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By B. Y. Wong

In April 1989, Southern Company Services signed a 3.5 year contract with DOE-PETC for generic engineering development of an advanced physical fine coal cleaning technology known as selective agglomeration. This technology offers the potential for significantly higher pyritic sulfur removal (90% +) than conventional coal cleaning (30 to 50%) while maintaining high Btu recovery (90% +). Engineering development will include bench-scale process development; component development; adaption or modification of existing unit operations; proof-of-concept (POC) module design, fabrication, testing and evaluation; and small commercial facility conceptual design. The information obtained during POC operation will be sufficient to result in a technical and economic design base that can support construction and operation of a small commercial plant. The major goal of the research is to develop selective agglomeration technology to achieve 90% pyritic sulfur removal while operating at Btu recoveries above 90% based on run-of-mine quality coal. This objective will be accomplished in two phases: Phase 1 -bench-scale and component development, and Phase 2 -POC module operation and conceptual design of a small commercial plant. Currently, work is proceeding under Phase 1 (Tasks 1-7) of the project. A review of the status of Tasks 1-7 is presented in this paper.

Jan 1, 1991

By K. Boakye, T. Newman, P. Bláha, M. B. Toelle

"This paper presents a quarry optimization plan using a block model and an in-house development quarry scheduling and optimization software (QSO Expert) to help improve quarry operations at Crystal River. The Crystal River Quarry is an underwater quarrying operation that barges limestone via the Gulf of Mexico, as the main source of raw material to a cement plant in Theodore, Alabama. To improve the quarry operation, an evaluation was completed to optimize the quarry planning and extraction procedures of the quarry. In order to achieve this, additional exploration drilling campaign was implemented, a new block model was re-calculated and the latest version of QSO Expert software was used. The primary economic impact is a higher recovery of limestone reserves; sustainability of resources, corresponding longer quarry life. Secondarily as the limestone is mined underwater and stockpiled above water, drainage reduces moisture content achieving direct cost reduction on limestone shipping. In addition, a considerable reduction in operational cost was achieved due to a significant decrease in consumption of electrical energy, reduced dragline maintenance costs and reduced dragline movements within the operation. INTRODUCTION Holcim is a Swiss-based global building materials and aggregates company. Founded in 1912, the company expanded into France and then throughout Europe and Middle East during the 1920s. In 1922, Holderbank, as the company was then known, expanded beyond the Swiss borders into France. By the end of the decade Holderbank held stakes in Belgium, Germany, the Netherlands, and Egypt (Holcim History 1912-2012) Positions in Lebanon and South Africa soon followed.. Holder bank later expanded in North America in the 1950’s. In the late 1970s and early 1980s, Holderbank continued its expansion in Latin America, Asia and Spain for the first time. The company expanded into Eastern Europe and experienced a boom in Spanish construction preceding the 1992 Summer Olympics. By 1986, Holderbank was the world's largest cement manufacturer. In the 1990s, the company consolidated its European holdings as the American market drove growth. Expansion into Eastern Europe and Russia continued (Holcim History 1912-2012). In 2001, the company changed its name from ""Holderbank Financière Glaris"" to Holcim (short for Holderbank ciment) (Holcim History 1912-2012). Holcim expanded by purchasing Aggregate Industries entering into the United Kingdom for the first time. That year, the company also expanded into India by acquiring a stakes in The Associated Cement Companies (ACC) and Ambuja Cement Eastern. In 2008, Holcim became the largest shareholder of China's Huaxin Cement with a 40% stake. In 2009, they acquired Cemex Australia. In 2014, Holcim and Lafarge announced they had agreed to terms on a ""merger of equals"" valued at nearly $50 billion in 2015. The new company LafargeHolcim based in Switzerland has a manufacturing capacity of 427 metric million tons a year."

Jan 1, 2017

By J. F. Snyder

Minor elements determined by atomic absorption spectroscopy include: zinc, cadmium, copper, cobalt, nickel, chromium, manganese, and iron. Of these elements, only three; zinc, cadmium, and copper are found to have been introduced with the ore-forming fluids. Iron, manganese, chromium, and nickel were increased in dolo-stone lithologies when compared to limestone lithologies. The uniform distribution of cobalt suggests this element was neither increased nor decreased during ore emplacement nor during dolomitization of the rocks. Zinc increases adjacent to ore result from leakages into open spaces rather than as pervasive aureoles surrounding ore bodies.

