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By D. R. Mathews

The solubility of carbon in electrorefined vanadium was determined to be approximately 0.27 wt pct at the eutectic temperature 1,650° C and 0.03 wt pct at 700° C. The tensile strength and hardness of vanadium increased with car-bon content to the solubility limit, but this effect was small, probably because of the narrow solubility range. Between the solubility limit and 0.3 weight-percent carbon, the second phase had essentially no strengthening effect in vanadium. The second phase, observed metallographically at the grain boundaries and within the grains, was shown by autoradiography to contain high-carbon concentrations. This second phase was identified as VgC by X-ray analysis. The VgC in the grain boundaries contributed largely to the poor cold-and-hot workability of vanadium-carbon alloys. Increased concentrations of V2C occurred at the grain boundaries of the high-carbon alloy ingots as a result of homogenization at 1,600° C for 1 hour. Alloy ingots containing more than 0.36 wt pet carbon (a calculated 2.9 wt pct VaC) following homogenization, cracked severely and failed by intergranular fracture upon swaging at 900° C.

Jan 1, 1965

By John Ward Smith, Neil B. Young

Shale specific - gravity to oil - yield relationships were developed for black shales of the New Albany Formation of Kentucky from data collected on core samples representing the complete section of the formation in three counties . Linear equations for estimating oil yield from measured specific gravity and for estimating specific gravity from measured oil yield were shown to be applicable within small error limits to all the sites tested . Variation in pyrite content is the largest source of error .

Jan 1, 1964

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By Paul M. Tyler, Amy B. CLINTON

The four elements fluorine (F), chlorine (C1), bromine (Br), and iodine (I) form the most intimate family in the entire system of elements and are grouped under the name "halogens" or salt formers (by derivation from the Greek). The first member of this family, fluorine, is the most chemically active element known; and fluorspar, and to a less extent cryolite, the chief sources of fluorine, are important commercial minerals. Fluorine occurs in nature chiefly in combination with sodium as common salt, but it also appears in other natural compounds in sea water, salt-well brines, and bedded deposits. In addition to common salt, various compounds containing chlorine (chlorides) have long been consumed by industry on a large scale, and within the last two decades that element itself has come rapidly into prominence as one of the leading industrial chemicals. Bromine and iodine, the two retaining members of the family, are less abundant in nature and less readily isolated and in consequence of their relatively high price have found few industrial uses, being consumed chiefly in medicine and in photography. Bromine, however, is now entering the industrial field to a considerable extent, due to the rapidly growing use of ethylene dibromide in anti-knock compounds for gasoline. The present paper is devoted to bromine and iodine, but in order to compre- hend the physical and chemical characteristics of these two elements (and hence their potential economic significance) it is convenient to consider them as members of the family series to which they belong. The family relationship of the halogens is illustrated by the following:4 (1) The similarity in the chemical and physical properties of the elements and their corresponding compounds is such that the prop- erties of any one member of the family can be said to summarize or rather to typify the properties of all the other members, although fluorine diverges a little in some of its properties. (2) The gradual transition of chemical and physical properties is such that if the elementa are arranged in order F, Cl, Br, I the variation in any particular property in passing from fluorine to iodine nearly always proceeds in the same order, and that is the order of their atomic weight. Taxing almost any property and comparing its magnitude in passing from the element fluorine to iodine, or from the fluorides to the iodides, a similar graiation will be observed. Thus, take the melting point of the cadmium, calcium, barium, sodium, or potassium salts, in degrees.

Nov 1, 1930

This manual provides instructions for installling, operating, and maintaining protective canopies on the Joy Mfg. Co. cutter. These instructions are based upon two actual installations: one made in a mine and one in the factory. The parts list and engineering drawings for the protective canopies are included at the end of the manual. And a discussion of some alternative design concepts is also included. The manual can also be used for retrofitting other cutters with similar protective canopies. Skilled mechanics can determine if the instructions herein would be applicable to the other cutters and can determine any necessary modifications if they are not.

Jan 1, 1973

By T. T. Campbell

This report traces the development of techniques for the preparation of high-purity rare-earth metals. Rare-earth metals, excepting samarium, europium, and ytterbium, were prepared by converting their oxides to anhydrous chlorides or fluorides and reducing the rare-earth halides with active metals such as lithium or calcium. High-purity, anhydrous rare-earth chlorides were prepared by dissolving the rare-earth oxides in hydrochloric acid to form hydrated chlorides and by subsequently dehydrating the hydrated salts in the presence of ammonium chloride at temperatures ranging from 70° to 360° C. while under reduced pressure (50 microns to 1 inch Hg). The chlorides were also prepared by direct chlorination of rare-earth oxide-carbon mixtures. Reaction efficiencies in excess of 95 percent were obtained by either method; however, purer chlorides were prepared by the aqueous ammonium chloride conversion method. Purification of yttrium chloride by high-temperature vacuum distillation proved to be an effective method of separating, oxygen-bearing compounds from the chloride. Yttrium metal prepared from purified chloride contained significantly smaller amounts of oxygen (990 p.p.m. oxygen in yttrium metal prepared from raw chloride and 200 p.p.m. in that prepared from distilled chloride).

