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By R. Pretorius, N. Mautsa

In a cobalt precipitation plant, phosphoric acid is used to eliminate excess uranium from the pregnant leach solution, resulting in a cobalt hydroxide product that has little uranium contamination. However, the amount of phosphoric acid added must be monitored and controlled to avoid financial and sustainability impacts and to prevent negative impacts on the final product quality. One possible solution to this problem is the use of online residual phosphorus measurement techniques to regulate the addition. By continuously monitoring the residual phosphorus levels in the solution, the plant can adjust dosing in real time to maintain the target residual phosphorus level. As a result, the cobalt precipitation plant can improve phosphorus level control, lowering the risk of overdosing, and ensuring consistent product quality. This approach can also improve process efficiency, reduce operational costs, and have a positive environmental impact

Jan 1, 2023

The June General Meeting of the Institute was held in Kelvin House, Johannesburg, on 18th June, 1969, at 4.30 p.m. Mr J. K. E. Douglas (Vice-President) was in the Chair. There were also present fourteen Members, Messrs R. J. Adamson, F. P. Bath, D. M. Jamieson, D. G. Maxwell, Dr J. T. McIntyre, and Mr P. W. J. van Rensburg (Council Members), Messrs B. F. Berry, A. F. Lee, J. E. van Leeuwen, G. G. Nicolson, N. F. Peverett, Dr A. G. Raper, Messrs E. R. Rudolph and H. R. Reid. Five Associate Members, Messrs T. D. Brown, M. R. Fuller-Good, J. S. Freer, Dr P. R. Jochens and Mr D. A. Viljoen. One Graduate, Mr P. G. Mrkusic. Five Students, Messrs N. A. Barcza, J. A. Cruise, R. P. W. Henrard, D. I. Ossin and J. C. M. Wethmar. Nine Visitors, Messrs M. Badenhorst, N. J. Bovey, H. H. Herold, Dr H. J. S. Kriek, Messrs M. S. Rennie, B. B. Segal, S. Selmer-Olsen, O. A. W. Strydom and B. Yates. Secretary, Mr D. C. Visser. Total present: Thirty-six. MINUTES The Vice-President: "May we confirm the minutes of the Monthly General Meetings held on 24th March, 16th April and 21st May, 1969 as published in the Journal?" Agreed. MEMBERSHIP The Vice-President: "I have much pleasure in announcing that the names of the undermentioned candidates having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades: Members: Wilfred Desmond Morgan, Abraham Kriek. Associate Members: Rodger Neville Hampson, Robert Richard Booth Lodge. Graduates: Beverley Hugh Waiters, Gwynne Hugh Johnston. Students: Colin Edward Alvery, Peter Marthinus Haikes, Charles Aubrey Husband, John Nowell Randell, Frederick Johannes Jacobus Blaauw, Johannes Andries Breytenbach, Peter Vos, Frederik Hendrik Coetzee, Petrus Nicolaas Jacobus Smit, Patrick Alien Boardman, Robert Nelson Guest. "May I welcome the newly elected members to the Institute." (Applause.) ELECTION OF SCRUTINEERS FOR THE 1969-70 BALLOT FOR COUNCIL The Vice-President: "In terms of By-Law 9.4, I now call for nominations for scrutineers for the 1969-70 ballot for CounciL" P. W. J. van Rensborg: "I wish to nominate Messrs R. C. J. Goode, V. C. Robinson, J. K. E. Douglas, P. Lambooy, D. G. Maxwell, H. Britten and H. Simon as scrutineers."

Report M294 A mineralogical investigation of potential gold-sorbing minerals and shales, by c.T. Logan. Dec. 1986. 12 pp. Computer software The Fifth IFAC/IFIP Symposium on Software for Computer Control (SOCOCO 88) is to be held in J ohannesburg from 26th to 28th April, 1988. Tunneling 88 The Institution of Mining and Metalurgy, with the cooperation of the British Tunneling Society, the Institution of Mining Engineers, and the Transport and Road Research Laboratory, Department of Transport, is pleased to announce the fifth international symposium, Tunneling 88, which wil be held in London, England, from 18th to 21st April, 1988. Ion-exchange processes ION-EX '87, an international conference and industrial exhibition on the industrial, analytical, and preparative applications of ion chromatography and ionexchange processes, wil be held in Wrexham (North Wales) from 13th to 16th April, 1987.

