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By D. F. Scott

The purpose of this study was to determine if miners were at risk from exposures to chemicals used in the mining industry and determine the nature and sources of the illnesses and injuries. The U.S. Mine Safety and Health Administration?s (MSHA) employment and accident, injury and illness database was reviewed. There were 2,705 cases of chemical-related injuries and illnesses reported from 1999 through 2006, involving 66 different chemicals. The main source (cause) of chemical-related cases was acids/alkalis (about 39%). The primary nature (effect) of chemical-related cases was chemical burns (about 57%). The job classification where workers incurred the most chemical-related injuries and illnesses was cleaning plant operator/media operator/boney preparation plant operator/crusher worker (cleaning plant operators are responsible for maintenance of plants, media operators are responsible for handling reagents, boney preparation plant operators oversee removal of ?bone? from coal, and crusher workers use large crushers to break mined material). From 1999 through 2006, the rate of ?nonfatal days lost? and ?no days lost? (resulting from injuries) did not change significantly; however, the rate of illnesses decreased significantly. Chemical burns accounted for a large number of injuries; mining companies should carefully examine their personal protective equipment (PPE) requirements, training methods and safety culture to ensure that their workers are protected.

Jan 1, 2009

By Herbert R. Babitzke

As part of a project to develop refractory metal alloys suitable for high-temperature structural applications, the Bureau of Mines applied solid solution and precipitation-hardening techniques to columbium and tantalum alloys. Thirty-three alloys were evaluated to determine their formability, strength, and oxidation resistance. Three alloys had tensile strengths near 40,000 psi at 1,200° C: Cb-1N-5W-5V-10Hf (No.4), Cb-15Hf-5W-0.5B (No. 31), and Cb-15Hf-SW-IB (No. 32). Oxidation resistance of the high-strength alloys was good. Alloy4 gained only 34 mg/cm2 at 1,200° C, and 21 mg/cm2 at 1,000° C in 2 hours. Hot forming was done without any protection from oxidation.

Jan 1, 1968

The mineral chromate is the sole current source of commercial chromium Chromite varies compositionally within limits permitted by the formula ((Mg,Fe,Zn,Mn)(A1,Cr)2O4) No chromate has been mined in the United States since 1961 In the past, almost all the chromate mined in the United States came from Alaska, California, Maryland, Montana, Oregon, and Pennsylvania, with about one-half of all production coming from Montana Primary chromate deposits occur only in certain kinds of ultramafic or closely related anorthositic rocks The two major types are stratiform (layered) and pod-shaped The Stillwater Complex of Montana is the largest known United States resource It is a stratiform deposit where several exposed zones of high-iron chromiferous material extend in length Since there is no commercial chromate mining in the United States, there are no environmental problems related to underground mining

Jan 1, 1975

By G. E. McElroy

The purpose of tins paper is not to present new date on the pressure losses due to bends and chances of area in mine openings through which air flows, but rather to correlate existing data, determined mainly on small duct systems and expressed in a variety of ways, according to uniform methods that facilitate their use in pressure-loss computations. These are required in such, air-flow problems as determining the quantity that will flow through is mine openings under a certain pressure difference or, conversely, the pressure difference that will be required to maintain a certain rate of flow. Air flowing through h ducts, such as mine airways, encounters resistance to flow due to interference of the individual air streams with each other caused by the wall surfaces. The result is that part of the kinetic energy of the flowing stream is converted to heat; and constant renewal of the kinetic energy from the total energy of the flow is required to maintain it. This process manifests itself by a decrease of the total pressure (static pressure plus velocity pressure; of the air in the direction of flow; in order that flow pray occur, there must necessarily be a differences in total pressure between the two cads of the air-ay equivalent to the pressure losses occasioned by the flow, which automatically adjusts itself in magnitude to the pressure difference maintained.

