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By F. L. Wideman

SPURRED by demands of a buoyant economy for mineral products, output from mines in the United States established a new record. Removal of waste material, necessary for the extraction of economic minerals, kept pace with mine production. Earth moving by these two activities exceeded 3 billion tons, an increase of 5 percent over that of 1963. Crude materials from which metal or nonmetal products were derived accounted for 75 percent of the total. The remainder, mostly worthless, was classified as waste. Changes in the minerals industry result from many causes. Technological trends and labor productivity are among several significant and interrelated indexes that assist in the analysis of the changes. Therefore, a. study of productivity is helpful in measuring technological growth in mining. Concepts of productivity tend to vary with the purpose for which the term is used; frequently, productivity is expressed in terms of units of output per unit of labor, such as tons of ore per man-hour or man-shift. Comparisons of levels of productivity for a group of products are usually made using composites of output. Data for all metal and nonmetal mines except gold, silver, mercury, platinum metals group, and sand and grave were used to compile the composite for determining productivity for 1960-64. Copper ore, iron ore, and phosphate rock are mined mainly by surface methods, but characteristics of the deposits and differences in processing the crude material affect production of the commodities. Therefore, productivity data for these selected segments of the minerals industry reflect the influence of physical conditions on the exploitation of them.

Jan 1, 1965

By Jon K. Ahlness

The Bureau of Mines, in cooperation with the Institute of Mineral Research of Michigan Technological University, and the Upper Great Lakes Regional Commission, conducted an investigation of electronic sorting of native copper ore from Upper Michigan. This report is based on research by the Institute of Mineral Research under contract to the Bureau. The test program evaluated the use of belt and rotary sorters on various size and grade fractions of ore. Both plant-scale sorting and lab sorting tests were run. The plant sorting objectives were to determine the sortability of different ores and the efficiency of the electronic ore sorters. High-and low-grade ores from both conglomerate and amygdaloid types were separated into four size fractions. The two larger sizes were sorted on belt sorters and the two smaller ones on rotary sorters. Copper recoveries ranged from 20.0 pct from a feed grade of 0.40 pct to 80.3 pct from a feed grade of 1.08 pct. Lab sorting tests of conglomerate ore were run to determine the efficiency of a belt sorter equipped with a second sensing coil located above the belt and to determine the sorting characteristics of larger ore size fractions than those used in the plant sorting. Copper recoveries from the combined feed sizes ranged from 47.0 pct from a feed grade of 0.13 pct to 96.8 pct from a feed grade of 4.87 pct. For all the ore types except one, it was found that the copper recovery increased with the feed size.

Jan 1, 1980

By T. L. Joseph

"In the January 3 issue of Iron Trade Review, Sweetser2, in referring to the problem of coke combustibility, points out that, ""Someone should formulate a rule for the rate of flow of coke through the zone of coke combustion that now appears to be confined to a comparatively restricted volume in front of the tuyeres,"" In formulating such a rule it is necessary to distinguish clearly between combustibility, a property of the fuel, and rate of combustion, which is determined by the rate at which air is supplied to the fuel bed. The rate of carbon gasified at the tuyeres of a blast furnace is independent of coke combusti-bility. A fast-burning coke will burn in a more restricted volume than a slow-burning coke, but both types of fuel will be consumed at rates determined by the supply of oxygen,A number of the definitions of combustibility that have appeared in technical literature relate more closely to rate of combustion than to combustibility. Perrott and Kinney) have correctly defined it as follows: ""Combustibility of coke from the standpoint of its use in, the blast furnace is inversely proportional to the mean rate of gasification per unit volume of the combustion zone, assuming other factors remain constant,"" Combustibility of coke refers therefore to those properties that determine the size or extent of the combustion zone. Relative differences in these properties can be measured by the depth of the fuel bed required to convert oxygen from the air into carbon monoxide."

