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By A. G. Kim

Coal formation begins in peat swamps or bogs, in which microorganisms alter plant material and initiate the formation of carbonaceous sediments. Methane, which constitutes about 98 percent of the hydrocarbon gas in coalbeds, is known to be a product of anaerobic microbial metabolism. To determine if other hydrocarbon gases could be produced in an environment similar to that of a swamp, samples of wood cellulose and lignin were inoculated with soil micro-organisms and incubated anaerobically. The resultant gases included methane, ethylene, propane, propylene, butanes, pentanes, and carbon dioxide. Hydrogen was also produced from the wood samples during the first month of incubation. Over 90 percent of the produced gas was methane; C02 was the other predominant component. Concentrations of all other hydrocarbon gases ranged from l to 20 parts per million, approximately 0.1 percent of the total hydrocarbons, which was less than the concentration in coalbeds. Therefore, although higher hydrocarbons could be produced in a swamp environment, subsequent mechanisms, either concentration by adsorption or formation during geochemical reactions, must affect the final concentration of higher hydrocarbons in coalbeds.

Jan 1, 1972

By W. S. Wright

"INTRODUCTION The Ward copper deposit was brought to the attention of the Bureau of Mines in September 1943 by John J. Knob, 217 E. Penn Street, Long Beach, N. Y. At that time all Bureau of Mines work on Seward Peninsula was being directed to the exploration of deposits of tin, a metal high on the strategic list. It was not until September 1946 that the Bureau could make a preliminary examination of the Ward prospect.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative work, and prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiation tests.Acknowledgment is extended to Robert S. Sanford, acting chief of the Alaska division, under whose supervision all exploratory work of the Territory is conducted."

Aug 1, 1947

Decrease dust concentra¬tions of longwall face workers by keeping them up¬wind of the headgate stage loader and crusher. Approach Direct the face airflow from tailgate-to-headgate, the direction of coal transport. How It Works Ventilation is the primary method of dust control on longwall faces, and the most effective ventilation control is to put workers upwind of dust sources. Recent ad¬vances in longwall dust sampling by the Bureau have shown that on some faces, the headgate crusher and transfer points are signifi¬cant sources of dust -some¬times making up more than half of the total dust to which the face workers are exposed. Also, when the air is coursed from head-to-tail, the relative velocity between the air and moving coal on the face conveyor can cause dust entrainment from the conveyor, particularly if the coal is dry. On the faces where these dust sources are a signifi¬cant problem, they may be eliminated by coursing the air from tailgate-to-headgate, provided that the mine roof is stable enough to permit the necessary intake of the tailgate along with an aux¬iliary intake at the headgate.

Jan 1, 1982

To reuse chromium, nickel, and molybdenum now lost in stainless and specialty steel-making wastes, and simultaneously to overcome the current environmental problem resulting from landfilling these wastes. Approach A variety of stainless and specialty steelmaking wastes are agglomerated and recharged into the plant's electric arc furnaces. How It Works Stainless and specialty steel-making wastes such as bag-house dust from the electric arc furnace, dust from the argon-oxygen decarburization unit, grinding swart, and mill scale are blended in proportion to the ratio in which they are generated. Next they are agglomerated on a pelletizer with an addition of a small amount of carbonaceous reducing agent, and air-dried in preparation for being recharged into the furnace. Some mixtures of wastes tested in the laboratory required the addition of binders and/or the use of ovens in lieu of air-drying to produce sufficient pellet strength. Although the optimal maximum particle size of wastes being pelletized is 35 mesh, somewhat larger particle sizes were satisfactorily pelletized during in-plant tests. The photograph shows a typical mixture of wastes and the pellets made from them.

Jan 1, 1981

Design a new acoustic monitoring system to more accurately forecast impending rock bursts, and to assist in understanding the rock burst phenomenon. Background Rock bursts arc the major cause of injuries and deaths in deep underground mines in the Silver District near Wallace, ID. Bureau investigations of the rock burst phenomenon resulted in significant improvements in computerized acoustic technology, and achieved limited success in forecasting several large events. Research demonstrated that the location of rock noise, and the rate at which these events occur, are indicators of areas that could fail violently. In minewide monitoring, the typical array of acoustic sensors (geophones) is arranged to cover an entire mine with 16 to 32 separate instruments. The mines intended to be covered may be 7,000 feet in depth and up to several miles in extent. While such an arrangement is capable of detecting and locating large seismic events (rock slippage along natural fractures or faults), the geophones are too far apart to accurately locate mining-induced events at the active workplaces. The Bureau devised a strategy to concentrate the geophones into typical slopes (mining areas about 200 by 500 feet) to record the rock noise in areas where the miners work. By using such a dense geophone array at a mine, the Bureau provided event location and rate information to mine operators who removed workers and ceased production from active mine areas that subsequently suffered rock bursts.

