coal, coke, gravel, and other bulk materials.

Jan 1, 1952

By Duah Philip, Awuah-Offei Kwame

Regulatory pressure to mitigate the cement industry’s environmental impact has intensified recently, spurring innovation in low-carbon cement technologies. In the United States, cement production, consumption, and carbon emissions are accelerating. Despite this trend, the adoption of environmentally friendly dry clinker production technology with combined preheater-precalciner systems has surged from 53.3% in 2002 to 88.5% in 2019. Concurrently, reliance on wet technologies, known for their higher environmental impact, has dropped from 16.5% to 0.6% within the same period. This paper presents the results of our comprehensive study, utilizing over 100 years of industry data, to analyze these technological shifts and their environmental implications.

Feb 1, 2025

By H. M. Woodroffe, H. K. Conn, S. J. Rice

World production of asbestos is estimated to be at a current level of almost 3.5 million tons, having more than doubled in the past ten years. A substantial part of the increase has been due to a rapid expansion in the Soviet Union. Production from that country during 1964 is estimated at 1.5 million tons and, as a consequence, Russia has displaced Canada as the leading world producer. Although traditionally the asbestos mining industry has been centered near Sverdlovsk in the Urals, two new producing areas have been under development for some time. It is expected that a new mine will be in operation in 1965 near Kiembi, Kazakhstan, some 300 miles south of Sverdlovsk, and an- other mine at Aktrovak in Tannu-Tuva, west of Lake Baikal. These developments will provide a significant increase in the production capability of Russia. Although internal consumption is expected to increase with the addition of new asbestos- cement producing facilities now under construction in Russia, there is some speculation that exports will also increase.

Jan 2, 1965

By E. S. Leaver

Experiments dealing with the dissolution of silver by cyanide from various silver minerals-were reported, several years ago.4/ This work showed that the silver in some silver minerals is completely and readily soluble in cyanide solution, whereas other silver minerals must be given special treatment before or during cyanidation to obtain much dissolution of the silver by cyanide. Flotation as a method for treating silver ores has not been studied much, except in the case of base-metal ores carrying silver, Particularly lead-silver ores. However, many mills now are concentrating gold ores by flotation, and when such ores also contain silver the recovery of the silver by flotation is of considerable importance. Moreover, many mines contain ore in which silver is the principal valuable constituent. Some of these ores are amenable to cyanidation, but the cost of a cyanide plant may be prohibitive because of limited ore bodies or other factors. In such instances the successful application of flotation would mean that the property could be operated.

Jan 1, 1939

By William J. Davis, R. Blair Hrabi, Sally Pehrsson, Amelia V. Logan, Ross Sherlock

"Abstract - The Meadowbank gold deposits are hosted by a series of polydeformed and metamorphosed auriferous iron formations located in the Neoarchean Woodburn Lake group, western Churchill province, Nunavut. The supracrustal rocks in the Meadowbank area consist of a thick sequence of intermediate-composition volcanic rocks with intercalated iron formation, ultramafic volcanic rocks, and quartzite to quartz arenite. U-Pb geochronology gives an interpreted age of 2711 ± 3 Ma for the host strata at Meadowbank.The intermediate volcanic rocks are predominately volcaniclastic and have a geochemical composition that is consistent with an active continental margin setting. Iron formation deposition was coeval with the intermediate volcanism, as indicated by incorporation of volcanic detritus in the chemical precipitate. The geochemistry of the iron formation indicates that it precipitated from a fluid that at one time was at high temperature (>250°C), reducing, and likely acidic. Intercalated ultramafic rocks rarely show spinifex textures and have trace element ratios that are consistent with mantle plume-related undepleted mantle asthenosphere, likely recording episodic mantle upwelling associated with rifting in an active continental margin. The contact between the ultramafic volcanic rocks and the overlying quartz arenite is a disconformity marked by a quartz pebble conglomerate. However, similar geology on the structural hanging wall and footwall of the contact suggests that the conglomerate does not represent a significant hiatus in deposition, and is more likely a prograding terriginous siliciclastic unit.Three metamorphic events are recognized. The first, M1, is a cryptic greenschist facies event that is pre-D2. The second event, M2, is a mid-greenschist to amphibolite facies, syn-D2 event. M3 is the last event recognized, and is a post-tectonic greenschist facies event that is regional but inhomogeneous in extent, possibly reflecting thermal aureoles around post-tectonic 1.7 to 1.8 Ga Nueltin granites. The structural geology of the area is complex with four phases of deformation recognized, two of which had a significant effect on the geometry of the deposit. All of these regional events are interpreted as Paleoproterozoic in age. Relationships between deformation fabrics and mineralization, as well as the overall geometry of the mineralized envelopes, suggest that the deposit formed during syn- to late-D2. Superimposed on the mineralization are D4 structural elements that postdate gold mineralization.The main control on gold mineralization is replacement of magnetite by pyrrhotite and pyrite in high-strain corridors. The composition of amphiboles and chlorites associated with gold mineralization is remarkably consistent and shows no spatial or temporal variation, suggesting that it was buffered by the iron-rich nature of the host rocks. The bulk metasomatic effect on the intermediate volcanic rocks is characterized by the addition of K2O and the loss of CaO, Na2O, and MgO, with little variation in the total iron content. The elemental losses are likely the result of destruction of feldspars, stilpnomelane, and ferroactinolite, which are relatively common in the unmineralized rocks, and the formation of sericite, chlorite, and grunerite."

