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By Neil B. Young

Analytical results for nahcolite, dawsonite, total extractable alumina, and oil yield are presented for samples representing Green River Formation oil shales in the saline section of two cores from Colorado's Piceance Creek basin. Analyses are also reported for samples extending the analyzed section of Colorado corehole No. 3 beyond that reported previously. These data permit evaluation of the deposit for possible production of three coproducts--shale oil, alumina, and sodium carbonates--from the saline section of the formation at these sampled points.

Jan 1, 1970

By Joseph Cervik, Maurice Deul, Albert Sainato

This Bureau of Mines report deals with water infusion of coalbeds, which can control methane emission at face areas during developmental mining and which may sometimes suppress dust. Studies show that water infused into the coalbed flows through the fracture system and displaces the methane in the fractures and prevents migration from the solid coal. Displaced gas migrates away from the face area that has been water infused and enters the return ventilation airways. A gradual decrease in methane emission is observed from the start of infusion until the infused zone is mined through. Depending on the permeability of the coalbed, infusion pressures ranged from 300 to 2,200 lb/in2. Face emissions in the Upper Kittanning coalbed were reduced by 89 pct; reductions of 38 to 79 pct were measured in the Pittsburgh coalbed depending on the relationship between the face cleat direction and mining direction. Respirable dust levels were reduced by about 75 pct on a longwall section in the Pocahontas No. 3 coalbed and by about 50 pct on a development section in the Upper Kittanning coalbed, but no statistically reliable reduction was found in the respirable dust levels in the Pittsburgh coalbed.

Jan 1, 1977

By Joseph J. Wallace

1. The Pocahontas No. 3 and Pocahontas No. 6 ere the two most important beds in Mercer County from the standpoint of present production and recoverable reserves. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of coal in place, are estimated at 188 million short tons as of January l, 1953. Of this total, 80 million short tons are in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1954

By Henry E. Blake

The purpose of this Bureau of Mines investigation was twofold. The first phase of the work was to determine the technical and mechanical feasibility of defluorinating low-grade siliceous fluorspars on an intermediate scale by high-temperature pyrohydrolysis in a rotary kiln. The second phase was to react the liberated hydrogen fluoride (HF) offgas with alumina monohydrate to produce commercial-grade aluminum fluoride (85 percent AIF3). The two phases of the work were to be integrated into a single continuous process. Evaluation of the data shows that low-grade siliceous fluorspars can be successfully defluorinated, either in a solid or a molten state, in a gas-fired rotary kiln in the presence of water vapor at 1,250° to 1,350° C. The water produced by combustion of propane was sufficient to yield defluorinatians of 75 to 85 percent.

Jan 1, 1962

By Lisa Steiner, Robin Burgess-Limerick

In 2004, underground coal mines in the United States reported 3,405 injuries to the U.S. Mine Safety and Health Administration (MSHA). Of these, 17 percent were associated with the use of bolting machines, 8 percent with continuous miners, and 4 percent each with scoop/load-haul-dump (LHD), shuttle cars and personnel transport. Analysis of the injury narratives identified five hazards that required attention. They are rock falling from supported roof inadvertent or incorrect operation of bolting machine controls, handling continuous miner cable, collisions while driving underground vehicles and driving or traveling in underground vehicles on rough roadways. The rate of lost-time injuries has steadily decreased during the past 10 years (from more than 10 per 100 FTE in 1995, to six in 2004). However, underground coal mining remains a hazardous industry. One of the contributors to this elevated injury risk is working with or near underground coal mining equipment. Roof bolting machines and continuous miners have been consistently identified as high risk equipment. They account for approximately 24 percent of all injuries to underground coal miners (Sanders and Shaw, 1989). LHD's, shuttle cars and personnel transports are also associated with injuries in underground coal mines (Burgess-Limerick, 2005). Conventional analyses of injury statistics typically provide tables detailing the breakdown of injuries by body part nature of injury or mechanism of injury. Such analyses are worthwhile and may be helpful in tracking broad trends over time. Further information is available in the narrative text field completed for each injury reported. The detail contained in these narratives varies. However, they generally provide some insight into the causes of the injury, such as the activity being performed at the tune of

By M. M. Fine

In an experimental study by the Bureau of Mines, in cooperation with National Lead Co., the roast-flotation process was found to be an effective means of upgrading certain cobalt-nickel stockpiles. The research was undertaken to determine whether the process could yield an enriched feed, with a minimum cobalt content of 6.0 percent, for the company refinery. The stockpiles (products of the company Fredericktown, Mo., milling operations) were essentially complex sulfides of cobalt, nickel, copper, lead, and iron, 1 sample of which contained 2.84 percent Co and 3.57 percent Ni. After a controlled oxidizing roast at 400° C., laboratory flotation with conventional sulfhydric reagents yielded an enriched concentrate analyzing 9.22 percent Co and 11.43 percent Ni, with recoveries of 84.9 and 85.8 percent, respectively. These are typical laboratory data; other data indicated higher grades were possible but at reduced recoveries. A brief, continuous campaign verified the applicability of the process to the raw material in question but was not continued long enough to establish optimum conditions. As a consequence, the results of the large-scale tests did not equal those obtained in the laboratory but definitely confirm the beneficiation possible from the roast-flotation process.

