Search Documents

By B. H. Johnston, B. N. Doyle

Introduction In 1983-84 Kidd Creek Mines Ltd. in Timmins, Ontario, started up the second commercial zinc pressure leaching plant based on the Sherritt Gordon Mines Ltd. direct pressure leach process. The first plant using this process was that of Cominco Ltd. at Trail, B.C. (Parker, 1981; Martin and Jankola, 1985). The Kidd Creek plant was constructed to take advantage of the extra capacity that the existing purification, cell house, and casting sections had in comparison to the roasters and acid plant. In addition, pressure leaching offered flexibility in other areas such as treatment of low grade concentrates. The process design package and the detailed design of the autoclave system was carried out by Sherritt. The detailed design for the rest of the plant was done by Cambrian Engineering Ltd. under the direction of Kidd Creek. The construction and commissioning of the plant has been described earlier (Johnston, 1983). This paper describes, briefly, the application of the direct pressure leaching process for zinc concentrates and the integration of the pressure leaching plant into the main zinc plant at Timmins. It discusses some of the startup problems and changes made to the plant. The damage following a fire inside the autoclave is also described. The subsequent repair and recommissioning of the autoclave has enabled Kidd Creek to demonstrate the originally sought advantages of pressure leaching and to take advantage of their extra cell house and casting capacity to produce more zinc. Process principles The development of the direct pressure sulphuric acid leach of zinc sulphide concentrate at temperatures above the melting point of sulphur and at elevated oxygen pressure has been described in detail in a number of papers (Martin and Jankola, 1985; Johnston, 1983; Veltman and Bolton, 1980; Kawulka et al., 1975; Veltman et al., 1977). The most significant aspect of the process is that sulphidic sulphur is converted to elemental sulphur in reactions that can be simply described as follows. ZnS + H2SO4 + 1/2 O2 ZnSO4 + S° + H2O (1) FeS + H2SO4 + 1/2 O2 FeSO4 + S° + H2O (2) The rates of these reactions increase with temperature. However, at temperatures above the melting point of sulphur, 12°C, the presence of a surface active agent is necessary to prevent the occlusion of the sulphide particles by elemental sulphur and the consequent termination of the leach. The zinc that is dissolved according to reaction (1), after purification of the zinc sulphate solution, is recovered by electrowinning. The iron that is put into solution according to reaction (2) is further oxidized to the ferric state and subsequently, as the acidity decreases, precipitates as hematite or as complex basic sulphates. MINERALS AND METALLURGICAL PROCESSING Examples of this are shown below. 2FeSO4 + H2SO4 +1/2O2 - Fe2(SO4)3 + H2O (3) Fe2(SO4)3 + 6H2O - Fe2O3.3H2O + 3H2SO4 (4) 3Fe2(SO4)3 + 14H2O - 2(H3O)Fe3(SO4)2(OH)6 + 5H2SO4 (5) (hydronium jarosite) The conventional zinc process involves concentrate roasting to produce zinc oxide and sulphur dioxide. The zinc oxide is leached in spent electrolyte and the sulphur dioxide is converted to sulphuric acid. The pressure leaching process can, therefore, be used to replace conventional concentrate roasting, sulphuric acid manufacture, and atmospheric leaching with one unit operation. Integration of pressure leaching into the Kidd Creek flowsheet A block flowsheet of the Kidd Creek zinc plant, with the new pressure leach plant integrated, is shown in Fig. 1. The original plant, which was constructed in 1972, is based on standard electrolytic zinc plant technology. Concentrates are dead roasted to remove sulphur. Sulphur dioxide is treated to produce sulphuric acid. Calcine is leached in two stages using cell-house electrolyte. Iron is precipitated as jarosite and solutions are purified to remove copper, cobalt, nickel, and cadmium to provide feed for a partially mechanized cell house. Zinc is plated from solution, and the resulting cathode is melted, cast, and sold (Johnston, 1983). The integration of the pressure leaching plant into the main zinc plant is relatively simple. As shown in Fig. 1, a fraction of the zinc concentrate and spent electrolyte are fed to the pressure leach autoclave, while part of the calcine from the roaster is used as a neutralizing agent in the oxidation step along with. the jarosite leach solution. The main exit stream from the pressure leaching plant is the slurry discharged from the oxidation step, consisting of neutral zinc sulphate solution, unreacted calcine, and precipitated iron oxides. This slurry is transferred to the neutral leach step in the main zinc plant. The leach residue from the pressure leaching step, consisting of basic iron sulphate and elemental sulphur, is washed and impounded along with the jarosite residue produced in the main plant.