Jan 1, 1987

By Nicolle Krusberski

Potential errors in XRF analysis are discussed and investigated with specific reference to the analysis of ilmenite samples. A selection of ilmenite samples was chosen and prepared using two XRF preparation techniques: pressed powder pellet and unroasted fusion bead. The merits of the two methods have been discussed in this paper for ilmenite analysis by XRF. Recommendations have been made regarding the use of pressed powder pellets especially with regard to the mineralogical effects that were evidenced during this investigation. The fusion bead technique was found to be far more accurate and able to meet short turnaround requirements provided the calibration methodology used is specific to the grade of samples analyzed.

Jan 1, 2014

COUNCIL AND STANDING COMMITTEES, 1974-1975 Office Bearers : Prof. R. P. Plewman (President), Dr R. E. Robinson and Dr M. D. G. Salamon (Vice Presidents), J. K. E. Douglas (Honorary Treasurer), and P. W. J. van Rensburg (Immediate Past President). Elected Members of Council: Dr M. G. Atmore, E. Collier, G. H. Grange, Dr P. R. Jochens, Dr D. I. Legge, D. G. Malan, C. T. Shaw, L. W. P. van den Bosch, D. A. Viljoen, H. M. Wells, P. A. von Wielligh. Branch Chairmen: B. T. Hosking (Witbank-Middelburg Branch), D. A. Smith (Orange Free State Branch). Past Presidents Serving on Council: R. J. Adamson, M. Barcza (until May 1975), H. Britten, H. E. Cross, Prof. J. de V. Lambrechts (until December 1974), R. C. J. Goode, Prof. D. D. Howat, Dr J. P. Hugo, D. M. Jamieson, D. G. Maxwell, Dr J. T. McIntyre, V. C. Robinson. Ten Council meetings were held during the year, with an average attendance of 19, and the standing and sub-committees held 74 meetings. COMMITTEE CHAIRMEN Membership, Dr M. D. G. Salamon; Technical Programme-Metallurgy, D. A. Viljoen; Technical Programme-Mining, G. H. Grange ; Vacation School-Metallurgy, Dr P. R. Jochens; Vacation School-Mining, Dr M. D. G. Salamon; Awards, Prof. R. P. Plewman; Excursions, Dr D. I. Legge; Constitution, Rules and Policy, P. W. J. van Rensburg and Prof. R. P. Plewman; Mines and Works, P. A. von Wielligh; Education, P. W. J. van Rensburg. REPRESENTATIVES ON OTHER BODIES Associated Scientific and Technical Societies Members: V. C. Robinson and Prof. R. P. Plewman. Alternates : Dr R. E. Robinson and Dr M. D. G. Salamon. Federation of Societies of Professional Engineers Members : J. K. E. Douglas and P. W. J. van Rensburg. Alternates : Prof. R. P. Plewman and G. H. Grange. South African Council for Professional Engineers Member : R. C. J. Goode. Alternate : G. H. Grange. Engineers' Liaison Committee (Pretoria) Member: Dr J. P. Hugo. Alternate: P. W. J. van Rensburg. MEMBERSHIP Thirteen Fellows, seventeen Members, eleven Graduates, three Associate Members, eighteen Associ¬ates, twenty-six Students, and one Company Affiliate were elected during the year. Nine Fellows, four Members, and three Associates were admitted to retired membership. Eight Fellows were elected to Honorary Life Membership. Three Members and one Graduate were transferred to Fellows, nine Graduates and two Students to Members, six Students to Graduates, one Student to Associate, and one Associate to Associate Member. Six Fellows, ten Members, three Associates, and one Student resigned. A statement of membership as at June 30th 1975 and the end of the previous year is shown in the following tabulation: 30th - 30th June, - June, 1974 - 1975 Honorary Life Fellows - 9 - 15 Honorary Fellows 8 - 8 Life Fellows 170 - 170 Fellows 544 - 536 Members 512 - 523 Associate Members 10 -15 Graduates 130 - 133 Associates 194 - 210 Students 173 -175 Company Affiliates 70 - 71 1 820 - 1 851 [ ] OBITUARIES Your Council records with deep regret the death during the year of the following members: M. Barcza, Honorary Life Fellow and Past President of the Institute; J. A. Boyd, F. E. Keep and J. H. Taylor, Life Fellows; I. D. B. Corner, C. O'G. Deane, R. E. Gilmour, A. C. Hofmeyr, M. W. Howell, T. J. Robin and F. C. Steinhobel, Fellows; J. J. Frankel, Member; T. J. Higgs, Associate. FINANCE The annual accounts, which follow this report, indicate that income again exceeded expenditure by a margin of R21 410 (last year R28 524). This year's income of R71 184 showed a further increase compared with last year's figure of R55 025. Costs, however, also in¬creased, and it is calculated that, excluding non-recurrent costs, the cost of running the Institute in¬creased by R6 654 from R25 501 to R33 155 for the current year. The main increases were involved in secretarial fees, stationery and print¬ing, and in publication of the Journal. All indications are that costs will continue to rise, and we have been advised that the A.S. & T.S. will be increasing their secretarial fees by 25 per cent in the year ahead to meet their rising costs. This year's surplus was derived entirely from the revenue from sales of publications (R13 644) and a surplus from the 1974 Winter School (RIO 654). There can be no certainty that revenue from these sources can be repeated each year. Our funds are in a satisfactory position because of these worth¬while activities, but the administrat¬ion of the Institute should not de¬pend on them. Council will accord¬ingly have to give consideration in the year ahead to an upward adjust¬ment of subscriptions to meet rising costs.

