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By G. Akdogan, C. Dorfling, L. Bumhira

Hydrometallurgical recovery of rare earth elements from phosphors obtained from end-of-life fluorescent lamps involve leaching followed by extraction of dissolved metals from solution. The similar properties of rare earth elements make selective recovery of individual elements challenging. The aim of the paper was to investigate the extraction of primarily Ce and Tb from a hydrochloric acid leach solution also containing other REEs (Y and Eu) as well as impurity metals (Ca and Al). Batch solvent extraction tests were performed with di-(2-ethylhexyl) phosphoric acid (DEHPA) at various extractant concentrations, pH conditions and organic-to-aqueous ratios. Extraction isotherms and separation factors for the range of conditions tested in the project are presented in the paper. Separation of individual REEs was not possible at the conditions investigated, but a mixed REE product can be obtained in a single extraction stage operated at a pH of 0.5 using 1 M extractant at an O/A ratio of 1; these conditions resulted in complete Y and Eu, 95 % Ce and 99 % Tb extraction with Ca and Al coextraction below 7 %. A better quality mixed REE product can be produced by operating at lower pH and extractant concentration conditions, but this would require a larger number of extraction stages. Keywords: Cerium, fluorescent lamps, phosphors, rare earth elements, solvent extraction, terbium

Jan 1, 2020

By R. Thomas

A Honeywell TDC 2000 central process control system was installed at Rössing in 1984. The system controls the metallurgical operations from crushing to the finished product of uranium oxide and manufacture of sulphuric acid. The operation was previously controlled from nine separate local control rooms. The paper briefly reviews the design and commissioning of the control system on an operating plant and discusses the impact on manpower organisation and training needs. Development of the process control system during its first two years of operation is reviewed and a summary is given of the current status of computer control at Rössing. The impact of the new system on overall plant operation and performance efficiency is also briefly described. In conclusion, future developments of computer control and overall optimisation of metallurgical operations are reviewed.

Jan 1, 1987

By T. Wajima

Recovery of precious metals from hydrochloric solution using sulfur-impregnated carbonaceous adsorbent was examined. Sulfur-impregnated adsorbent with adsorption abilities of precious metals can be prepared from activated carbon using pyrolysis at 600 oC under 10 % H2S gas flow, and the adsorbed Au and Pd were precipitated as metal phase on the surface of the adsorbent. The adsorbents after precious metals adsorption were burned at 700 oC to obtain the residue mainly containing precious metals. The adsorbent was found to be highly efficient and selective for the uptake of precious metals, especially Au, in the presence of excess base metal ions from simulated spent automotive catalyst eluted solution using a column pack test. Keywords: Gold, platinum, palladium, reduction precipitation

Jan 1, 2020

By H. Matsuoka, M. Kawata, K. Mitsuhashi, C. Tokoro, T. Kato

Copper sulfide minerals generally have high floatability, but their floatability decreases when surfaces are oxidised under some conditions. Sodium hydrosulfide, NaHS, is known both as an activator and as a depressant for copper minerals. NaHS at low concentrations activates copper oxides by sulfurising surfaces, but at high concentrations depresses copper sulfides by interfering with the adsorption of collectors. In this paper, we applied NaHS to activate oxidised chalcocite and bornite and focused on the conditions of NaHS treatments such as dosages and pH, and the effect of these conditions on the floatability of those minerals. The pure minerals treated with NaHS were analysed using zeta potential analyser and X-ray photoelectron spectroscopy. Analyses indicated that the reactions of NaHS and the products on the mineral surfaces after the reactions (i.e. oxidation, pH change) depended on whether NaHS reacted with copper or iron, and the reactions between NaHS and iron depend on NaHS concentration and pH. Flotation tests using a small column cell were performed with a single pure mineral, and using a Denver-type flotation machine with a copper sulfide ore. The results of each flotation test were utilised to clarify the floatability. The relation between flotation behaviours and analysis results were also discussed. Keywords: Chalcocite, bornite, NaHS activation, flotation, floatability