Jan 1, 1987

By N. Arbiter

During the first four decades of flotation practice, close to 200 machine designs were patented, although only about a score were ever used commercially. By the end of that period, the rigors of use had resulted in obsolescence of most pneumatic cells, with a few mechanical cells dominating the field. After World War II, newer designs began to appear but most were modifications in varying degrees of older designs with special features added. Of the dozen or so most recent developments, almost all are pneumatic, relying on compressed air instead of impellers for motive power, although in several cases pumps supplement compressors. Table 1 lists a few of the more fully documented new cells, with their significant characteristics, along with similar characteristics of a widely used mechanical cell. New designs in general are emphasizing: bubble size control; in several cases, methods for delivering feed directly to the froth; methods for introducing and dispersing air through nozzles, eductors, packed beds, or permeable walls; and variable cell volumes, relative to capacities, ranging from very small, with less than a second of retention time, to the largest, with retention times of over 20 min. An important question is the extent to which any of the newer designs are based on locating weaknesses in current mechanical cell designs and then using these as a starting point for innovations. In the present study, the key subprocesses which must take place in a cell are outlined; mechanical cells are analyzed to establish where weaknesses may exist; and then alternative subprocesses are considered which could effect improvements. COMPONENTS FOR CELL DESIGN It is assumed that mineral surface chemistry has been modified as necessary to provide optimum potential floatability. While the cell process may affect this to a degree, cell design is primarily concerned with actualizing the existing potential floatability. The cell design problem is to provide more effectively for the following: 1) Dispersion of air to obtain an optimum bubble size distribution at an optimum ratio of air volume to feed volume. 2) A hydraulic environment which permits most effective contact of potentially floatable particles with bubbles: [Table I - Cell Comparisons* Cell Type Mechanical Column Deister Miller ASH No. of units Multiple Single Single Single Retention time min.10/20 17/27 3.8 ca. is Capacities mt/m3s 0.022/0.066 0.066/0.20 0.11 10.4 st/ft3d 1/3 0.3//0.9 m5.0 469 Air hold-up % 15/20 20 n.a. 50/80 Air escape velocity m/s 0.015/0.0200.020/0.025 n.a. n.a. ft/m 3/4 4/5 n.a. n.a. * References: Mechanical (Harris, 1976,1985), (Bassarear, 1985); Column (Travis, et al. 1987); Deister (Zipperian and Christophersen, 1985); ASH (Air-Sparged Hydrocyclone) (Miller 1989).]

Jan 1, 1989

By P. Otto, G. Borm, Th. Dickmann, F. Amberg, R. Giese

Based on many years experience, the well approved Tunnel Seismic Prediction System (TSP) has been substantially enhanced for online geological prognosis in underground construction. The method provides high resolution seismic images of the rock mass ahead of a tunnel face via an array of standard anchor rods. These contain3D-geophones and can routinely be installed during the excavation process. A further outstanding feature of the system is the newly developed high frequency repetitive seismic source which can easily be fixed at a tunnel boring machine. A user-friendly software package enables online data acquisition, processing, 3D-visualization, and interpretation.

Jan 1, 2001

By Stephen R. La Brooy, Tong Deng, Pritam Singh, David M. Muir, A. J. Monhemius, G. W. Warren, E. Peters

The controlled addition of ammonia to cyanide solutions inhibits the leaching of copper minerals but extracts up to 80% Au using as little as 10% of the cyanide compared with conventional cyanidation of copper-gold ores. The solubility of copper minerals and copper speciation in solution is dependent on NH3, CN-, pH and Eh. Rotating disc and electrochemical studies show that gold is leached by a mixed Cu-CN--NH3 complex with either Cu(II) or O2 as oxidant. This complex is slowly oxidised to CuCN and Cu(OH)2 by air.

