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By J. Hadjigeorgiou, T. R. Stacey

This paper introduces the Quantified Value-created Process (QVP), a decision-making process for use in mine design and operation. The implementation of the QVP is founded on a ten-step rock engineering design process and a ten-step strategic planning process. The potential of this approach is demonstrated by examples of value created as a result of good research, design, and planning. The QVP is divided into two parts, namely, a ‘planning the process’ section and an ‘implementing the process’ section, and can be considered to be an extension of the risk approach. All costs, direct and indirect, associated with a significant mining decision (design, operational, investment) must be quantified in advance of committing to that decision, to determine the value that will be created in the short, medium, and long terms. Ethical values, associated with health, safety, the environment, public perception, and social aspects, may be difficult to quantify in economic terms, but must nevertheless also be considered. In contrast with a traditional risk approach, the QVP will identify the upside, and allow executives to make more informed strategic decisions. In this context it is essential to actively engage upper management in the decision process.

Feb 2, 2022

By Richard F. Link, Jr. Koch

"A mathematical simulation model has been devised to guide the layout of surface or underground mine workings, drill stations, and drill holes that are established in order to search for tabular ore bodies. The ore bodies may be contained within veins, sedimentary beds (including reefs), or other tabular structures.Programmed for a time-shared digital computer, the model contains both stochastic and deterministic variables. Stochastic or natural variables include the number of ore shoots and their sizes, orientations, locations and values. Deterministic or controllable variables include (i) locations and costs of workings (for underground exploration); (ii) drill station locations and costs; and (iii) drill hole azimuths, inclinations, lengths and deflections (if any).For various assumptions about the natural variables, the model is run while the controllable variables arc changed deliberately. Thus, layouts are devised to determine the percentages of the total number of assumed ore shoots found at different costs. In order to choose among the various layouts, cost-effectiveness measures are calculated."

Jan 1, 2014

By M. Bryson, G. Marap, M. Ntlhane, M. D. Hlahane

This study investigated flotation of phosphate from a low-medium grade 8-12% P2O5, 65-73% SiO2 sedimentary phosphate ore from Kropz Elandsfontein (herein referred to as Elandsfontein) in South Africa. Quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN) was used to determine apatite grain size distribution, liberation and mineral association in the F2 horizon sample. The mineralogy indicated that apatite was liberated and for the Elandsfontein plant to operate at the design throughput, the flotation feed has to be milled to a coarse grind ranging between 300 μm and 425 μm. Reverse flotation process routes using varying reagent dosages, and flotation feed top sizes that could possibly yield a final product of 31% P2O5,10% SiO2 at a reasonable +70% P2O5 recovery were investigated. Based on the results, a split circuit of coarse (-300+212μm) flotation and fine (-212+20μm) flotation, was mostly preferred as compared to treating the whole ore. A final combined concentrate of 31% P2O5 and 10% SiO2 with P2O5 recovery of 84% could be produced from the reverse split circuit. The robustness of reverse flotation for both coarse and fine fractions was further investigated. Reverse flotation of the fines fraction was found to be robust and produced a final product of 31% P2O5. It was however more challenging to achieve the required product grade and recoveries on the coarser fraction (-425+212μm), suggesting that reverse circuit was not adequately robust at fractions coarser than 300μm. Keywords: Phosphate, sedimentary, reverse flotation, particle size

Jan 1, 2020

By J. Trcková

This paper describes the method of modelling rock mechanical problems on experimental models. Based on an actual experiment used as an example, assessment of the surface deformation due to undermining, the extensive possibilities of using a 3-D physical model and application results in practice are demonstrated. A special method of modelling the underground mine progress by using paraffin melting is presented. Keywords: undermining, subsidence of surface, 3-D experimental model

Jan 1, 2009

Spiral concentrators are compact, cost-effective and generally efficient gravity concentration separators for a wide range of applications (for example: coal, beach sands, iron ore, chromite and tantalite). Large mineral processing plants consist of thousands of spiral concentrators resulting in large plant footprints (capital intensive) and the adjustment of splitters is time consuming, impractical and is in many cases neglected?high capacity (HC) spiral concentrators aim to address these shortcomings. As a result Exxaro Namakwa Sands is currently investigating high capacity spiral technology for the spiral circuit upgrade at the primary concentrator plants (PCPs). This article summarizes the rougher spiral performance evaluation that was conducted on different types of spiral concentrators (the traditional MG4 spiral concentrator and the high capacity (HC) spiral concentrator) under different feed conditions. In addition, the effect of slimes on the spiral concentrator performance was also investigated. Slimes rheology was linked to the poor concentrator performance at the higher slimes concentrations. The test campaign shows a sacrifice in recovery under design-feed conditions can be expected when using high capacity spiral concentrators in the rougher stage when compared to traditional spiral technology currently in use. Both spiral concentrators show a detrimental impact of slimes on the performance, but the high capacity spiral concentrator is more sensitive to the higher slimes conditions.