Jan 1, 2020

By J. D. Steenkamp

In 2002 the commissioning of an ilmenite smelter on the North Coast of South Africa was extended by three months due to the failure and subsequent replacement of the magnesia-based refractory lining. The lining failed due to the hydration of magnesia caused by an unexpected source of water. The incident resulted in significant financial losses and a prolonged insurance claim which was settled in 2009. As magnesia-based refractories are used extensively in both ferrous and non-ferrous applications, the authors of the paper want to share the experience gained from this incident with others. The paper reviews the literature available on furnace start-up practices and explains the hydration of magnesia using available sources. The incident is studied in more detail, both technically and economically, and the costs incurred are quantified in terms of the cost of the original lining. The paper concludes with lessons learned and recommendations made for future work. The intention of the paper is to stimulate open debate regarding best practices in preheating of furnaces lined primarily with magnesia. Keywords Commissioning, hydration, start-up, magnesia.

Jan 1, 2011

By K. Cole, D. Mesa, P. R. Brito-Parada, M. R. van Heerden

Turbulence in stirred tank flotation vessels determines the bulk transport of particles and has an important role in particle-bubble collisions necessary for attachment. Positron emission particle tracking (PEPT) produces quantitative measurements of the kinematic motion of different particle classes inside flotation vessels. This paper presents flow profiles of the vessel, residence time distributions, flow profiles through the mesh and macroturbulent kinetic energy distributions as experienced by valuable (hydrophobic) mineral particles in a laboratory scale flotation vessel. The results highlight the impact of the rotor-stator design and a retrofit mesh modification at the upper part of the vessel which improve recovery by decreasing turbulence in the quiescent zone and at the interface. Keywords: Flotation machines, turbulence, PEPT

Jan 1, 2020

By N. Duda, P. Śliwiński, P. Stefaniak, B. Jachnik

Ventilation and air-conditioning are some of the most energy-consuming processes in deep underground mining. Additionally, the energy consumption of these processes systematically increases along with the expansion of the mine. Therefore, proper energy efficiency assessment and consumption forecasts of these systems are particularly important in modern mines for ongoing tracking and planning of the likely costs. In the article, a short-term prediction model for surface air–conditioning stations is described. This model takes into account dependencies that were identified, based on the data from the supervisory control and data acquisition (SCADA) systems. These dependencies between the response value and the external conditions are then incorporated into the model. This way, for example, the ambient temperature or the total number of specific days of the week (with sometimes significantly lower or higher than the weekly average energy consumption levels) are included. Taking into account these dependencies, and e.g. forecasted average monthly temperatures allow us to include the seasonality of energy consumption in the presented model. In the article, a sample energy efficiency analysis of the A/C system based on an example of the KGHM Polish Copper Polkowice-Sieroszowice mine is performed. The results of the solution proposed in the article are then evaluated, and compared to the currently functioning, more basic forecasting methods. However, given the general nature of the dependencies used in the model, similar solutions could be used in other case studies.

Sep 1, 2021

By D Olivier

De Beers' Finsch Mine is situated in the Northern Cape province, 170 km northwest of Kimberley. The concentrator facility, designed and constructed by Bateman Engineering, was commissioned in 1967 and upgraded in 1979 using diamond liberation and extraction technology available at the time of design. Since then significant advances in diamond processing and technology have been made and these -have been incorporated into the new main treatment plant and recovery plant flowsheets, making diamond liberation and recovery from the Pre-1979 dumps a viable economic option at Finsch."