Jan 1, 1989

This report describes magnetic field measurements in the Helvetia Coal Co. Lucene #8 Mine for purposes of deriving a mapping of the magnetic field strength covering the major haulageways which contain conductors. The measurements were performed by Terry S. Cory, P.E. under U.S. Bureau of Mines purchase order P0372716. Assisting in performance of the measurements were personnel from the Bureau of Mines, PMSRC, and Helvetia Coal Co. Acknowledgement is given to Engineer Tom Strong of Helvetia Coal Co. who accompanied the measurement team and who lended support in performing the measurements and in supplying valuable engineering information for use in evaluation of the results. The results of the testing at medium frequency show that coverage of the entire mine area containing conductors can be achieved employing wireless radio techniques whereby radio signals are coupled into and are carried by these conductors. These results confirm earlier qualitative testing of the Collins Mine Wireless Radios in this mine. These results, performed over the frequency range 71-2890 KHz, illustrate the effect of frequency on the radio propagation with the conclusion that the best overall coverage is obtained at frequencies approximating 1000 KHz. This report presents all the raw data and the reduced data in the form of magnetic field strength contour maps. Sufficient information is provided to enable independent reduction of the data. A summary of observations which can be made directly from the contour maps is given.

Jan 9, 1977

Prevent the explosion of methane gas or coal dust by replacing air with inert gas inside highwall mine excavations. Approach Use combustion gases as a source of inert gas with low oxygen content to blanket the cutting, head of highwall mining machines. This gas is placed strategically at the collar of the excavation where it enters the hole to replace the mined coal volume. The elimination of oxygen from the hole prevents explosions of gas or dust. How It Works Highwall mining methods arc used when surface mining becomes uneconomical. One method of highwall mining involves use of a horizontal auger to enter the coalbed from a surface mine bench. The coal is mined in a series of horizontal, parallel, and large-diameter holes. Historically, little methane has been associated with auger mining. However, mining technology has extended the reach of auger mining, which can increase the occurrence of methane. Methane explosions at auger mining operations have been increasing. Methane has been the primary fuel source of these ignitions, but coal dust also may have been involved.

Jan 1, 1993

By Rollien R. Wells

A REPORT of technological advancements restricted to a specific 12-month period is impractical. Inherent in the nature and development of technology is the element of time; rarely can a new process or product be attributed to a particular year. An overall picture of general trends and pattern changes, however, is indicative of technological growth. This paper presents selected observations and discussions of current metallurgical research and practices in an attempt to develop' such a picture. Of the estimated $16.5 billion spent for research and development in the United States in 1962, at least 80 percent was earmarked for the aircraft, electronics, chemical, and machinery industries. Much of the effort was of the end-use variety and was oriented closely to the national defense and aerospace programs. Only a small fraction of the total research money was directed to studies of the utilization and improvement of metals. Even if the investigations in allied fields such as solid state physics are included, the total research expenditure for metal and mineral materials barely reached $500 million. An additional $200 million was spent by industry and government for development of minerals recovery and processing methods.

Jan 1, 1963

Reduce the noise levels to which operators of double-drum longwall shearers are exposed without compromising the operational effectiveness of the shearer. The Problem Noise produced by double-drum longwall shearers can be harmful to machine operators. Typical noise levels at the lead-drum operator position range from 100 to 105 dBA, and Federal noise regulations allow only one to two hours of exposure per shift at these levels. Noise radiated by the shearer cutting drum is the primary contributor to the overall noise level. However, test of a noise-controlled cutting drum developed by the Bureau of Mines reduced the operator noise level to 95 dBA, thereby increasing the allowable operating time to four hours per shift. Approach The key design aspect of the noise-controlled shearer drum is its reduced vibration-al response to coal-cutting forces. Laboratory studies have shown that these forces are concentrated in the low-frequency region (500 Hz and below). Since the cylindrical core and the cantilevered I plate-like helix of the standard shearer drum are easily excited by these forces (natural vibration frequencies be-

Jan 1, 1985

Determine the extent to which remote-sensing techniques, primarily lineament analysis, can be used to identify geologic structures that may affect the location and migration of subsidence over abandoned underground coal mines in the Colorado Springs, CO, area. Compile data using a geographic information system (GIS) to allow efficient and reproducible comparisons and analyses. Background The basis for evaluating abandoned mine land (AML) sites with remote-sensing techniques comes from past and ongoing Bureau ground control research using remote-sensing data to identify potential hazards caused by geologic structures (faults, joints, etc.) above active underground coal mines. Research showed that lineament (linear feature) analysis of Landsat Multispectral Scanner (MSS) images could indicate locations of fractures and fracture trends that had varying, but significant, impacts on the stability of mine openings. Such geologic structures should be identifiable over abandoned mines as well. If fractures are present, even if they arc not faults, they should represent areas of potential instability over these mines and, therefore, should tend to localize subsidence when it occurs, particularly for deep and moderately deep portions of mines.

