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By D. E. FOCG, A. E. Wells

When the United States entered the World War governmental agencies found little definite knowledge available as to the exact capacity of each sulphuric acid plant in the United States to manufacture acid under the stress of a great emergency. It is true that on account of the demand for acid for the manufacture of munitions for the Allies, prior to the entrance of this country into the war, most of the acid plants near industrial centers in the Eastern and Northern States were running at or nearly their maximum capacity, but, . for various reasons, many plants in these States and plants in other districts were not. For a number of years statistics as to the production of acid by the plants of the country were compiled by the United States Geological Survey, but obviously such figures did not give information as to the maximum capacities that might be available for meeting the he.a vy war ·requirements, or as to the steps that would have to be taken to bt-ing these capacities into use. During the summer and early fall of 1917 various attempts were made to obtain the desired information, but no satisfactory or complete data were obtained. Late in 1917, under the authority granted to the Bureau of Mines by the explosives act, the Director of the Bureau of Mines directed A. E. Wells, metallurgist of the bureau, to uiake a complete survey of the situation. Mr. Wells personally conferred with officials of the acid companies and visited most of the acid plants in the North that are east of the Mississippi River. The information obtained through this personal survey, together with that obtained through the ready cooperation of the subcommittee on ncids, and the subcommittee on fertilizers of the Committee on Chemicals of the Council of National Defense, enabled the preparation of a report containing the desired data concerning the sulphuric acid industry. This report was made immediately available to the War Industries Board and to those offices in the War and Navy Depart- ments that were most directly concerned in planning the explosives program and in obtaining the necessary supplies to produce the explosives. Beginning with this survey and report, the sulphuric acid section of the war minerals investigations of the Bureau of Mines took an active part in all matters pertaining to the sulphuric acid industry during the remainder of the war. Mr. Wells, the chief of the section, was appointed an associate chief of the sulphur, pyrite, and sulphuric acid sections of the War Industries Board. .Also, by this direct contact with the War Industries Board, the data obtained by Messrs. R. R. Hornor, H. A. Buehler, a.nd 0. Lindstrom, who were in charge, for the bureau, of the investigations concerning the supplies of pyrite and sulphur, were constantly made available to all interested Government agencies. D. E. Fogg, of New York City, was appointed chemical engineer to the sulphuric acid section to make special investigations relating to the acid industry, especially the possible utilization, in an emergency, of those sources of raw material.not then being used. Mr. E. E. Corbett, of Brooklyn, N. Y., was appointed chemical engineer to make investigations concerned primarily ,vith the conservation of acid. Direct and intimate contact with the industry was had through the close cooperation with the committee on acids of the Chemical Alliance, this committee during the greater part of 1918 occupying rooms with the acid section of the bureau. With the ending of the war and the close o:f the active work of the acid section of the bureau, the suggestion was made by many interested parties that a bulletin be prepared giving some qf the fun. damental and most important facts regarding the sulphuric acid industry, including a discussion of the technical :features of the manufacture of acid. During the war the bureau received -a vast number of inquiries in regard to various phases of the industry, a.nd this fact also made such a bulletin seem desirable. Therefore, the present bulletin was prepared to cover the main facts in regard to the industry in this country, including a discussion of the supplies of sulphur-bearing raw materials, the situation of the acid plants, the principal points in regard to manufacturing processes, and the uses of the acid. No attempt has been ma.de to discuss at length the manufacturing processes, as details differ more or less at the different plants and in general are carefully guarded by the acid ·companies. A great deal of the data given in this bulletin may be found in various pub]ications, but this is the first publication in which such data have been assembled and made readily available. Most of the data were obtained directly from observation and from cooperating acid companies or from individuals who had been or are now engaged in acid manufacturing and were liberal and generous in making their information available for publication. Care has been exercised to publish no data that were obtained as confidential by the bureau's representatives. The average acid manufacturer may be already more or less acquainted with most of the information presented in this bulletin, yet it is believed that the bulletin will be of value to those who wish to obtain a. general review of the present condition, both the economic and technical, of the sulphuric acid industry in the United States.

