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By Robert J. Timko, Charles D. Taylor, Edward D. Thimons, Tom Mal

A test system was developed for measuring airflow in the National Institute for Occupational Safety and Health (NIOSH) ventilation gallery using a three-axis ultrasonic anemometer. The gallery was used to simulate face airflow conditions in underground mines having a blowing curtain. Airflow data collected at multiple sampling locations between the face and the end of the curtain were used to draw airflow profiles for different curtain setback distances, intake flow quantities and entry widths. In addition, methane was released at the face, measured at the sampling locations, and displayed as methane distribution in the area between the curtain and the face. Entry geometry had a significant effect on airflow patterns, and the flow patterns affected the distribution of methane in the entry. Flow measured at and parallel to the face was a good predictor of methane dilution and removal within two feet of the face.

By k. Osei-Boakye

This paper presents the calibration of a real-time aerosol monitor, the TSI DustTrak?, to the NIOSH 5040 method being used by the Mine Safety and Health Administration (MSHA) for compliance enforcement evaluation. The standard NIOSH 5040 instrument for compliance evaluation of diesel particulate matter (DPM) has an inherent time lag of up to two weeks for laboratory processing of sample results. Therefore, providing the underground mines with a means of quantifying DPM conditions in real-time, will enable them to efficiently and effectively manage DPM levels to ensure compliance with the regulated limit.

Jan 1, 2009

By M. Dhainaut

This paper presents computations of the electric field inside a furnace. We first look at the effect of contact between two coke particles from an electrical point of view. We give values for the amount of contact resistance in the total resistance of the system formed by the two coke particles. We show that the effect of contact resistance decreases rapidly with increasing contact area. We then look at the complete electric field inside a full scale furnace. The aim is to evaluate the amount of current that short-cuts the metal bath for different vertical positions of the electrodes. We show that electrodes high above the metal bath are undesirable since they offer a larger surface of conductive charge materials where current can flow through. On the other hand, deeper electrodes force the current to go the whole way down to the metal bath. Ohmic heating along this path ensures a high temperature of coke and slag that are beneficial for metal recovery.

Jan 1, 2004

By A. Martin

Detailed porewater profiles of arsenic and other interstitial metabolites were used to assess the relationship between trophic status, sediment redox chemistry and arsenic mobility in a historic tailings repository. The results demonstrate that in eutrophied systems which exhibit greater sediment oxygen demand, the depth of the Fe(III) redoxcline, and hence depth of arsenic release, may lie in close proximity to the sediment-water interface. As a result, arsenic scavenging mechanisms are significantly reduced, resulting in a greater flux of arsenic to the water column. Such considerations have important implications for the management of pit lakes, tailings ponds and contaminated lakes which may consider: 1) the discharge of sewage to the water body during operations; and/or 2) post-closure fertilization as a remediation strategy.

Jan 1, 2002

Resistant Tape A new oil-resistant tape for rapid insulation build-up on splices in large power cables has been announced by Minnesota Mining & Mfg. Co. Designated Scotch brand electrical tape No. 25 is made of synthetic rubber providing greater dielectric strength and resistance to high temperatures. The chemical-resistant qualities of the tape make it suitable for use in oil drilling, mining and underground [ ] cable operations, while the 40-mil thickness and extreme stretch (1500 pct breaking point) make possible smooth insulation wraps on irregular surfaces. Dielectric strength is 15,000 v and 10,000 v at 500 pct elongation. It has an electrolytic corrosion factor of 1.0 and an insulation resistance of 100,000 megohms. Circle No. 1 Hydra-Lift The Pitman Mfg. Co. announces that is now has in production a new model of the Pitman hydra-lift, recently-developed crane with hydraulically-powered boom that can be mounted on the frame of any truck, 1 ½ tons or larger. According to the manufacturer, the new model hydralift model B features a variety of improvements over the original production model, introduced late in 1950. Changes incorporated in the new model, according to officials, not only have resulted in improved crane, but also have given the unit a new profile which distinguishes it sharply from the original model. The two chief improvements in the new model are: a big increase in the unit's safety margin and the fact that it is now shipped almost completely preassembled, cutting the time and cost of installation. Rated capacities of the hydra-lift are based on the tipping factor of a 1 1/2 ton truck, with outriggers down, and thus have not been increased. Circle No. 2

Jan 1, 1952

By H. Saroglou

Anisotropy is a characteristic of intact foliated metamorphic rocks (slates, gneisses, phyllites, schists). Testing was used to establish the anisotropic behaviour of selected gneissic rocks. The effect of anisotropy on various mechanical properties (strength, deformation) and dynamic properties (wave velocity) was examined. The rock samples were also tested at successively higher confining pressures in order to evaluate the effect of anisotropic behaviour at high overburden pressures.