Jan 1, 1992

A construction material based on plasticized sulfur and mineral aggregate, that is superior in corrosion resistance and strength to portland cement concrete. The material can be used in the chemical, metallurgical, and fertilizer industries, and will also provide an attractive market for by-product sulfur resulting from compliance with pollution regulations. How It Is Made Sulfur concrete is thermoplastic material. Plasticized sulfur is mixed with sand and gravel aggregate heated to 375-400° F. The sulfur melts and acts as the binder or cement. The sulfur concrete is poured hot and sets at a temperature of 200° F. Full strength is attained in a few hours, compared to several days for portland cement concretes. Sulfur concrete even pours and sets in freezing weather. Although unmodified sulfur with aggregate will produce a sulfur concrete with good initial properties, it undergoes crystallographic modifications, and deteriorates with time, particularly when exposed to moisture or freeze-thaw conditions. The Bureau of Mines has developed plasticizers which, when reacted with the sulfur, give sulfur concretes with excellent moisture and freeze-thaw resistance. The plasticizers are based on mixtures of dicyclopentadlene (DCPD) and ollgomers of cyclopentadiene. About 5 percent by weight of the plasticizers is reacted with molten sui fur for several hours. The sulfur cement can be used directly or allowed to solidify for easier handling and storage.

Jan 1, 1981

Determine whether the total delay time in blasting may be safely increased beyond the currently permitted 0.5 s, without igniting a methane or methane-coal dust atmosphere and determine the minimum borehole spacing to avoid misfires. Approach At present, regulations limit the delay time used in short-delay blasting to a total of 0.5 s. Many in industry and government would like to see this total delay time increased to 1 5 to permit an increase in the number of different delays available for short delay blasting and an increase in the time between delay periods. The Bureau of Mines conducted research to determine whether the total elapsed delay time for blasting coal in underground mines could be safely expanded, with resulting improvements in productivity. The research was conducted at a surface mine in St. Clairsville, Ohio. Experimental shots were conducted in several pits, each of which had a 5-foot-high coal seam (Pitts-burg No.8) in a 50-foot highwall. The coal seam and a mobile gallery provided a good simulation of an underground coal face. The Bureau also examined the relationship between borehole spacing and misfires, to check on reports over the past few years that permissible explosives frequently misfire. These reports were not well documented, but were numerous enough to warrant investigation. Misfires of permissible explosives in an underground coal mine can be very hazardous; a burning cartridge of explosive may be ejected from a borehole and ignite the gas or dust in the mine, or a misfired cartridge in the muck pile may detonate during drilling and mucking operations, causing serious injuries.

Jan 1, 1986

Improve surface mine haul-age truck safety and efficiency by providing a means for sensing the weight and distribution of the truck's load. Approach The safety hazards and the economic implications of overloading mine-haulage trucks were analyzed to determine the net effect of that practice on mine operations. The analysis indicated that: Ten to 25 pct overloading is typical; Higher haulage, tire, and maintenance costs occur due to overloading (a 20 pct overload was estimated to increase operating costs 7 pct per ton); Ten to 15 pct of haulage? truck injuries and fatalities are attributable to overload conditions, at a cost over one million dollars per year to the mining industry. Vehicle-weighing technology that conformed to the performance specification for an off-highway haulage truck overload detection system was selected for in-mine testing. How It Works Normally, volumetric estimates are made during the loading sequence which do not account for the varying ore density. Hence, the actual weight of a load is never precisely known. By providing a precise measurement, an overload detection system will not only indicate vehicle overloading, but will also show under-utilization of the truck. One system tested by the Bureau of Mines was the ?Load Analyzer" manufactured by Pactronics Corporation in California. This system consists of a meter-type analog readout for the cab console and three "Electrosensors" (linear variable differential transformers) attached to the main frame. Using conventional welding and brazing techniques, two sensors are attached between the front members of the engine sub-frame and the top of the left and right trailing arms (one sensor per arm). The same techniques are used to attach the third sensor to the rear centerline of the truck. between the main frame cross member and the A-frame. The readout unit on the cab console indicates by color-coding whether each sensor loading is under (green), at (yellow), or over (red) the pre-set rated load. The three-sensor configuration with in-dependent readouts also detects uneven distribution of the load.