May 1, 1924

By D. B. Gawthrop

"In connection with the proposed use of Cordeau-Bickford to fire L.O.X. (liquid oxygen explosives) in well drill holes, the question has arisen as to the effect of very low temperatures on (1) the rate of detonation of Cordeau-Bickford; (2) the sensitiveness to detonation of its TNT filling; and (3) the lead covering of Cordeau-Bickford.The Cordeau-Bickford used in this investigation was the standard 6 mm. size, such as is regularly used in blasting, and was manufactured and furnished by the Ensign-Bickford Company, Simsbury, Conn. All pieces tested were taken from rolls, all of which were from the same melted batch of TNT in order that all the pieces tested might be as nearly identical as possible.Different portions of this Cordeau-Bickford were tested plain (not countered), countered, and double countered. The countering and double countering was carried out by the manufacturer prior to shipment.The determination of the temperature at the instant of making a test was accomplished by the use of a Leeds and Northrup potentiometer and copper constantan thermocouples. Each couple was made from No. 28 B & S gage wire with short junctions. One junction was inserted in a hole drilled by a No. 60 drill through one lead wall of the Cordeau-Bickford to approximately the opposite wall, so that this junction was in the center of the TNT filling while the other junction was immersed in ice water. The potentiometer readings in millivolts were converted to °C. from the calibration curve of the thermocouple wire,"

Jun 1, 1924

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies for syn¬thetic Cu2S and CuS were measured. This investigation is part of the Bureau of Mines goals to provide thermodynamic data essential to the more efficient processing of copper ores, and thereby minimize the current dislocations in energy, environment, and mineral supply. Heat capacities were measured with an adiabatic calorimeter from 5 to 310 K, and resulted in S°298 = 27.76 for Cu2S(c) and S°298 = 16.05 cal/deg mole for CuS(c). Low-temperature values are tabulated for Cp°, S°, -(G°-Ho°)/T, and H°-Ho°. Enthalpies were measured with a copper block calorimeter from 298.15 to 1,600 K for Cu2S(c,1) and 298.15 to 780 K for CuS(c). The thermal behavior of CuS showed no transitions or other significant anomalies for the low- or high-temperature investigations. Cu2S showed reversible transitions at 376 K with an isothermal heat absorption of 0.865 kcal/mole, 720 K with an isothermal absorption of 0.280 kcal/mole, and approximately 1,400 K (congruent melting point) with a heat of fusion of 3.070 kcal/mole. High-temperature data are tabulated for H°-H°298, Cp°, S°, and -(G°-H°298)/T. Enthalpies are also expressed in equation form. The low¬and high-temperature data were combined with data from the literature to cal¬culate and tabulate ?Hf°, ?Gf°, and log Kf as a function of temperature.

Jan 1, 1978

By Roy H. Grau

Increased awareness of a healthy work environment is common to all industries and the stone industry is no exception. The presence of operating diesel equipment, welding, stone production blasting, and silica dust in a working environment all contribute to air quality issues in underground stone mines. Particularly recognized is the exposure of workers to diesel particulate matter (DPM). Recent regulations call for a DPM standard of 160TC ug/m3 (TC = Total Carbon). The National Institute for Occupational Safety and Health (NIOSH) has conducted research to improve the ventilation of these mines and consequently reduce the exposure of workers to harmful airborne contaminants. The results have shown that the ventilation of underground stone mines can be significantly enhanced using improved ventilation controls and techniques. Large-opening stone mines present specialized ventilation challenges because their entries are much larger than in other types of mines. Most stone mines have entries about 40 feet wide and up to 30 feet high, with bench areas that may extend even higher. These large entries present the positive opportunity to move large air quantities at relatively low mine fan pressures resulting in lower fan horsepower and reduced operating costs. However, the difficulty in ventilating large-opening mines is that even with large air volumes, the air velocity is often less than 100 feet/minute. Higher ventilation velocities more quickly dilute and remove contaminants from the face areas. Higher ventilation airflow velocities can be achieved by effective ventilation planning and proper choice of ventilation fans.

