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By D. J. MacDonald

The Bureau of Mines has conducted bench-scale investigations leading to the design of an integrated process for producing reactor-grade zir-conium oxide (Zr02) from zircon sand, which avoids the air pollution, water pollution, fire hazard, and odor problems associated with the hexone-thiocyanate process. The integrated process consists of three steps: production of crude zirconyl sulfate solution, solvent extraction, and production of Zr02 from strip liquor. This report describes the solvent extraction step. Multistage, countercurrent liquid-liquid extraction with a tertiary amine in kerosine was used to separate zirconium from a dilute H2S04 solution containing hafnium and other impurities. Process steps de-scribed include extraction from an aqueous feed solution to form a hafnium-contaminated, zirconium-bearing organic-phase solution, scrubbing to separate zirconium from coextracted hafnium, stripping to transfer hafnium-free zirconium into an aqueous strip liquor, chloride-loading to produce a chloride-bearing organic solution, scrubbing with the chloride-loaded organic solution to remove traces of uranium impur-ity from the zirconium-bearing strip liquor, and regeneration to pre-pare the organic solution for reuse. These steps were performed simul-taneously in steady-state, bench-scale experiments. Zirconium recovery of up to 93 pct was achieved. Results of an economic evaluation are included.

Jan 1, 1984

By L. S. Harner

This paper which describes the milling practice at the Golden Cycle mill is one of a series of similar papers being prepared by the United States Bureau of Mines. The mill of the Golden Cycle Corporation, formerly known as the Golden Cycle Mining and Reduction Co., is located at Colorado Springs, Colorado, and has been operated since 1907. It is now and has been from its inception almost exclusively a custom mill.

Jan 1, 1933

By G. L. Oldright

In the first Report of Investigations of the present series?(No. 4562) the usual course of progress ill reducing the minerals of low-grade ores to their valuable metallic components had been noted as advancing along two lines to concentrate a usually diminishing percentage of these minerals to a smaller bulk of richer product, and then to smelt the smaller bulk more cheaply per pound of metal produced. Fundamental properties of lead compounds made it difficult to treat much richer lead products than are treated at present in several steps of conventional lead smelting, unless ?marked modifications were made. No limits to the richness of the feed itself' were set by the ore (Scotch) hearth; on the contrary, the richer the feed, the better the results given by the hearth. The natural field of operation of the hearth, as determined by the ores available, was seen to lie in the Central United States, with their lead concentrates containing negligible quantities of precious metals and. with few ores of such metals available for use as fluxes. It was noted) however, that even in its chosen field, the Scotch hearth, or "ore" hearths developed from them, was not always used; the usual smelting practice was followed, at times, of sintering followed by blast-furnace smelting for even rich ores.

Jan 1, 1949

By Gerhard Braüner

The present knowledge on ground movements and mining damage is mainly based on observations made when mining seamlike deposits. The studies, rules, and regulations in different countries agree in that the differential ground movements, especially the strain, account for the damage to structures. Accordingly, large buildings are particularly susceptible. The opinions on what amount of ground deformation induces what degree of structural damage are not quite uniform. Mining damage can be reduced or prevented by structural and/or underground precautions. The latter comprise measures for generally reducing the ground movements (leaving pillars, filling, partial extraction) and for reducing temporary movements (rapid extraction, specially arranged workings). Because the differential movements decrease with increasing depth of mining, safety pillars are largely dispensable at greater depths. Shafts are mainly affected by the vertical derivatives of rock displacements, but extraction in the vicinity of shafts is feasible even under difficult conditions. The theoretical concept of the ground movement process established in part 1 of this work is in qualitative agreement with the facts herein observed. As a quantitative approach, it should be applied to calculating ground surface movements rather than rock movements about underground openings. It can be extended by introducing more detailed strata characteristics.

Jan 1, 1973

By Edmund Newton

This paper is one of a series comprising the Mineral Industries Survey of the United States, which was begun in 1935. It describes the simple methods of mining and beneficiating manganese ore, in eastern Tennessee and compares these methods with those used elsewhere in the Appalachian region. The report contains general information on manganese to give a clearer understanding of the methods and costs of mining and. beneficiating manganese ore foam a widespread deposit, an in addition presents zone difficulties normally fond in these operations. The marketing, uses, and value of manganese ore are discussed as well as the amount of capital necessary for effective operation on given scale of production, and requirements are outlines for successful operation of manganese, property in this region.

Jan 1, 1941

By Arthur V. Petty

In Bureau of Mines research on recycling chrome-containing refractory wastes, used refractories from argon-oxygen decarburization and electric steelmaking furnaces were beneficiated. By means of dry magnetic separation on minus 6-mesh crushed wastes, a concentrate was produced. After minor adjustments to the particle size distribution, full-size refractory brick were dry-pressed by a commercial producer and fired to 1,450° and 1,730° C. Standard testing procedures were used to determine the cold-crushing strength, modulus of rupture at 25°, 1,300°, and 1,500° C, hot load, thermal shock resistance, thermal expansion, and slag resistance. Optical and electron microscopy were used to determine grain-bonding mechanisms, and energy-dispersive analysis of X-rays was used to determine elemental distribution. The test results indicate that the beneficiated material could be used to produce a refractory product suitable for moderate-temperature applications.