Jan 1, 2010

By Z. Luo, W. Chen, Y. Zhao, Y. Fu, L. Dong

The gas-solid dense-phase fluidised bed includes a complex multiphase fluid-particle system; different complex exchanges significantly affect the stability of the fluidised bed. To elucidate the characteristics of fluidisation in a gas-solid dense-phase fluidised bed, this study used experimental performance tests to obtain the static density characteristics, and the attachment and flow characteristic of the dense medium. The results indicate that the bulk density of the dense medium increases first and then decreases with the increase of particle size. The airflow rate difference is used to quantify the wall attachment characteristics of dense medium and the average pressure gradient in the axial direction of the bed is approximately 20 Pa/mm under the fluidisation results. At the same settlement location, with the decrease of fluidisation number, the settlement velocity of large and small particles becomes slower, the boundaries of settlement displacement and location probability are gradually disrupted, and the falling velocity of particles with a radius of 20 mm is faster than that of materials with a radius of 15 mm. This work also established a theoretical basis for regulating the stability and separation characteristics of gas-solid dense-phase fluidised bed. Keywords: Fluidised bed, different size particles, fluidisation characteristics, flotation bubbles, settling motion

Jan 1, 2020

By D. van der Westhuizen, H. Krieg, M. Kruger

In the field of Fischer-Tropsch synthesis catalysts, cobalt, platinum, and aluminium are the primary metal constituents of the conventionally used cobalt catalyst. While platinum recovery remains a focal point in this field, a recent endeavour by a South African company emerged, which aimed to recover cobalt and aluminium from spent Fischer-Tropsch synthesis catalysts for potential use in the agricultural sector. This study aimed to optimally separate cobalt and aluminium from spent Fischer-Tropsch synthesis catalyst for this purpose. It further leverages the OLI database to predict metal speciation during solvent extraction to aid with experimental planning. Shake-out tests were conducted to determine optimal separation. conditions, which were validated using three distinct methods: (i) evaluating the experimental error, (ii) comparing results with similar research, and (iii) validating results against the OLI database. The investigation revealed the pivotal role of the aqueous pH yielding effective separation at pH 3.13 ([H2SO4] = 2.5 × 10−4 M) when using 20 vol.% CYANEX 272 and 50 mol.% pre-neutralisation. Effective cobalt scrubbing was achieved with 50 g/L Al at pH 2.8, while successful stripping required 1 M H2SO4. Competitive interactions between complexing aluminium and cobalt species were observed when contacting with CYANEX 272 at a pH < 4. Equipment design analysis for a targeted separation efficiency of 87% dictated the necessity of two mixer stages and a settler measuring 1.5 m × 1.5 m × 6.0 m (height × width × length). This settler would ensure sufficient residence time for gravity separation at a flow rate of 10 m3/h.

May 27, 2025

By W. Wilmans

Electrokinetic dewatering of kimberlite slime under constant direct curents of 0,5 to 2 A and dewatering under constant applied potentia Is of 16,5 to 46,5 V are considered. The combined efects of electrophoresis and the addition of 8,3 x 10-3 M Mg2+ ions on the one hand, and 1 to 10 p.p.m. of the anionic polyacrylamide flocculant Praestol 2935 on the other, were investigated in a 3-litre Perspex electrophoretic cel. .The electro-osmotic dewatering experiments were conducted in a 3-litre Perspex electro-osmotic cel at various electrode spacings, as well as with a moving anode (top electrode). During electrophoretic dewatering, the zeta potential of the kimberlite particles did not change significantly, whereas the pH and temperature showed marked increases with time. The addition of Praestol 2935 enhanced the setling of the sludge bed owing to the additional effect of flocculation. The addition of electrolyte Mg (CIO4)2 retarded the separation process, partly as a result of gel formation in the slurry. During the electro-osmotic experiments, the rate of dewatering was found to be approximately proportional to the applied constant direct current, and to be independent of the electrode spacing. In general, electro-osmotic dewatering seemed to be more energy-efficient than electrophoretic dewatering.