Jan 1, 1932

By B. R. Mohal, S. Chander

"The adsorption and wetting behavior of freshly ground and aged coals has been determined in the presence of a nonionic surfactant. The amount of surfactant adsorption changes with the concentration and ""age"" of the coal. The freshly ground coal has smaller amounts of adsorption at lower surfactant concentrations than the ""aged"" coal whereas at large surfactant concentrations, the order is reversed . In the latter case, more surfactant is adsorbed on fresh coal than on the ""aged"" coal . . It is proposed that at low concentrations, the surfactant adsorbs through both hydrophobic and hydrophilic interactions with the molecule lying parallel to the· surface, whereas at higher concentrations surface micelles form at the hydrophobic sites. The wetting behavior correlates well with the adsorption behavior.INTRODUCTIONNonionic surfactants have many applications in the coal and mineral processing industry. They can be used as dispersing agents to modulate flotation, flocculation and filtration of particulates (1). They can also be used to increase the wettability of hydrophobic solids such as coal and can hence be used as dust suppressants (2,3). Although the adsorption of representative nonionic surfactants such as Triton N-101 (an ethoxylated nonylphenol with 9.5 moles of ~thylene oxide and HLB equal to 13.4) have been studied extensively on substrates such as calcium carbonate (4), silica (5) carbon black (6) and graphite (7), very few studies are available for coals. Coals differ from other substrates with respect to two important characteristics: 1) coal are porous and 2) coals consist of a patchwork of hydrophobic and hydrophilic sites (8). Since the adsorption characteristics of a surfactant are influenced significantly by the nature of the substrate the characteristics of the coals must be taken into consideration."

Jan 1, 1989

By R. L. Grayson

"Compliance standards for respirable dust, which are reduced because of high quart: concentrations, have become an industry-wide problem. Research on the physical and chemical character of quart-classified particles in respirable coal mine dusts indicates that they may exist in intermixed layers or may be coated by clay or coal material. The relative amount of intermixing varies with the coal seam being mined. If most of the quart: particles of a mine dust are ""pure,"" then the dust may have a high fibrogenic risk potential because of truly free silica and the compliance standard should be lowered. lf, however, quart: is locked inside another material matrix, or coated, a reduced compliance standard may not be appropriate.Although much research has been done on coal workers' pneumoconiosis (CWP) over the past decades, the etiologic agents of the disease still have not been pinpointed. The predominant methods of characterizing respirable coal mine dusts were bulk analysis techniques for determination of elemental and mineralogical concentrations, the results of which were used in statistical analyses to determine relationships between dust composition and the occurrence of CWP. These methods are incapable of finding the etiologic agents in the dust primarily because of complicated and confounding physiochemical factors, which may be discovered if the focus of characterization was done on a dust particle level.The SEM/EDXA-based research discussed here shows a significant difference in the number of ""pure"" quartz particles in respirable dusts collected from different mines. Some of the results have been reported previously (Grayson, Andre, and Simonyi, 1988). Concurrent research by other investigators (Wallace et al., 1989) demonstrates an SEM/EDXA-based methodology to pinpoint the location of the ""contaminating"" substance(s ) in a quartz-classified particle. The research of the European Economic Community has also begun analyses on the respirable-dust-particle level (Robock and Bauer, 1988).Since the compensatory and intangible costs of CWP are substantial in the United States, it is important that the etiologic agents be determined and then either controlled or neutralized in a cost-effective way. This line of research is especially important consid-ering the forecasted. near-term growth of coal production and the evolution of high productivity longwall panels (an immediate problem in compliance) and continuous mining sections ( a probable future problem).This need has been accentuated now that nearly all respirable dust samples submitted to MSHA are analyzed for free silica (Tomb, Parobeck, and Gem, 1986). Today a real problem exists in the coal industry, both underground and surface, because of high quartz levels in respirable dusts causing substantially reduced compliance standards (Murphy, 1989).The combined results of the respirable dust particle investigators indicate that conventional bulk sample analyses may not faithfully represent the amount of biologically available or active quartz in all mines with a high level (greater than 5% ) of quartz in the dust For example, some mine dusts might contain predominantly occluded (or coated) quartz particles where bulk analysis would result in anomalously high ""free silica"" measurements. The same result would occur when quartz particles are intermixed substantially with other minerals that can alter the surface of the composite particle away from a quartz-behaving character."