Jan 1, 1984

By Hewitt Wilson

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Jan 1, 1927

By D. Harrington

Research in connection with occupational diseases, including silicosis or, more definitely, pneumoconiosis, has been prosecuted much more actively in North American countries during the past 5 or 10 years than in any other known period. This applies particularly to the United States, owing largely to the fact that in recent years compensation for ill health presumed to be caused by industrial work of certain kinds is being paid to a far greater extent in this country than previously. Most other countries have had occupational-disease laws for many years. Court rulings in the United States, which started 5 or 6 years ago, have given a few heavy verdicts in connection with ill health or death caused, or alleged to have been caused, by some phase of occupational work other than traumatic injury, and these have called attention to the fact that ill health and even incapacitation can be caused by some kinds of employment. With the onset of the world-wide financial depression, which resulted in permanent abandonment of many business or industrial enterprises (among them mines) in the United States, the workers frequently believed that they could expect nothing in the future from their former employers, hence they felt free to demand monetary benefits or damages because of ill health which they suffered, or thought they suffered, because of their previous employment. The result was a flood of lawsuits and. compensation claims for occupational disease, particularly where dust was involved.

Jan 1, 1938

By Arcy P., D&apos Banister

Several gold-antimony geochemical anomalies were outlined near Stibnite, Idaho, using the humus sampling technique. Several hundred reconnaissance humus samples were collected and analyzed by a combination fire-assay atomic absorption method. The results partially outlined several gold-antimony anomalies and are very encouraging for further work in this part of Idaho.

Jan 1, 1970

By David Cooper, Susan Robertson, William Wiehagen, Launa Mallett, Charles Vaught, Joan Dickerson, Richard Conkle, ROBERT PETERS, Mike Brnich, Charles Urban

This trainer’s guide is designed as a reference manual. The purpose is to offer information and examples to skills trainers to assist them in structuring training for new operators of Walk-Thru roof bolting machines. Trainers can use this manual as a resource for helping trainees learn, understand, and apply knowledge and skills. In this sense, the guide is not prescriptive. It is designed to offer information and trigger ideas on what might be done to accelerate learning to those who are new to the roof-bolting task. On-site trainers can modify this guide to fit their conditions, machines and equipment, and work procedures. They can integrate roof control plans, company policies and procedures, and operators’ manuals from the manufacturers of the original equipment into this guide. Every trainee is different and will come to the job with varying levels of relevant knowledge and skills. The trainer’s decisions on where to start, how to organize the on-the-job and classroom training portions, and when and how to offer different aspects of the training will be based on (1) a pretraining assessment of the trainee’s knowledge and skills and (2) the trainer’s experience in conducting skills training. The “Skill Check” section might be useful for deciding where training should start among miners who have underground experience but limited knowledge of roof-bolting techniques. Every job carries a learning curve and likely has a number of “teachable moments” where significantly new knowledge and skills can be learned. The videos on the DVD that accompany this guide can be shown at the beginning of training to give trainees an idea of what the job entails and related requirements. They can also be used within the training cycle (after the trainee has some experience in the job) to reinforce key points or as a trigger for eliciting questions about particularly difficult parts of the job. The video segments are meant to be visual models of good performance. They are designed to elicit discussion on good (lower risk) ways to do the job. In this context, they can be used very creatively at different times within the training cycle. The section on “Talking Points” offers a number of questions that can be used in the classroom to support and elaborate on certain aspects of the job duties. If the trainee has a fair amount of underground experience, some of the questions can also be used to support the pretraining assessment (i.e., skill check) of knowledge and skills. Likewise, some of the questions can also be used while teaching on the job to reinforce key points affecting safety, production, or maintenance. The section dealing with a mine’s roof control plan should be used at various times in the training cycle to make sure the trainee understands the plan and knows how to apply it in performing the job. The supplemental materials offer additional resources that can be used to support initial job training or follow-up. Learning continues well after an individual has been trained. The supplemental materials can help reinforce good operating skills and provide an opportunity for further discussion on better ways to do the job.