Jan 1, 1958

By A. J. Barry

Two methods of testing anchorages of headed expansion-type mine roof bolts were investigated by the Federal Bureau of Mines to determine whether they are acceptable for general use. In both methods a load was applied to a tightened bolt with a hydraulic jack. A total of 80 tests, 40 using each method, was conducted in 4 test areas in 3 commercial coal mines. Electric resistance strain gages were used in all tests to indicate true bolt load as the bolt was tightened and when an additional load was applied with the hydraulic jack. The results indicate that: 1. The relationship between the true bolt load and the jack load will vary according to the test method until the two loads become equal. The bolt load-jack load relationship below this point can be determined only with strain gages. 2. The point at which the two loads become equal can be estimated by noting the load when the hardened washer becomes loose in one method, and when the bearing plate becomes loose from the roof in the other. It also can be approximated for either method of testing by noting the load when the first abrupt change in the slope of the jack load-bolt displacement curve occurs. 3. The anchorage characteristics of the test bolt can be determined from the data obtained from either method by examining the slope of the jack load-bolt displacement curve above the point at which the true bolt load is equal to the jack load.

Jan 1, 1960

By S. R. B. Cooke

Certain saturated and unsaturated fatty acids and a variety of resin acids were used as collectors for specular hematite, magnetite, and goethite. Vacuum flotation tests were used with each collector and mineral to delimit the fields of flotation and nonflotation as functions of concentrations of collector and of hydrogen ion. The experimental results of these tests lead to the following conclusions. The respective fatty and resin acids exhibit characteristic fields of flotation and nonflotation for the three iron oxides. The fields are somewhat similar, and specular hematite apparently is the most floatable mineral. The insolubility of some of the organic acids may seriously restrict flotation at low pH, although the saturated fatty acids, caprylic and capric, collect minus-100, plus-150-mesh specular hematite only in acid pulp. The presence of a lower "critical pH" is explained on the basis of the dissociation and hydrolysis of dilute soap solutions.

Jan 1, 1959

By John B. Shutack

In an effort to improve the performance of the explosive-anchored rock bolt, the Bureau of Mines studied the effect of the detonation velocity of the explosive and type of charge (linear or nonlinear) on the fracturing tendency of the anchor tube. Also, different types of tubing were compared to determine the one most suitable for use as an anchor tube. The Bruceton up-and-down method was applied in tests in which steel shooting blocks having boreholes ranging from 1-3/8 to 2-1/8 inches in diameter were used. Of the four types of tubing evaluated, a welded A-178 tubing that was drawn over a mandrel and renormalized gave the most promising results. The A-179 seamless tubing that is normally used with the explosive bolt was the most inferior. Both types, however, gave significantly better anchorage than the conventional shell when tested in both laboratory and underground experiments. Within the range of velocities studied (5,000 to 7,000 m/sec), the type of explosive showed no significant effect on anchor-tube performance. In general; linear explosive charges provided better anchorage than nonlinear charges.

Jan 1, 1968

By R. B. Prater

Research by the Bureau of Mines includes efforts to devise means for maximum recovery of critical and strategic metals from primary and secondary domestic resources. As part of that effort, the Bureau developed a hydrometallurgical process to recover Co, Ni, and Cu from Missouri lead-smelter matte. The process includes leaching with H2S04 plus Mn02 as an oxidizing agent, liquor purification, selective precipitation of CuS, (Co,Ni)S, and MnC03, and crystallization of Na2S04&apos; This report is concerned primarily with liquor purification, in which As and Fe are removed from the leach liquor by pH adjustment and filtration. Two variations of the purification step are described. One variation provides liquor containing <1 mg/L As and Fe but requires two solid-liquid separations, The other is achieved with only one solid-liquid separation but leads to a lower degree of purification.

Jan 1, 1987

By Robert R. Stein, Roy C. Bartholomae, William W. Aljoe

This Bureau of Mines report describes in detail the design and operation of a test apparatus for measuring the sound power levels of drills used by the mining industry. The two major components of the test apparatus are a computer-controlled automated drill test fixture (ADTF) and a large (45,000-ft3) reverberation chamber that houses the ADTF. Design specifications and performance capabilities of the ADTF and the reverberation room are given. Initial test results for three types of drills--a pneumatic percussion drill, a hydraulic percussion drill, and a pneumatic rotary drill--are given to illustrate the types of experiments that can be conducted with the test appartus.