Jan 1, 2004

State ownership of minerals results in domestic legislation regulating mining operations. The mining industry today is dominated by a number of transnational companies, each subject to internal and external pressures for a more responsible approach to resource management. Thirty to 40 major companies are responsible for the bulk of the worldÆs mineral production with the balance coming from state-owned, second tier and junior companies and from artisanal miners.Mining companies operating within competitive commercial environments formerly focussed on mineral production. Companies worked to standards and expectations then current which largely failed to recognise the impact of mining activities on community interests. The mining industry acquired a reputation for arrogance, and for placing profitability ahead of issues considered equally or more important by local communities. Current perceptions continue to reflect disquiet about industry attitudes towards traditional land-owners and access to their lands, to environmental contamination, handling and storage of waste materials, utilisation of water and electricity, and to rehabilitation of worked out areas. Major international mining companies concerned at continuing criticism sponsored a series of initiatives with the objective of providing guidance on working harmoniously within the community. Industry commissioned studies, performed through the agency of disinterested parties, resulted in May 2002, in a Declaration being issued at an International Conference in Toronto. The Declaration was based on, but did not reflect all of the recommendations of the MMSD Report, æBreaking New GroundÆ.This paper considers whether benefits would result from the negotiation of a legally binding and enforceable international protocol encompassing the objectives of the MMSD report or the Toronto Declaration. It attempts to identify the problems associated with implementing and enforcing international mining law, should it be introduced. Aspects of mining operations having cover under customary international law are reviewed, as are rights, obligations and remedies for breaches of national mining law. Conclusions are drawn based on established procedures relating to implementing international agreements. The continuing ability of mining companies to operate within communities will result from each satisfying the communityÆs expectations rather than by complying with largely unenforceable legislation.

Jan 1, 2004

During incineration of municipal solid waste (MSW), various environmentally harmful elements and heavy metals are liberated partly into bottom ash, and partly carried away with the off-gases and subsequently trapped in fly-ash. If these waste incineration residues are not properly processed and immobilized, it can lead to secondary environmental pollution to the air, soil and water. The stricter environmental regulations require a higher immobilization efficiency of the waste incineration residues, which is the main objective of the present cooperation research. Within the present project, a systematic scientific research on various MSWI residues has been carried out, including sampling, low or high temperature processing and leaching tests. In the present paper, the major results have been summarized. The research results reveal that through appropriate combined pre-processing and high temperature vitrification, the bottom ash and fly ash can be efficiently stabilized. The results achieved provide a valuable alternative route to treat the solid residues from incinerators, and to make efficient recycling and safe utilization possible.