Jan 1, 1987

The May General Meeting of the Institute was held in Kelvin House, Johannesburg, on 21st May, 1969, at 4.30 p.m. Mr J. K. E. Douglas (Vice-President) was in the Chair. There were also present twenty-two Members, including Messrs F. P. Bath, M. Bareza, A. R. C. Fowler, D. M. Jamieson, C. M. Mavrocordatos, D. G. Maxwell and J. A. Nixon (Council Members), Messrs T. Davidson, G. L. Diering, E. T. Dunstan, D. E. H. French, K. Hodgson, O. A. E. Jackson, A. F. Lee, A. Louw, D. L. Starkey, R. K. Wheeler and M. Youngworth. Four Associate Members including Messrs D. Blair Hook and G. R. Still. One Student Mr N. A. Barcza. Thirteen Visitors, including Messrs S. H. Ash, D. L. G. Bayne, E. Bayne, S. Bell, W. S. Garrett, L. S. Gibbs, R. C. Hamilton, M. Maguire, D. Rose and J. D. van Niekerk. Total Present: Fourty-one. OBITUARY The Vice-President: "It is my sad duty to announce the death of the following member of the Institute: Thomas Spence Haldane, Member, who joined the Institute in 1924 and passed away on 21st December, 1968. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, those present stood and observed silence for a few moments. MINUTES The Vice-President requested that confirmation of the minutes of the previous meeting be held over as they would only be appearing in the Journal of the following month. He also requested that confirmation of the minutes of the 75th Anniversary Meeting be held over. MEMBERSHIP The Vice-President: "I have much pleasure in announcing that the names of the under-mentioned candidates have been published in accordance with By-Law 5.2.2, and Council has elected them to membership of the Institute in the following grades: Members: Gideon Jacob Haumann, Peter John Cumming, Ian Stanley Dudman, Roderick Goldston Murchison. Associate Members: Francois Alwyn Beyers Fouche, Alan Marsh, Johannes Petrus van der Westhuysen, Waldo Edmund Stumpf, Ian Nicholas Ridley. Affiliates: Lutgerus Kolver Jooste, Roger Ainsley Ralph Kebble, Edward John Wainwright, Lewis William Davies. Graduate: Clive Graham Knobbs. MEMBER TRANSFERED TO A HIGHER GRADE From Student to Associate Member: Diethard OUo Eduard Fahrbach. I welcome the newly elected members to the Institute and congratulate the member who has been transferred to a higher grade." (Applause).

The May General Meeting of the Institute was held in Kelvin House, Johannesburg, on 21st May, 1969, at 4.30 p.m. Mr J. K. E. Douglas (Vice-President) was in the Chair. There were also present twenty-two Members, including Messrs F. P. Bath, M. Bareza, A. R. C. Fowler, D. M. Jamieson, C. M. Mavrocordatos, D. G. Maxwell and J. A. Nixon (Council Members), Messrs T. Davidson, G. L. Diering, E. T. Dunstan, D. E. H. French, K. Hodgson, O. A. E. Jackson, A. F. Lee, A. Louw, D. L. Starkey, R. K. Wheeler and M. Youngworth. Four Associate Members including Messrs D. Blair Hook and G. R. Still. One Student Mr N. A. Barcza. Thirteen Visitors, including Messrs S. H. Ash, D. L. G. Bayne, E. Bayne, S. Bell, W. S. Garrett, L. S. Gibbs, R. C. Hamilton, M. Maguire, D. Rose and J. D. van Niekerk. Total Present: Fourty-one. OBITUARY The Vice-President: "It is my sad duty to announce the death of the following member of the Institute: Thomas Spence Haldane, Member, who joined the Institute in 1924 and passed away on 21st December, 1968. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, those present stood and observed silence for a few moments. MINUTES The Vice-President requested that confirmation of the minutes of the previous meeting be held over as they would only be appearing in the Journal of the following month. He also requested that confirmation of the minutes of the 75th Anniversary Meeting be held over. MEMBERSHIP The Vice-President: "I have much pleasure in announcing that the names of the under-mentioned candidates have been published in accordance with By-Law 5.2.2, and Council has elected them to membership of the Institute in the following grades: Members: Gideon Jacob Haumann, Peter John Cumming, Ian Stanley Dudman, Roderick Goldston Murchison. Associate Members: Francois Alwyn Beyers Fouche, Alan Marsh, Johannes Petrus van der Westhuysen, Waldo Edmund Stumpf, Ian Nicholas Ridley. Affiliates: Lutgerus Kolver Jooste, Roger Ainsley Ralph Kebble, Edward John Wainwright, Lewis William Davies. Graduate: Clive Graham Knobbs. MEMBER TRANSFERED TO A HIGHER GRADE From Student to Associate Member: Diethard Otto Eduard Fahrbach. I welcome the newly elected members to the Institute and congratulate the member who has been transferred to a higher grade." (Applause).