By M. M. Fine

A satisfactory mean: of beneficiating a Brazilian phosphate rock was developed in a mineral-dressing-research study by the Bureau of Mines. High-grade concentrates well ever the specified minimum grade of 70 percent tricalcium phosphate, were produced, with goad recoveries by agglomerate tabling and flotation. A lower gads but usable secondary product was recovered by sedimentation of the minus-200-mesh fraction of the ore. The ore wan representative of an extensive deposit recently discovered near Recife in the State of Pernambuco, Brazil, which will be exploited in a plant planned to eventually produce at the rate of 500,000 tons of concentrate annually. Although Brazil has been reported to Lave a substantial reserve of phosphate rock,3/ the country has never been more than a small producer of this commodity. From 1945 to 1950 the highest production of phosphate rock attained in Brazil amounted to 10,421 tons. Production in 1949, the most recent year for which figures are available, was 4,553 tons.4/

Jan 1, 1954

Part Two of this report is based upon six working memoranda prepared during the first half of 1972 at an early stage in our work for the Bureau of Mines. This work presents preliminary performance estimates of baseband voice and narrowband through-the-earth electromagnetic communications systems of principal interest to the Bureau for operational/ emergency mine communications applications. The calculations were prepared to obtain early indications of the feasibility and governing parameters of such communications systems. They are based on limited, but pertinent, coal mine electromagnetic noise data acquired to-date by Bureau of Mines contractors; on theoretical signal-attenuation characteristics for two transmitter antenna types of present interest to the Bureau and on semi-empirical models which describe the intelligibility of voice communications as a function of the frequency variations of the signal-to-noise ratio across the voiceband. This work examines the cases of baseband voice and narrowband communications for uplink and downlink transmissions, for frequencies up to 3kHz. Downlink transmissions are via a horizontal wire antenna, and uplink transmissions via a vertical-axis loop antenna, for typical mine depths of 300, 600, and 1000 feet. Representative coal-mine overburden conductivities of 10-2 mhos/meter (moderate and common) and 10-1 mhos/ meter (high) were used; the former figure for both voice and narrowband calculations and the latter for narrowband calculations only. Examples of high, moderate, and low, surface and subsurface, harmonic and broadband-impulsive noise conditions were taken from NBS and Westinghouse (WGL) mine noise data, together with examples of high- and low-levels of ELF atmospheric noise taken from M.I.T. Lincoln Laboratory data. The effects of simple voice spectrum shaping techniques on the intelligibility of through-the-earth voice communications are examined, and indexes of intelligibility more broadly based than signal-to-noise ratio are discussed. Finally, a means of overcoming the affects of 60 Hz noise and its harmonics which are the largest contributors to typical audio frequency in-mine noise, is suggested. These feasibility calculations are not intended to serve as definitive and complete treatments, but as a starting point: to establish first-order estimates of the magnitude and variability of transmitter power requirements under different noise, overburden conductivity, and mine depth conditions; to identify relationships, conditions, or frequencies that are likely to limit or enhance system performance; to reveal items requiring further investigation and data still required; and to suggest practical methods for optimizing system performance. These objectives were met by the calculations. Simple experiments to support these calculations can and should be carried out; together with more detailed investigations of specific modulation, coding, noise-suppression, voice-compression and signal-conditioning techniques, aimed at producing through-the-earth operational/emergency mine-communication systems that are not only effective, but practical and economically sound.

Jan 1, 1974

By Daniel Edelstein

The supply of arsenic trioxide in 1982 was adequate to meet domestic demand. Allocation of supply by major domestic and foreign producers that began in 1977 ended during the first quarter of 1982. Major demand was about evenly divided between industrial chemicals and agricultural chemicals. Domestic Data Coverage.-Commercial- grade arsenic trioxide and arsenic metal were produced by only one U.S. company. In order to prevent disclosure of proprietary data, arsenic production data have been withheld.

Jan 1, 1983

By P. D. Bergman

The high price of pollucite ore, its limited availability, and the need to provide stack removal of S02 present formidable obstacles to the use of pure cesium as a seeding material in MHD power generation. Cost estimates indicate that mixed potassium-cesium seeding is preferable to the use of either pure cesium or pure potassium. Cheaper electricity and higher open-cycle MHD operating efficiencies result from the use of mixed seed. Savings of $3,000,000 per year in power costs for a 1,000-MWE open-cycle MHD power-plant are envisioned if the mixed seeding technique is adopted.