Jan 1, 1993

By B. Catalano, D. Ifrim

The Annacis Island Outfall Project includes two TBM bored tunnels with face pressures above 3.5 bar, with an internal diameter of 4.2 metres. This paper discusses the innovative approach to TBM tunnelling and TBM design at the Annacis Outfall Project. The TBM custom design includes a 3.6 m OD core machine manufactured by Herrenknecht and a 5.0 m add-on by the Contractor (Bessac), acting as an extension kit, with optimized gantry design to accommodate for short tunnel drives and quicker launches. This novel design approach produced safety improvement, cost and schedule savings while streamlining logistics of TBM retrieval.

Dec 1, 2022

By P. Todd, K. Dever, P. S. Mills, A. A. Campoli

Resin bolt performance is dependent on the size of the resin annulus, i.e., the difference between the hole and bolt radii. The majority of the millions of resin roof bolts installed each year in the United States employ an annulus of 3.175 or 4.775 mm (0.125 or 0.188 in.). Short encapsulation pull tests with resin annuli of 3.175 and 2.413 mm (0.125 and 0.095 in.) resisted an average of 0.08 t/grouted mm (2.25 st/grouted in.) with no significant variation. Resin loses to simulated fractures increased as annulus size decreased.

Jan 1, 2003

By Jan K. Wolski

The PC computer program PCVENT, version 3.3, for the ventilation network analysis now incorporates a real-time fire simulator. Position of the fire or a source of contamination and the character of the event are input from the keyboard. There are several options of type of fire: heat only, contaminant only, or both with a constant burning rate or with oxygen as the only limiting factor. Airway resistances or fan characteristics can be modified during a fire simulation. This allows testing of various fire suppression strategies. Program application in the analysis of a real mine fire is presented.

Jan 1, 1991

By S. K. Mishra, S. B. Kanungo

Because conventional (physical) methods of ore dressing are not suitable for reducing the phosphorus contents of high-phosphorous manganese ores from Andhra Pradesh (AP) and the adjoining area in southern Orissa, India, the adoption of chemical methods becomes imperative. An attempt was therefore made to reduce the phosphorus content of partially beneficiated manganese ores from AP by roasting with sodium carbonate and then leaching with hot water. However, due to the higher phosphorus contents of the manganese ores from Nishikhal mines in southern Orissa, and because of their apparent resistance to dephosphorization by roasting with Na2CO3 alone, a mixture of Na2CO3 and NaCl was found to be necessary to reduce the phosphorus content to below 0.15%. Free-energy calculations at 700°C and above indicated that Na2CO3 (or Na2O as the active component) is a more active reagent than NaCl. Various process parameters, such as the temperature and time of roasting, the amount of sodium carbonate and the temperature and time of leaching, were studied to arrive at the optimum conditions for dephosphorization.

Jan 1, 2000

By T. F. Tomb

on' January 6, ,1992, the Mine Safety and Health Administration (MSHA) issued an Advanced Notice of Proposed Rule Making (ANPRM) for diesel particulate (DP). The ANPRM identified five areas where the Agency was seeking additional information to assist in the rule making process. These areas were exposure 'limits, risk assessment, consideration of other information, sampling and monitoring methods, and feasibility. The period for submitting information relative to the ANPRM closed July 10, 1992. Prior to issuance of the ANPRM, the agency was involved in conducting studies to evaluate sampling and control technologies and to gather information with respect to occupational exposures to diesel particulate in underground mining operations employing diesel-powered equipment. Since issuance of the notice, additional studies have been conducted to provide supplementary information in these specific areas. Results of these additional studies indicate that average DP levels in coal mines not using aftertreatment range from 0.9 to 2.1 mg/m3. Aftertreatment devices can reduce these levels by approximately 50 to 90 percent. Studies conducted in metal and nonmetal mines showed average DP levels ranging from 0.3 to 1.6 mg/m3.