Jan 10, 1975

1. Book review Steels- microstructure and properties, by R. W. K. Honeycombe. London, Edward Arnold, 1981. 244 pp. Rl9,90. (Reviewer: P. T. Wedepohl) 2. New books Decision making in continuous steel casting, by Mark A. Vonderembse. New York, Bowker Publishing Co., 1981. U8 pp. Handbook on continuous casting, by E. Herrmann' Diisseldorf, Aluminium-Verlag GmbH, 1980. 742 pp. Cloth DM 1250, leather DM 1500. Pore structure analysis from a nitrogen adsorption study of porous materials using a volumetric method. User's guide to the FORTRAN programs: PORESl and PORES2, by E. G. K. Woods. Pretoria, CERGCSIR (P.O. Box 395, Pretoria 0001), May 1981. Oil and gas from coal, by Dick Olliver. London, Financial Times (10 Cannon Street, London EC4P 4BY), 1980. £120. The seventies: a review, the eighties, a preview, by W. Hibbard (editor). Oxford, Pergamon, 1981. 120 pp. £12.50. Computers in materials technology, by T. Ericsson editor). Oxford, Pergamon, 1981. 230 pp. £14.50.

Jan 1, 1981

By M. Asghari, R. Amiri, A. Haratian, M. Noue Parast, S. Haji

Today the roller screen has a wide range of applications in the steel-making industry. It is used for screening of green pellets before using the kiln. Since the appropriate size of a green pellet is -16+9 mm, there are different gaps between rollers that make green pellets classified in three categories: -9 mm (undersize), -16+9 mm (onsize) and +16mm (oversize). The efficiency of a roller screen is specified according to the weight percent of undersize in onsize as a fine material, and weight percent of onsize in oversize (loss). This efficiency is influenced by different operational parameters such as roller diameter, roller speed, and roller gap, material type of rollers and inclination of roller screen. This study investigates the effect of different material types of rollers in efficiency of Ardakan roller screens, located in the Yazd province of Iran. The rollers of the existing roller screens in this pelletising plant are made of polyurethane which according to this investigation, has a maximum lifetime of about six months. Operating the polyurethane rollers beyond its lifetime generates serious problems such as high wear of rollers, and consequently, material buildup on the roller surface which then significantly decreases the roller screen efficiency. So, after examining different roller materials, stainless steel 304 with higher surface roughness to help pellets move properly on the roller screen surface was selected as a solution to this problem. The new roller screen was constructed by Fakoor Meghnatis Spadana (FMS) and replaced the previous one. In this way, the maximum capacity of the roller screen was increased about 17% and the roller screen efficiency was increased about 15%. Keywords: Roller screen, green pellets, efficiency, onsize, operational parameters