Jan 1, 2014

By Ron Zevenhoven

In Finland one opportunity for large-scale CO2 capture, utilisation and storage (CCUS) is CO2 mineralisation, i.e. mineral carbonation. A process route under development towards industrial application involves production of magnesium hydroxide or sulphate from serpentinite rock (serpentine = 3MgO·2SiO2·2H2O), followed by conversion either in a pressurised fluidised bed (PFB) reactor, giving magnesium carbonate, or in an aqueous solution process giving magnesium hydro-magnesites. Iron present in the rock is typically obtained FeO(OH). Results obtained with these process routes and progress towards industrial demonstration is addressed, process heat integration and operation on flue gases (without CO2 pre-separation!) being key features for economic viability. A process route utilizing calcium-containing slag by-product from iron- and steelmaking under development towards large-scale application is the so-called slag2pcc concept. It converts an industrial by-product into valuable material, reduces use of natural material and streams to landfills while binding CO2 produced by the process generating the slag. Using ammonium salts, calcium is extracted from steel converter (BOF) slags and subsequently carbonated in a two-stage aqueous process (at ambient temperatures and pressures). Precipitated calcium carbonate (PCC) is produced while regenerating the ammonium salt. Process performance and scale-up while guaranteeing a certain PCC quality are presented.

Jan 1, 2015

By James R. Boyle

The value of Alabama's nonfuel mineral production in 1978 and 1979 was 8831.8 million and $336.4 million, respectively. In 1978, nearly all commodities registered an increase in production and value; unit value increased for all commodities, with the exception of native asphalt and sand and gravel. Alabama led the Nation in the production of crushed marble and was second in bauxite, third in masonry cement, kaolin, native asphalt, and oyster shell, and fourth in bentonite, dimension marble, fire clay, and scrap mica. Trend; and Developments.-The Alabama State Docks at the Port of Mobile handled more than 10 million tons of bulk material in fiscal year 1978; volume dropped slightly to 9.8 million tons in fiscal 1979. Bulk materials comprise the major activity at the facility, with iron ore and bauxite being two of the major materials handled. The movement of these ores is vital to the operation of many heavy industries in the State.

Jan 1, 1981

By David Schlain, C. B. Kenahan, F. X. McCawley

The electrodeposition of protective coatings of tungsten from a sodium and lithium borate - tungstate - tungstic oxide fused salt electrolyte was investigated . Soluble tungsten anodes were employed . Deposits were made on molybdenum , Carpenter 20 stainless steel , Inconel , and nickel . An atmosphere of argon was maintained around the electrolytic cell , and the electrolyte was stirred by rotating the cathode . Thick deposits of tungsten (up to 26 mils ) were made at a temperature of 900 ° C and cathode current densities of 0.3 to 0.4 ampere per square inch with high current efficiencies . The effects of variations in temperature , current density , electrolyte agitation , and tungstic oxide content of the electrolyte and of the presence of impurities such as moisture , air , iron , and nickel were investigated .

Jan 1, 1964

By M. Rahman, P. C. Kapur

The fixed-time locked-cycle grinding test is employed to simulate the industrial closed grinding circuit on the laboratory scale. A mathematical algorithm for 'cyclewise' computer simulation of the locked-cycle test has been derived and used to study an idealised laboratory-scale model of a closed ball-mill circuit. The agreement between simulated and experimental results is reasonably good, except when the grinding times are relatively long

Dec 1, 1971

By KNona C. Liddell

The ion interaction model Pitzer proposed twenty years ago is today the most widely used method for calculation of osmotic coefficients and electrolyte and single ion activity coefficients in aqueous solutions. This is due in part to the accuracy of the results that have been obtained for many concentrated electrolytes. An additional factor is that, compared to alternative activity coefficient models, there are many more parameter values available for the Pitzer equations. The important features of this model are reviewed. Published parameter values for Co, Ni, Cu, Zn and Fe are tabulated, and applications of interest in the aqueous processing of these metals are described.