Jan 1, 2010

By S. Liaghat, J. Rosenkranz, P. Semsari Parapari, S. Chehreh Chelgani, A. Tohry

It is commonly accepted that the energy consumption for comminution within mineral processing is responsible for around 3% of the global electrical energy usage. However, it was clearly noted that inside mills, less than 1% of this energy efficiency is actually consumed for particle size reduction. Therefore, monitoring of grinding parameters and modelling of product particle size distribution (e.g. characterised by the 80% passing size P80) play an essential role in operating costs of a mineral processing plant. Several empirical models have been introduced for the prediction of the P80. Since in the industrial scale usually a few numbers of grinding variables are monitored, these models cannot identically be used in plants. In addition, these empirical models do not always indicate the magnitude of correlations between milling variables. This study proposes to introduce the Hilbert-Schmidt independence criterion (HSIC) as an intelligent model for exploring linear and nonlinear relationships between grinding variables and P80 for an industrial scale data assessment. HSIC can rank variables based on their importance and help to select the most effective one for the generation of predictive models. HSIC modelling through various monitored grinding variables (ball charge, feed input rate, F80, power draw and work index) of an industrial plant indicated that F80 as a feed property has the highest effect on P80 of the ball mill products. Modelling results highlighted that the P80 can be accurately predicted, based on effective variables by using a HSIC model. These outcomes showed that HSIC as a powerful modelling tool can assess the relationships between monitored grinding parameters, select the most effective grinding parameters and satisfactorily predict the P80. Keywords: Product particle size, variable importance measurement, Hilbert-Schmidt independence criterion, mill charge

Jan 1, 2020

By I. V. Filippova, Y. Foucaud, M. Badawi, L. O. Filippov, S. Lebègue

To optimize the flotation of Ca-minerals, their separation contrasts were investigated by coupling experimental and theoretical techniques. We showed that they mainly rely on structural properties such as the Ca-Ca distance on their exposed surfaces but also on the ability to control the intermolecular interactions. An optimized composition of the carboxylic collector by calculating the collector-mineral and the intermolecular interactions was developed. Blending the saturated acids and non-ionic molecules with a fatty acid collector significantly increases the flotation selectivity between scheelite (CaWO4) and fluorite (CaF2). The theoretical results were validated by experimentally improving the separation contrast between Ca-minerals. After the tests of several depressants and collectors, the best depression of gangue Ca-minerals (fluorite, apatite and vezuvianite) was found by combining sodium silicate and sodium carbonate. Keywords: Ca Minerals, Fluorite, Scheelite, Carboxylic acids, Unsaturated Acid, Fatty acids

Jan 1, 2020

By B. M. V. Baloyi, D. Mchabe, D. Chetty

South Africa accounts for the largest global manganese ore production share, primarily from its Kalahari Manganese Field deposit. Despite this, domestic smelting is beset by energy constraints, resulting in most ore being exported for smelting. Mintek is investigating energyefficient pathways for ore reduction, specifically undertaking prereduction tests to reduce energy consumption for manganese smelting. The present contribution considers the effect of methane, anthracite, and holding time, at a fixed temperature, on the extent of reduction of Mamatwan-type ore, primarily from a mineralogical perspective. In particular, the aim was to carburise the monoxide Mn phase to Mn carbide, as this is less energy intensive than producing metallic Mn from the monoxide. Based on thermogravimetric test results, the ore and products from three experiment sets were analysed using X-ray diffraction and scanning electron microscopy to assess the phases and textures present. The findings show that carburisation of manganese monoxide and its equivalents is most advanced under conditions of 8% anthracite, 10% methane, and 60 minutes of holding time, thus confirming with the thermogravimetric data. These results show promise for reducing energy consumption for Mn smelting in ferromanganese production.

Mar 4, 2025

By L. Gutierrez, R. Yepsena

Enargite in porphyry copper deposits is an important mineral as it displays good floatability under the presence of the collectors usually used in the flotation of copper sulfides. As a result, copper concentrates grades are reduced. As scarcity of water resources is a problem relevant to Chilean mining, the use of seawater is a feasible solution. The behaviour of copper sulfides and molybdenite in the process of flotation in seawater was previously studied but not for enargite. The objective of this research is to study the behaviour of the enargite in different conditions of electrochemical potential during the process of flotation using seawater. The study was carried through micro-flotation tests using pure samples of enargite, at Eh values ranging from -300 to 500 mV(SHE), both in seawater and aqueous solutions containing calcium and magnesium. The results show that at pH 10.5 in seawater, the enargite and chalcopyrite recoveries are reduced throughout the whole range of Eh studied. At pH 9 in seawater, enargite and chalcopyrite are depressed under reducing and slightly oxidising conditions. The recovery of both minerals drastically decreases at Eh values lower than -100 mV and greater than 400 mV. The behaviour of enargite in seawater flotation differs from that observed in conventional water, since in the latter case the recovery of enargite decreases at higher potentials close to 500 mV. Keywords: Enargite, flotation, seawater, redox potential

