Search Documents

By D. Raicevic

The presence of residual uranium and other radionuclides in the uranium mill tailings are posing a continuous health concern to the surrounding environment. The slow generation of sulphuric acid from residual sulphide minerals is the cause of persistant dissolution and discharge of many metallic components of the tailings. The most effective long term solution to these problems would seem to be to produce chemically stable tailings. This paper describes two possible answers to the objective: (1) Removal of radionuclides and pyrite from tailings by mineral dressing techniques; some 60 - 68% of the residual uranium, 70 - 75% of the radium, 60 - 65% of the thorium and 95 - 98% of the pyrite have been rejected from the Elliot Lake tailings. The decontaminated tailings contained 0.003% uranium, 50 - 60 pCi/g radium226, 0.01% thorium and less than 0.1% sulphur as pyrite. (2) Preconcentration of radionuclides and pyrite by beneficiation from Elliot Lake ores prior to leaching; applying this approach about 97% of the uranium, 95% of the radium, 92% of the thorium and 98.5% of the sulphides were concentrated in a radionuclide and pyrite concentrates comprising 25% and 8% of the ore, respectively. The preconcentration tailings (waste) produced contained 0.004% uranium, 20 - 25 pCi/g radium226, 0.005% thorium and less than 0.1% sulphur as pyrite. Economic and environmental advantages of both approaches and the leaching of the concentrates are also discussed.

Jan 1, 1980

By R. A. Burns

Kaolin clay has a broad range of applications with the paper market representing the largest end-use. Calcined kaolin finds application in paper, paint and plastics primarily for its high brightness and light scattering ability. It is well known as an extender for TiO2. Meta-kaolin possesses a unique set of physical and chemical characteristics finding use in both traditional kaolin/calcined kaolin markets as well as other unique applications. This paper discusses the intricacies of manufacture and the key physical and chemical properties of meta-kaolin. Specific applications and the relationship of the physical/chemical properties to end-use performance are discussed.

Jan 1, 2002

By Winfield G. Wright, Greg P. Meeker, Philip L. Verplanck, Douglas B. Yager, Dana J. Bove, M. Alisa Mast

A really extensive acid sulfate-altered and mineralized rock in the southeast Red Mountains area is noted for its association with naturally occurring and mine-related acidic and metal-rich waters. Integrated geologic and aqueous geochemical studies demonstrate that the degree of metal mobilization and acid production in natural waters correlates well with the type of hydrothermally altered rock and structural features in which these water interact. Quartz-sericite-pyrite, quartz-alunite, and argillic alteration assemblages are associated with some of the most naturally acidic, high-metal waters in the study area; calcite-bearing propylitic rocks are related to the most pristine waters and buffer sulfate-rich, acidic waters produced by pyrite oxidation. Trace metals in natural waters are mostly derived from enargite, zinc-rich tetrahedrite and sphalerite. Pyrite oxidation contributes very little with respect to base-metals in these natural waters.

Jan 1, 2000

By Davidtz. John C.

INTRODUCTION The effectiveness of collector type on sulfide mineral flotation is generally determined by the amount and type of functional groups of collector molecules that interact with surface and water at the mineral/collector/water/gas interface. The final interfacial state when bubble contact takes place is preceded by chemical and physical reactions that involve these gas/liquid/solid interactions. These interactions differ not only for different minerals, solution and gas composition, but also for different collector molecules. The purpose of this paper is primarily to summarize the developments and status of short (C2-C6) and long (C12) chain, aliphatic collectors that contain three sulfur atoms in their polar function. These are trithiocarbonates (TT'Cs). For purposes of comparison, similarities in molecules containing 0, N and S are compared. Mostly short chain ionic collectors molecules of dithiocarbonates (DTCs) and TT'Cs were compared. The studies, largely bench scale flotation and plant testing, were carried out on ores containing Cu, Ni, Au, and PGM's. Studies of long chain 'ITC collectors are reported on Ni, PGM and auriferous pyrite ores containing uranium. Under starvation dosage conditions, surface activity coefficients of short chain collector molecules and interacting water were calculated. Based on the UNIFAC group contribution method of activity coefficient calculations, the Gibbs Excess Free Energy

Jan 1, 2005

By Philip L. Hageman, Paul H. Briggs

An important tool for use in the geochemical assessment of abandoned mine-waste piles is a leach procedure that can easily be done in the field and used for on-site screening of historic mine-waste material. We have developed a simple field leach test that is an effective indicator of waste pile geochemistry and can be used in order to establish the relative geochemical fingerprint for a given pile. This simple procedure also provides indication of the potential chemical composition of run-off from the weathered surface of these piles. As part of developing the technique, a comparative study was carried out on eight mine-waste composite samples from different deposit types. Splits of all eight composites were leached using the field leach test procedure and a modified version of EPA Method 1312 (SPLP). We found that the field leach test consistently provides relative indication of leachate geochemical trends comparable to leachate data derived from the more regulated, time consuming and laborious EPA Method 13 12 (SPLP).

