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By LB. Berger

"INTRODUCTION The use of gasoline engines as the motive power for lift trucks, tractors, and other types of mobile equipment operated in enclosed spaces, such as industrial plants and warehouses, may create a hazard because of the carbon monoxide present in the exhaust gases of the engines; gasoline-powered equipment should not be used in mines or tunnels. Because the equipment is mobile, local ventilation usually is impracticable, and general ventilation of the spaces is nec-essary to dilute and remove the carbon monoxide. To estimate the rate of ventilation required in such situations, information is necessary on the concentration of carbon monoxide in the exhaust gas and the rate at which exhaust gas is produced under given operating conditions. The purpose of this paper is to present data that may be used in making estimates of ventilation requirements.COMPOSITION OF GASOLINE-ENGINE EXHAUST GASThe exhaust gas of a gasoline engine consists mainly of carbon dioxide, carbon monoxide, hydrogen, oxygen, and unburned hydrocarbons (usually reported as methane), together with the nitrogen present as a residue from the air sup-plied for combustion. 3/ The exhaust also contains water vapor resulting from combustion of the hydrogen of the fuel. The water-vapor content is not included in exhaust-gas analyses calculated on a ""dry"" basis and is not involved in the estimation of ventilation requirements."

Jun 1, 1947

By Martin Hertzberg

The Bureau of Mines 8-liter flammability system was used to study the effectiveness of a variety of powdered inhibitors in preventing the propagation of explosions of coal dust or methane in air. Over 35 different chemical additives were evaluated against Pittsburgh seam pulverized coal. The least effective inhibitors were the carbonates, which required mass additions in the range of two to three parts inhibitor to one part of coal dust in order to prevent propagation. The most effective inhibitors were the derivatives of ammonium phosphate, which were effective quenching agents at additions of only one part inhibitor to four parts of coal dust. Alkali halide powders were of intermediate effectiveness. These laboratory-scale results are in good agreement with full-scale mine experiments in all cases where detailed comparisons have been made. Data were also obtained for the effectiveness of several of the same powdered inhibitors against methane-air explosions. Their relative order of effectiveness and the concentration ranges required for quenching the gas explosion are comparable to those measured for coal dust explosions. Data are also presented for the effectiveness of N2 and CF3Br addition. Some preliminary data are also presented for powder addition to methane burner flames. Those data are compared with other burner data and evaluated in terms of their relevance to explosion tests.

Jan 1, 1982

"An active list of permissible explosives was published in September 1935 as part of United States Bureau of Mines Report of Investigations 32S6, under the title ""Active List of Permissible Explosives and. Blasting Devices Approved. Prior to July 31, 1935."" This list included 154 brand names,Changes in the list that have been authorized subsequently placed 24 addi¬tional brands of permissible explosives on the active permissible list as a re¬sult of tests, changes in brand names, or transfer from the inactive list. Eight permissible explosives were transferred from the active to the inactive list. The present active permissible list contains 170 brand names. The brand names of the permissible explosives placed on the active list are as follows:Black Diamond Nu-Gel No. 4 By test.Black Diamond Special A,do.Burton 11, L. F. By change in name,Burton G, L. F. By test.Columbia B By change in name.Columbia C Do.Columbia D Do.Columbia E Do.Columbia. F Do.Columbia G Do.Columbia 1 Do.Columbia 2 D.Columbia 3 DoColumbia 4 Do.Columbia-Gel 1 Do.Columbia-Gel 2 Do.Genite 5, Do.Genite 7, Do.Genite G Do.Lump Coal C By test.Peerless No, 1 By transfer from inactivePeerless No. 8, L. F. Do.Tri-State Special No. 1 Do.Unilite No. 2 Do."