Jan 1, 1972

Abandoned Mme - A mine that a not producing any mineral and will not continue or resume operation Abatement - The lessening of pollution effects Acidity - A measure of the extent to which a solution is acid Acid Mme Drainage - Any acidic water draining or flowing on, or having drained or flowed off, any area of land affected by mining

Jan 1, 1975

By V. Rajaram, S. Bhattacharya, M. F. Dunn

During a mine fire or other emergency, it may be desirable to reverse the airflow in order to provide an escapeway or to isolate a fire. Also, (in colder areas, the airflow may be reversed to prevent ice buildup. When reversing main mine fans, the mine operator usually does not know what operating characteristics of flow and pressure to expect. Laboratory a field tests of vane axial main mine fans in the 7- to 9-ft diameter size range were conducted to establish forward and reverse performance characteristics under controlled conditions and at typical mine installations. The data obtained suggest that reverse performance characteristics are dependent upon the blade angle and the hub to tip ratio. There is also evidence that reverse performance can be predicted for a family of blade angles and a given hub to tip ratio. Generally, quantity of air is 30% to 65% less in reverse than when operating in the normal forward mode.

Jan 8, 1983

By A. G. Starliper

Research was conducted by the Bureau of Mines to determine feasible roasting methods for the removal and the recovery of germanium, cadmium, and lead as enriched fractions from sphalerite concentrates. The two types of roasting processes studied were: (1) Batch, with a stationary bed, and (2) continuous, with a suspended bed, Results indicated that either method gave satisfactory metallurgical recoveries} but the continuous process is recommended because of inherent advantages. Final products were enriched fractions that could be treated by conventional methods for production of metallic germanium, cadmium, and lead. In the batch process, the concentrates were placed in a large tube furnace and heated at 1,080° C, an average of 3 hours. During the heating period, inert, reducing} or sulfur-laden gases were passed over the stationary charge to convey the sublimed metal sulfides from the hot portion of the tube to a lower temperature condensing zone at the end of the tube, where the metal sulfides were collected on baffles and recovered. In the batch and fluidizing roasting processes alike, the gases passed over or through the charge and served only as carriers for the sublimates and as suspension media in fluidization roasting. Since both processes depended on the volatilization, at relatively high vapor pressures, of the sulfides of germanium, cadmium, and lead, it was imperative that very little oxygen come in contact with the charge to alter the sulfide minerals. Germanium has a high affinity for oxygen, but in this instance it was buffered by being in solid solution in zinc sulfide.

Jan 1, 1961

By R. B. Tippin

Research investigations conducted on five ore samples show the applicability of heavy liquid separation (HLS) techniques to mineral processing. Under proper operating conditions, semicontinuous tests in small fluid cyclones yielded 90 percent sink-float concentrates with recoveries exceeding 90 percent on minus 35-mesh ore samples of kyanite, potash, spodumene, fluorspar, and beryl. Although none of the ores were examined in detail, their response to this novel concentration method provides basic examples that are typical of the process. Various aspects of cyclone design and operational characteristics of heavy liquid cyclone circuits were studied which demonstrated the flexibility of HLS by using multiple units connected in series. A comparison of two heavy liquid solutions, tetrabromoethane and methylene bromide, exhibited their individual advantages and limitations. Unique problems relative to this process are discussed including liquid viscosity, mineral composition of the ore, toxicity, and material handling hazards.

Jan 1, 1968

By T. J. Driscoll

In this Bureau of Mines investigation, the electrochemical polarization behavior of Fe and Fe-1BCr has been characterized in rigorously controlled 1[N] H2S04 solutions stirred with oxygen or an inert gas. Samples that under-went various levels of corrosion or passivation were examined using Auger electron spectroscopy (AES) and ion sputtering. Passivation of iron occurred at a potential of approximately 0.6 volt (1) in poorly stirred, oxygen-saturated solutions for forward polarization (scanning from cathodic to anodic potentials); (2) in pH-adjusted (increased), well-stirred, oxygen-saturated solutions for forward polarization; and (3) in well~ and poorly stirred, oxygen-and helium-saturated solutions for reverse polarization. Passivation of Fe-18Cr occurred at a potential of approximately -0.1 volt in helium-, nitrogen-, and oxygen-saturated solutions for all cases of forward polarization and most cases of reverse polarization. Elemental depth profiles obtained from AES sputtering measurements indicated that films or adsorbed species were present on iron samples in solution subjected to open-circuit, active, and transpassive corrosion, cathodic reduction, and passivation. This conclusion was reached by considering the distribution of the solution species, primarily sulfur, in the films, which were composed primarily of iron and oxygen. Sulfur was present throughout the films on actively corroding samples, in the outer regions of films of passive and transpassive samples, and on the film surfaces of open-circuit and cathodically reduced samples. For Fe-18Cr, sulfur was found on the surfaces of films on passive samples only, indicating that only the passive samples had films on their surfaces in solution. The films on electropolished and passive Fe-1BCr samples had the largest chromium concentrations, estimated to be approximately 45 at. pct, with less chromium in films of cathodically reduced, active, and open-circuit samples, in that order.

Jan 1, 1979