Jan 1, 1961

By Graham W. Marks

In broadening the utility of spectrochemical methods 9f analysis of ore samples 3,4/ a procedure employ in the total energy method, has been adapted to determination of silver in ores. Silver is the first element in group I of the periodic table to be studied in the Bureau of Mines program. Two silver lines in the spectrum, Ag X\ 3280.683 and 3382.89lR were used in the study, and the problems that had to be overcome were: (1) Influence of extraneous elements on line intensities, (2) preparation of standard curves, and (3) improvement in equipment and technique to increase accuracy. Sodium, potassium, sulfur, selenium, iron, cobalt, and nickel yielded low intensities and hence low results, particularly on the samples high in silver, but addition of 60 percent or more of lime counteracted these effects. One calibration curve must be used for samples low in silver and other for those high in silver. The chocks with fire assaying were close enough for preliminary or exploratory investigations, and the method is much more rapid.

Jan 1, 1948

By Jacob Schoder

This is one of a series of papers published by the Bureau of Mines on mining and milling methods and costs. The Tennessee-Schuylkill Corporation, Chloride, Ariz., mines and mills a lead-zinc ore containing gold, silver, and a small amount of copper. The mill products are lead and zinc concentrates that are shipped to smelters. The company was the second largest producer of lead and zinc in Arizona in 1937 and was seventh in gold production. Operations discussed are those being conducted at the mine in October 1938 and are representative of the complete operating period from 1936 to date.

Jan 1, 1939

By R. R. Sayers

Mine operators and managers for a number of years have known that the maintenance of health among the workers has an appreciable financial value, In order to maintain the health, it has been found ne cessery to imow; 1. The health hazards existing in the industry as a whole and the specific hazard in the individual mine. 2. The physical condition of applicants for employment as well as that of the old employees. This can be determined only by systematic physical examination of all applicants and of regular employees at intervals of at least once a year thereafter. 3. All cases of sickness that occur among the workers. No operator or manager, or personnel, medical, or safety organization can control or prevent sickness without knowing where, when, and under what conditions the sickness actually occurs. In order to obtain information as to the hazards of industry, investigations have been and are being made of the effects of the condi- tions both in the field under usual working practices and in the laboratory. In the field several factors are generally present which affect the health. The effect of these factors may be determined by studying each of them separately in the laboratory. However, both the field and the laboratory studies are limited in value in that such studies usually have been made over a comparatively short period. While we have some information as to their immediate effect, we do not know to what extent extreme heat, humidity, the presence of dust or other health hazards are the cause of disability. Mortality statistics are probably the most easily available indices as to the hazards of industry. As an example, a study of such statistics among coal miners of Indiana shows a marked increase in the death rate in 1918.

Mar 1, 1923

By Joseph M. Pugliese

This work was done by the Bureau of Mines to provide quarry operators with an uncomplicated, first-approximation method for designing blast patterns, considering geologic structure, and to show the valid use of the technique by comparing drill and blast pattern dimensions used in the quarry with those determined by the presented method. The author visited 12 limestone and dolomite quarries in Ohio (Adam, Crawford, and Highland Counties), Wisconsin (Milwaukee, Racine, and Waukesha Counties), and Minnesota (Fillmore, Olmsted, and Wabasha Counties); observed the blasting practices; studied the major geologic features; and after discussion with the quarry managers, foremen, and blasters, compared the quarry blasting patterns with those as calculated by the empirical formulas (after R. L. Ash), with geologic structural considerations. When geologic structure such as bedding, jointing, folding, and caves, as well as explosive properties and field performance characteristics are accounted for in a manner suggested by the research, the presented empirical formulas may be used as a good first approximation. The included steps in planning a blast design and generalized blast patterns should be of help to the quarry operator. Design changes are recommended for those quarries where problems are occurring.