Mar 1, 1992

"For a good many years the Bureau of Mines and various state mining experi¬ment stations have endeavored to develop some method of utilizing the immense deposits of lignite in the United States. Work in relent year has indicated that the best method of this is to drive off the moisture and most of the volatile water from the lignite in some form of carbonizing apparatus leaving a residue high in fixed carbon and low in moisture and volatile matter, which by briquetting can be made into a high-grade fuel. The earlier forms of carbonizing equipment tried were complicated, costly to build and keep in repair, and could not be operated intermittently without being seriously damaged. During the year 1922, however the Bureau of Mines devised a very simple carbonizing oven which produces a uniformly well carbonized product. This oven is essentially a vertical shaft with means for supplying raw lignite at the top and discharging the carbonized limited at the lower end. Air in regulated amount is admitted to the shaft at two horizons, and a zone of combustion maintained through which the column of lignite passes. The lignite is thus carbonized by construction of its contained matter and a small proportion of its fixed carbon, leaving most of the fixed carbon in the carbonized product or ""char"". The degree of carbonization can be closely controlled by varying the volume of air supplied to the oven and the rate of travel of the charre down the shaft.The ""lignite char"" produced is a soft material resembling charcoal more than coal or coke, but somewhat harder than charcoal. A typical analysis is shown in the table headed ""Fuels,"" further on in this papers."

Feb 1, 1924

By M. J. Reasor, M. DiMatteo, J. M. Antonini, K. Van Dyke, Z. Ye

"The inhalation of silica has been shown to produce a dramatic inflammatory and toxic response within the lungs of humans and laboratory animals. A variety of cellular and biochemical parameters are used to assess the silica-induced lung injury. The purpose of this paper is to introduce the use of luminok:Jependent chemiluminescence as a new method to study inflammation in both phagocytic cells and lung tissue recovered from silicaexposed animals. Chemiluminescence, or the emission of light, accompanies the release of reactive forms of oxygen when phagocytic cells are challenged. In this study, male Fischer 344 rats were intratracheally instilled with either silica (10 mg/100 g bw) or saline vehicle. One day after the instillations. a marked increase in the chemiluminescence was observed in the lung tissue and bronchoalveolar lavage cells recovered from the silica- treated animals when compared with the saline controls. The light reaction was markedly decreased by either superoxide dismutase or N-nitro-Larginine methyl ester hydrochloride. Superoxide dismutase is involved in the enzymatic breakdown of superoxide anion. while N-nitro-L-arginine methyl ester hydrocholoride, a nitric oxide synthase inhibitor, prevents the formation of nitric oxide. When superoxide anion and nitric oxide react. they form the highly oxidizing substance peroxynitrite. This study then implicates peroxynitrite as an agent that may be responsible for some of the oxidant lung injury that is associated with silica exposure. The use of luminol-dependent chemiluminescence may prove valuable as a method to measure the earliest events in the inflammatory process. and may be an adjunct in studying the mechanisms that produce inflammation. - Environ Health Perspect 102(Suppl 10):37-42 (1994) IntroductionResearch on inflammation has not produced a method that links the initial events of the process to the controlling events. Rather, a variety of parameters are measured that are the result of and not the basis of the inflammatory reaction. Parameters such as tissue weight, edema, blood flow, enzyme and protein release, or production of metabolites (prostaglandins, leukotrienes) have been used extensively. A method is needed that could be applied to cells of a particular type, groups of cells of different types, and even tissue, in an attempt to study the kinetics of the inflammation as well as being sensitive enough to monitor the early events of the process . Since inflammation is so complicated, the relationship between the control of the initial events and the oxidation process has never been explained nor studied in any derail."

Dec 1, 1995

By Stanton L. Tainter

"INTRODUCTION Molybdenite, the only common mineral and ore of molybdenum, occurs wide¬-spread but is concentrated as the main ore mineral in commercial quantities in only a few known deposits. Consequently, the Government sought additional sources of the minerals as a precaution against the possible shortage of moylbdenm for war uses. Upon request by the War Production Board, the New Year’s Eve and Esperanza properties of the Amargosa Molybdenum & Copper Corp. were investigated by the Geological Survey 3/ and the bureau of Mines 4/. The Survey appraised the mineral potentialities of the deposit and prepared topographic and geologic maps, and the Bureau made a preliminary engineering examination. The deposits were previously examined by W. J. Vanderwilt, consulting engineer. It was largely due to his recommendations that interest was stimulated in the deposits.Development on the New Year’s Eve deposit indicated a small tonnage of sub marginal ore. There was little development at the Esperanza, but surface examination revealed a large volume of rock containing a little molybdenite and a trace of copper in the oxidized outcrops. Some molybdic oxide was noted suggesting that some molybdenite might have been leached from the oxidized outcrops and that the molybdenite content in the sulfide zone might be higher."