Jan 1, 1977

By Hasan Nizamoğlu, M. Deniz Turan, MÜCEVHER TURAN, RAMAZAN ORHAN

Tailings (flotation waste) that is formed during copper production may be considered in the class of valuable wastes due to the amount of copper it contains. Owing to the decreasing grade values in copper ores, utilization of wastes such as tailings that carry certain amounts of copper as secondary sources has become a necessity in both the economic and environmental sense. This study investigated the usage conditions of five different ammonia salts as leaching reactants for the purpose of selective extraction of copper from tailings. For this purpose, the effects of parameters such as leaching temperature and leaching time were examined at different concentrations of ammonium hydroxide, ammonium carbonate, ammonium nitrate, ammonium chloride, and ammonium persulfate. The copper extraction efficiency in the case of using the aforementioned salts by themselves were listed as (NH4)2CO3 (73%) > (NH4)2S2O8 (69%) > NH4OH (64%) > NH4Cl (42%) > NH4NO3 (40%). The highest copper extraction efficiency was obtained in the leaching process that was conducted with the solutions obtained by mixing ammonia salts in the best conditions. Accordingly, as a result of 6 h of leaching at 30 °C in the presence of 22.5% NH4OH and 100 g/L (NH4)2S2O8, 91.47%of the copper was transferred into the

Jun 3, 2020

By R. F. Korcak

There exists a wide array of industrial by-products that can be shown to produce beneficial responses in the soil/plant environment. These materials range from clean coal technology residues produced in the generation of electric power, particularly those high in gypsum, to mineral 'fines' produced by the aggregates and crushed stone industries. A number of these materials will be examined in relation to potential nutritional interactions in soils and crops with emphasis on trace elements. The significance of utilizing these materials in agriculture as a component of sustainable agricultural systems will be discussed.

Jan 1, 1995

By John M. Gullbert

It is the task of this portion of today's session on the new meaning of regional tectonics in the search for ore districts to discuss known interactions of tectonics and ore deposition in the 'new global tectonics' context. I will speak particularly about known applications of the recent tectonic advances to ore finding. Stated yet another way, it's getting on in time toward the "put up or shut up" stage-¬and I would not be here if I thought that the new tectonics were not an effective present matrix for ore finding. Before delving into specific geologic relationships--and I propose to discuss mainly the evolution of an idea which may reveal the presence of a major copper deposit on mainland Mexico--I must note that there have been no published accounts that I know of which assert that a particular discovery has been made soley and specifically because of an interpretation based upon mechanisms directly linked to sea floor spreading or plate tectonics. It is nonetheless true" that several major exploration efforts are based upon such interpretations, and, as is normal when exploration ideas are involved, one does not wish to call attention to an advantageous position in a highly competitive business. Little might be expected to have been announced in so fast-moving and potentially lucrative an area. Another point which needs to be made is that people such as B. S. Butler (1933), Billingsley and Locke (1935 and 1941), Harrison Schmitt (1935), and more recently Mayo (1958) have been working for decades with the tectonic expressions of the emergent tectonics without recog¬nition of the driving forces or the unifying tectonic concepts

Jan 1, 1971

By J. Drelich

The adsorption of oleate at the surface of titanium dioxide from aqueous solutions was examined by Fourier transform infrared (FT -IR.) spectroscopy using a germanium internal reflection element coated with a thin film of TiO2. This thin film, with a thickness of 100-200 A, was deposited on the surface of a germanium single crystal by RFIDC magnetron reactive sputtering. It was found that significant adsorption of oleate from a 0.02-0.03 mM aqueous solution on the surface of TiO2 thin film occurs at neutral pH, from about pH=5.5 to pH=7.7. Adsorption of oleate at the surface of the amorphous TiO2 thin film appeared to be reversible, involving soap-acid dimers.

Jan 1, 1997

By J. E. Kulas

Red Dog is a Mississippian to Permian aged sulfide deposit located in the western Brooks Range north of Kotzebue, Alaska. It belongs in the family of black Shale hosted sedimentary exhalite deposits but lacks classic sulfide sedimentary textures. Pervasive silicification, and a significant portion of the mineralization, is replacement in nature. An extensive feeder vein system cuts the footwall and the exhalite package. A Jurassic to cretaceous age compressional event has repeated the ore section through thrust faulting and folding. The orebody contains 77,000,000 metric tons averaging 17.1% Zn, 5.0% Pb and 82 g per metric ton of Ag. Weathering has locally altered the sulfides to sulfates and formed elemental sulfur.

Jan 1, 1992

By B. E. Davis

A problem that has continued to plague the Florida phosphate industry is the loss of coarse phosphate in the flotation circuit. Attempts to remedy this problem such as floating the coarse material (plus 425 µ m) in a separate circuit have resulted in limited success, but recovery is still not optimum. The Bureau of Mines is investigating ways to improve the recovery of coarse phosphate through improvements in the conditioning step. Studies to optimize conditioning parameters such as agitation energy, conditioning time, conditioner solids, and residual clay content have resulted in improved P2O5 recovery. Optimizing these and other conditioning parameters resulted in a rougher concentrate grading 30 pct P2O5 with a P2O5 recovery of 97 pct.