Jan 1, 2000

By Z. T. Bieniawsk, C. A. F. F. Santos

The effects of artificial weathering on the mechanical properties of the Loyalhanna sandstone have been investigated. Weathering was simulated in the laboratory by subjecting cylin- drical specimens of rock to alternate cycles of wetting and drying (in distilled water at 2O0C 2 5OC and in an electric oven at 105OC t 1°C, respectively). The total number of cycles was 100 and the geomechanical characteristics of the altered material were determined through uniaxial compressive and indirect tensile ("Brazilian") tests, with the determination of axial and trans- verse strains and monitoring of acoustic emission activity (rate and total event count). Moisture content and weight loss data were collected after each cycle and the mechanical parameters (unconfined strength, indirect tensile strength, young's modulus, Poisson's ratio, permanent set and AE/MS activity) were determined for unweathered specimens and after 10, 20, 50 and 100 cycles of wetting and drying. Hypotheses for the effect of weathering on the geomechanical properties of the Loyalhanna sandstone are proposed as reinforced by petrographic analyses carried out for the different stages of artificial weathering. A methodology for assessing the degree of physical weathering of rocks is proposed based on the number of wetting and drying cycles.

Jan 1, 1986

By T. W. Healy, M. S. Moignard

The use of electrokinetic or zeta-potential phenomena in studies of the properties of mineral sulphides has increased greatly over recent years. This review aims to examine and discuss the body of literature on the subject of electrokinetic properties of sulphides in a comprehensive and critical manner. Although the review covers the period from 1925 to 1975, it is only in the past ten years that researchers have been fully aware of the implications and problems of chemical reactions, notably oxidation and precipitation reactions, on the surface properties of sulphide minerals. These papers are discussed in more detail than the earlier publications. A table containing a list of determinations of iso-electric- points and points-of-zero-charge of mineral sulphides, and the methods employed in obtaining these results, is presented.

Jan 1, 1976

By G. Triantafillou

The aim of this paper is to present the progress of the plan of the Greek Public Power Corporation S.A. (PPC S.A.) at the Lignite Centre of Megalopolis in Peloponnesus (southern Greece) to manage impacts on local communities in areas affected by its activities during the lignite mining operation and post-closure. The reclamation works in the waste dump areas of the mines that constitute the Megalopolis Lignite Centre, concerning the utilization of waste dumps for infrastructure community projects constructions are discussed. Moreover, selected environmental indicators concerning land use and closure and rehabilitation are presented.

Jan 1, 2008

By J. A. Herbst

Mineral liberation modeling can be traced back to the early work 0fA.M. Gaudin up through more recent population balance modeling by R.p. King, J.A. Herbst and G.T. Adel. A more micro-scopic look was taken at the University of Utah in the form of the J.E. Sepulveda and J.D. Miller Pargen model which permits the creation of an arbitrary shape, multiphase particle made up of discrete grains. Recent work on image analysis and tomographic analysis by J.D. Miller and C.L. Lin have laid the experimental ground work for model validation, but until now it hasn't been possible to include the necessary physics of the particle stressing process to allow the development of a 'ffirstprinciples"mode1 which does not presuppose a "mode” of liberation (e.g., random or by detachment). Recent developments in discrete grain breakage (DGB) modeling now make a generalized physics based model feasible. This paper describes current work that is being done to develop a physics based discrete grain liberation (DGL) model. Two-dimensional and three dimensional simulation results exploring the effects of particle size, phase properties and loading type are presented. Relationships between energy based liberation efficiency, degree of random liberation and material properties are identified.