Jan 1, 2009

By H. A. Doerner

Tellurium is a silver white solid with metallic luster, the e17atal.line torm being ver., brittle aud e.g,s!ly powdered. It has a specific gravity of 6,27, melta at 45a0c. and boils at red het, giving off a. golden 1ellow vapor when air 11 excludei. When heated in air, telluri'UiD burns with a bl\te name tinged with green, and evolves wh1 te vapors ot tellurium dioxide. An amorphous form of tel­lurium, obtained by red.uction and precipi ta.tion from so).ution, haa II specific gr1.vity ot 6,015, and when heated ia cho.nged to the cry:.,talline variety. Telluri,a 11 insoluble in water, c&rbon diaiJ.phido, or h;rd.rochl oric acids, but it 11 41a-1olved bJ nitric or concen t1·ated. sulphi.U·ic acid. It 1..oea not tamiah in moiet ah•• 11 ree11tant to alkaline solutions, e,;:ctpt concentrated KOB, but it 11 cliaaolvecl by tuaed. &lkl 1••. I ts 11.to!!lic weight h..'l.a been the "J.Ubject ot mch controverq, bu\ t.he value 137 .5 :.a bl!ten generally accepted, Tho chflmietr:, of tellurium ia eim1lar to that ot IUlphur. It tonne throo xid.ee TeO, To02, and Te0 , al10 tellur14ea, t•llurite,, and. tellur1.t11, A number of halide compoWld.1, a 3iulph1de, and. a .ulpbat.e are known.

Aug 1, 1922

By W. E. Wallace, P. S. Mike, C. A. Hill, V. Vallyathan, M. J. Keane

Respirable quartz duet and a kaolin clay dust have been found to be of comparable cytotoxic potential in vitro on a specific surface area basis (Wallace, et a1,1985), despite the distinctly different potentials of quartz and clay for causing pneumoconiosis or pulmonary fibrosis (Sheers, 1984). A respired particle depositing in a respiratory bronchiole or alveolus will contact a pulmonary surfactant hypophase, of which a primary component is diacyl glycerophosphorylcholine, or diacyl lecithin (DPL) (Clements, et al, 1970). Several studies have found that adsorption of such surfactant suppresses in vitro cytotoxic effects of quartz dust (Marks, 1957). Subsequent phagocytosis and digestion by a macrophage may remove the coating, restoring cytotoxic potential and initiating disease processes (Iles, 1979). Adsorption of dipalmitoyl lecithin (DPL) from emulsion in physiologic saline by respirable sized quartz dust and kaolin dusts, and consequent diminution of the dusts' hemolytic and macrophage cytotoxic potential have been reported (Wallace, et al, 1985). This report presents additional data on the cell-free in vitro phospholipase A2 enzymatic digestion of dipalmitoyl lecithin adsorbed on a quartz and a kaolin respirable sized dust (Wallace, et al, 1988) to investigate mineral specific differences in the rates of digestion and of consequent restoration of dust membranolytic potential. Respirable crystalline alpha quarts used was eighty percent smaller than 5 micorometer aerodynamic diameter with a nitrogen adsorption specific surface area of 3.97 m2/g. Respirable kaolin dust was ninety percent smaller than 5 micrometer diameter and had a specific surface area of 13.25 m2/g.