Dec 1, 1936

By J. J. Demeter

Anthracite from the four producing regions in Pennsylvania was both ashed in the laboratory and burned on a chain-grate stoker to determine the sulfur-retention properties of its ash. The retention of sulfur in laboratory-prepared anthracite ash was shown to be related to ashing temperature and to the amounts of sulfur and calcium present in the coal. At the usual laboratory ashing temperature of 750° C sulfur retention ranged from 0.8 to 13.2 percent of the total coal sulfur. Sulfur retention in the ash was negligible, o to 0.3 percent, at 1,200° C, which is the thermal decomposition temperature of calcium sulfate; thus calcium sulfate does not form and cannot serve as a sulfur-retaining agent. In several tests the anthracite was mixed with 6 or 10 percent dolomite prior to firing in the chain-grate stoker. The dolomite did not improve sulfur retention owing to the high temperature in the fuel bed. Sulfur retention was, however, related to the unburned carbon in the ash. The relationship of the percentage of original coal sulfur retained in the ash (Y) to the percentage of the original carbon in the coal remaining in the ash (X) is expressed by Y = -0.579 + 0.914X. The percentage of sulfur retained is almost directly proportionate to the percentage of original coal carbon in the ash.

Jan 1, 1968

By J. E. Schiller

The Bureau of Mines has investigated the surface charge of amphibole asbestos fibers and nonasbestiform cleavage fragments, as part of the Bureau's fundamental studies to provide new knowledge on the physical and chemical properties of the amphibole minerals. Microelectrophoresis was used to measure the electrophoretic mobilities, in water, of particles from six asbesti-from amphiboles and seven nonasbestiform amphiboles over the pH range of 5 through 9. The particles generally ranged in size from 2 to 5 µm wide by 10 to 30 µm long. The isoelectric point was determined for four of the minerals, and values were found to be between pH 3.5 and pH 5. The minerals studied had zeta potentials that generally ranged from -25 to -so mv in neutral solution. Attachment of colloidal positively charged AgI was also studied as a means of determining surface charge. Scanning electron microscopy of amphibole particles that had been in contact with aqueous AgI showed equal attachment of AgI to asbestos fibers and to cleavage fragments; the extent of AgI coating was the same for both. The electrophoretic mobilities of asbestos fibers were essentially the same as those of elongated cleavage fragments of the same aspect ratio (particle length divided by width). Blocky particles from both asbestiform and nonasbestiform specimens had lower mobilities.

Jan 1, 1980

By Peter J. Clarke

Afghanistan's mineral industry continued to be dominated by the production and export of natural gas, although several mining and related industrial projects, all under the supervision of Soviet technicians, were in the planning stage in 1982. Afghanistan produced minor quantities of barite, cement, coal, fertilizer materials, iron, and lapis lazuli, all for domestic consumption.2 Large-scale projects being investigated were a copper mine and concentrating plant at Ainak, extensive mining of the Hajigak iron ore deposit near Kabul, construction of an oil refinery at Angot, increasing production and processing of natural gas, and implementing an intensive geologic prospecting and exploration program for areas of mineral potential. Afghanistan's gross domestic product (GDP) was estimated at $2.76 billion3 and has remained stagnant for the past several years. Total exports in 1982 were estimated at $700 million, only a marginal increase from the 1981 figure of $694 million. Exports of natural gas to the U.S.S.R. earned $385 million in 1982, representing just over one-half of Afghanistan's total exports. Natural gas revenues were down approximately 11% from the 1981 level, owing primarily to increased antigovernment activity in the northern part of the country.4 About 90% of the country's natural gas production was exported to the U.S.S.R.5 About 38% of Afghanistan's development budget had been earmarked for mining and industrial projects in 1982.6