Jan 1, 2020

By Y. Cao, C. Li, A. Song

Bubble size plays a key role in determining flotation efficiency. Bubbles can be formed by passing air through pores. Bubble detachment from a pore is driven by lifting forces including buoyancy force and momentum force. Enhancing the momentum force is the key to accelerate bubble detachment and to minimise bubble size. Recent studies show that replacing steady air with oscillatory air supply could significantly decrease bubble size by enhancing the momentum force. To date, the underlying mechanism for the improved momentum force with oscillatory air supply is not yet clear. This work, for the first time, developed a qualitative model for the momentum force as a function of frequency, on/off time ratio and gas flow rate. It was found that the momentum force was positively correlated with the frequency as well as the air flow rate, and was negatively related to the on/off time ratio. The relation between bubble size and these operating parameters was also investigated. Keywords: Flotation, bubble size, momentum force, modelling, oscillatory air supply

Jan 1, 2020

By M. M. Makhofane

Anhydrous zirconium tetrafluoride can be used as a precursor for the manufacturing of nuclear-grade zirconium metal. This can be done by fluorinating plasma-dissociated zircon with ammonium bifluoride in a batch reactor. This paper describes the batch process. It was proved that anhydrous zirconium tetrafluoride can be manufactured by this route as confirmed by X-ray diffraction. The process shows potential for scaling up to the kilogram scale and possibly the tonnage scale.

Jan 1, 2012

By H. Uygucgil, C. Kwang

The use of remote sensing and geographic information system techniques in mineral exploration is still underutilised. There is a need to explore the potential of new robust remote sensing and geographic information system techniques in the field of mineral exploration. In this study, we mapped the argillic alteration associated with epithermal gold-silver mineralisation. A band ratio of band5/band6 and Crósta technique on Advanced Spaceborne Thermal Emission and Reflection Radiometer within the Google Earth Engine Environment was applied. The bands 5 and 6 were selected for the band ratio after critically analysing and comparing the illite spectral extracted from the Advanced Spaceborne Thermal Emission and Reflection Radiometer image and the illite spectral obtained from the United States Geological Survey spectral library. The band ratio and Crósta technique identified and mapped the Ovacik goldmine and other argillic alteration zones. Even though both methods mapped out the argillic alteration zones associated with gold-silver mineralisation, the Crósta technique produced the optimal argillic alteration. The study demonstrates the analytical capabilities of Google Earth Engine in image processing and analysis for mineral exploration, such as discovering hydrothermal alteration associated with mineralisation.