Jan 1, 1988

By Benjamin Petkof

Production quarry blasts in three rock types were photographed with a high-speed camera. Analysis of the films showed that step increases sometimes occur in the horizontal velocity of the broken rock. These step velocity increases were observed only in the first foot or so of rock movement. This observation indicates that the gaseous products of the explosion do additional work on the rock after it is crushed and cracked by the initial compressive-stress pulse and the reflected tensile-stress pulse. The observed initial fly-rock velocity is compared with the calculated fly-rock velocity for reflection spalling. A mechanism possibly causing the velocity increases is discussed. INTRODUCTION When a small concentrated charge of explosive is detonated at the bottom of a drill hole near a free surface, two modes of rock failure have been observed; both are associated with the stress pulse generated in the rock by the detonating explosive. The first mode of failure is the crushing and radial tensile cracking associated with the initial passage of the compressive-stress pulse as it propagates outward from the explosion. This type of rock failure is usually confined to the immediate vicinity of the charge hole. The second mode of failure is the tangential and radial tensile cracking associated with the tensile-stress pulse that is reflected from the free surface. This mode of failure is commonly called scabbing or spalling and has been shown to be a primary cause of rock failure in crater formation at one free surface. (3).4

Jan 1, 1961

"While control of dust-related diseases, the objective of the Generic Mineral Technology Center for Respirable Dust, is of prime importance from the human standpoint it is also essential to the economic well-being of the mining industry (FIGURE 23). Although significant progress has been made, the problem continues to be a major concern to the mining community. An increasing global demand for coal and other minerals means that production and the number of miners employed is on the rise. Therefore, the importance of this research to the mining industry cannot be overemphasized.The five areas of dust research are 1) control of dust generation, 2) dilution, dispersion and collection of dust in mine airways, 3) characterization of dust particles, 4) interaction of dust and lungs, 5) relationship of mine environment, geology, and seam characteristics to dust generation and mobility. Some experimental projects where the research is conducted almost exclusively in the laboratory may still rely on industry for imput. No industrial resources are necessary to the research of the non-experimental projects, for example computer modeling .The remaining research is classified as experimental and these projects do require interaction with industry in varying degrees. Periodic trips to mining sites in Western Pennsylvania, Southern Ohio, and West Virginia are necessary to record measurements or collect samples. Or companies may provide needed samples or equipment to the university for use in the laboratory. On several projects interaction is limited to advice or information supplied to the researcher by industry personnel."

Aug 31, 1989

Apply state-of-the-art monitoring and computer systems technology to remotely monitor geostructural data and evaluate ground conditions in near real-time. Background Recently, the coal mining industry has progressed dramatically from a labor-intensive industry to highly mechanized and automated systems achieving significantly higher production rates. In underground longwall coal mines, production and face advance rates have increased by almost tenfold in the last 15 to 20 years. With increasingly high advance rates, geologic anomalies which affect rock mass quality are encountered more frequently, far exceeding the current rate at which ground control information can be processed and analyzed. As a result, mine operators find themselves with insufficient time or resources to cope with the rapidly changing ground conditions. To keep up with the technological advancement in mining and the associated ground control problems, the Bureau of Mines is conducting a multi-phase research pro¬gram to implement a computer-assisted Ground Control Management System (GCMS). Research is ongoing at present, but when completed the system will be designed to 1) monitor and evaluate data on rock properties, geologic conditions, and rock mechanics data from underground sensors in near real-time; 2) interpret the analyses to evaluate the interaction between various critical ground control parameters; 3) assess the structural integrity of the mine; and 4) determine failure modes and provide recommendations for control measures, design modifica¬tions, and alternative support procedures. The system will be expanded into its full capability during various phases of this research program.