Jan 1, 1984

By James H. Russell

Several solid sorbents were compared for their effectiveness in removing sulfur dioxide from flue gases. The materials were tested for the rate of sorption and capacity at about 300° C, and rate of regeneration around 700° C in thin beds and in 4-inch-diameter fluidized beds. Rates of material loss were also estimated. The sorbents tested included three samples of alkalized alumina, two samples of sodium carbonate-impregnated alumina, and one proprietary sample of porous silica impregnated with copper and iron compounds. The results showed that all the alkalized aluminas had good sorption capacities and rates, required high temperature regeneration, and suffered excessive material loss; the sodium carbonate-impregnated aluminas (1) had high sorption rates but barely adequate capacities, (2) required high temperature regeneration, and (3) suffered excessive material losses; and the copper-iron impregnated silica suffered only slight material loss and could be regenerated at a relatively low temperature, but the sorption rate and capacity were too small. None of the sorbents met all the arbitrary performance criteria that follow: sorption rate constant of 1 min-1, sorption capacity of 0.1 g sulfur per g sorbent, regeneration rate constant of about 0.075 min-1 at a reasonable temperature, less than 0.07 pct per hour material loss during operation, and a chemical life of 500 cycles.

Jan 1, 1971

By C. M. Bouton

Although much valuable work has been done in the study of dust explosions, the laboratory technique has not been developed to the point where the many factors involved can be properly controlled, and thus where really fundamental information can be obtained. This paper presents a brief discussion of the difficulties encountered in fundamental work on dust explosions, a description of apparatus intended, to overcome some of them, and an account of some results obtained. FACTORS INVOLVED IN DUST EXPLOSIONS The more important factors pertaining to the dust cloud itself which are known to determine the phenomena of explosions are (1) the kind of dust; (2) its fineness; (3) its concentration in the exploding cloud; and (4) the nature of the interior motions, or turbulence, of the cloud before and during the explosion. These factors are arranged in what seems to be an ascending order of complexity. The kind of dust is the factor most easily subject to control. The fineness of the dust at first sight seems to be a controllable factor, but when it is recalled [that] most explosible dusts are mixtures of particles of continuously varying sizes so small as to pass through the finest woven sieves, and therefore difficult to separate either for purposes of analysis or experiment, the fineness is seen to be a factor difficult to control accurately.

Jan 1, 1929

By John H. Soulé

"INTRODUCTION The property of the Silver Spot Mines Co. is in the Boston Hill area within and adjacent to the southwest corner of Silver City, N. Mex. The area was visited by Bureau of Mines engineers 3/ in 1941 and 1942 during the investigation of possible sources of manganese. The area was visited again in November 1944 4/ to study the possibilities of geophysical exploration of the manganiferous-iron deposits. This geophysical work was performed in 1945 5/, confirmed the existence of known deposits of manganiferous-iron ores, and indicated the probable extent and situation of others.The Silver Spot property was churn-drilled from 1926 to 1929 during exploration for manganiferous-iron ores. The sludges from a number of the holes indicated low-grade lead-zinc mineralization. Lead and zinc minerals also were found on the dumps of some of the old shafts when the property was visited by D. H. Mullen, an engineer of the Bureau of Mines late in 1946. A diamond-drilling project was proposed. It was started in April 1947 with the intention of investigating the best of the known ore indications as shown by the old churn-drill holes and thus gathering new data upon which to base future work. Only one hole was drilled before the project was terminated because of lack of funds and time."

Mar 1, 1948

By J. I. Paige

The Bureau of Mines, U.S. Department of the Interior, conducts research on methods to minimize the requirements for mineral raw materials through conservation, substitution, and increased minerals and metals recovery from primary and secondary domestic resources. To further this goal, prior Bureau research had devised a pyrometallurgical technique (RI 8211) to recover metallic iron and copper from molten copper smelting furnace slags by carbothermic reduction. As a continuation of this Bureau research on the carbon injection technique, reverberatory and electric furnace slags were treated in an 800-kva electric arc furnace by simultaneously top feeding the slag and injecting coke breeze into the bottom of the molten bath. Results of the tests show that 76 to 89 pct of the copper and up to 48 pct of the iron contained in the smelting furnace slag were recovered in a metallic phase, while 56 to 82 pct of the carbon injected into the sys-tem was utilized as the reductant. Laboratory evaluation has shown that the metal product, which contains 86.9 to 95.0 wt-pct iron and 1.3 to 4.1 wt-pct copper, will be a satisfactory medium for recovering copper by cementation. The expected energy consumption for the process is 110 kwhr per ton of molten slag treated and 520 kwhr per ton of solid material charged.