Jan 1, 1994

By Leslie S. Halasz

This paper describes the techniques implemented at Randfontein Estates to develop twin-haulages at 'high speed'. An operation which culminated in the world record advance for twin-end multiblast cyclic development in hard abrasive quartzites. A major expansion project was planned for the mine, with the sinking of a third twin-shaft system (to be known as Cooke No. 3), to raise the level of ore production from 3 500 000 to 5 000 000 tonnes per alumm. Subsequent redesign of the proposed shaft system as a single 9 m brattice wall shaft took place, reducing the planned shaft sinking period by 12 months and saving an estimated R 250 000 (U.S. $ 330 000) in sinking costs. The advancement of the Cooke No. 3 Shaft sinking and development programme necessitated a rapid excavation schedule for two interconnecting twin-haulages from the existing Cooke No. 2 twin shaft complex to provide a second means of egress. An early holing between the two shafts would provide significant financial and technical benefits. Pre-development and equipping of shaft pillar excavations would enable a rapid shaft production build up and blocking out of at least one year's ore-reserves.

Jan 1, 1983

By Jack E. Fraley, Robert E. Simpson

INTRODUCTION Spokane Mining Research Center (BuMines) is researching sealants for underground coal mines to: 1. Reduce sloughing of shale roofs. 2. Reduce sloughing of coal ribs. 3. Seal block stoppings against air losses. 4. Construct stoppings by spraying over jute cloth or metal lath. 5. Render incombustible in-place polyurethane foam. Originally the work was directed towards reducing sloughing of shale roofs. Many underground coal mines have shale directly over the coal which weathers severely after exposure to the mine atmosphere. Lab investigations(l, 2, 3, 4) have shown that many shales separate into layers when immersed in water or stored in a high relative humidity environment. Upon drying or after removal from high humidity, the shales continue to separate. Underground coal mines become wet in the warmer months from condensation of the ventilating air. Conversely, the mines become dry in the cooler months from evaporation. The mines experience severe shale break-up during the summer and much less break-up during the winter. Figs. 1, 2 and 3 show weathered shale roofs. in underground coal mines. Fig. 4 shows fallen shale on the entry floor. Sealing the shale reduces this sloughing problem.

Jan 1, 1974

By W. K. Collins, C. L. Dahlin, D. C. Dahlin, W. K. O’Connor, G. E. Rush

Direct mineral carbonation has been investigated as a process to convert gaseous CO2 into a geologically stable final form. The process utilizes a slurry of water, with bicarbonate and salt additions, mixed with a mineral reactant, such as olivine (Mg2SiO4) or serpentine [Mg3Si2O5(OH)4]. Carbon dioxide is dissolved into this slurry, resulting in dissolution of the mineral and precipitation of magnesium carbonate (MgCO3). Optimum results have been achieved using heat pretreated serpentine feed material and high partial pressure of CO2 (PCO2). Specific conditions include: 155°C; P002=185 atm; 15% solids. Under these conditions, 78% conversion of the silicate to the carbonate was achieved in 30 minutes. Process mineralogy has been utilized to investigate the appropriate feed characteristics, identify the process products, and interpret the mineral dissolution and carbonate precipitation reaction paths.