Jan 1, 1991

By Raja V. Ramani, Robert L. Frantz

"In response to the U.S. Bureau of Mines (USBM) Request for Proposal (RFP) for "" the establishment of a Generic Mineral Technology Center (GTC) in Respirable Dust,"" the Mining and Mineral Resources Research Institutes (MRIs) at The Pennsylvania State University (PSU) and West Virginia University (WVU) in association with participating MRIs at Massachusetts Institute of Technology (MIT), and the University of Minnesota (UMN) have prepared the comprehensive research program described herein. Michigan Technological University (MTU) joined the Center as an affiliate after its inception. This program was developed with recognition of the stated objective of the Federal Mine Safety and Health laws which is to "". . . permit each miner the opportunity to work underground during the period of his entire adult working life without incurring any disability from pneumoconiosis or any other occupation-related disease . . . .""Exposure to respirable contaminants in mine atmospheres has long posed a serious hazard to miners. The control of these hazards, some of which can have sudden and catastrophic consequences and some others, slow and long enduring, has been a major concern for labor, management and the government. This concern has manifested itself in four mechanisms of control -- (1) regulatory control through minimum standard setting by the passage of mine health and safety laws, (2) engineering control through design and operation of mines according to the best recommended practices, (3) interaction of dust and lung control through periodic physical examinations, wearing personal protection devices, etc., and (4) legal and social control through workman's compensation laws for occupation related health deterioration."

Aug 31, 1989

By K. L. Rubow

"Diesel exhaust and mineral dust concentrations have been measured for aerosols generated in the laboratory and as found in five underground coal mines- 3 utiliting diesel-powered hallage equipment and two electric-powered equipment. Two source apportionment techniques have been applied to differentiate between the mineral dust and diesel exhaust aerosol concentrations. The first technique, using a microbrifke uniform deposit impactor CMOUDI) for size selective sampling, is based on modeling aerosol size and the premise that the diesel exhaust portion of .the aerosol is predom1nately submicrometer and the mineral dust portion is mostly greater that one micrometer in size. The second technique, Chemical Mass Balance CCMB) modeling, was used to referee the analysis of diesel exhaust and mineral dust aerosol concentrations from the size selective sampling results. ,The MOUDI size distribution data were modeled to obtain parameters describing the fine and course fractions of the sampled aerosol and to estimate the contributions to each mode from both mineral ·dust and diesel exhaust aerosol sources. The results showed the size distribution of the mixed aerosols exhibited two definite modes with the minimum between the modes occurring at 0.8 um. For the diesel equipped mines, this analysts yielded an average value for the fraction of the fine aerosol attributable to mineral dust of 1 pct. Less than 5 pct of the coal mine diesel aerosol was found in the coarse size fraction. CMB analysis confirms the original premise for using aerosol size to separate diesel exhaust and mineral dust aerosol during sampling."

Jan 1, 1988

By Vernom F. Swanson, George E. Fish

A study was made during 1959-60 of reported nelsonite occurrences in Nelson and Amherst Counties, Va. The investigation was limited to core drill- ing on one deposit and beneficiation studies on three deposits. Three diamond-drill holes totaling 562 feet were drilled on the E. M. Hughes property to determine subsurface continuity. Although outcrops as much as 30 feet wide were present on this property, the only nelsonite intersected in the holes ranged from 4 to 18 inches thick. The ilmenite content of the core ranged from 50 to 75 percent. These nelsonite deposits are of secondary importance as a source of titanium, being small, rarely exceeding 1,500 feet in length and 30 feet in width, but they are high grade. Due to the proximity of some of the bodies it might be possible to mine several of them as one operation feeding one mill. Electromagnetic separation on composited samples recovered 83.0 percent of the Tio as an ilmenite concentrate in 68.5 percent of the weight. Two flotation procedures were developed. The first method, using oleic acid as a collector and fluo silicic acid as an apatite depressant on deslimed feed, produced an overall recovery of 59.3 percent in batch tests. The second procedure eliminated desliming. Laurylamine hydrochloride removed silicates in an acid pulp followed by an alkaline apatite flotation with oleic acid as the collector and dextrine as the ilmenite depressant. The ilmenite-rich tailing represented a 66.2-percent recovery of Tio in the batch tests.