Jan 1, 2005

By Murray D. Lester

The relationship between bauxite and energy has two distinct aspects. On the one hand, since virtually all of the bauxite that is mined winds up as aluminum metal, the economic health and future of the bauxite industry and of the bauxite-producing countries depend on the continuing vigour and competitiveness of aluminum against alternative metals and materials. The price of aluminum is, in turn, particularly dependent on the price of energy. Hence, the need for bauxite is ultimately affected by the price of energy. The second aspect relates to location of the bauxite industry. There is no shortage of bauxite resources in the world. For various reasons, as we shall see, there is a growing tendency toward the integration of bauxite mining, bauxite refining and aluminum smelting in those countries that have the resources both of bauxite and of energy necessary to support the entire production chain. Thus, the availability of attractive energy supplies will increasingly favour development of bauxite mining: the traditional export of bauxite as a simple raw material is likely to diminish in relative terms. In short, both the amount of bauxite mined and where this mining will take place are related to energy considerations. Let us first have a brief look at the four basic activities that are involved in our integrated operations: A. The bauxite is mined and moved to an ore plant. This step does not require more than relatively modest amounts of energy normally associated with excavation, loading and shipping of any bulk material. We need about four or five tonnes of bauxite for every tonne of metal produced.

Jan 1, 1984

By J. F. T. Agapito, R. R. Goodrich

Yield pillars have been used for many years to help reduce stresses near mine openings and improve roof and floor stability. A yield pillar is often defined as a pillar that fails but retains residual strength. Stress transfer occurs through the roof and floor after the peak strength of the pillar is reached. High stresses are transferred from around the openings onto abutments that can be barrier pillars or unmined ground. This mechanism, often referred to as pressure arching, is possible as long as the width of yield pillar mining (panel width) is less than the critical width above which stresses cannot be carried by the overburden. Significant stress transfer also can occur due to small amounts of pillar and/or floor yielding before the peak strength is reached. This is accomplished in a quasi-elastic manner with little or no visible roof and pillar fracturing or floor heave. Long-term stability may be achieved when stresses and mechanical properties are favorable to prefailure yielding. This paper gives practical examples where improvements in stability and resource recovery were achieved with this mechanism. Yielding was assessed by comparing measured and calculated vertical pillar stresses. Results indicated that calculated stresses in the pillars were 25% to 40% higher than the measured stresses, demonstrating significant arching load transfer to the abutments. Prefailure yielding is probably often present but unintentional in both development and production areas. Better recognition and use of this mechanism should lead to design improvements, as mines become deeper.

Jan 1, 2003

By K. T. Dreher, J. A. Brierley, C. L. Brierley

Water from underground uranium mines located in the Ambrosia Lake district near Grants, New Mexico, U.S.A., is treated to reduce levels of uranium, selenium, radium and molybdenum. The treatment system consists of a series of ponds and an ion exchange plant. Bacterial and algal populations present in the pond system are considered agents which actively assist in removal of the pollutants present in the water. Pondbottom sediments maintain a reducing zone and a large population of sulfate-reducing bacteria of the genera [Desulfovibrio] and [Desulfotomaculum]. Uranium, molybdenum, and selenium accumulate in the pond sediment. Stimulation of the microbial sulfate-reducing activity resulted in a decrease of soluble concentrations of these elements in laboratory systems. Predominant components of the treatment ponds’ algal flora are the filamentous [Spirogyra] and benthic [Chara]. Laboratory study indicates that [Spirogyra] is more active than [Chara] in removal of uranium and molybdenum from solution. However field-collected algal samples of both of the genera contain uranium and molybdenum. Laboratory studies indicate that death and decay of the algae in association with pond sediment does not result in return of cellbound uranium and molybdenum to the water. The algae appear to act as bio-filters for accumulation of particulate pollutants and agents for adsorption and/or absorption of soluble pollutants.

Jan 1, 1980

By Michael J. Howes

The nature of business in a free enterprise system is to maximise the return on an investment i.e. to maximise the wealth of the shareholders. This is normally achieved within constraints dictated by many agencies, one of which is the health and welfare of the employees. In the mining industry considerable effort has been expended in improvements in this field, however, the major problem still confronting the practicing ventilation or environmental engineer is the determination of what standards he should design for, which satisfy both the economic and health requirement s. Normally the basic health requirements are satisfied by the minimum standards defined in regulations and codes of practice. These are, however, based on an acceptance of a certain risk or lower production potential. A prime function of the ventilation engineer is therefore to financially justify and implement improvements to both standards and systems. The main purpose of this paper is to examine the basis and techniques of providing this financial justification. Changes in existing methods to achieve the same standards but at lower costs are also covered.