Jan 1, 2004

By G. Deschênes

The Eleonore property (James Bay district of Northern Québec), owned by Goldcorp, hosts gold within stockworks of quartz-tourmaline-arsenopyrite veins and veinlets contained within microcline (potassic alteration) and brown tourmaline replacement zones. The preliminary investigation to recover gold from drill core samples showed that flotation followed ultrafine grinding and cyanidation is the preferred option. Ultrafine grinding is used to liberate gold finely disseminated in sulphides. The flotation concentrate used in the investigation had a P80 of 11 microns and contained 75.5 g/t Au, 5.0 g/t Ag, 10.3% S, 0.07% Cu and traces of antimony (0.03%). The mineralogical characterization showed the presence of 65% gangue minerals, 23% pyrrhotite (hexagonal), 9.6% arsenopyrite, 2.2% pyrite and 0.08% chalcopyrite with trace amounts of galena (0.05%) and sphalerite (0.03%). Gold was in the form of native gold and electrum. A straight cyanidation conducted at pH 11.0, DO of 3-5 ppm, 2000 ppm NaCN, 20 C 72 hours extracted 97.0% Au and consumed 31.5 kg/t NaCN. The equilibrium was reached within 24 hours. Increasing the dissolved oxygen to 16 ppm reduced the consumption of cyanide to 22.0 kg/t with 96.7% Au extraction. A 16-h pretreatment with 2.0 kg/t lead nitrate, followed by a 24-h cyanidation reduced the cyanide consumption to 6.0 kg/t with a gold extraction of 97.5%. Increasing the lead nitrate addition to 6.0 kg/t reduced the cyanide consumption to 1.2 kg/t by passivating the surface of pyrrhotite. The gold extraction remained at 97.0%. It was possible to decrease the concentration of cyanide to 800 ppm NaCN without compromising gold extraction. The associated cyanide consumption was 1.2 kg/t NaCN. The passivation of gold grains was an issue when the cyanide concentration was decreased to 550 ppm NaCN. The gold extraction decreased to 92.2%. The average lime addition for all the tests was 7.4 kg/t and the average silver extraction was 80%. Efficient cyanidation of an ultrafine sulphide concentrate with only 800 ppm NaCN represents an advance in leaching of ultrafine sulphide concentrates.

Jan 1, 2013

By Sherwin F. Kelly

Twenty five years of exploration has shown that the "geophysical dollar" is worth $1780 in the Orange Free State, $1488 on the Witwatersrand, $85 in Sweden, $28,000 in the Transvaal and $3500 or more in the U.S.

Jan 6, 1951

By Don Langlois, Udo Weber

"The effect of grinding media performance on milling and operational behaviour was demonstrated under different selected milling conditions of calcium carbonate. A variety of grinding media material and bead sizes, along with 2 different stirrer tip speeds, were used in the grinding process to generate a particle size reduction of the calcium carbonate (CaCO3). To determine the optimum milling parameters the collected test data was used to calculate and evaluate specific energy as well as stress intensity under different milling conditions.INTRODUCTIONAs a result of increasing energy costs and raw material prices it is important to look at the efficiency of the manufacturing process. Wet grinding and ultrafine wet grinding in stirred media mills are now a possible cost-effective production step for the processing of industrial minerals and precious metals. The generation of smaller particle sizes (down to micrometer scale) can be advantageous for further production steps – i.e. better liberation of precious metals or improved industrial mineral qualities.In the following, the wet grinding process is investigated under different milling conditions of calcium carbonate. Different grinding media materials varying in specific weight, bead size and stirrer tip speeds are used to determine optimal energy consumption for the milling process.DESCRIPTION OF TEST CONDITIONS AND PARAMETERSMill ParametersTests were performed in a Drais Laboratory Perl Mill PML H/V with an installed electrical motor power of 3 kW. The mill chamber is silicon carbide where as the stirrer and discs are made of yttria stabilised zirconia. The mill working volume is 0.9 l. A screen cartridge with a screen size of 0.2 mm is used to separate the beads and slurry at the outlet of the mill. All tests were performed with a grinding media filling grade of 80% (Mill working volume). The stirrer tip speed was set at 6 m/s and 10 m/s."