Jan 1, 1964

By Robert P. Vinson, Kissell. Fred N., Edward D. Thimons

"The Bureau of Mines investigated the presence and extent of methane accumulations in mine roof cavities using a full-scale mine model. Methane was released at a constant rate into the roof of a cavity built onto a 700-ft wind tunnel. Two box-shaped roof cavities were used in the study: one had a volume of 114.7 cu ft; and the other had a volume of 57.3 cu ft. Methane concentration was measured at 28 sampling points in the cavities using 21 different combinations of gas emission rates and air velocities. Brattice hung in the cavity helped reduce methane concentrations without auxiliary ventilation. It was also found that the effective ventilation rate increased by a factor of 40 in the large cavity and by a factor of 20 in the small cavity when air velocity was increased from 100 to 600 fpm.INTRODUCTIONAny location in a coal mine where 5 pct or more of methane is present constitutes a potential site for an explosion and roof cavities are likely locations. Unfortunately, little is known about the buildup of methane in roof cavities. Some research has been done using scale models where no air flows past the cavity so that methane disperses only by diffusion (5) 4 a rare situation in mines.No known cavity-model investigations have been made that simulate air and methane flow conditions normally encountered underground. These Bureau of Mines studies were undertaken to determine the extent and manner of methane buildups in coal mine roof cavities with air velocities in the range normally found in coal mines and with various methane emission rates."

Jan 1, 1978

By John P. Harmon

A group of organic chemicals, known as wetting agents, has been developed, primarily for use in the textile industry. These chemicals have the property of reducing the surface tension of water when mixed with it in very dilute solutions. The advantage of lowered surface tension is recognized in dust-control work, and several wetting agents, have been tried by dust-control engineers with varying degrees of success. It is well-known that certain solids, coal for instance, are extremely hard to wet with plain water because of the high surface tension of water and the water-repellent action of coal. If the surface tension of the water is reduced, it can be demonstrated that the coal can be wetted easily. This is accomplished practical and at law cost by dissolving a very small percentage of wetting agent in the water that is to be used for wetting purposes. (Care should be exercised in using a wetting agent to be sure that it will not interfere with a subsequent process.) For some time, the comparative efficiency of various wetting agents has been the subject of considerable work by dust-control men at coal mines, as well as by members of the Bureau of Mines 3/, 4/, 5/, 6/. In this connection, a number of samples of air-borne dust have been collected in the mines. With the exception of dust-control measures conditions of dust generation and dissemination were maintained as, nearly uniform as possible. Samples were collected when water alone was sprayed on the cutter bar of a mining machine; various wetting agents were then successively added to the water and more samples of air-borne dust were-collected.

Jan 1, 1946

By Thomas W. Martin

This chapter includes tables from 1984 that were not available in time for publication of the 1984 Minerals Yearbook, but does not include corresponding tables for 1985. The value of raw nonfuel minerals produced in the United States during 1985 was estimated at $23.2 billion, an increase of $0.07 billion over the value for 1984. This is the third consecutive year that the value has increased, and except for a decrease in 1982, the value for each year has increased since 1971, or 13 out of 14 years. However. while the value of industrial minerals production continued to grow, reflecting the growth of the domestic economy, the value of metal mine production decreased in 1985 by 6%. This drop was more than offset by a 3% increase in the value of industrial minerals production because the value of industrial minerals produced was more than three times larger than the value of metals. The decrease makes 1986 the third year in the past 5 years in which a drop in the value of metal mining production occurred in the United States where production continued to lag behind growing world production. Domestic production of such major commodities 88 aluminum, copper, iron ore, phosphate rock, and zinc continued to decline owing to a number of international and domestic factors. Gold continued to be the most active commodity in the domestic metal mining industry. Despite lower prices, gold output increased to 2.5 million troy ounces, a 19% increase over that of 1984. The estimated annual production capacity of new gold mines beginning production exceeded 1 million ounces.