Jan 1, 1982

By H. Robert Ensminger

The Belizean economy had an estimated annual growth of about 3.4% over that of 1986. Economic growth during the 2 previous years was slower and was characterized by a negative trade balance. The gross domestic product (GDP) was an estimated $200 millioni2 in current dollars. Limited natural resources and scarce finances continued to make the Government's task a difficult one. Belize and China signed an economic cooperation agreement in April under which the Chinese Government is to provide technical assistance, a cash grant of $60.000, and a long-term, interest-free loan of approximately $1.5 million. In May, it was reported that gold was discovered in a remote area of the Maya Mountains in western Belize. An estimated unassayed value of $400 million has been placed on the deposit by one of its discoverers. However, the government in Belmopan has played down the discovery. Two U.S. oil companies. Seahawk Oil International of California and Alston Oil Co. of Texas, were granted licenses to explore for oil. Seahawk Oil will explore a large area of the Orange and Corozal Districts, while Alston Oil will prospect a 90,000-acre area of the western Cayo District. Another U.S. oil company, Pecten Oil Co., recently completed seismic studies off-shore of Belize City. Pecten Oil has made plans to start drilling in 1988.

Jan 1, 1989

Provide an accurate, reliable means for determining when a sealed mine or mine section can be safely reopened after a fire. Approach The Bureau of Mines performed a research investigation that resulted in the development of a mathematical formula for deriving a quantity, called RATIO, which can be used to define when a sealed mine or mine section has returned to safe recovery conditions after a fire. Research Results There were two major results from this Bureau research. Over a period of several years, the Bureau of Mines conducted six experiments at its Bruceton Experimental Mine in Pennsylvania. The experiments involved sealing the mine after several tons of piled coal had been allowed to burn continuously for 2 to 3 days. Although gas data obtained during the experiments revealed nothing significant, measured smoke particle levels were found to correlate with the stages of combustion and temperatures of the smoldering coal pile. Moreover, it was found that no smoke particles are produced when high-temperature smoldering exists deep within the mass of the coal pile since the smoke particles are filtered by the coal surrounding the hot region. Smoke is emitted into the mine atmosphere only if combustion is occurring near exposed surfaces. As suggested by these findings, any decision to recover a sealed mine area based primarily upon the absence of smoke particles is not a wise derision.

Jan 1, 1988

By P. G. Kovalchik

Overexposure to noise remains a widespread, serious health hazard in the US mining and other industries despite 25 years of regulation. Most categories of illnesses and injuries associated with mining have improved, with the exception of hearing loss. The drilling of rock in a confined work environment contributes to high levels of noise exposure in mining. The National Institute for Occupational Safety and Health (NIOSH) is conducting research to reduce the noise exposures of jackleg drill operators and to prevent additional cases of noise induced hearing loss (NIHL) by developing and evaluating low-cost retrofit noise controls for equipment. This report describes the procedure for the measurement and reporting of noise from portable pneumatic tools such as jackleg drills. The technique used in this research allows for the determination of the source A-weighted sound power levels and the radiation patterns in octave and 1/3 octave bands. Overall sound power level is also determined. This paper also reports the results obtained by using this procedure to evaluate a SECO S215 standard production drill and a CSIR Miningtek prototype rock drill incorporating engineering noise control measures. It was found that by using the manufacture?s recommended operating pressure of 496 kPa (72 psi) that the CSIR prototype?s sound power was 10 dB(A) less then that of the SECO S215.