Jan 1, 1920

By J. E. Dooley

A mass spectral scheme of analysis was devised which can be used to identify individually a single compound from a larger group of similar compounds. Mass spectra for 32 alkyl aryl sulfides are provided for future reference work, and analytical correlations used in producing the analytical scheme are discussed. Some of the correlations show that base peaks are either the same mass as the parent peaks or may be derived from cleavage alpha to the sulfur atom with migration of one hydrogen to the sulfur atom. Other spectral consistencies provide means of separating ortho-, meta-, and paratolyl arrangements in an overall analytical scheme. Determinations of chain lengths and separation of isomeric species are also discussed.

Jan 1, 1972

By Gustavo Queiroz Esteves

O objetivo deste trabalho foi avaliar a utilização de peneiras de alta frequência em circuitos de beneficiamento mineral. Foram testadas diferentes aberturas de telas (mm), taxa de alimentação (t/h) e percentual de sólidos para verificar a eficiência global de peneiramento na fração 0.15mm. Frações retidas nesta malha têm sido apontadas como críticas para a flotação, sobretudo flotação em colunas. O circuito clássico das usinas normalmente utiliza ciclones para classificação de partículas finas (

Aug 1, 2018

By R. L. Marek

The number of Persons fatally injured in the petroleum industry in California in 1930 was 50, a decrease of 20.6 per cent from 1929, when 63 men accidentally lost their lives. The decrease in the number of fatalities for 1930 has caused the first downward trend in the fatality curve of the California petroleum industry since 1927 and is coincident with a period of little active development in new fields, the shutting in of many wells, and reduced activity in the older fields of the State. That a direct relationship exists between the number of accidental deaths and the rapidity of new field development is particularly emphasized by the fact that in 1929, a year of intensive field development in California, 48 men were killed in the drilling and producing division, whereas in 1930, a year of less development work, only 25 men were killed in this division. The figures for the average number of drilling and producing wells in 1930 decreased appreciably from comparable figures for 1929 and a greater percentage of producing wells were shut-in in 1930 than in 1929.

Jan 1, 1931

By R. L. Marek

The number of persons fatally injured in the petroleum industry in California in 1930 was 50, a decrease of 20.6 per cent from 1929, when 63 men accidentally lost their lives. The decrease in the number of fatalities for 1930 has caused the first downward trend in the fatality curve of the California petroleum industry since 1927 and is coincident with a period of little active development in new fields, the shutting in of many wells, and reduced activity in the older fields of the State. That a direct relationship exists between the number of accidental deaths and the rapidity of new field development is particularly emphasized by the fact that in 1929, a year of intensive field development in California, 48 men were killed in the drilling and producing division, whereas in 1930, a year of less development work, only 25 men were killed in this division. The figures for the average number of drilling and producing wells in 1930 decreased appreciably from, comparable figures for 1929 and a greater percentage of producing wells were shut-in in 1930 than in 1929.

Jan 1, 1931

By Saurabh Kundu, Shakuntala Tudu, Indrajit Paul, Chandra Sekhar, Manikanta Nallamilli, Shaik Mahaboob Basha, Neha Gupta, Srinivas Dwarapudi, Dhiraj Madhukar Kadhe

Iron ore pelletizing using compressive and shear action on wet mixture feed has been studied. The physical properties, namely, moisture content, drop strength, green compressive strength (GCS), dry compressive strength (DCS), porosity, and cold crushing strength (CCS), have been studied. Pelletizing tests were carried out on four different types of ore, namely, hematite ore, magnetite ore, goethite ore, and sinter return fines. The inference of shear forces on silica distribution index in dry pellet has been studied using optical and scanning electron microscopy. Significant improvement in physical strength was observed due to compressive and shear forces on the pellet mixture feed. However, decrease in moisture content and ball porosity has been observed. Silica distribution index improved by 1.72 times for hematite ore, 1.47 times for magnetite ore, and 1.68 times for goethite ore. It has been found that bubble cavity has been reduced which is good indicator in terms of physical properties.