Jul 23, 2025

By W. K. Brinsden

In August 1965, the late Mr Alan Smith, then Mill Superintendent at Gold Mines of Kalgoorlie (GMK), Australia, asked me to investigate the planting of vegetation on the GMK slimes dams in order to ease the dust problem in urban and industrial areas-a problem that is caused largely by dust from these barren slimes dams. My early sources of information were the comprehensive papers in various issues of the Journal of The South African Institute of Mining and Metallurgy. However, the climate of Johannesburg differs from that of Kalgoorlie. The average Johannesburg rainfall, which falls mostly in summer, is 730 mm, and the average maximum summer temperature is 26°C (top 34°C). The winters are cool, the average maximum being 18°C (low -7°C). Kalgoorlie, on the other hand, receives, on average, 257 mm of sporadic rainfall, has hot dry summers with an average maximum of 35°C (top 45°C), and cool winters with an average maximum of 18°C (low -2°C). My obvious choice was to look at established trees growing on the GMK lease. A number of Athel pines were growing vigorously adjacent to the Oroya mining and geology offices and also on a nearby sand dump. The Athel pine (Tamarix aphylla), which is native to North Africa, Asia, and India, was originally introduced into Australia in 1936 by Mr Essington Lewis, then manager of BHP. His cuttings were planted in Whyalla, where some difficulty had been experienced in finding trees and shrubs that would flourish despite the district's low rainfall. In August 1965, cuttings of approximately 20 cm length and 1 cm diameter were taken from the GMK trees, stripped of leaves, and placed in jars of water in the sun. When the cuttings had sprouted both leaves and roots, they were planted in local soil in tins (about 20 cm high and 10 cm in diameter), and watered daily. In October 1965, when the new shoots were about 8 cm long, the trees were transplanted onto a lower flat section¬approximately 30 m wide, 30 m long, and 2 m high-of the Trafalgar slimes dam. No additional soil or fertilizer was used, and the trees were planted in their tins, the bases of which had been removed (the tin would eventually rust away). A few common varieties of non-prickly cactus and two native salt bush (spp Atriplex) were also planted, but did not survive, probably because of the acidity of the slime. During the summer of 1965/1966, Kalgoorlie's rainfall was 88 per cent above the average, and this probably helped the trees to survive. The moisture content was usually about 2,5 per cent from about 10 cm below the surface, and the pH value of the slime (d80 approximately 75 µm) was about 6. The trees were watered twice a week for the first four months and then left untended. By 1974 they had grown to only about 0,7 m, which indicated that their growth in slime was very slow. Other Athel pines were planted on the wall of the dam, but did not survive beyond 1974, probably because of the steep (about 500) slope and the hardness of the walls, which were initially formed by hand-shovelling of the slime as the height of the dam was raised. Five of the six Athel pines planted in 1965, which probably reached maturity (approximately 5 m in height) in 1981-16 years after being planted-have survived. In the early 1980s, waste rock had to be dumped on the dam, but the management of KMA (now KCGM) took care to ensure that the trees were not buried. Trials are being conducted on other tailings dams so that the performance of cuttings taken from the trees on Trafalgar dam can be compared with that of cuttings taken at various sites in Western Australia. It might also be worth while for an attempt to be made to strike cuttings from Trafalgar dam in pots containing different mixtures of soil and slime.

Jan 1, 1991

By Y. Yang, L. Li, X. Liu

Coal mining in China is facing the transition from output to quality. Based on the total mining capacity and average production, the current situation of coal mining at mine, city, and province levels is analysed, and data in support for the layout of sustainable mining development and the optimization of output provided. The results show that 87% of China's coal is mined by underground methods, with an average production capacity of 0.93 Mt/a per mine. Open pit mining accounts for 13%, with an average mine production capacity of 5.73 Mt/a. The average mining capacity of coal mines in China is 1.05 Mt/a, with 1181 coal mines with an average capacity less than 0.3 Mt/a, accounting for 35% of the total coal mines but contributing only 4.51% to output. They are distributed in about 48 cities in six provinces, seriously restricting the transition to green coal mining. The coal industry should speed up the closure of small coal mines in key provinces and cities, eliminate outdated production capacity in the central region, increase the speed and proportion of coal resources moving westward, and promote high-quality development of coal mining.

Jan 26, 2023

By D. Yu Pleev, V. G. Krivolapov

Mines of Southern Kuzbass working out, basically, coal formations of flat seams. Seams, as a rule, are inclined to self-ignition. Detection at early stages of the centers of endogenous underground fires has great value for safe conducting mountain works. One of methods of detection of an early stage of underground fires in the worked out space is the method of superficial radon survey. In the report the method is de-scribed and examples of superficial radon survey on concrete layers are given.