Jan 1, 2009

By David C. Oyler, Gregory Hasenfus, Gregory M. Molinda

Few studies have specifically measured and documented the large-scale loading behavior and durability of ventilation stoppings to mining induced movements, particularly from longwalls. Ventilation stoppings are more commonly the concern of ventilation engineers, and ventilation stopping response to ground movement has only been documented in an incidental manner. This paper presents the investigations of underground measurements that have been conducted to determine the loading response of stoppings constructed from lightweight aggregate concrete masonry units (CMU). These investigations have produced some interesting results that may prove beneficial, not only for developing and assessing alternative stopping construction techniques, but also for designing and selecting standard construction methods for use in varying mining conditions. For instance, the interface friction that results from wedging a CMU stopping during construction plays a substantial role in its ability to resist both lateral and vertical loads. Although they are not intended for ground support, the study showed that block stoppings can resist vertical loads of at least 2,700 to 3,000 kN. Asymmetric loading of a stopping may result in localized failure of blocks within a stopping, which, depending on the severity, can be a precursor of impending stopping failure. In addition to measurement results and implications, the paper will also present details of field measurement methods used to assess stopping response. Stopping stiffness and material strength characteristics will also be presented.

To improve the reliability of the Bureau developed bore-hole gage now widely used to determine the absolute state of stress in rock. Approach Use the knowledge gained by extensive field tests to design a more rugged and reliable Instrument using lighter and stronger materials. How It Works The original gage consisted of a stainless steel cylinder 1-3/8 Inches In diameter and 10-1/2 inches long. The new gage is made from titanium. This lighter material reduces the weight of the gage by 43 percent, which enhances the gage placement and depth of overcoring in vertical up? holes. For added strength, the titanium case and placement end are now threaded to the gage body instead of using screw fasteners. Three pairs of strain gaged transducers are positioned to measure the diametral deformation of a 1-1/2 diameter borehole at 60-degree intervals around the Inner surface of the borehole. Each transducer consists of a beryllium copper cantilever with a strain gage cemented on each side. These transducers are secured Into the gage body by a tapered shank for minimal creep. The transducers opposite each other are wired together to form a 4-arm external bridge circuit. A pair of transducers is referred to as a component. Any deformation of the borehole, which occurs during overcoring, is detected by pistons which translate the motion to the components. Each

Jan 1, 1982

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX B - DEVELOPMENT OF FOAM-CONCRETE SLURRY MINE SEALANT 1. Introduction This appendix describes the results of an experimental development and laboratory evaluation of foam-concrete as a rapid setting, lightweight, self-supporting mine sealant material. Foam concrete, otherwise known as Aerated Concrete, is a form of lightweight concrete whose structure consists of air bubbles held together by a hardened cement mortar. Its principal applications are found in roofing, insulation, shock absorbing, and backfill. The air bubbles in foam concrete are formed either by chemical reaction in the wet, placed mortar, or by introducing a stable foam into the mortar during mixing. The mortar is usually a cement slurry with fine sand or fly ash as filler. Our attention focused on preformed foam concrete, since this is most adaptable to field applications. Equipment is available,* which simultaneously mixes and pumps a slurry of foam concrete. Such a slurry can be produced at a rate of up to 50 yards/hr and has been pumped in a 2-inch-diameter hose 1000-feet horizontally and 250 feet vertically up without significant bubble deterioration. One very attractive feature associated with the use of foam concrete concerns site logistics. Foam concrete can be generated with densities as low as 20 lbs/ft3, and hence the total number of

Jan 1, 1973

1. Mine drainage constitutes surface or ground water which flows from mines or mine sites and is usually characterized by concentrations of acidity or alkalinity. 2. The regional geology controlling the ground water flow pattern in conjunction with the life cycle mining plan can serve as a basis for making decisions about quality of water that can be expected to be encountered. 3. In regard to the prevention and control of acid water formation in underground coal mines, much is left undone in research and education: (A) Very little literature is available on this specific subject although much has been written on water management in underground mines. (B) Little or nothing is contained in the text books and curricula used in mining departments at colleges and universities with the result that educational offerings may be seriously deficient in these areas. 4. Prohibiting water entry into underground coal mines is the best method of preventing water pollution. Since this is not possible as mining operations are extended, preventing water or oxygen from contacting acid producing material may offer the next best alternative. 5. More emphasis is needed during the mine planning stage on steps to prevent water pollution. Such life cycle considerations as type of mining, sequence of development and spatial configuration as well as the elements of the drainage network and final network organization and extent must be considered.