Jan 1, 2009

A research project was commissioned by the Australian Coal Association Research Program (ACARP) to improve the understanding of tailgate strata mechanics and to provide a more rigorous engineering basis for tailgate support design. A deformation mechanism termed æskew roofÆ was defined which relates the regional influence of differential horizontal strata movement (shear) about longwall extraction to gateroads. Confirmation of the mechanism was achieved by field investigations which included measurement of the shear displacement along weak interfaces. Under geological and mining conditions where the skew roof mechanism operated, strata units were found to move progressively further towards the goaf with height into the roof. 3D numerical modelling was used to assess the major geotechnical factors controlling the mechanism and to determine appropriate support strategies within a æskew roofÆ environment including the role of cables versus standing supports. The skew mechanism is considered relevant to; all roadways in the vicinity of longwall extraction including the faceline itself, chain pillar design, and support design.

Jan 1, 2005

By Jarc H

The steeply dipping silver/lead/zinc orebodies at Mount Isa mine have been extracted most recently by a combination of cut-and-fill and open stoping methods. Bench stoping was first used at Mount Isa Mine seven years ago to allow safe extraction of a highly stressed cut-and-fill stope. Subsequent benches have shown that the method offers significant cost and safety benefits through increased productivity and reduction in man exposure. The success of benching has lead to cut-and-fill mining being replaced at Mount Isa.Significant resources have been focussed to optimise benching. This paper describes the operational, planning, and research and development aspects which have contributed to the method to date. A brief look is also taken at the future direction of benching at Mount Isa.

Jan 1, 1992

This sheet explains your audiogram (hearing test) and gives some basic information about protecting your hearing. Keep it so you can refer to it later. What is an audiogram? • An audiogram is often called a “hearing test,” but there’s no pass or fail • It is a written record of your hearing levels • A series of audiograms can track changes in hearing over time • Your hearing threshold levels (the quietest sounds you can hear) are measured in decibels (dB) at different frequencies from low (500 Hz) to high (8000 Hz) Why should I get audiograms? • To measure your hearing ability • To identify hearing problems • To monitor success at maintaining your hearing • To see if noise exposure is affecting your hearing Do I have normal hearing? Compare your hearing threshold levels to this scale: -10 – 25dB Normal hearing 26 – 40 dB Mild loss 41 – 55 dB Moderate loss 56 – 70 dB Moderate/severe loss 71 – 90 dB Severe loss 91 – 100dB Profound loss [ ]