Jan 8, 2006

By F. W. Davis

For some years this subject has been of interest to metallurgists. Previous to the War some work was done in :Belgium. on the enrich.ntSnt of the blast with oxygen i.."'l. connection with the smelting of iron orei.; in the blast furnace. In the United States, the late .J. E. ,Joh."lson, .Jr., \ve.s :interested in the possible use of 0J1.:ygen for metallurgical operations ar.:i cerried on some experic:.ental work along these lines pre..,,-ious to his de.e.hft Dr. F. G. Cottrell, formerly Director of the :Bureau of Mines, De7?,H''(;:,-of,,:a:t: of the Interior, and now Direc'cor of the Fixed lifi trogen Itesearc:l-1 La -:c r;a.-o='Y, Depart­ment of .Agriculture, first directed. the Eurec:ru 1 s attention to this subject. When it first began this work, the Director of the Burea.t1. of Mines, beca11se of his interest in this investigatio:::i, asked :Mr. M. H. Roberts: Vice-President of the FraU:din Railway Supply Company to select an Advisory Corr:nittee to work with the BJ::eau on tl1is subject; it also asked Mx-. Robez·ts to act as Cha.irman of this C<)1.,_1l!lHtce. T!le personneJ. of the Comrnitee which was selected. by r. Roberts is as follows:

Jul 1, 1923

By N. S. Dalal, X. Shi, V. Vallyathan

"Electron spin resonance (ESRJ spectrum of the hydroxyl (· OH) radical spin adduct with .the spin trap 5,5-dimethyl-1-pyrrolintt-N-oxide has been obtained in suspensions of freshly ground quartz particles. The concentration of the spin adduct (and hence of the • OH radicals) increases with the amount of grinding. The dust's potential for the generation of the· OH radicals is maximum when fresh (i.e., immediately after grinding) and decreases to 50% in about a day on storage in air. Studies involving metal chelates .indicate that the • OH radical formation involves mainly the silica surface and H20 rather than the Fenton reaction. The results suggest that hydroxyl radical reaction(s) could be important in the lipid peroxidation and fibrogenicity by quartz dust, particularly .in acute silicosis. INTRODUCTIONIn this paper we report on our electron spin resonance (ESR) detection of the formation of hydroxyl (·OH) radicals in aqueous suspensions of freshly crushed quartz particles. This work was undertaken with a view to find possible clues to the role of free radicals in the pathogenesis of quartz-induced fibrogenicity, commonly known as silicosis. We noted that while silicosis is one of the major health hazards in coal and mineral industries, the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still poorly ·understood (Reiser and Last, 1979; Singh and .Rahman, 1987). It is generally thought, nevertheless, that the action of quartz particles on the biological membranes is the starting point of the silicotic process (Parazzi et - al., 1968). A possible clue to the mechanism of the membrane damage by quartz particles, in terms of the role of oxygenated free radicals, is suggested by the following observations. A suspension of quartz particles in contact with alveolar macrophages has been reported (Gabor et al., 1975; Koike et al., 1982) to initiate an enhancement of lipid peroxidation, defined broadly as the oxidative deterioration of polyunsaturated components of lipids. Hydroxyl (· OH) radicals are known to be capable of peroxidation by abstracting hydrogen atoms from cell-membrane lipids (Halliwell and Gutteridge, 1985) and of initiating lipid peroxidation in lysosomal membranes. (Fong et al., 1973). Arong other lines, it is known that exposure of cell membranes, fatty acids, and unsaturated food oils to ionizing radiation, which generates· OH radicals, causes rapid peroxidation (Halliwell and Gutteridge, 1985). Thus • OH radicals (and also other oxygenated species such as Oi, 10 2, and H20 2) might be expected to play a role in the toxicity of quartz. Earlier studies of the aqueous chemistry of quartz suspensions have reported detection of H2O 2 (Kalbanev et al., 1980), implicating the formation of ·OH radicals as transient species. However, we are not aware of any report of the detection of • OH radicals in quartz reactions, and thus the present study was undertaken. Since it-is known that, because of their high reactivity (hence short lifetime) in aqueous media, the • OH radicals cannot be detected via ESR directly (Finkelstein et al., 1980; Buettner, 1982) we have used .ESR combined with the spin-trap methodology (Finkelstein et al., 1980) for studying the· OH formation. The results show that· OH radicals are indeed formed in aqueous suspensions of freshly ground quartz; thus pointing to ·a possible new clue to the cytotoxicity of freshly formed quartz particles and thereby to silica fibrogenicity."

Jan 1, 1988

By John C. Hartley

Three systems that monitor ventilating fans are described. These electronic monitoring systems automatically perform most of the operations required to conform with the provisions of the Federal Mine Safety Code in the event of fan failure or slowdown.

Jan 1, 1964