Jan 1, 2001

By Dale S. Preece

INTRODUCTION The Waste Isolation Pilot Plant (WIPP) is a research facility located in Southeastern New Mexico. The WIPP is being developed by the U. S. Department of Energy (DOE) to demonstrate the safe storage of defense-related radioactive wastes in bedded salt. Since the WIPP is a research facility. a number of large-scale in situ experiments have been planned and are currently under construction (Munson, 1983). These experiments were designed to study various aspects of nuclear waste storage in bedded salt such as mechanical responses and creep closures of drifts, thermal response due to heated canisters, and thermally-induced fluid migration. One purpose of the WIPP is to develop and demonstrate a general predictive structural analysis capability for a bedded salt repository. One set of experiments, called the Geomechanical Evaluation (Room G), is heavily instrumented to study the creep around several rooms with different configuration. A Layout of the Geomechanical Evaluation room is shown in Figure 1. One portion of it consists of wedge shaped pillar where two drifts intersect at an angle of 7.5 degrees. The pillar can be seen at the bottom of Figure 1. One purpose of the wedge pillar experiment is to study progressive pillar failure in the tip region. Another is to determine how nonuniform pillar thickness affects creep closure of the drifts. An important aspect of the experiments is the correlation between experimental data and corresponding pretest finite element analyses of the site. The finite element simulations serve two purposes. First, the computer simulations aid in understanding the experimental results by providing calculated stress. strain and displacement fields that cannot be measured directly. Second, comparison of calculated and measured drift closures serves as a method for validating or improving the finite element models and the constitutive models employed. The wedge pillar geometry required a 3-D finite element creep calculation. Results from these 3-D calculations will be presented in this paper. A 2-D plane strain double drift model which approximates the wedge pillar geometry at a slice perpendicular to the drift has also been performed and will be compared to the 3-D results in this paper. FINITE ELEMENT COMPUTER PROGRAMS Two finite element computer programs. JAC (Biffle, 1984) and JAC3D (Biffle. 1986), were used. JAC is a 2-D finite element program developed for quasi-static analysis of non-linear solids. It employs the conjugate gradient iterative technique to obtain a solution Spatial integration is performed using a single gauss point in each four node quadrilateral element. An hourglass viscosity technique is used to control the zero energy modes that occur with single point integration. The single point integration combined with the explicit nature of the program and exploitation of CRAY-1 computer architecture results in very efficient execution J4: results were compared to results obtained with eight other 2-D structural creep computer codes in the second WIPP benchmark exercise (Morgan, 1981) JAC3D was derived from JAC to treat 3-D finite element models and has many of the same characteristics including single point integration and hourglass viscosity. These characteristics have made 3-D creep analyses more reasonable by significantly reducing computation time The first exercise of the creep capability

Jan 1, 1986

By Jaime Adasme, Héctor González, Benjamín Celada

"INTRODUCTION Santiago de Chile is a 7 million inhabitant city which has a 103 Km long subway network operated since 1975 by Metro S.A. This network is used on a daily basis by 2.3 million people. In 2012 Metro S.A. started the biggest enlargement of the network in its history, through the design and construction of the new Line 3 (21.7 Km) and Line 6 (16.5 Km). The detailed engineering contract for civil underground works of Line 6 (L6) was awarded to the Consortium integrated by ZAÑARTU Ingenieros Consultores and GEOCONTROL S.A., in which Geocontrol was in charge of the design of 11 stations and 14.5 Km of tunnel. L6 crosses L3 in Ñuble and Ñuñoa Station, L2 at Franklin Station and ends, intersecting L1, at Los Leones Station as shown in Figure 1. LOS LEONES STATION DESIGN Location and Characteristics Los Leones Station is placed at the North end of the L6, next to the same named station of the L1 and it has four construction units, as is shown in Figure 2: I. Access Shaft (49 m x 47 m). II. Access Gallery (34 m long). III. Station Tunnel (120 m long). IV. Connection Gallery with L1 (104 m long). A singular feature of Los Leones is that the western section of the station tunnel, built from the access gallery, is located below an underground parking lot which is located in Providencia Avenue, as shown in Figure 3. It is important to highlight that the distance between the vault of Los Leones Station Tunnel and the foundations of the underground parking lot is only 6 m."

Jan 1, 2016

By W. Trask

The state of the art in crawler transporters for loads to 3 kt (3300 st) is sufficiently advanced to allow compilation of job cost figures showing the economics of tracked vehicle use under a wide variety of circumstances. Initial costs, cost per ton of capacity, and operational and maintenance expenses are presented. Data is derived from participation by the Neil F. Lampson Co. in more than 3 Mt - km (2.05 million st - mile) of crawler operation during the past 16 years. The effects of economics on future design trends will be examined with particular reference to versatility, portability, and capacity.