The June General Meeting of the Branch was held in the St. Helena Club on Wednesday, 18th June, 1969. Mr J. G. Kirchner (Chairman of the O.F.S. Branch) was in the chair. There were also present: Eight Members: Messrs A. F. Leger, J. N. Saunders, T. Zadkin (Committee Members), Messrs M. G. Cullen, M. S. Grobler, C. J. Isaac, S. L. S. Swart, P. S. Turner. Eight Associate Members: Messrs R. Campbell, D. E. Couperthwaite, J. D. Couperthwaite, A. Hepburn, P. A. Hoffman, H. J. Reeders, R. B. Sutherland, P. R. Wheeler. Two Graduates: Messrs M. T. G. Davies, B. D. Goodwin. Two Affiliates: Messrs L. D. Hulley, K. L. Wilson. Three Visitors. Total Present: 24. Apologies were received from Mr L. O. W. Leimer. The Chairman declared the meeting open and, after extending a welcome to all visitors, said that it was his sad duty to announce the recent death of Mr. R. Jack, Associate Member. As a mark of respect to the deceased and in sympathy with the bereaved, those present stood in silence for a few moments. MINUTES OF PREVIOUSGENERALMEETING The Minutes of the Previous General Meeting held on the 19th February, 1969, which were published in the April Journal, were taken as read and their adoption proposed by Mr J. N. Saunders and seconded by Mr D. E. Couperthwaite. MA TTERS ARISING FROM THESE MINUTES There were no matters arising from these minutes. ELECTION OF SCRUTINEERS Mr V. J. Isaac proposed and Mr M. S. Grobler seconded a motion that Messrs J. G. Kirchner, J. N. Saunders and M. G. Cullen be elected scrutineers in the forthcoming election of Committee Members. GENERAL BUSINESS The Chairman announced that a visit to the South African Railways Workshops in Bloemfontein had been arranged for the 23rd July, 1969 and expressed the hope that this would be well patronised. TALKS The Chairman called first on Mr D. E. Couperthwaite to present his paper on &apos;Heavy media separation&apos; and then on Mr A. F. Leger to present his paper on &apos;Engineering plastics&apos;. Both presentations, which were illustrated with diagrams, proved of great interest to all members. A vote of thanks to both speakers was proposed by Mr T. Zadkin. CLOSURE After thanking the speakers, the Chairman thanked all present for their attendance and declared the Meeting closed at about 9.30 p.m. Refreshments were then served.

By A. G. Journel, CH. Huijbregts

"Centre de Morphologie MathématiqueSpecial problems arise in the evaluation of lateritic-type orebodies (Ni-Co, bauxite) or, more generally, orebodies affected by surface weathering. In this type of orebody, the vertical grade distribution shows, from the hangingwall downwards, a systematic increase followed sometimes by a certain decrease, or vice-versa. These trends appear together with irregular variations from one drill bole to the other.The problem is to characterize a vertical structure that is representative not only of the drill hole but of an entire panel or zone of influence, in order to define mineable thicknesses for given cut-off grades. The vertical grade distribution observed on the drillhole is replaced by a new curve, called &apos;derive&apos; (drift), which is computed by &apos;universal kriging&apos;.Once the vertical study is completed, new &apos;service-variables&apos; are defined in the horizontal plane, such as mineable thickness and the corresponding average grade, economical functions (combination of the grades of several minerals). The local and global estimation of these variables can then be performed by a simple bi-dimensional kriging plan. The global estimation is summed up by several tonnage-cut-off grade curves.The practical valuation according to the above scheme of a New Caledonian lateritic nickel orebody is presented."

Jan 1, 2014

By A. Melkumyan, M. Balamurali, J. Zigman

Understanding the contribution of geophysical variables is vital for identifying ore indicator regions. Both magnetometry and gamma-rays are used to identify the geophysical signatures of the rocks. Density is another key variable for tonnage estimation in mining, and needs to be re-estimated in areas of change when a boundary update has been conducted. Modelling these geophysical variables in 3D will enable investigation of the properties of the rocks and improve our understanding of the ore. The Gaussian Process (GP) was previously used to generate 3D spatial models for grade estimation using geochemical assays. This study investigates the influence of the following two factors on the GP-based autonomously generated 3D geophysical models: the resolution of the input data, and the number of nearest samples used in the training process. A case study conducted on a typical Hammersley Ranges iron ore deposit using geophysical logs, including density, collected from the exploration holes, is examined in this paper.