Jan 1, 2020

By G. C. Lindeque

"A downward trend in tyre life on haul trucks at an open pit iron ore mine prompted an investigation into the current tyre management strategy in order to improve tyre life. ‘Best practice’ was compared to the current tyre management strategy at the mine to determine aspects that could be improved. Aspects that showed significant room for improvement included employee tyre awareness, tyre pressure maintenance, and road conditions. For each of these aspects a plausible alternative was suggested.A new tyre management strategy was formulated as a step-by-step guide on how to implement the proposed changes. Each step introduces new initiatives but at the same time builds on the previous step’s success. A sensitivity analyses was performed to determine the impact of the proposed changes, with the variables being the reduction in the percentage of premature tyre failure, and the reduction of the site wear rate.The ‘most likely’ scenario showed an increase in tyre life of 41% for the Komatsu 730 trucks and 105% for the CAT 777 trucks if the entire tyre management model is implemented. This would result in a possible annual saving related to tyre usage of R9.2 million. OverviewThe study focused on the tyre life on the main haul fleet at an open pit iron ore mine. The haul fleet consisted of 17 Komatsu 730 (180 t) haul trucks and 12 CAT 777 (90 t) haul trucks.The haulage operation consists entirely of tyre-based haul trucks. Five per cent of the total mining budget is related to tyre costs. Since 2012 there has been a steady decrease in tyre life as measured in operating hours (Figure 1) due to the high percentage of tyres that fail prematurely. In 2014 a total of 41% of all tyres failed prematurely and 61% were classified as ‘worn out’."

Jan 1, 2016

By M. de Paiva Bueno, G. Barakos, S. Luukkanen, K. Luolavirta

Lifelong development of skills and knowledge of mining professionals has been recognised worldwide as a challenge for the development of a sustainable mining sector. Practical training and learning over the mine value chain are among the key components of this knowledge building. However, the number of available mining sites for continuous education in real-life conditions is limited; also the specifications for practical training are not clearly defined. The project MINETRAIN was developed to (i) evaluate the potential of the shortly-closing Pyhäsalmi Mine, in Finland, as an educational and training underground facility, and thus, prolong the utility of the existing modern mine site, and to (ii) develop and test practical training programs for mining and mining industry related professionals. Pyhäsalmi facilities enable training among all disciplines related to the overall mine value chain and hence, the project has potential in providing education for sustainable management of any phase of mining operations. The philosophy underpinning the MINETRAIN approach to mining activities is to assist the clients in minimising the technical and financial risks by providing a competitive and skilled personnel asset while optimising the value drivers in their operations. As a first major step of the project, a pilot training course, involving basic-level online theory and hands-on training at the Pyhäsalmi mine site, was undertaken in summer 2019. Feedback from the pilot test group of mining professionals has proved to be very positive. The comments from the participants strongly emphasised the added value of the practical onsite training for improved understanding in the large scale picture of mining on the entire value chain. As a second phase of the project, a new test course was launched in June 2020. The second MINETRAIN course focuses on new technologies and digitisation in mining. Keywords: Lifelong learning, mining education, mine value chain, research and education mine, educational research project

Jan 1, 2020

By B. S. Agbenuvor, R. Morrison, V. Jokovic, C. Antonio

Body breakage usually involves breakage of particles by compression between two surfaces or impacted against a rigid surface, with the latter of interest in this current study. This mode of breakage has been identified to be the most elementary size reduction process and the most effective breakage process in comminution devices. It has been found in the literature that the progenies produced from this form of breakage possess a residual velocity at which they move, after the breakage event. In the pursuit of efficiently utilising applied comminution energy, a laboratory-scale breakage device has been developed to deliver precise specific impact breakage using the concept of a fast-moving hammer and a slow-moving particle to effect breakage. The residual velocities of the progenies from the breakage event may be used to generate secondary breakage without further addition of energy if the particle encounters a stiff obstacle such as a steel plate at right angles to its path. To measure the extent of secondary breakage, the steel wall of the device was lined with a rubber material to suppress the second set of breakage events. The performance of the new device is analysed, based on calculated t10 values and measured residual velocities of the moving daughter particles. Testing involving anvils showed a much finer PSD and higher t10 compared to the test involving rubber lining. This finding is corroborated by the measured residual velocities of the progenies. The resulting energies calculated from the measured residual velocities of the progeny were found to be approximately 42-88% of the primary specific impact energy. This retained energy was found to be sufficient for secondary breakage. Keywords: Impact breakage, residual velocity, secondary breakage, energy utilisation