Jan 1, 1993

By T. W. Meikle

Three nutrient amendments and a biological seed inoculant were evaluated for use in establishing vegetative cover on waste rock substrates. Randomized blocks were placed on three substrates. Treatments included two types of organic fertilizer, mineral fertilizer, Azospirillum bacterial inoculant, plus controls. The seed mix consisted of native grass species adapted to low nutrient conditions. Canopy cover has been monitored for three growing seasons. Results indicate: 1) two of three substrates support plant growth following amendment with organic fertilizers; 2) organic fertilizers increase cover substantially over mineral fertilizer; and 3) Azospirillum had no effect on canopy cover.

Jan 1, 1999

By S. S. Peng

A well designed mining plan is one which minimizes the cost and the mining induced problems and maximizes the recovery of the coal reserve. In order to minimize the negative effects on surface structures caused by ground subsidence process due to underground mining activities, two kinds of practices are commonly employed by the mine operators. One is the support techniques which leaves an area of coal un-mined or partially mined beneath the structure to be supported. The other is the protection techniques which protect the structure when it is subsiding with ground taking advantage of the ground subsidence process (Luo et al., 1992). In designing the supporting techniques, the only currently available method in the U.S. is the one stated in the Pennsylvania Underground Coal Mining Rules (1985). However; The size of the support area designed by this method will be excessively large resulting in wasteful use of coal reserve when the overburden depth is more than 350 ft. A more scientific method is proposed in this paper for de-signing the support area. This method is based on a large amount of subsidence data collected throughout a number of major U.S. coal fields and the authors' experience with monitoring and protecting surface structures undermined by longwall panels. It considers the critical deformation in-dices that a structure can tolerate, and depth and height of underground extraction. The support area designed by this new method will not only assure the safety of the structure to be supported but also maximize the extraction of the coal reserve.

Jan 1, 1993

By B. Zane Egan

The Calsinter process for recovery from fly ash involves sintering the fly ash with calcium sulfate and calcium carbonate at 1200°C, followed by a dilute sulfuric acid leach step. Flue gas desulfurization sludge containing calcium sulfite, calcium sulfate, and unreacted calcium carbonate may be substituted for the calcium sulfate and calcium carbonate. Conversion of aluminum in fly ash by the sintering process to an acid-leachable species was measured as a function of sintering time and temperature in the range of 800°-1200°C The sinter-leach steps were investigated using thermogravimetric analysis, x-ray diffraction, scanning electron microscopy, and elemental analysis. SEM photographs indicated that the glassy spheroids in the original fly ash were converted to a crystalline structure by the sintering reaction.

Jan 1, 1980

By T. McCallum, C. Cooper, B. Hutzler

"In copper solvent extraction, managing the quality of the organic phase is a key parameter to ensure optimal physical and metallurgical performance in the plant. Increased throughput as a result of declining ore grades coupled with advances in plant design and practice, resulting in reduced organic losses, has pushed the limits of the status quo with respect to organic quality. Clay treatment of plant and recovered organic at the optimal dosage is critical in maintaining quality, however, achieving the optimal dosage through existing filtration capacity and practice can be difficult. Cytec has developed a process aid that increases efficiency of existing filtration equipment that has been successfully implemented at two commercial SX operations. ACORGA® CB1000 enables higher dosages of clay while allowing for more efficient use of existing filtration capacity. This study analyzes results from commercial trials and demonstrates that improved organic quality and clarity is achievable through optimization of current treatment practices. INTRODUCTION Decreasing ore grades have prompted copper solvent extraction operations to raise PLS flow rates, increasing plant throughput to maintain production1. The ability to process higher flow rates through existing mixer-settlers historically came at the expense of increased entrainments2. However, advances in mixer-settler design, practices and improvements in organic recovery processes have enabled operations to maintain, and in some cases reduce organic losses while achieving higher flow rates through existing equipment. Based on the increased demand on the SX equipment and reduced losses (or more efficient recovery) maintenance of the circuit organic quality through efficient clay treatment is now more important than ever. This paper discusses common industry practices and related issues in organic clay treatment, and presents benefits achieved in commercial operations through the use of ACORGA® CB1000 Clay Binder. IMPROVEMENTS IN DESIGN AND PLANT PRACTICE Mixer-settler design has improved since the first commercial copper SX operation in the late 1960s. Advanced designs in mixer, settler, and settler internals have contributed to reductions in entrainments. For example, improved impeller designs have been reported to decrease organic in aqueous entrainment from the ‘old designs’ of 50-200 ppm3 to as low as 4 – 10 ppm confirmed via diluent and reagent consumptions . Similarly, operations are reporting a 20-50% decrease in reagent consumption when compared to the original design criteria3. Operations have optimized settler internals to increase coalescence and have improved settler operating practices which have been shown to reduce entrainments7. Comparison of the SX world operating data from 1999 and 2007 shows reductions in organic entrainment losses with increases in flow rates."