Jan 1, 1972

By G. E. McElroy

Changes in existing airway and fan-installation conditions offer the most common opportunities for effecting economical operation of mine ventilating systems, but the largest possibilities for securing this result lie in the original design of the main airways for efficient service. Formulas, and. charts for their graphical solution, are presented herewith for the determination of the elements of airways design when the conditions of service are known, or may be roughly approximated. Although the analyses are made with particular reference to metal-mine airways, there is no essential difference between metal and coal mine main airways, and the methods presented are equally applicable to both. Little attention is paid to designing airways for maximum economy in the ventilation of metal mines. Most of the openings used as main airways are originally designed and used for transportation and other operating purposes. Even where openings are made primarily for ventilation, the possibility of their future use for other operating purposes, or even custom alone, usually results in the selection of a size and shape similar to those of existing openings. Natural conditions, such as heavy ground, often seriously limit the size of opening that can be maintained without excessive expense; and various operating factors, such as velocity limitations on traveling roads, often dictate size requirements in excess of those required for economy in ventilation only. In metal mines the main airways are, as a rule, too small rather than too large for economic service, with the general result that the quantities in circulation are often less than the mine's proper requirements over long periods, even though excessive amounts of power are applied in an effort to remedy conditions.

Jan 1, 1932

By Jr. Fish

As a part of a study of iron are resources in the Appalachians, 9 diamond drill holes aggregating 1,580.7 feet were drilled in a portion of the Butt Mountain area of northeastern Giles County, Virginia. Three hematitic sand-stone beds were intersected in the Clinton formation but only one was consistent in thickness and grade in all 9 drill holes. This bed averages 18.9 percent iron over an average thickness of 24 feet. The drill cores were logged and chemical analyses were made on 161 individual samples and 22 composite samples. Beneficiation studies were made of three composite hematitic sandstone samples each representing a separate bed containing 14.6, 19.8 and 20.0 per-cent iron. Major mineral constituents of the samples were hematite, quartz, and sericite.

Jan 1, 1967

By Ernest Ph. Hérivel

The mine and treatment plant of the Teziutlan, unit of the Mexican Corporation, S. A., are located at Aire Libre, in the District of Teziutlan, near the northwest edge of the State of Pueblo, Republic of Mexico. The property is leased from the Teziutlan Copper Co. The town of Teziutlan is the terminus of a branch railroad starting from Oriental Junction or the Mexico-Jalapa-Veracruz narrow-gage system of the National Railways of Mexico. A branch line 18 km in length from Teziutlan to Aire Libre belongs to the Teziutlan Copper Co. and is leased and operated in conjunction with the mine.

Jan 1, 1933

By Walter D. Holland

This document is one of a series of instruction guides developed to help instructors present health and safety training courses to workers in the metal and nonmetal mining industry. This course is intended to provide above ground metal and nonmetal mining employees with training which will assist them in performing their work safely and healthfully. A document entitled, "Airborne Contaminants in Above Ground Metal and Nonmetal Mining and Processing Work Areas," is used as a manual for the students during the course. The unique features of the teaching guide are thumb rules for recognizing hazardous situations, candidate contamin¬ants for each work area and descriptions of control devices and work procedures.

Jan 1, 1977

By Lung Cheng

Based on earlier tests that showed steel to be much more likely to cause frictional ignition than tungsten carbide, the Bureau of Mines redesigned coal-cutting bits to reduce the hazard of face ignitions. Two bit designs--a mushroom-shaped bit with a conical shank and a dove-tail bit with a rectangular shank--are described, as well as bit wear tests conducted in the laboratory and in an operating coal mine. In laboratory tests, for 1/8-, 1/4-, and 1/2-in-deep cuts and cutting speeds of 280, 500, and 660 ft/min, the mushroom bit had significantly longer tip wear life than the conventional bit; the dovetail bit was also superior to the conventional bit. Results of in-mine tests on the mushroom bit agree well with laboratory results. In-mine tests of the dovetail bit are underway.

Jan 1, 1983

By Jack I. Paige

The Bureau of Mines conducted studies to provide data on the room temperature mechanical properties of Ti-6Al-4V alloy cast in waterglass-bonded zircon sand and to determine the effect of hot iso-static pressing (HIP) on these properties. Data on the cast and annealed Ti-6Al-4V alloy were compared with published data for forged and investment-cast Ti-6Al-4V alloy. The average Charpy V-notch impact strength compared favorably with the typical values of 17 ft?lbf for wrought material and 19.2 ft?lbf for investment-cast material. The room temperature mechanical proper-ties of cast and annealed material compared favorably with published values for investment-cast Ti-6Al-4V alloy and exceeded the specifications for (1) titanium and titanium alloy castings, grade C-5 according to ASTM B367-69, and (2) titanium alloy bars and forgings as specified in AMS4928H, except for the AMS4928H minimum requirement for reduction in area (25 pct). The minimum requirements are: tensile strength, 130 ksi; yield strength, 120 ksi (0.2 pct); and elongation, 6 pct. None of the specimens tested met the AMS4928H minimum requirement for reduction in area. The HIP process healed the internal casting porosity in the test specimens, but the fatigue strength was not significantly improved. The fatigue properties of both the cast and cast plus hot isostatically pressed castings were significantly lower than those of wrought products.