Feb 1, 1947

By L. H. Duschak

"This paper is based on the results of work conducted of the bureau's experiment station at Berkeley, Calif., in connection with the investigation of properties and methods of utilizing Western magnesite. The experiments described herein were made under the supervision of the writer, by W. C. Riddell and E. H. Delius, of the station's staff.In calcining magnesite for the production of magnesium oxide to be used in the preparation of oxychloride cement, the calcium carbonate present in the original rock may remain unchanged or appear in the finished product, either as CaO, or in combination with SiO2, A12O3, etc. As there is reason to believe that free CaO may have an effect on the behavior of caustic magnesia in the cement reaction, it is desirable to have a method for the determination of the relatively small amounts of free CO in the presence of a large quantity of MgO.The extraction of the free CaO with water free from CO2 at once suggests itself as a possible method. The solubilities of Ca(OH2)2 and Mg(OH)2. are given by Seidell in his book an ""Solubility of Inorganic and Organic Compounds."" (2nd Edition, 1919) as follows:"

Jun 1, 1920

By William E. Dennis

"INTRODUCTION The San Antonio Canyon prospect was examined by engineers 3/ of the Bureau of Mines in March 1943 and again in October 1944. In July 1944, the United States Geological Survey mapped the prospect and submitted a report 4/ recommending core drilling by the Bureau of Mines. The drilling project, which was supervised by the author, was started on January 10 and completed on May 10, 1946.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative work, and prepares the final report. The Metallurgical Branch, O. C. Ralston, chief, analyzes samples and performs beneficiation tests. Acknowledgment is made to W. D. McMillan, engineer in charge of the Austin field office, and to J. H. Hedges, chief of the Tucson Division, Mining Branch, for general direction and advice. The samples were analysed in the laboratory of the Metallurgical Branch at Rolla, Mo., C. Travis Anderson, chief."

May 1, 1947

By A. U. Miller

Protection against fire is a greater problem at a coal mine, than at an ordinary industrial plant. Generally mines are located in isolated districts and do not have the protection of city fire departments; consequently fire fighting aquipment must be installed by the mining company. Fire protection around a mine is just as essential as it is in the city.. and undoubtedly is more important if the fire should be underground where many lives would be endangered and all means of escape cut off. A surface fire can generally be attacked from any angle, but an underground fire can be attacked only as conditions will permit.. U. S. Bureau of Mines engineers have investigated many serious mine fires that undoubtedly could have been extinguished in incipiency if a fire extinguisher or fire hose and water had been readily available. In past years very little attention was given..to fire fighting equipment and organization around mines, but in recent years three gen a derde hange of opinion among many of those engaged in mining, and nearly all up-to-date mining companies now have some kind of fire protection about their mine Probably the first company in Illinois to install regular fire fighting equipment and effect a fire fighting organization at its mines, was the Madison Coal Corporation, which operates several mines in Illinois. The main office of this company is in Chicago and the general field office is at Glen Carbon, Ill.

Jul 1, 1930

By J. Bruce Clemmer

[Gypsum is one of the mo .. t iJf.l)ortant nonmp.tal1.ic T!1inerals, as is indicat-? ed by the fact that tlle Uni ted states cO!1sUl:Ied p, roximn..tely 3,500,000 tons of natura.l and calcinecl e::,j;-psum in 1937. The b\.'.ilr:.in.; traces \"fe.ro the largest users and required 2,520,000 tons of calcine for the r-roductiop. of plaster,]

Jan 1, 1941

By R. R. Wells

This report summarizes the results of preliminary mineral-dressing studies by the Bureau of Mines on five samples of copper-bearing ore from various Alaska de-posits. The work on each sample was not extensive enough to warrant individual publication. The results, however, indicate the possibilities and limitations of concentration of the respective ores. The information therefore may be helpful in future development of these ore bodies. Four of the five samples tested were submitted to the laboratory by engineers of the Bureau of Mines as part of the examinations and survey investigations of strategic-mineral deposits in Alaska. This program is conducted to assist development of mineral resources in the Territory and particularly to aid economic exploitation of marginal or complex ores. The fifth sample was submitted by engineers of the Defense Minerals Exploration Administration.