Jan 1, 1987

By D. M. Muir

Thiosulfate offers a nontoxic alternative to cyanide for processing gold ores. The mechanism of leaching gold using ammoniacal thiosulfate solution is driven by the Cu(II)-Cu(I) redox couple and is complicated by competing ligands such as NH3 and S2O32; It is shown that an understanding of the copper speciation and sulfur speciation is required to optimize this system. This paper presents Eh-pH and speciation diagrams for varying concentrations of Cu(II), S2O32- and NH3 and discusses the conditions under which various copper and sulfur species are stable.

Jan 1, 2002

By D. C. McIntire

The Homer City Station, jointly owned by New York State Electric and Gas Corporation and Pennsylvania Electric Company is a three unit coal fired station. The first two units were put into commercial operation in 1969; the third unit became commercial in 1977. Units 1 and 2 are subject to the Pennsylvania State Implementation Plan (SIP) emission limit of 3.7 pounds of S02 per million BTU. Unit 3, having started construction later, is subject to the Clean Air Act, New Source Performance Standards emission levels of 1.2 pounds of 50-2 per million BTU.

Jan 1, 1988

By K. Hanumantha Rao, K. S. E. Forssberg, H. R. Manouchehri

The responses of calcite, feldspar and quartz minerals in a laboratory free-fall electrostatic separator after tribocharging with stainless steel, PVC and copper plates were investigated. The effects of H3BO3 and BaC12 chemical pretreatment on the electrical properties of the above minerals were examined. The changes in the electrical properties are discussed along with the determined charge, dielectric constant and electrical conductivity of the mineral samples. The electrical properties of the minerals and their responses to the electrical field during separation after tribocharging and chemical pretreatment are explored relative to the electrical behavior of the minerals.

Jan 1, 2000

By Morgan M. Sears

The stability of gateroad pillars is crucial in deep-cover longwall mining, especially during transitions to wider panel layouts. This study evaluates the transition from a 700-foot to a 1,000-foot panel layout with an inter-panel barrier in a deep-cover longwall mine in Southwestern Virginia to identify a configuration that enhances stability and reduces operational risks. Using the LaModel program, three pillar configurations were simulated to assess their performance based on stress distributions and pillar safety factors. These included the previously used 4-Entry Yield-Abutment-Yield layout, the current 3-Entry Yield-Abutment layout with a 220-ft inter-panel barrier, and the proposed 3-Entry Yield-Yield layout with a 320-ft inter-panel barrier. The findings of this study suggest that the proposed 3-Entry Yield-Yield pillar layout is more effective in managing stresses in deep-cover mining environments. By optimizing pillar placement and improving load management, this layout could positively impact mineworker safety and health. The study underscores the importance of advanced simulation tools in developing innovative solutions to address the challenges of modern longwall mining operations.

Feb 1, 2025

By Gregg J. Hodges

The Stillwater pt-pd mine and flotation mill are located about 130 km (80 miles) southwest of Billings in Stillwater county, M6ntana~ The pt-pd ore zone stretches about 43 km (27 miles), but varies in thickness from 0 to 6 meters (0 to 20 feet, but generally 3-6 feet) and dips 55-90,degrees from horizontal. The ore is hosted in basic, layered igneous rocks containing about 1% sulfide minerals which include chalcopyrite, pentlandite, pyrrhotite, and minor pyrite. The pt-Pd minerals are intimately associated with these sulfide minerals and are found as precious metal sulfides, tellurides, bismuthnides, and arsenides as well as native Pt metal. Approximately 90 different precious metal minerals have been found, but about 80% of the pd is in solid solution in the pentlandite. The ore assays about 0.1% Cu, 0.1% Ni, 6.2 g Pt/tonne (0.18 Troy ounce Pt/short ton (opt)), 21.3 g Pd/tonne (0.62 opt Pd), 0.21 g Au/tonne (0.006 opt Au), and 0.21 g Rh/tonne (0.006 opt Rh). The ratio of pd to Pt in the Stillwater ore and concentrates is about 3.5.

Jan 1, 1988