Jan 1, 1984

By Richard D. Hagni

The character of phosphorous-bearing minerals in the Birmingham red Iron ores and iron-bearing minerals in the Eufaula bauxite deposits in Alabama has been Intensively studied by petrographic, ore microscopic, luminescent microscopic, scanning electron microscopic, electron microprobe, and x-ray diffraction techniques. A total of 15 types of phosphorous-bearing mineral grains have been recognized in Birmingham iron ores by their characteristic sizes, shapes, and distributions. Size measurements, modal analyses, and texture analyses have permitted an estimate of potential liberation of phosphorous from the iron ores by beneficiation to be 27% In areas of previous mining and 60% in areas of current iron reserves. Fine grinding, selective flocculation, and flotation may constitute the best beneficiation technique for future research. Hematite and goethite are the most important iron minerals in Eufaula ferruginous bauxites, but pyrite, marcasite, and siderite are Important iron minerals in some varieties of ferruginous bauxite, and lepidocrocite and ilmenite occur locally in minor quantities. Although simple screening will remove the coarsest iron-bearing grains, research on the utilization of high gradient magnetic separation to reduce the amounts of iron-bearing grains is recommended.

Jan 1, 1981

By Roy J. Greenfield

The overall purpose of this research was to improve the understanding of how the post disaster seismic location system works, what determines the signal size, what is the character of the seismic noise, how well the system can detect blows from a trapped miner, and how well the source of the blows can be located. Based on an improved understanding of the system, improvements were suggested in the seismic subarray configuration, and in the system deployment procedures. An important part of this research was to become familiar with the seismic system operation and to work with the Westinghouse Electric Corporation and MSHA personnel to modify and improve the system. To accomplish this we participated in the planning, execution, and data analysis for a number of seismic field tests. Several in-mine field tests were conducted. From these tests the capabilities of an in-mine seismic system were analyzed and specifications were made for designing an operational in-mine system. Several portions of the work done on this grant were covered in previous reports. In particular the capabilities or the presently operational surface based seismic location system has been thoroughly documented by Durkin and Greenfield (1981). Portions of the location procedures and effects of mine openings on seismic signals have also previously been published. These portions or the work will only be summarized in this final report.

Jan 1, 1982

By Linda C. Carrico

Those who manage the Nation's mineral resources rely upon a variety of organizations both public and private--to give them accurate mineral data, technical guidance, and expert advice. This directory provides a list of such organizations--a list that should prove a useful tool for those seeking mineral-related information and technical assistance. The directory lists Federal and State governmental agencies and national, regional, and State associations with activities in the mineral, metal, and material sectors of the economy. These organizations regulate mining, monitor mineral production, establish and enforce health and safety standards, identify and evaluate mineral resources, conduct scientific research, predict market trends, resolve environmental issues, and promote the interests of the mineral industry, its individual sectors, and its workers--to name a few of their functions. The listings in this directory--arranged by State--should help users who manage mineral resources identify agencies and organizations that can provide mineral-related information or technical assistance.

Jan 1, 1993

By Gerald T. Homce

A system capable of monitoring mine electrical power systems and detecting impending component .failure could significantly improve power system safety and reduce unscheduled equipment downtime. Such monitoring would require a method of evaluating electrical parameters, calculated from terminal values, for indications of component deterioration. The U.S. Bureau of Mines has targeted electrical failure of squirrel cage induction motors and examined the use of mathematical models to aid in this evaluation. The initial stage of this work is complete, and has produced polynomial networks called adaptive learning networks (ALN's) that can detect and quantify winding insulation leakage simulated on laboratory motors. In this modeling process, empirical data from laboratory motors were used to select the electrical parameters most significant for assessing? motor conditions, and mathematical expressions relating these parameters to simulated deterioration were formed. ALN's developed thus far can process readily measured motor terminal information and quantify power and current levels of laboratory-simulated leakage to within 1% and 3% of full load values, respectively, for motors in the 10-to 150-hp size range. The next stage of this research is validation of these ALN's for actual motor failures; this stage is currently underway, using accelerated life testing of laboratory motors.

Jan 1, 2010