Jan 29, 2022

Producing robust agglomerates with desirable structural properties is the key to success of the heap leaching of complex, low-grade nickel laterite ores. Mechanically strong but porous agglomerates with narrow size distribution (e.g., 5 ? 40 mm) are required to build permeable and perennially stable heaps of 4 ? 10 m height. The characterization of granules? microstructure is essential for greater understanding and correlation with the concomitant mechanical properties and robustness. In this study, we used non-destructive, computed X-Ray tomography analyses and scanning electron microscopy (SEM) in tandem with conventional compressive strength,and integrity/stability tests to draw links between nickel (Ni) laterite agglomerate strength/stability, internal microstructure (e.g.,porosity, inter-particle bridges) and binder type. It is shown that binder composition (e.g., tap water vs. 30% w/w H2SO4) and post-agglomeration drying both significantly impact on granules? physicochemical and microstructural properties. Acidic binder, in contrast with tap water, leads to significant incongruent leaching of different species from particles during ore-binder mixing and agglomeration. Upon wet agglomerate curing, solidified/recrystallized leached species form strong intra-granular solid bridges which, lead to greater compressive strength of dry agglomerates. Structural stability/integrity of cured agglomerates in acidic solution, however, decreases dramatically due to greater porosity and acid solubility of intra-granular solid bridges. These findings are useful in shedding more light on agglomerate structure characteristics and their optimization for enhanced column and heap leaching with concentrated sulphuric acid.

Sep 1, 2012

By Arthur L. Crawford, R. E. Head, Fred E. Thackwell, A. Lee Christensen

"The data in this report are the result of a detailed, microscopic study of composite samples of mill products collected over a 14 day period. The samples were collected and assembled under the direction of W. R. Lindsay, superintendent of the Anyox plant, and are fairly representative of the heads, middlings, tailings, and products peculiar to the scheme of concentration practiced at Anyox in 1930.The work was done in the Cooperative Microscopic Laboratory at Salt Lake City, Utah. This laboratory was equipped by the mine and mill operators of the Salt Lake Valley and functioned under a cooperative agreement between the United States Bureau of Mines the University of Utah. This is the fourth of a series of papers 6/ dealing with a microscopic study of mill products."

Oct 1, 1935

By W. Hodge Caraway

This report presents the results of an evaluation of several indirect methods of measuring the water content of oil-reservoir rocks. The water content of oil-base cores is considered to be most nearly representative of the water content of the undisturbed petroleum reservoir and therefore, the direct method of measuring the volumes of water in cores cut in oil-base drilling fluid was adopted as a standard for comparison. The indirect methods evaluated included (1) displacement through a semipermeable membrane by air, (2) centrifuge, (3) evaporation, (4) mercury injection, (5) chloride dilution and (6) electric logs. Approximately 270 samples of cores from petroleum-reservoir rocks were used in the study. The cores, most of which were cut with oil-base mud in the hole, were taken from oilfields in California, Texas Gulf coast, Colorado, Oklahoma, and Alaska.

Jan 1, 1959

By R. Guardia, J. Hoskins, E. Claros, Y. Kamiya, R. Ramirez, J. Dalenz, P. Fernandez, E. Ilgren

Crocidolite is a well known causative agent for mesothelioma. Studies have shown that the pathogenicity of the fiber from different mines varies considerably and it has been postulated the parameter that appears most likely to account for this variation is fiber width. Epidemiological studies have shown that ‘thin’ fibers from mining areas of Western Australia and the Cape Province, in South Africa are associated with a high mesothelioma risk while exposure to ‘thick’ asbestiform amphibole fiber of the same fiber type are associated with little or no mesothelioma risk. This study is concerned with ‘thick’ Bolivian crocidolite but similar findings also probably explain the paucity of mesotheliomas in the Finnish anthophyllite, South African amosite and African Transvaal crocidolite mines. The findings from the present study suggest the incidence of mesothelioma in the three major cities of Bolivia is not significantly elevated above background even though Bolivian crocidolite has been used for the past 60 years commercially and residentially in all three cities. Although some cases of mesothelioma may have been missed due to a failure to reach hospital or a shortened natural lifespan, mesothelioma generally occurs after the age of 50, we cannot tell precisely the extent to which these were confounding. We suggest the most likely explanation for the lack of mesotheliomas despite the large populations at risk from the long and extensive residential and commercial use of crocidolite containing products, is related to an increased fiber width distribution and a concomitant reduction in the ‘Stanton fiber size’ fraction.