Jan 1, 1987

By Stephen C. Brown

THE expansion of the world economy which has been in process since 1958 continued in 1963 and both production and consumption of minerals rose. Gross national product (GNP) rose sharply in the United Kingdom and Japan, continued to expand in the United States and Canada, and maintained a high though slightly declining rate of growth in the European Economic Community (EEC) despite the appearance of excess capacity in certain lines and inflationary pressures in Italy and France. The steel and motor vehicle industries both increased output in North America, Western Europe, and Japan. The less developed areas benefited substantially from an improvement in their terms of trade, and their export earnings increased some 8 percent in 1963; although estimates of GNP for the majority of them are 110t yet available, it is probable that this increase was partly reflected in a substantial rise of GNP.2 In the United States the expansion was steady and extended through all sectors of the economy producing no distortions likely to disturb its continuing growth; at yearend with unemployment still at about 5.5 percent of the labor force and operating rates of industry estimated at about 87 percent of capacity, there was a substantial margin for further expansion. Though the balance of payments was still in heavy deficit for the year, in the last half it was moving rapidly toward equalibrium as net exports rose and capital outflows declined; prices were relatively stable, inventories increased only slightly and the activity of mineral-consuming industries remained high, steel output rising by 11 percent to highest level since 1957 and the auto industry output equalling the 1955 record.3

Jan 1, 1964

By A. B. Needham

The Great Eastern nickel deposit is located in the western foothills of the Virgin Mountains in the Copper King or Bunkerville district situated in the southeastern part of Clark County, Nev. It is covered by a group of eight claims that can be reached by turning south from U. S. Highway 91 at Riverside, Nev., and driving about 12.6 miles southeast over a winding mountain road, which rises from about 3,000 feet to 4,000 feet in elevation. The climate is dry, with only a small amount of rainfall throughout the year. The temperature ranges from hot during the summer to short periods of freezing weather during the winter months. The vegetation is of the desert variety, and no timber is available for mining. Water for mining purposes would have to be pumped from lower areas. A granitoid gneiss comprises the largest part of the rock outcrops. It has a steeply dipping foliation that strikes about N. 75° E. The gneiss was intruded by basic dikes, which in turn were intruded by pegmatite dikes. The ore occurs as lenticular bodies formed by the convergence of several pegmatite dikes within the main dike. The principal sulfide minerals are pyrite, pyrrhotite, and chalcopyrite, which contain a small amount of nickel. Late in the year of 1939, the Bureau of Mines undertook an exploration project on the Great Eastern property to extend or delimit the known mineralization. Underground work, consisting of 590 feet of drifting and crosscutting, was completed in September 1940, and 1,091 feet of diamond, drilling for downward extension of an ore body in the Lower edit, which was completed in February 1941.

Jan 1, 1950

By J. E. Pahlman

As part of its goal to minimize the requirements for mineral commodities through conservation and substitution, the Bureau of Mines is conducting research to determine the resistance of alumina refractories to corrosion by alkali-containing slags that could result from burning of the abundant Western lignites in metallurgical operations. Static corrosion tests were performed at 1,000° to 1,350° C and dynamic tests were performed at 1,400° to 1,600° C to investigate the stability of refractory specimens in slag environments. In general, the degree of refractory attack increased with decreasing alumina content in the refractory and with increasing alkali content of the lignite ash. The parabolic kinetics observed in static tests suggested that a reaction product layer is formed through which ionic diffusion must occur to sustain the reaction with the refractory material. The linear kinetics observed in dynamic tests in high-viscosity slags indicated a shearing of the reaction product layer by viscous slags. The observed lesser attack of refractories by low-viscosity slags can be explained on this basis. Two 99-percent-alumina refractories and two 90-percent-alumina refractories formed an expanded protective layer with the more viscous slags but not with the less viscous slags. Corrosion of 90-percent-alumina refractories increased exponentially with temperature. In refractories with the same nominal alumina content, those that contain a combination of a-Al203 and mullite (3A1203?2Si02) have better corrosion resistance than those containing a combination of a-Al203, cristobalite (Si02 mineral), and mullite. In alkali environments (1,300 to 1,400° C), 90-to 99-percent-alumina refractories are recommended for use as furnace linings.

Jan 1, 1980