Jan 1, 1980

By D. Oyler

The National Institute for Occupational Safety and Health’s(NIOSH) Pittsburgh Research Laboratory (PRL), RAG Pennsylvania and Strata Control Technologies of Australia have collaborated to conduct an extensive study of roof bolt strata interaction at the Emerald mine in Southwestern Pennsylvania. The primary goal of the project was to obtain detailed data on the interaction between the mine roof and the support elements for use in modeling studies. The study site was a longwall tailgate subjected to high horizontal stress. Three arrays of instruments were installed at the site, one in the tail-gate entry and two in an adjacent crosscut. Pumpable concrete cribs were present in the tailgate array, and cable bolts were installed in one of the crosscut arrays. The instruments included mechanical and sonic extensometers for measuring roof movement, instrumented roof bolts, and three-dimensional roof stress cells. The study was ultimately successful in determining the magnitude of the horizontal stress concentration, the height of roof failure and the roof failure sequence, and the loading history of the primary roof supports.

Jan 1, 2004

By William A. Dupree, Mark J. Schultz, William J. Francart

Maintaining intake escapeways clear of contaminants from mine fires has been an issue for many years. Removing fire sources from these entries reduces the risk of contamination greatly. In recent years, concerns have been raised related to contamination of the intake escapeways by leakage when fires occur in adjacent airways. This paper discusses measured leakage rates for multiple stoppings at various pressure drops across stopping lines in a number of actual coal mines. Also addressed are methods for reducing the contamination risks for the intake escapeways, considering the ventilation system employed. The Effects of Air Leakage The effects of air leakage through ventilation controls has been well documented. While normal leakage is expected through stoppings, overcasts and other structures, abnormally high leakage results in an inefficient ventilation system and can increase operational costs for a mine. In addition, excessive leakage results in less control over mine ventilation airsplits. This may compromise the isolation of mine escapeways, and allow adjacent entries to be rapidly contaminated by products of combustion in the event of a mine fire. A study was conducted at ten mines in which air pressure and quantity measurements were taken near the active sections. The method used to construct the ventilation controls to separate airways was also noted. Stopping Construction Table 1 shows the type of stopping construction commonly used in the 10 mines included in this study. Main entry stoppings were normally built with mortared joints (wet stacked) with sealant applied to the high pressure side of the stopping. In most cases the entire face of the stoppings were sealed. In one case only the joints between blocks were sealed but the perimeters were sealed in all cases. Some mines also sealed the low pressure side of the stopping. Solid blocks were normally used for main entry construction and hollow blocks were sometimes used for longwall panel development. [ ]

Jan 1, 1993

By Miroslav Cervenka

The Coal, characterized by coal quality parameters as for example, ash content (Ad), moisture (Wrt), heat content (Qr1), sulphur content (Sd) and other parameters is still in many countries the basic source of energy. Energy is life, especially in modern society, where the demand for ecologically clean energy is very high; and therefore, there is great importance in effective coal utilization Direct utilization - burning of coal for energy generation, is still one of the most effective methods. In most cases, it is one of the cheapest energy transformation methods in spite of the fact that this energy transformation is connected with the deterioration of our surroundings. Deterioration can be substantially reduced if the burning of coal at power stations, heat power stations and other coal consumers is optimized. That means the burning is done in steam boilers, the technical state of which is very good; the coal has minimimum .variations with respect to the projected values; and the burning process is controlled and checked not only from a regulation point-of-view but also from an ecological point-of-view. The instrumentation capable of measuring the characteristic coal quality parameters in real time exists and it forms the basic assumption for the work our research team has made. The proper application of this instrumentation is able to provide information for burning process optimalization. It is the main topic of this paper, which is the compilation of the information on our work -made during the last five years. The whole information is based on practical experience and applied systems in Czechoslovakia in the mines and power engineering industry. See [Cervenka, 1989]

Jan 1, 1992

By P. Diehl

The increasing public interest in a useful framework for an assessment and classification of mineral resources (1) is documented by the recently published international classification scheme of the United Nations (1979) and the revision of the classification system of USBM/USGS (2) (1980). Moreover, various classification systems are currently discussed by the mining industry. In spite of major improvements in respect of the concepts, definitions, and taxonomy of ore classification, it has been recognized that the recent practice to classify mineral resources does not create truly reproductible results, i.e. an assessment to the various categories which is free from personal bias or corporate interests. Following are geostatistical methods proposed for a standardization and quantification of various terms in ore classification. After critical review of present practices, we will establish a precise link between the classical terms such as "measured", "indicated", and "inferred" reserves and the geostatistical concept of estimation errors. Moreover, we will demonstrate, how the basic criteria of economic feasibility, geologic assurance and recovery can be taken into account by geostatistics. A specific algorithm will be proposed to block out and to classify reserves according to the degree of geologic assurance. . We will also show computerized methods which perform complete classification procedures, and will also exemplify them with typical case studies.