Jan 1, 2012

By J. Seiter, S. Cox, E. Kim

Mining has always been among the most hazardous of occupations, and with the increasing demand for coal and minerals, safety in mines assumes even greater importance. Worldwide, underground miners are being exposed to noise and respirable dust hazards associated with roof bolt drilling. These hazards are now being understood to cause irreparable damage to the health of miners. The objective of this research was to discover if a polycrystalline diamond compact (PDC) drill bit generates less respirable dust and hazardous noise than a competing tungsten carbide (WC) bit in dry vacuum drilling. In order to control the drill parameters the drilling tests were conducted in a laboratory setting. The results were obtained by determining the quantities of dust and noise generated using each drill bit and analyzing those levels, using monitoring devices and software to collect the data. This paper includes information on the experimental setup, equipment used, drilling parameters, and data collected. Our results indicate that PDC bits produce significantly less noise and dust than WC bits. Our findings can contribute to improving the working conditions of rock bolter operators by reducing noise and dust generation.

Jan 1, 2014

By Edward E. Johnson

The Bureau of Mines publishes in its ?Minerals Yearbook? a series of indexes on the domestic minerals industry. Among these are the index of physical volume of mineral production, indexes of stocks, and indexes of average unit mine value and implicit unit value, This report describes the material coverage of these indexes and the methods used in their construction. Detailed descriptions are given for several other mineral-oriented indexes regularly published by other government agencies. These descriptions give the index user a better understanding of what each index purports to measure and aids him in selecting the most appropriate index for his purpose.

Jan 1, 1965

By Edward E. Johnson

The Bureau of 'Mines publishes in its ?Minerals Yearbook? a series of indexes on the domestic minerals industry. Among these are the index of physical volume of mineral production, indexes of stocks, and indexes of average unit mine value and implicit unit value, This report describes the material coverage of these indexes and the methods used in their construction. Detailed descriptions are given for several other mineral-oriented indexes regularly published by other government agencies. These descriptions give the index user a better understanding of what each index purports to measure and aids him in selecting the most appropriate index for his purpose.

Jan 1, 1965

By R. W. Stahl

An award is a form of recognition given for superior performance in a special field of endeavor. Each year awards are given by the Joseph A. Holmes Safety Association and the National Safety Council to mineral industries' mines, quarries, and plants that have worked a specific number of man-hours without a lost-time injury. These awards have a dual significance in that they prove that efficiency can be attained without injury to persons. Safety awards do not result from luck or good fortune but do result from sincere desire coupled with sufficient effort and cooperation to achieve a desired goal.

Jan 1, 1963

By John H. Nicholls

In this paper, Imperial Oil Limited reports briefly on the drilling by contract rigs of twenty-nine slim holes in the Virden, Smiley, and Souris Valley areas. The investigations showed that slim-hole penetration rates, as a result of careful control of drilling variables, can approach those achieved with 7 7/8-inch bits. It is concluded that slim-hole drilling is acceptable for development or exploratory work. Imperial also reports on the completion techniques and equipment that have been developed on twenty-seven tubingless 2 1/2-inch casing completions. Indications are that the method is economically desirable where excessive gas or water production is not anticipated.

Jan 1, 1958

By Eduardo Poltronieri Trés, Francisco de Assis Dutra Macedo, Gilvandro Bueno, Anderson Denadai Thomzini

The first industrial applications of roller presses at the comminution were in 1984 in the cement industry. Since then, the equipment has taken more space in the mineral industry. However, many challenges are still present in this equipment, more specifically regarding to ore breakage predictability. The application of this equipment in the pellet feed preparation is fundamental to increase the surface area (blaine index) of the mineral using reduced energy consumption. However, even after several pressing steps, it is still challenging to achieve granulometry in percentages required for the pelletizing process. Currently these levels are reached in wet milling processes, typically carried out in wet ball mills. For the of pellets formation in pelletizing plants, both pelletizing and the firing processes requires finer granulometry. The motivation of this work is to study the pelletizing process, comparing the physical quality of the pellets produced only through comminuted ore in roller press the pellets produced in conventional comminution using circuit with ball mill.