Sep 1, 2021

By P. E. L. Balestra, A. O. Filmer

The kinetics of the reactions involved in the non-oxidative dissolution of nickel concentrate in hydrochloric acid were studied by electrochemical and powder-leaching methods. It was found that the rate of non-oxidative dissolution increases with a cathodic shift in the mixed potential, which can be achieved by an increase in the nickel-to-sulphur stoichiometric ratio at the reaction surface. An unactivated concentrate with a sulphur content of 36 per cent exhibited a mixed potential of +O,3V (SCE) and could not be leached satisfactorily in 3 M hydrochloric acid at 60°c. When activated material (18 per cent sulphur) was leached, it had a mixed potential of -O,3V, and high iron and nickel extraction rates. Results reported by other workers on the non-oxidative dissolution of sulphides are explained in terms of the mixed potentials at which dissolution occurs.

Jan 1, 1981

"SAMPLING: THE IMPACT ON COSTS AND DECISION MAKING1. INTRODUCTIONFor years those in the minerals industry have been taking samples to assist them in making decisions; whether they be about investing billions of rand in a new mining operation, or simply whether a truck load of mineralised material should go to the mill or the waste dump, - we need a sample to help us make our decisions. This paper emphasises the importance and significance of sampling as a process, some of the associated technical problems and some of the advantages, especially in the light of traditional approaches that has usually left mine sampling to the least educated and lowest paid individuals on the mine. Perhaps the most important aspect that requires attention is the variability, usually measured in terms of precision, that tends to infect the sampling procedures. Francis Pitard 12 has stated: ""There is no such thing as reliable feasibility studies, unbiased ore grade control, accurate environmental assessments or effective process control, if you cannot identify and minimize the seven (ten) major sources of sampling variability. "" It is these ten sources of sampling variability and the way they arise that are briefly investigated. Variability is measured in terms of variances and rather than being self-compensating, there is good evidence to indicate that they are in fact additive at every step in the sampling and analytical process."

Jan 1, 2014

By R. Castro, R. Gómez, F. Betancourt, M. Moncada

In block cave mining, rock fragmentation is a key parameter that influences the production level design and mine planning. Fragmentation occurs mainly by natural breakage during the caving process and in the draw column. The breakage that occurs within the column is known as secondary fragmentation. Secondary fragmentation has been successfully described using the block caving comminution model, which replicates the fragmentation mechanics between particles under drawn and vertical loads in a draw column. This model is based on a kinetic and population balance approach, in which non-normalized and normalized assumptions can be used depending on material and comminution system behaviour. In this paper, the non-normalized and normalized approaches are applied and compared to laboratory data to determine which assumption should be used for secondary breakage in block caving. Approaches are compared graphically, with the mean square error and the Fisher test with a false-rejection probability of 0.05. Based on a statistical analysis, the results show that the normalized model can be applied to all the rock types tested.

Nov 1, 2021

By I. Soto, E. Córdova, A. Anani

The new caving megaprojects that are planned to go into production in the next decade have scheduled horizontal developments at very high rates, which are difficult to achieve. Research has been conducted that seeks to model the construction times for underground developments to determine the feasibility of achieving the planned rates. However, these previous attempts do not consider all the operational aspects that make up the mine development cycle. Here, we present a discrete event simulation (DES) model that individualizes each unit operation of the development cycle to determine the construction rates that new projects will be able to attain. The developed model was applied to the New Mine Level (NML) of the El Teniente Division (DET). The results indicate that it would be impractical to achieve the advance rates scheduled in the original plans if the unit operations of the mine continue to be executed using the status quo. The metres developed after six years in the sections analysed can be significantly improved by changing the maintenance strategy for the equipment (457 metres increase), orepass availability (194 metres increase), and the initial planning sequence (1 598 metres increase). It is recommended that the mine implements a flexible maintenance strategy, defines a strategy to ensure and increase orepass availability to contractors, and makes use of current simulation tools for a more robust development sequence planning.