Jan 1, 2008

By Syd S. Peng

University research in the U.S. consists of three components; faculty, funding, and graduate students or postdoctorals. Individual faculty is the unit area of research that is not limited, although faculty normally performs research in their areas of expertise. Faculty can and often do join with other faculty in multidisciplinary research. Faculty research achievements or reputation reflects the standing of the program and university. Therefore, research is highly encouraged and regarded within the university community. Graduate students are the work force of faculty research and doctoral students are preferred for high-quality products. The federal government provides the majority of funding sources, with the remainder coming from industry, state government and others. Compared with other engineering majors, the mining engineering programs in the U.S. are unique in that they: ? Are small in terms of the number of programs, and number of faculty and students in each program. ? Serve a single industry (i.e., mining) and are thus cyclic, reflecting the up and down economic state of the mineral industries. Enrollment statistics during the past 70 years show that a cycle consists of approximately 30 years with the first 10 years up, followed by 20 years down. ? Have curriculum designed to emphasize and thus serve for either the coal, hardrock or industrial minerals industries. These unique features make mining engineering programs hard to manage in university environments. Funding for mining research has relied primarily on the federal government, i.e., the former U.S. Bureau of Mines (USBM) and currently the National Institute for Occupational Safety and Health (NIOSH). The mining industry does not directly perform, nor sponsor research projects. Federal funding provides primarily in-house research. In the last four decades, federal extramural funding was only available when Congress appropriated extra funding in response to mine disasters. For instance, a string of coal mine explosions in the mid to late 1960s prompted Congress to enact the Coal Mine Health and Safety Act of 1969. It provided massive research funding from 1970 to 1983 covering all mining-related subject areas. From 1984 to 1995, federal extramural research funding was minimal, through two generic mineral technology research centers for selected mining engineering programs. In 1995, Congress closed the USBM and transferred the health and safety of miners program to NIOSH. Federally-funded extra-mural research practically stopped from 1995 to 2006. In 2006 and 2007, in response to a series of disasters, including those at Sago, Aracoma, Darby and Crandall Canyon, Congress again appropriated funding for short-term re-search in selected subjected areas such as underground tracking and communication, mine seal and ventilation, and deep cover pillar extraction. Therefore, to develop a meaningful academic mining research program during the past three decades, funding needed to be drawn from other sources such as the mining industries. A ?meaningful? program requires a sufficient amount of consistent funding in order to produce effective results. A review of federally funded extramural research pro-grams shows that a great majority of contractors/grantees are private entities, involving few mining engineering faculty. This, in part, is due to the fact that mining engineering involves so many different subjects. Therefore, a small mining engineering program can only have resources to cover teaching in the core subject areas (i.e., extraction, ground control, ventilation and material handling), at best. In this respect, a successful and meaningful academic mining re-search effort requires strong supporting programs such as geology/geophysics, structural (applied) mechanics, material sciences, compute/software application, etc. Therefore, academic mining research had to rely on private sources such as coal companies, in the author?s case, for sustained funding in the past three decades. Relying on funding from coal companies presents several problems. The projects were small and considered routine consulting projects requiring practical answers in a very short time frame. This is not really suitable for academic research, for which the major goal of research is the training of graduate students. These short-term projects vary with time and mines, most of which are driven by U.S. Mine Safety and Health Administration (MSHA) or U.S. Office of Surface Mining (OSM) regulations. So sustained funding under such condition requires broad experience of coal mining operations, which is also not well-aligned for academic research where faculty tends to specialize in a narrow field. Consequently, under such a funding environment, it is important to keep in mind how to develop long-term academic research objectives from conducting small short-term consulting projects that require quick solutions. In other words, how to look beyond the quick answers and to develop broader and more fundamental theories applicable to other situations that advance the-state-of-the-art. In order to achieve this objective, faculty must act as the connecting link because graduate students come and go. Faculty must know the detail of each project such that they know what are the important unsolved problems, what to assign to specific graduate students and how to guide the next group of graduate students to continue the development and advance the mining science. Under such funding environments, the most effective way to conduct academic mining research and ensure quality products is to maintain a research group consisting of postdoctoral, PhD, and MS students of various rankings such that the senior ranks can assist in guiding the junior ranks, especially the senior PhD students who are experts in their dissertation research areas. A weekly meeting should be scheduled for the group in which problems encountered in the research are discussed or individuals take turns presenting the progress of their projects. During each meeting, the importance of open discussion on scientific issues must be emphasized. Thus, opinions are encouraged, debated, and rejected or accepted. Students are encouraged to listen to and analyze other points of view. In addition to training of this thought process, the meeting also helps identify the strengths and weakness of each individual. As the subject of research expands over time, the group?s and, thus, the faculty?s research experience broadens. With this approach, companies can get the quick answer they desire from expert research experience and the faculty can engage in meaningful applied and basic research that is most relevant to routine mine operations. The end result is that companies will have a high regard for academic mining research.

Jan 1, 2009

By Nuno Cruz, Saúl Rodríguez

"When executing offshore bored piles there are several specific factors and problems to consider in order to guarantee excavation stability. One of the methods employed to carry out this type of work consists in setting up a floating work platform, typically a barge, and implementing a soil stabilization system that combines a partial steel guiding casing with third generation polymeric drilling fluids. The main aspects to take into consideration when performing offshore pile boring works are soil stabilization, project design, work methodology and operational aspects. An example of a work methodology problem arises before any pile boring work takes place as the steel guiding casing contains water, sometimes salt water. What to do with this water in order to replace it by an adequate polymer fluid will determine the stabilization capacity as soon as the shaft advances below the protection of the casing. Another example of operational problem may derive from barge movements while executing boring activities. This study is the result of extensive field data collection and concrete logging analysis from marine projects using polymers in different continents. The bored pile stability target was set ranging between 2% to 15% of concrete overbreak. Values above 15% or below 2% mean that there is a stability problem. Then the off-target pile’s data is collected, analyzed and classified under categories. Thus, a direct correlation is established between the problem category and the final results. Modifying steps in the pre-established construction methods or operational variables guarantees target results without the need to replace the approved construction methods. As a general conclusion, the worldwide experience in large diameter marine works, allows to provide truthful information and solutions for these problems. In knowing how to follow a logical sequence of work and applying adequate work methodology will be the key for success.GENERALBackgroundTo carry out the drilling process of offshore bored piles there are two main options to take into consideration: drilling the pile by using full guiding casing until final depth; or using a combined system of partial steel guiding casing and support drilling fluids.The knowledge and situations described in this paper come from the experience acquired in different projects where the second method was employed. This construction method consists in installing a steel guiding casing by vibration and thus covering the water table and further stabilizing the soil below it with polymeric fluids until reaching the pile’s final depth. The Fig. 1 schematic shows an example of this method where H corresponds to the length of the steel guiding casing whereas the remainder of the shaft’s length is stabilized by polymer fluid. The entire bored length is full of slurry up to top of casing.In most cases this kind of civil works results from the need to build a bridge or executing port structures in places where the creation of temporary artificial peninsulas with fill material is impracticable or not allowed. Hence the need to use floating work platforms, commonly referred to as barges."