Jan 1, 1970

By R. H. Nafziger

As part of its program to help decrease the dependency of the United States on foreign imports of nonfuel minerals and to devise technology for the efficient and economic use of domestic resources, the Bureau of Mines smelted and sulfation-leached an ilmenite from northern Minnesota. The objective was to assess the feasibility of preparing chlorination-grade titanium feedstock. The concentrate was smelted with woodchips, coke, and soda ash in 91-kg-and 1-metric ton (mt)-capacity electric arc furnaces to form Ti-rich slag and commercial-grade pig iron. The slag contained from 67 to 77 wt pct titanium oxides and from 1.8 to 7.2 wt pct iron. Sulfation occurred in a 4.5-kg/h moving-bed reactor using S02-air mixtures at temperatures of 8000 to 8500 C to form soluble salts of the Ca, Mg, Mn,and Na impurities, which cause plugging of fluidized-bed chlorinators. Subsequently, the sulfated slag was leached in acid to remove the soluble sulfates. The final product from small-scale testing contained up to 95.5 wt pct Ti02, a minimum of 0.6 wt pct Fe, and a minimum total of 0.3 wt pct of the four impurities of interest. The final product meets charge specifications for chlorination. However, more large-scale testing is necessary.

Jan 1, 1987

By Thomas V. Falkie, R. Venkataramani

1. Summary This investigation is concerned with description of the loading function at the underground coal face, and the identification of varia¬bles - geological, geometric, mechanical, and operational - that affect the loading function. The immediate objective of this work was to provide information for operations-research studies as applied to underground coal mining, and the broad objective was to provide guide¬lines for planning and equipment selection in underground coal mining. The loading function was expressed as -a statistically-developed linear mathematical model. Originally, fifteen independent variables were considered which potentially could have influenced the loading function. These variables were constructed on the basis of measurable or estima¬ble geometric and geological properties at the working face, mechanical characteristics of the mining machine, and certain operational proce¬dures of mining. The original model explained 64.0 percent of the experimental variation. The final condensed model explained 54.1 percent of the experimental variation in terms of only five indepen¬dent variables, namely: 1. Ratio: width of cut/total width of cutter 2. Ratio: height of cut/diameter of cutter 3. Total horsepower of cutter-drive motors 4. Rotation speed (RPM) of cutter 5,. A subjective estimate of machine quality and operator skill Certain limitations were found to exist in the evaluation of the variables. Principle among these limitations was the impossibility of precise measurement of tonnage loaded in certain instances.

Jan 1, 1972

By J. H. Maysilles

The Bureau of Mines is examining a variety of low-grade uranium ores because projections indicate that an appreciable percentage of future U.S. uranium production will be derived from resources containing 0.01 to 0.1 percent U308. One possible source is represented by a granitic material from Wyoming; the available samples contained 0.06 and 0.12 percent U308. Tests were conducted to explore the general leaching characteristics of this potential resource. The material responded to both acidic and alkaline leaching techniques. Conventional acid leaching extracted 93 percent of the uranium in 18 hours; the required acid addition was 50 to 100 pounds of H2S04 per ton of ore, and the oxidant addition was 3 pounds of NaCl03 per ton of ore. The acid consumption continues after maximum uranium recovery has been reached; this effect may complicate heap or in situ leaching with acidic solutions. Some variation in reagent requirements was noted between the two ore samples. Conventional carbonate leaching with strong solutions at 85° C extracted 94 percent of the uranium in 24 hours. These granitic materials also showed some response to dilute carbonate solutions, and the results suggest that the material may be chemically amenable to heap or in situ leaching with dilute carbonate solutions.

Jan 1, 1977