Jan 1, 2020

By J. E. Gebhardt, B. Temel Mckenna, W. Lee, C. S. Macomber

X-ray diffraction (XRD) data was extracted from various sources to develop qualitative ternary and tetrahedral plots differentiating mineralogy, bond work index (BWi) and hardness of ore bodies at different mine sites. A large number of historic reports and compiled characterization laboratory data were used to create a searchable "data lake." The data lake provides a means to locate, consolidate, and visually represent XRD from disparate sources. Visualizations with large amounts of mineral ore XRD characterization data provide a qualitative assessment of ore properties, including comminution qualities such as material hardness. The visual map can be employed to quickly estimate expected ore character and behavior, given XRD analysis of samples from newly characterized and unfamiliar ore. Keywords: Mineralogy, Characterization, Comminution, Database, Ternary, Tetrahedral

Jan 1, 2020

By M. Onifade, B. Genc, P. O. Akinseye, M. Fourie, K. O. Said

Coal is mined by both surface and underground methods and its extraction is normally characterized by numerous hazards that can lead to catastrophic accidents, which result in devastating effects such as injuries or fatalities, damage to mining assets, and destruction of mineral resources. These hazards exist due to the ability of coal to support combustion and its association with toxic, flammable, and explosive gases. Underground coal mining entails higher safety risks than opencast coal mining, chiefly because of issues relating to mine ventilation and mine collapse. Furthermore, coal mine collapses mostly occur due to crumbling of mining supports, especially in room and pillar mining systems. To avoid such adverse occurrences, safety management systems need to be in place. This study reviews the various technological safety systems and principles that are used for safe-rescue and self-escape of miners in underground coal fires, particularly in South Africa, using data obtained from Mines Rescue Services in Carltonville, South Africa. The outcome of the review shows that practising safety culture has been given priority across many South African underground coal mines through setting up safety management systems and encouraging workers to stay committed to safety principles.

May 2, 2022

By A. W. S. Schumann

A. W. S. Schumann The first reason for todays success lies in the very high standard which was set by our speakers today and I think that we owe a very special vote of thanks to Messrs P. M. C. Wilson, A. A. Oakes, M. J. Deats, A. C. Coetzee, R. E. Burnton and J. G. Ferguson. This, however, cannot account for the fact that there was a tremendous response even before anyone knew who was going to speak or what they were going to speak about. I suggest that the response was enthusiastic because people expected a more informal gathering with a greater opportunity for feedback, for an exchange of views and for questions and answers. The very popularity of the idea has defeated its own ends to some extent. This gathering is too big and many people must have been left with questions unanswered. Possibly one should arrange for a number of meeting places-there are many in the Chamber and the surrounding mining houses-and then have separate meetings in the morning with joint reporting session in the afternoon. Alternatively, we could have a symposium after the colloquium, using Webster's definition of a symposium as as 'a drinking party of merry fellows'. We all know that it is easy to discuss mining into the small hours. Obviously one cannot summarise todays papers and discussions, but I would like to make a few comments on technical matters and after that I would like to speak for a moment about what I see as major trends or tendencies which arise from discussions of this nature. Regarding the question of placing a village on a mine or away from a mine, I would mention that there is quite a body of literature on the adverse sociological effects on the development of children in any community in which the great majority of parents share the same occupation. It is something to be avoided if possible. We discussed the concept of the moving stockpile. If this is proved to be successful, it could save a considerable amount of money for Escom who could then avoid the construction of very large and costly staithes which are now regarded as parts of power stations. One does not see why both a moving stockpile and a staith should be necessary. By the way, speaking of Escom, I see that Mr Bob Scott is here; he has stopped pulling my leg by saying that we sell stone to Escom; perhaps someone has told him that if this is true, it must be the cheapest stone you can buy in this country. My next point relates to the use of epidiascope. It struck me again that this instrument which provides a visual image to accompany your message, can be very effective if it is properly used. These papers speak of a great deal of hard work which went into their preparation, and one really feels that the authors should have taken a few minutes more to prepare their drawings specifically for the epidiascope. There should be nothing on the drawing which is not necessary to illustrate a particular point and there should be nothing on the drawing which is not visible from the back of the hall. In particular, if one cannot read the figures along the sides, then one

By H. Laitala, M. Lampi

Metso Outotec has developed a wide range of solvent-extraction technologies over decades and has introduced Metso Outotec VSF®X solvent-extraction plant. Standardized and modularized, Metso Outotec VSFX Plant provides a novel way to design, manufacture, transport, install, operate, and maintain solvent-extraction plants far better than in the past with highly sustainable and safe methods. For the customer, this means fast-track projects with savings in means of time, costs, quality, and operation. Sicomines and Metso Outotec have together implemented and commissioned a modern and efficient copper solvent-extraction plant. Plant commissioning and ramp up of the plant were fast and the plant is now operating efficiently. This paper presents Sicomines’ VSFX copper solvent-extraction project and gives a sight into operating figures for the plant.