Jan 1, 2017

By L. Mukka

The existing main mine ventilation system for the production areas to the Kiruna mine was constructed during the period 1994-1996 and extended with 4 more shafts, including fan stations, for the sea ore body from 1997-1998. Two papers have been presented from this project at the 7th US Mine Ventilation Symposium in 1995 and at The 6th International Mine Ventilation Congress in 1997. In 2005, pre-studies for a new main haulage level were started. Different haulage methods were presented including ventilation systems. The pre-studies showed that the existing ventilation system, including fan stations for the new main haulage system in the production area, could be extended. However, a new system for the central area, which was not in the initial investment program, would be needed. In the beginning of 2006, a decision was made to design a new ventilation system for the central area to make it possible to get air to the development work for the new main haulage system, independent of the haulage method. This system was operational by the beginning of 2007. The new main haulage system, which was decided to be located on level 1365 m, only requires that the existing shafts be extended - the capacity of the fans seems to be enough. However, the problem is that the existing level 1045 m and the new level 1365 m have to be in operation in parallel for approximately 7-8 years. The challenge for the moment is determining how to ventilate the production areas for both levels at the same time, while simultaneously constructing the extended system. This paper will describe the problems associated with the extension of the main ventilation system and some potential solutions for these problems. The new main haulage level 1365 m must be in operation by 2012.

Jan 1, 2009

By Serhan Guner, Sundar Chiluwal

Although significant research has been conducted on helical piles, there is a lack of research and official design provisions on the helical pile-to-pile cap connections. These connections may govern the global response of pile cap systems—especially in tall and light structures where uplift forces dominate the response. To improve future industry practice, the objective of this study is to understand the influence of pile-to-pile cap connections on the global behavior of concrete pile caps and develop recommendations for their efficient design. For this purpose, 108 high- fidelity nonlinear finite element simulations are conducted to quantify the influences of bracket type, embedment depths, longitudinal reinforcement percentages, shear span-to-depth ratios, and loading conditions on the load, deformation, cracking, and failure behavior of concrete pile caps. The results indicate that the design configurations involving single bracket type may result in premature concrete cracking around the anchorage zones with a 25% reduction in the uplift load capacity. The investigations also confirm that high reinforcement percentages and low shear span-to-depth ratios result in higher load resistance in all bracket types, and that the load capacities of the double and studded bracket types are similar. For applications requiring the use of lower embedment depths, it is recommended that either double or studded bracket types be used. The research findings have applicability to both helical and micro piles given that both include similar connection types. INTRODUCTION Tall and light structures may experience significant uplift forces at their foundations due to large overturning moments from wind or other lateral loads. Helical piles (e.g., Fig. 1a) can provide a cost- effective, practical, and resilient solution for resisting significant uplift forces. In order to realize the full potential of helical piles, it is imperative that the helical pile-to-pile cap connections (see Figs. 1b, c and d for examples) are properly designed to resist the applied forces. However, there is a lack of research and associated knowledge on the influence of pile-to-pile cap connection detailing on the global response of pile caps.