Jan 1, 2015

By N. Merriam

This report describes Koppelman's work to develop the K-Fuel® Series C Process used to dry and stabilize Powder River Basin coal. It also contains summaries of the results of bench-scale and pilot plant tests conducted to prove the Series C Process. The process is being used by the KFx-Thermo Ecotek partnership for a 500,000 ton per year commercial plant that has been constructed near Gillette, Wyoming. The plant is presently undergoing shakedown.

Jan 1, 1997

By R. L. Stone

By means of laboratory balling tests and a procedure for determining bentonite concentration in a green ball the present study revealed that the bentonite savings by mulling concentrate and bentonite prior to balling was sufficient to warrant installation of a full-size unit in a pellet plant. On the basis of this work, a muller was put on stream at Bethlehem Steel Corporation's Cornwall pellet plant in June 1969, and has operated continuously since then. Plant tests showed that the use of the muller resulted in bentonite savings of about -502 without any loss of green, dry, and fired ball quality. Virtually no maintenance problems have been encountered. This information is important to future pelletizing operations both from the standpoint of product quality and economics.

Jan 1, 1971

By Ihsan Berk Tulu, Mustafa Can Suner

The synthetic rock mass (SRM) approach and discrete fracture network (DFN) model, generated from the field surveys, are novel methodologies to study fracture rock mass behavior. In this paper, SRM and DFN methodologies were used to understand the influence of natural fractures on the mechanical response and failure mechanisms of stone mine pillars. First, a multi-stage up-scaling procedure with the homogenization process is established. Later, a stochastic sampling process on the SRM model to have further insight on the stone mine pillar mechanics is performed. Two-dimensional Universal Distinct Element Code (UDEC) is utilized to represent intact rock with the Voronoi-Trigon discretized blocks and to capture fractured rock mass behavior. The laboratory-size limestone mine rock specimens are systematically up-scaled to the average width of the field-size stone mine pillars. Then, the DFN model, generated from field data, is sampled to construct the SRM of the field-size pillars. By doing so, the effect of discrete discontinuities on pillar stability is studied by assessing the pillar strengths and failure mechanisms in various width-to-height ratios.

Jul 8, 2022

By Y. C. Guan

The cementation of gold on to copper and zinc in ammoniacal solutions has been studied using rotating disc electrodes. The cathodic reduction of aurous ammine was studied on a gold rotating disc electrode and the anodic dissolution of copper and zinc was studied in the absence of aurous ammine. The cementation rate was found to be a first order with respect to the concentration of aurous ammine and to be proportional to the square root of the disc rotating speed. Based on the results obtained, it was concluded that the cementation reaction was controlled by mass transfer of aurous ammine to the reaction surface under the experimental conditions.

Jan 1, 1995

By Michael J. Friedel

The permeability and flow capacity in unsaturated media is investigated by the Bureau of Mines for application to in situ copper leach mining at the Cyprus Casa Grande mine site. Moisture retention properties are derived and combined with scanning electron microprobe data to characterize the mineralogy, texture, pore size, distribution, and permeability of the host rock. Finite element modeling is used to derive a saturated permeability, ambient degree of saturation, and assess various injection-recovery schemes. Recommended design modifications for optimization of solution distribution and maximum recovery from the rock matrix requires either (1) the injection pressures on the order of 1500 psi and recovery wells operating in a suction mode, or (2) performing permeability enhancement, through rubblization. By producing a maximum block diameter of 4 m, injection pressures can be reduced to 500 psi with improved recovery and containment of solutions.

Jan 1, 1991

By M. Misra

The dielectric properties and flotability of different ranks of Argonne Premium Coal samples are presented. The flotability of different ranks of coal are correlated with the dielectric properties and intrinsic moisture (or bound water) content. Measured dielectric properties of as-received coals and other constituents are incorporated into a mixture equation to calculate the dielectric properties of bound water present in the different ranks of coal. The nature of bound water present in low-rank hydrophilic coals is significantly different from that present in high-rank hydrophobic coals. The water molecules present in low-rank lignite have an oriented dipole-dipole interaction and are tightly bound to the surface. For high-rank coals, the water molecules are not bound to the surface and have a randomly distributed clathrate ice-like structure. Controlled thermal treatment can modify the structural nature of bound water present in low-rank hydrophilic coals and increase their flotability.

Jan 1, 1990

By G. L. Brooke

At present, there are two known cobalt deposits in the 48 contiguous states. This paper is a brief description of one of these deposits. It is a Mississippi Valley type deposit, but somewhat atypical in that the metal of greater interest is cobalt as opposed to lead, zinc, and copper. The history and present work are outlined along with a discussion of the geology and mineralogy.

Jan 1, 1981