Oct 1, 2019

By N. P. Mabasa, N. Naudé, A. M. Garbers-Craig

An improved methodology is presented for assessing the economic feasibility and effectiveness of recycling MgO-C and Al2O3-MgO-C refractory bricks, which are widely used in the steelmaking industry. Since approximately 28 Mt of refractory bricks are discarded each year, it is logical to recycle them. When furnaces and ladles are relined, the spent refractory bricks become mixed up, and need to be sorted before recycling. This study examined the use of a hand-held X-ray fluorescence analyser (HH-XRF) to distinguish between spent oxide-based and oxide-carbon-based refractory materials, with special emphasis on spent MgO-C (MC) and Al2O3-MgO-C (AMC) bricks. HH-XRF analysis was conducted on 18 oxide-carbon refractory bricks as well as on MgO-chromite and bauxite-based refractories. X-ray diffraction, reflected light optical microscopy, and scanning electron microscopy with energy dispersive spectroscopy were used to characterize the MgO-C and Al2O3-MgO-C bricks to confirm the accuracy of the HH-XRF analyses. This study also underlined the importance of calibrating the HH-XRF analyser for the refractory bricks to be sorted. The HH-XRF was successful in distinguishing between the different oxide-carbon-based refractory bricks both before and after cleaning. This result is important as it proves that HH-XRF provides a method whereby spent MC and AMC bricks can be sorted quickly and reliably.

Jan 26, 2023

By Claudilene Ribeiro Chaves

Nanopartículas de carbono são uma nova classe de nanomateriais fluorescentes que têm atraido bastante interesse por apresentarem alta estabilidade óptica, ajustáveis comprimentos de onda de excitação e emissão além de excelente biocompatibilidade. Neste trabalho, apresentamos um método de síntese de nanopartículas por carbonização hidrotermal de quitosana. O processo de síntese ocorre em solução aquosa, é biocompatível e de baixo custo.

Aug 16, 2017

By Anderson Azevedo Agra

Esse trabalho teve como objetivo avaliar o efeito da adição de diferentes teores de coque verde de petróleo (5, 15 e 30%) nas propriedades termoplásticas de misturas de carvões contendo carvão nacional da camada barro branco. A caracterização termoplástica das misturas foi realizada a partir de testes de plastometria Gieseler e dilatometria Audibert-Arnu. A caracterização dos carvões mostrou que o carvão nacional possui propriedades termoplásticas muito superiores aos demais carvões. Por consequência, verifica-se que a sua introdução nas misturas causa aumento das propriedades termoplásticas nos testes de plastometria e dilatometria. O coque verde de petróleo, em contrapartida, é um aditivo inerte e atua como um depressor das propriedades termoplásticas. Constatou-se que a adição do coque verde de petróleo às misturas causa redução da fluidez, do intervalo plástico e dilatação nos testes realizados. A sinergia entre do carvão nacional de alta fluidez e o caráter inerte do coque de petróleo mostrou-se vantajoso.

Oct 30, 2017

By C. Kathryn Sole

The close proximity of cobalt and nickel on the Periodic Table and their frequent occurrence together in nature means that their separation in primary hydrometallurgical flowsheets is not only often necessary, but requires the use of innovative chemistry to achieve high selectivity. Today, increasingly stringent demands for the high-purity cobalt and nickel salts required for battery applications in consumer electronics, electric vehicles, and solar applications are again challenging the state of the art. The evolution of cobalt–nickel separations is traced from the basic precipitation technologies employed in 1960s, through commissioning of the first cobalt solvent-extraction plant in South Africa in 1974, to the commercialisation of organophosphinic-acid extractants (which provided a step-change improvement in selectivity) and their eventual widespread use in the 1980s and ’90s. This was followed later by their sulphur analogue, which enabled different possibilities for laterite processing in the new millennium. Separations in chloride media, which take advantage of the different speciation chemistries, and nickel extraction by oximes in ammoniacal systems are also discussed. More recently, chelating and solvent-impregnated resins have added further dimensions to the possibilities for flowsheet design and enabled higher purity products to be attained from both primary and secondary sources. Selected case studies and flowsheets are described.