Jan 1, 2019

By ?. ?. Zimin, B. A. Kutlin, X. Baddamsuren

"The ore features of Mongolian fluorspar deposits are shown in the paper. The possibilities of the technological of ore processing on the Bor-Undur combine scheme improvement are analyzed there. Some recommendations are done for scheme development: spare output technologies, the usage large-sized ore separation, flotation by columnar flotation cells, leaching and concentrate agglomeration.New evaluation and usage of mineral sources approach was developed for Mongolian fluoride ores. The conception allows using maximally available mineral resources for getting of metallurgical and acid fluoride concentrates while mining and technological processes: mining (as well as quarrying) -storing, blending-crushing, grinding-combined processing methods-metallurgical using preparation It has been established mining and processing technological schemes should include:• spare blasting technologies providing minimum effect on fluorite crystals which follows ore selective excavation;• large-sized ore separation methods resulted in maximum recovery for these operations in respect to metallurgical fluorite concentrates;• grinding and flotation regimes providing high-quality flotation concentrates getting for their usein chemical industry;• fluorite concentrates agglomeration technologies for providing ability of their use in metallurgical and cement industriesThe results of industrial usage of jugging machines, columnar and pneumomechanical flotation machines for fluospar dressing.The technological approaches implementation in “Bor-Undur” plant maintenance within 1993-2002 years leaded to:• change plant status from just flotation one to gravitational-flotation characterized by technological process stages which are traditional for metallurgical industry and plant capacity increase from 400 to 600 thousand tones of treatment ore as well as concentrate production increase from 120 to 150-170 thousand tones including 120-140 thousand tones of acid grade concentrates with 97% CaF2 ."

Jan 1, 2003

Escalating energy and electricity costs have become one of the largest drivers of expenditure in mining operations. Over the last eight years, energy costs have tripled when expressed as a percentage of total expenses in South African mines. In an effort to manage and reduce electricity costs, energy management strategies can be developed, inefficient operating units replaced, and the operation of energy-consuming components of ventilation systems optimized. Power consumption on mines is controlled mainly by three strategies, namely load clipping, by which energy use is reduced for certain parts of the day; load shifting, by which energy use is shifted to other parts of the day; and energy efficiency, by which energy use is reduced permanently. In this paper several projects that were implemented using the first two strategies of load clipping and load shifting are investigated. The actual and potential savings that can be achieved by implementing such energysaving interventions are presented. To reduce the operating costs of ventilating and cooling underground mines permanently, system optimization studies must be completed. Methods that can be used to reduce energy usage by optimizing cooling and ventilation systems are described, and network simulation models that accurately reflect the current and planned ventilation conditions are discussed. These models are then used to examine various options for improving the overall ventilation and cooling strategy. Different optimization scenarios can be simulated, and this assists the design engineer in obtaining the most energy-efficient system that will satisfy design workplace conditions. The final outcome is a reduction in operating costs, which can result in better operating margins and an extension of the life of mine.

Jan 1, 2014

Milling circuits are known to be difficult to control. In order to address these difficulties, it was decided to develop and test a model predictive controller (MPC) for a milling circuit. A milling simulator was written using Microsoft Visual C++ and used to design and test the MPC controller. Due to the large number of tuning parameters in a controller of this type, an optimizing algorithm was written that automatically tunes the controller. Good, robust control was obtained when the controller was tuned using this algorithm. Control was further improved by combining feedback and feed forward control and by using quadratic programming in the MPC algorithm. The movement of the manipulated variables was reduced by using a novel technique that allows the controlled variable to vary within a specified region around the set point. An optimiser controller was also successfully implemented to control the circuit at its maximum throughput.

Jan 1, 2000

By Stephen J. Roberts

Gold catalysts were prepared on co-precipitated, calcined copper oxide - zinc oxide support by an inverse deposition-precipitation method. These catalysts were characterised by X-ray diffraction (XRD) and temperature-programmed reduction (TPR) and studied for CO oxidation activity at various catalyst calcination temperatures. TPR studies of the support material exhibited a double peak and shift to lower temperatures for the reduction of Cux+ to metallic copper, as opposed to the single reduction peak for pure CuO. This phenomenon is possibly caused by an interaction with the zinc oxide. The addition of gold to the support CuOZnO led to a further shift in copper reducibility to lower temperatures. Gold present in the initial uncalcined catalyst as Au3+ was auto-reduced to Au0 under various calcination temperatures. The Au3+ reduction peak was observed to shift to lower temperatures with increasing calcination temperature. The catalytic activity was found to pass through a minimum value with respect to calcination temperature. Catalysts with both gold in entirely the 3+ or metallic oxidation state were found to exhibit high activity. Furthermore, the catalysts were found to decrease in activity with decreasing Au3+ content up to an intermediate calcination temperature, afterwhich the activity increased sharply. Possibly at higher temperatures, a stronger Au-support interaction is formed, leading to a new active site.

Oct 1, 2003