Jan 1, 2023

By A. Rödfalk, P. Bloemer, J. P. Nilsson, N. Brogden

"Reliable and accurate metal transfer information during silicon tapping from an EAF is invaluable for decision-making and process optimization, while obtaining such information safely is a necessity.Elkem Thamshavn Norway, a producer of metallurgical-grade silicon, identified inherent safety problems with gauging fill levels in ladles using dip bars while molten metal was continuously pouring from a rotating EAF. Operator safety was a paramount concern, and an alternative automatic method of controlling the tapped fill level needed to be found.It was also considered that further benefits could be achieved such as monitoring the tapping flow from the EAF in order to identify any clogging, as well as the potential to use the live feed from such a system to assist decision-making regarding work around the taphole area.Agellis Group AB, Sweden, a company with over 30 years of experience in gauging molten metal levels in the metals industry, was able to design a solution for Elkem Thamshavn that would provide the required real-time process data while enhancing operator safety.This paper shows how the Agellis AB EMLI-L system was successfully installed at Elkem Thamshavn’s EAF continuous tapping area, how ladle fill levels were constantly monitored, and how full ladles were replaced by empty ones without the need for operators to be in the tapping area to take level readings. The results were used to compare the accuracy and reliability of Elkem Thamshavn’s current measuring methods with that of the EMLI-L system. The paper also covers how problems such as how to connect, run, and protect cables in and around the EAF tapping area, as well as connector and cabling survivability during the three day refractory pre-bake period, were solved. Finally, the paper discusses the potential production improvements, maintenance requirements, and data integration attainable through the installation of the system, as well as the major safety improvements that have been achieved."

Jan 1, 2014

By H. Jiang, W. Wang, Y. Zhao, Q. Jinpeng, C. Duan

Dry deep screening is an important method of classifying moist fine mineral. The rigid-flexible coupled elastic screening technology can simultaneously solve the problem of traditional screen surface plugging and the low service life of a screen surface in the process of deep screening. In this paper, two kinds of rigid-flexible coupled elastic screen surfaces were introduced. The structural characteristics of a screen surface were studied. The mechanism of a rigid flexible coupled elastic screen surface to overcome hole blockage was revealed. Finally, 3 mm and 6 mm screening experiments were carried out. When the external moisture content was below 12.79% for the 6 mm dry screening experiment of elastic rod screen surface, the screening efficiency was above 81%. When the external moisture content was below 11.31% for the 3 mm dry screening experiment of elastic screen surface based on ball hitting, the screening efficiency was above 83%. Keywords: Moist fine mineral, rigid-fexible coupled, elastic screening

Jan 1, 2020

By X. Zhang, E. Li, Y. Xiao, Z. Yu, H. Han, J. Xie, J. Tian, W. Sun, K. Hong

In a pulp environment, the surface properties of magnesite and dolomite tend to be similar, due to the re-adsorption of dissolved calcium species, which makes the flotation separation difficult. In this paper, the chelating reagent EDTA is introduced to eliminate the adverse influence of the calcium species and to restore the selectivity of magnesite-dolomite separation using sodium hexametaphosphate (SHMP) as a depressant. Flotation experiments confirm that the recovery of magnesite improves significantly in the presence of EDTA. Zeta potential experiments confirm that the negatively charged EDTA4+ and HEDTA3+ species can form soluble and stable chelates with positively charged Ca2+ and Ca(OH)+ species preventing their adsorption on the magnesite surface. Adsorption measurements prove the addition of EDTA can decrease the adsorption of depressant SHMP on the magnesite surface. X-ray photoelectron spectroscopy (XPS) measurements further confirm the transformation from the surface of magnesite to dolomite in the presence of calcium ions, and the possible adsorption mechanism of EDTA and SHMP on the magnesite and dolomite surface. Key words: Magnesite; Dolomite; Surface dissolution; Flotation separation