Oct 1, 2022

By J. W. van der Merwe, C Strydom, D. C. Odendaal, M. I. Sampson

Keywords: Sphalerite, Bio leaching, Chemical leaching Sphalerite concentrates were prepared from tailings dam samples obtained from Rosh Pinah Mine in Namibia. The samples were subjected to froth flotation and concentrates containing between 7% and 14% Zn were prepared. Leaching of these froth flotation concentrates were studied in ferric chloride solutions at different Fe3+ concentrations for different times at different temperatures with the influence of other species on the kinetics in mind. Complementary to this research, GeoBiotics, LLC and Exxaro Resources have developed proprietary bioleaching technology for the oxidation of base metals concentrates using GEOCOAT bio heap leaching technology in a sulphate medium. The ferric chloride laboratory work was performed in a fluidising leach reactor. The studied material was obtained from flotation concentrate produced during an investigation into the recoverability of a tailings pile at Rosh Pinah mine in Namibia. The optimum conditions for the laboratory investigation were found to be a Fe3+ concentration of 0.3 mol/dm3 at 80°C. A control was performed by using synthetic zinc sulphide. GEOCOAT evaluation tests are performed for the purpose of evaluating the bioleaching of ore and flotation concentrates by means of mesophilic bacteria, Column tests were carried out on the flotation scavenger concentrate from Rosh Pinah to assess the application of the GEOCOAT® process for the oxidation of a low grade zinc concentrate. In this study an attempt was made to demonstrate the relationship between the Kinetic models and the experimental data by plotting the fraction of Zinc leached against time and applying the different equations to the data. The kinetic models were applied to the data obtained from both the test regimes. Habashi (1999) proposed that if a process is controlled by a chemical reaction at the interface (phase boundary controlled reaction), the following equation applies. kCt =1 ? (1-R) 1/3 Alternatively a process is controlled by diffusion through the product layer the following equation applies: [kt = 1 23- X (1 ? X) 2/3] As the anodic dissolution reaction progresses, reaction product forms either a more or less dense reaction product layer on surface As this product layer forms, a diffusion problem develops governed by the nature of the product layer. The conclusion from the study was that the kinetics is very dependent on the type of ore processed relating to the mineral composition of the ore body.

Jan 1, 2007

By D. Nardini

The need to move towards faster and safer mine development is a key priority in mining houses globally. In addition to this, South Africa faces an array of challenges introduced by labour-intensive operations; hence a study was conducted to look into improving development rates and labour productivity, specifically in the areas where trackbound flat-end development is required. The aim of the study was to propose a method to deliver fit-for-purpose tracked tunnels that advanced at a rate of one blast per end every single working day. A major part of the study was to optimize the selection of an appropriate trackless fleet and mitigate any constraints introduced with the mechanization. This was done by creating scenarios, based on a typical case study, looking into the aspects around safety, mine design, mine activity cycling, men and machine requirements, service installations, and trackless-trackbound interfaces. The case study was based on a deep-level gold mine developing twin headings with connectings; however, with the move to extend and deepen platinum operations it is foreseen that twin end development will become more prevalent due to ventilation, logistical, and other requirements. With the introduction of the trackless mechanized system suggested, development rates of 56 m of system advance are expected (189 m total development), with on an average of three headings and fixed blast times. Scenarios run with multi-blast conditions yield expectations of 75 m/month advance of the system, significantly higher than the conventional performance seen today.

Jan 1, 2012

By R. Dehghan, M. Zarei, A. Tohry, S. C. Chelgani

Typical depressants for selective reverse flotation of iron oxides from complex silicates do not generally show high levels of efficiency. Therefore, as a hot topic, there are several ongoing investigations in this area. The main aim of this paper is exploring the potential of using humic acid (HA) as a depressant in reverse cationic flotation of hematite from complex silicates. For such a process, the wettability and flotation behaviour of pure minerals (hematite and silicates) was investigated at pH 10 in the presence of HA and cationic collector. Adsorption mechanism of HA on these minerals was measured by zeta-potential and FTIR. Results of flotation tests showed that at the lower concentrations of HA, selective separation of silicates from hematite is beneficial, where the floatability of amphibole was higher than pyroxene. A higher separation efficiency of hematite through reverse flotation was observed in the presence of amphibole, in comparison with the presence of pyroxene. Wettability studies showed that HA has a significant effect on reducing the hydrophobicity of treated minerals with the collector. The adsorption, ZPC and FTIR test results indicated that HA was adsorbed on both silicates and hematite. However, the absorption intensity onto hematite was much higher than silicates. It was found that the adsorption mechanism of HA on hematite takes place through both strong H-bonding and ligand exchange. Keywords: Reverse cationic flotation, humic acid, iron oxide, complex silicates, surface adsorption

Jan 1, 2020