Jan 1, 1993

By Paul R. Thimas, Edward H. Boyle

"The Bureau of Mines evaluated the long-term cost and availability of primary gold production from 135 mines and deposits worldwide. Collectively, the evaluated countries represent 93 pct of world gold production. Total recoverable gold available (as of January 1984) from a subset of 111 significant producing mines and developing deposits in 13 market economy countries (MEC's) is estimated at 810 million tr oz. The Republic of South Africa is estimated to account for 87 pct of total recoverable gold. The United States and Canada account for 4 and 4.5 pct of the total, respectively. Eighty-three percent of total recoverable gold is available at a constant 1984 break-even price of $400/tr oz, and 70 pct is available at $300/tr oz. South Africa accounts for 90 pct of the gold available at $400/tr oz or less.Major conclusions are that (1) South Africa should remain the largest world producer through the year 2000, (2) annual MEC output in 2000 should not be significantly different than current output given constant 1984 gold prices of more than $300/tr oz, and (3) there may be a significant decline in production after 2010 in the absence of major new discoveries and continued development of new mines to offset the depletion of the South African mines. INTRODUCTIONSince the late 1970's the world gold mining industry has been characterized by dynamic growth in production and volatility in price. World production in 1983 was almost 15 pct greater than in 1980, and the short-term trend continues upward. Annual dollar-based price changes since the early 1970's have been unprecedented in both magnitude and volatility. This commodity, which sold for $35/tr oz3 for over a third of a century, reached an annual average $612/tr oz in 1980. Until 1980, the future price of gold seemed set on an upward trend. Since that year, however, world gold prices have fallen by over 50 pct to slightly over $300/tr oz at the end of 1984.Against this background, this study was undertaken to determine (1) the level of world demonstrated gold resources, (2) total and annual availability of gold mine production, (3) long-run production costs per operation and by national aggregates, (4) the economic and technical factors that impact upon cost and availability, and (5) probable future mine production and cost trends."

Jan 1, 1985

By Y. P. Huang

Experiment results and operation practice on reutilizing old tailings dumped at SCIM (Shang-chang Iron Mine) of KISCO (Kunming Iron and Steel Corp.) are presented. In a production period over 30 years SCIM dumped about 8 million tons of iron ore tailings. For improving resources utilization instead of wasting, experiments on processing for reutilization of the old tailings are con-ducted. These tailings are fine size fractions of weathered iluvial ores rejected out by classification- des-liming in ore washing and dressing processes, containing TFe 21%~22% in hematite mainly and limonite occasionally. Their particle size distribution, in average, is of 72.26% minus 0.037mm and 30.88% minus 0.005mm. Existence of plenty of micro-fine particles makes the tailings refractory to process, resulting in poor metallurgy. The whole sample of the old tailings without size-classification is fed into experimental process. Slon-100 type high grads WHIMS (wet high intensity magnetic separator) with cyc-pulsing is adopted, which magnetism-focusing rod?s diameter is changed from 3mm into 2mm. Operational conditions of optimizing rougher separation tests are strengthened. An iron concentrate assaying 52.21% Fe at quantity rate of 18.39% and iron recovery of 44.40% is obtained. Operational practice shows that metallurgy and economy of the old tailings treatment are close to what achieved at experiments. It is estimated, therefore, that some 1.4 million tons of this iron concentrate may be recovered from the old tailings. This means that KISCO has moved its key one-step in re-mining and reutilizing the secondary resources, which would be a good demonstration in this industry. This is also of social and economic significance in response to China government?s request on reducing consumption of resources and establishing society with economy for achieving sustainable development.

Jan 1, 2014

By K. K. Kelley

The heats of formation of two lead vanadates (Pb2V207 and Pb3V208) and manganese vanadate (MnV206) were determined by hydrochloric acid solution calorimetry, supplementing previous Bureau of Mines measurements of the vanadates of calcium, magnesium} and sodium. Heat and free energy data for 11 vanadates were assembled on a common basis. The stability of comparable vanadates (with respect to the oxides) increases in the following order: Magnesium, manganese, lead, calcium, sodium.

Jan 1, 1963

By W. W. Graff

This paper describing the mining practices at Mine, No. 4 on the Marquette range, Michigan, is one of a series of articles on mining methods and practices in various mining districts in the United States. Mire No. 4 is located in the Swanzy district, in the southern end of the Marquette range, about 3 miles from Gwinn, Mich. The Swanzy district is an isolated ore-bearing formation, and Mine No. 4 is at the extreme southeastern end.

Jan 1, 1930