Jan 1, 2020

By Y. Ren, B. Yang

The magnetic field characteristics due to electromagnetic stirring in the secondary cooling zone of an extra-thick slab during continuous casting are numerically determined using Maxwell's equations, with particular emphasis on the distribution of magnetic induction intensity and electromagnetic force, as well as the influence of process parameters on the magnetic field. The orientation of the electromagnetic force is the same when the electromagnetic stirrers at the 30° and 60° posistions of the arc-shaped slab are powered in the same direction; otherwise, the orientation is opposite. The magnetic induction at the centre of the section of the stirrer's central axis at the 30° positio, as well as the current, frequency, and fitting formulae, are as follows: B = {0.075I.(1/A)-0.3} mT and B = {-1.75f.(1/Hz)+22} mT. The electromagnetic force and current fitting formula at the central point of the B-B section is F = {0.03168I2.(1/A2)-03.762I.(1/A)+326.7} N/m3, and the fitting formula of electromagnetic force and frequency at the centre point is divided into two segments. The first takes the form of a parabola: = {-21((f-4.3).(1/Hz)2)+970} N/m3, and the second segment is negative linear: F = {-1.65f.(1/Hz)+51.5} N/m3.

Apr 16, 2024

Book review Proceedings of the Symposium on Mining Methods. London, Institution of Mining and Metallurgy, 1974. 160 pp. The Symposium was held from 30th October to 1st November, 1974, and the papers include an interesting range of subjects in coal-mining operations, covering the improvements achieved to date, current practice, and required development for the future. Salamon, M.D.G., and Oravecz, K. 1. Rock Mechanics in Coal Mining. 119 pp. NIM reports Report no. 1822 Stability constants and linear free-energy relations for the platimtm-group metals. (22nd Oct., 1976). Report no. 1852 A revised method for the dissolution of platiniferous materials by the sealed-tube technique. (18th Oct., 1976). Report no. 1828 y-picoline adducts of the nickel, copper, and zinc chelates of 2-thenoyltrifluoroacetone. (26th Nov., 1976) Report no. 1847 A pilot-plant investigation of a kinetic model for flotation.(19th Nov., 1976)

Jan 2, 1977

By L. A. Cornish, J. W. van der Merwe

"The hydrofluoric acid (HF) industry in South Africa uses normalized mild steel (SA 516 Gr 70) for the storage and distribution of its technical-grade product (70% HF). The technical-grade acid is split from the anhydrous hydrogen fluoride (AHF) product during distillation just after HF is produced, in a stainless-steel-lined kiln, from the reaction of calcium fluoride (CaF2) with sulphuric acid (H2SO4). Uniform corrosion of the storage tanks is mitigated during commissioning by contacting the steel with 70% HF. A corrosive reaction takes place (2H+ + 2F- + Fe - H2 + FeF2) to form scale inside the tank which diminishes the attack of the steel by fresh HF, thus prolonging the service life expectancy of the vessels. This iron fluoride scale in the vessel grows continually, resulting in corrosion of the vessels continuing at a predictable rate (approx.0.5 mm/a) since the first commissioning of the tanks at Necsa in 1993. In early 2012, an increase in the average corrosion rate of the tanks to 3 mm/a measured at and below the liquid band in the storage vessels was noted. Three months later the corrosion rate had increased to 30 mm/a, just before the first leak from the tank was detected. The tanks were decommissioned shortly afterwards and an investigation revealed that the rapid corrosion was due to the presence of increased levels (>50 ppm) of nitric acid (HNO3) in the tanks, which attacked the fluoride layer protecting the steel.The oxidation characteristics of high concentrations of HNO3 with low concentrations of HF on stainless steel surface treatment are well documented. The effects of low levels of nitric acid on the corrosion of steels in sulphuric acid are also known, but no suitable published data currently exists on corrosion by high HF concentrations with low HNO3 concentrations. Establishing the rate and mechanism of corrosion by HNO3 (0.1 to 1%) in 70% HF is currently a high priority for the HF industry in South Africa and will become increasingly important in the near future due to depleting fluorite reserves and cheaper, but less efficient, processes producing H2SO4 with higher impurity levels, which were not anticipated in the original plant design. The aim of this study is to simulate the corrosion conditions in the plant on a laboratory scale in order to establish the corrosion characteristics of the steels used in the HF plant, which are increasingly exposed to the HNO3 impurities that tend to concentrate in the final technical-grade HF acid product."

Jan 1, 2016