Jan 1, 2003

By M. A. El-Sayed

"Double oxide films (bifilms) are significant defects in light alloy castings that occur when, during melt handling, the oxidized surface of the melt is folded over onto itself and then entrained into the liquid metal, encapsulating a portion of the local atmosphere. These defects create crevices in the final castings and have been shown to decrease tensile and fatigue properties, and also to increase their scatter, making casting properties unreproducible and unreliable. This paper reports on two different experiments performed to study the behaviour of such defects in Al alloys. In the first experiment and as a proxy for a bifilm, air bubbles were held in an Al-5Mg alloy melt for varying periods of time before the melt was allowed to solidify. The composition of the gas content of the bubbles was subsequently analysed using mass spectrometry to ascertain how it changed with time. In the other experiment the influence of the age of bifilms on the mechanical properties of Al-5Mg castings was assessed by holding castings in the liquid state for different times before solidification, followed by mechanical property testing and SEM and EDX studies of the fracture surfaces of tensile test bars. This research could provide a better understanding of the behaviour of double oxide film defects, and may lead to the development of new techniques by which these defects could be eliminated, or at least deactivated, in light alloy castings. Introduction One of the major structural defects affecting the reproducibility of mechanical properties of aluminium castings is the double oxide film defect (El-Sayed and Essa, 2017; El-Sayed and Ghazy, 2017). This type of defect is usually created as a result of poor filling system design. Owing to the very high reactivity of liquid Al-Mg alloy with oxygen in the air, the surface of the liquid metal can be considered to be permanently coated with an oxide film (Weigel and Fromm, 1990). As a consequence of surface turbulence, the oxidized metal surface can become folded over onto itself, but not fused, and then submerged into the bulk liquid, with a portion of the mould atmosphere being entrapped within it (Campbell, 2003; Al- Sayed, 2016; El-Sayed, Hassanin, and Essa, 2016)."

Nov 1, 2018

By K. Wu, X. Yuan, R. Du, C. Chao

"Lump coals are currently employed to replace part of coke in the COREX melter-gasifier for ironmaking. In order to optimize the process, the pyrolysis kinetics of Datong coal used in the COREX process was studied. A sectioning method is proposed to overcome certain shortcomings of traditional methods for studying the pyrolysis of coal. Based on the sectioning method and the characteristics of the coal pyrolysis process, the temperature range was divided into three intervals. In the first, the adsorbed gas and water of crystallization were removed; in the second, the coal was transformed into semi-coke; and finally, the semi-coke was further coked. Three models of reaction were then established to study the different stages of the pyrolysis process: an interfacial chemical reaction model, a random pore model, and internal diffusion with shrinking volume. The results showed that the experimental data fitted the models well, with all correlation coefficients (r2) exceeding 0.97. Finally, the mechanisms of reaction and kinetic parameters for each temperature range were derived, which laid a necessary foundation for optimizing the usage of non-coking coal in the COREX process. IntroductionIn view of environmental concerns and the shortage of good-quality coking coal, the COREX process was designed as a new ironmaking technology, attracting wide attention (Fang et al., 2005). In this process, lump coal and a small quantity of coke are directly charged into the melter-gasifier, where a high-quality reducing gas is generated for the reduction of the iron ore (Kumar et al., 2009). In contrast to the conventional blast furnace (BF) process, non-coking lump coal is used as the reducing agent and as the energy source, and the iron charge consists of lump ore and/or pellets, which results in the elimination of the coke oven and sintering plant as well as a decrease in investment (Kumar et al., 2009; Liu et al., 2012).Although the COREX process has made great progress, in current production practice the energy consumption greatly exceeds that of the BF, and it requires a certain amount of coke to maintain permeability of the semi-coke bed (Wang et al., 2008). In addition, the process consumes a lot of good-quality lump ore and lump coal. The pyrolysis of coal is the first step in most coal conversion processes, such as carbonization, gasification, and combustion (Aboyade et al., 2013). The reaction behaviour of lump coals in the COREX melter-gasifier is crucial, as it determines energy utilization and gas composition, as well as the metallurgical properties and particle size of the semi-coke produced (Prachethan et al., 2011; Zhang et al., 2014). In order to optimize the process and improve its competitiveness, the pyrolysis kinetics of Datong coal used in Baosteel’s COREX C-3000 facility was studied."

Jan 1, 2016