Jan 1, 1956

By Zsuzsanna Zborovszky

Investigation of the discharge duration power and current relation required for ignition. The current and power amplitude-discharge time curve was found to flatten out over 3 ms. It is concluded that discharges having at least 3 ms power maximum are required for reliable testing of the ignition limit for resistive circuits. Investigation of the effect of molten cathode on the discharge duration and igniting ability of the discharge. The surface tension of the liquid metal causes a very fast separation and consequently a much shorter discharge duration than the solid electrode would have. The minimum discharge voltage effect overrides the effects of the temperature of electrode, material, or atmosphere. Investigation of the effect of different surface layers on the discharge duration. Oxides and sulfates were found to give significantly longer duration than the "clean" metal itself in most cases. The lowest ignition current was obtained with CdS04 coatings. Ignition was obtained with 0.7A at 30V, which is below the corresponding minimum igniting current obtained from the BASEEFA curve for circuits containing Cd, Zn or Mg.

Jan 1, 1977

By J. A. HUFF, V. V. BAKER

This circular contains a statement of the statutory provisions of the several States regarding the appointment , qualifications , and remuneration of State mine inspectors . States have been omitted where no specific provision has been made by the State law for mine inspectors .

Jul 1, 1931

By J. Bruce Clemmer

[Gypsum is one of the most important nonmetallic c minerals, as is indicated by the fact that the United States consumed approximately 3,500,000 tons of natural and calcined gypsum in 1937. The building trades were the largest users required 2,520,000 tons of calcine for production of plaster, wall board, tiles, block, and various other insulating and building materials. The glass and ceramic industries and other manufacturers required an additional 126,000 tons. The balance was used in the uncalcined condition as retarder in Portland cement and or agricultural purposes.]

Jan 1, 1941

By K. R. Van Doren

The polynomial method for estimating virial coefficients from experimental data suffers from three serious defects: (1) There is no known relationship between the polynomial coefficients and the virial coefficients, (2) the values of the estimates depend upon the degree of the polynomial and the particular set of values used for the independent variable, as well as the random errors in the dependent variable, and (3) the variances calculated for the estimates do not represent the mean square errors of estimation. Attempts to overcome these defects have thus far been unsuccessful; these attempts have also failed to account for the fact that none of the virial coefficients are uniquely determined by the values of the dependent variable for a finite set of values of the independent variable. The conclusion is that virial coefficients cannot be reliably estimated from experimental data unless additional information about the virial expansion itself, such as its rate of convergence, is available.

Jan 1, 1969

By Joseph A. DeCarlo, Eugene T. Sheri dan

The process of converting coal into coke is known as carbonization. Essentially, carbonization is destructive distillation in which the volatile matter of coal is released when coal is heated above its decomposition temperature and passes through a plastic stage before solidifying and forming coke. The mechanics of coke formation are complex, and the specific properties of certain coals that allow them to "cake" or form coke are still unknown. Coke is a hard, cellular, carbonaceous mass, formed by heating coal in the absence of air. It is porous, irregular in size and shape, and is similar in appearance to wood charcoal. Coke, however, is denser, more porous, and more abrasive than charcoal. Coke has been in use for several thousand years. History has recorded its use in Greece before the birth of Christ, and it is thought to have been used in China even before that time. It was not until the l6th century, however, that a method for coking was developed in Europe that subsequent ly evolved into the coking process that is known today. The coke industry in the United States began in the latter half of the 19th century when beehive-coke ovens were built to supply fuel for iron blast furnaces. Before this time, an iron industry fueled principally by charcoal had been in existence for several hundred years. With the depletion of timber resources, coke gradually replaced charcoal as blast-furnace fuel, and by 1875 more iron was made with coke than with any other fuel. Before 1893 a 11 coking was done in beehive ovens. These ovens are refractory kilns with arched roofs, sometimes joined together to form batteries.

Jul 1, 1964

By R. A. Cortese

The U.S. Bureau of Mines has developed a flame-radiation-powered trigger device to explosively activate suppression barriers to quench gas and coal dust explosions. The major component of the device is a silicon solar panel, which converts radiation from the developing explosion into electrical energy to initiate an electric detonator, which releases an extinguishing agent into the advancing flame front. Solar panels that are rated to produce 20 W of electrical power when exposed to the sunlight are producing about 200 W when exposed to a full-scale dust explosion. The solar panel is electrically isolated from the detonator by a pressure-sensitive switch until the arrival of the precursor pressure pulse, which always precedes a deflagration. This combination of pressure arming and flame-powered photogenerator prevents false barrier activation and requires no external power supply.

Jan 1, 2010