Jan 1, 1982

By E. W. Hawk

he power generation industry may be required to reduce carbon dioxide (C02) emissions if regulations related to global climate change are enacted. Coal-fired generation emits more than 80% of the power sector CO2 and would be a likely target for CO2 reductions. Compliance with the Kyoto Protocol will require a 33% reduction from the projected year 2012 emission level, even with moderate load growth. This article describes an analysis of power industry CO2 reduction options and their costs. It assesses how a generator would make compliance decisions under a mandatory CO2 emissions reduction program. Carbon sequestration, fuel switching and new plant construction are considered. The Global Climate Change Treaty signed at the Rio de Janiero Earth Summit in June 1992 set the long-term goal of stabilizing CO2 concentration in the atmosphere. The December 1997 Kyoto Protocol established short-term mandatory targets for the United States and 37 other developed countries. The United States' target is a 7% decrease by 2012 from the 1990 "greenhouse gas" level. Developing countries are exempted from reductions, according to the Kyoto Protocol, despite projections that indicate a significant increase in their emission levels. The Kyoto Protocol must be ratified by the US Senate. US power industry carbon emissions were 490 Mt (540 million st) in 1990 and are projected to be 680 Mt (749 million st) in 2012, according to the US Energy Information Administration. Coal-fired generation emits more than 80% of the power sector CO2. Assuming that the power industry is only required to reduce emissions by a proportional share, a 33% emission reduction, or 225 Mt (248 million st) of carbon, would be required to comply with

Jan 1, 1999

By N. Champigny

The geostatistical estimation of the reserves of an ore deposit is highly dependent on the quality and stability of the variograms of the sample grades. Gold deposits commonly show a skewed grade distribution. The few high grades at the tail end of the distribution produce unstable variograms that are difficult to model. If these grades are cut to a lower grade value or removed, more stable variograms are obtained. However, outlier grades may make a deposit economically viable, and their cutting or removal should be treated with caution. To reduce (but not to eliminate) the effect of high grades, a transformation of the raw data can be performed. Most commonly used transformations are: logarithm, gaussian anamorphosis, rank and indicator. Variograms of the transformed grades are resistant to high grades and present a clear structure. The weak point of data transformation appears when grades are estimated by kriging; the estimates are very sensitive to slight variations in the parameters of the back-transformation. More robust variogram estimation procedures can also be used, but often these procedures are not suitable for skewed grade distributions as they are based on an assumption of a contaminated normal distribution. The Porgera gold deposit in Papua New Guinea has a highly skewed grade distribution, with grades ranging from 0.01 to 3500 g/t and a coefficient of variation greater than 5. For the geostatistical estimation of the high grade zone of the deposit, the influence of the high grades was quantified by calculating and comparing the following variograms: raw grades, raw grades with the highest grades removed and transformed grades. The study confirmed that there is no general method for handling high grades in a geostatistical reserve study. Several methods should be tried to quantify the influence of high grades.

Jan 1, 1991

By L. J. Dahl, S. E. Paulson, H. L. Kuhlman

To provide basic information on the processes occurring during in situ leaching, the US Bureau of Mines developed a geologic characterization research program. This includes laboratory experiments wing leaching apparatus that can accommodate whole core samples. Whole core experiments result in a higher proportion of ore mineral contact by the leach solution than packed column experiments. They also allow for the assessment of permeability changes taking place as the result of mineral dissolution, precipitation, and clay swelling within the flow channels of the rock. The leaching apparatus developed can be wed for either constant-pressure or constant- flow rate experiments and allows for the control of flow rate, pressure, and temperature during the experiments. Details of the experimental apparatus are presented, as well as preliminary results from the first series of experiments on an oxide copper ore from the Casa Grade, AZ area.

Jan 1, 1988