Jan 1, 1982

Senior staff representatives of the Bureau of Mines and the National Institute for Occupational Safety and Health (NIOSH) met in Washington on September 6, 1972, to review and evaluate their cooperative accomplishments to date and to consider the planning and conduct of future coordinated activities. The six presentations given at this joint staff seminar are published here for the benefit of those concerned with the problems of coal mine health, and especially those with responsibilities in administering the Coal Mine Health and Safety Act of 1969.

Jan 1, 1972

By James R. Kerr

Although metallurgical benefits of processing metals in a vacuum or reduced atmosphere have been realized for a hundred years, the problem of creating a vacuum in the range from 10-0 to 10-4 mm. of mercury in a moderately sized furnace chamber has been difficult to solve. The demand for these and lower pressures, with the advent of World War II, for separating the fission-able uranium isotope from its stable twin by the electromagnetic process, gave impetus to developing pumps capable of delivering extremely low pressures. With the release of data by the Atomic Energy Commission on methods of securing high vacuum in large equipment, steel companies took the initiative, and the growth of the vacuum-melting industry was assured. Vacuum-induction melting of steel in the United States began on a small scale in early 1945 and in 10 years grew to 60,000 pounds per month or 720,000 pounds per year. The years following 1954 showed tremendous expansion, culminating in 1958 in a capacity of more than 36 million pounds.

Jan 1, 1962

By Ernest E. Berger

"INTRODUCTIONOne of the outstanding problems in the normetallic industries, and one which involves two of the greatest of these industries, cement and gypsum, is the reaction of Portland cement with calcium sulphate. To all Portland cement clinker there is added in the manufacturing process, a small amount of retarder, as a necessary ingredient of the finished product. This retards the initial set, increases the strength, and adds to the plasticity of the cement so it will have the desired working and setting qualities. The retarder commonly used is gypsum, (CaSOA.2HO), which is the hydrous form calcium sulphate. Calcium sulphate is also available as plaster of Paris (CaSO4 1/2 HC) and anhydrite (CaSO4). The purpose of this inquiry was to determine the form or mixture of forms best adapted for retarder. The problem is complicated by the fact that cement clinker is a complex mixture of calcium silicates and aluminates, and that clinker from different mills, making cement of approximately equal quality, differs considerably in chemical constitution. Thus the same retarder may give very different results with different types of clinker, especially in the percentage of retarder required for the same degree of retardation.It has been known for some time that a small percentage of plaster of Paris will greatly retard the time of set of Portland cement as well as increase its strength and plasticity, but whether gypsum and anhydrite will have a similar effect is as such disputed question. The offects of gypsum have received little consideration in laboratory research because, even though it will not retard a clinker when the two are mixed in the laboratory, as has been noted in some instances, the cement will have a normal set when the two arc mixed in the large tube mill at the plant, so that practically, gypsum seems to be equally as goou as plaster of Paris, and because of the great saving in cost it has been used almost exclusively."

Sep 1, 1925

By Raymond O. Dannenberg

The gas-combustion retort developed by the Federal Bureau of Mines at the Rifle Oil Shale Project near Rifle, Colo., is a continuous, gravity-feed retort. The heat required to convert the kerogen in the oil shale to liquid oil is generated by the combustion of product gas and carbonaceous residue remaining on the retorted shale after the kerogen has been converted to oil, gas, and residue. A study of the effects of the process variables on retort operation, product yields, and product properties is important to the successful solution of the problems encountered in the development of a satisfactory process. Statistical methods were used to design the experiments and analyze the effects of the rate of shale throughput, the composition of dilution gas, the height of the shale bed above the air entry, air-gas distributor design, shale size range, and the ratios of the flow rates of the various gas streams entering the retort to the rate of shale throughput.

Jan 1, 1960

This section presents highlights of world economic and mineral industry performance in 1982, a year characterized by continued recession, and selected 1983 forecasts of economic indicators of importance to the mineral industry, some of which indicate a modest improvement in the economies of the United States and Western Europe. The U.S. Economy in 1982 In 1982 U.S. gross national product (GNP) in current dollars increased at a rate of 4 percent, but GNP adjusted for inflation (real GNP) declined at a rate of 1.8 percent. Yearend 1982 real GNP was at roughly the same level as in 1980 (table 1). Thus no growth in real terms had taken place in the United States during the 1980-82 period.

Jan 1, 1983

By Richard S. Gaps

The Derby and Alexander Claim, located within the Tunnel Ridge Wilderness Study Area (WSA), has placer gold resources. No lode deposits are known within the area, but lode gold deposits are found within 1 1/2 mi of the WSA. In additon, rock units which contain lode gold deposits north of the WSA are found within the northern portion of the study area. INTRODUCTION The Tunnel Ridge Wilderness Study Area (WSA), CA-030-402, encompasses 4,623 acres of BLM administered public land in Trinity County, California, about 35 mi west-northwest of Redding (fig. 1). Major access to the Tunnel Ridge vicinity is by U.S. Highway 299. Ac-cess to the WSA boundary is by a secondary paved road from Junction City and several light duty dirt and gravel roads (fig. 2). The WSA is on the southwest slope of Weaver Bally Mountain. The topography is rugged with moderate to steep slopes; elevations range from about 1,600 ft to 5,900 ft.

Jan 1, 1983

By Frank E. Cash

As a part of its safety program the United States Bureau of Mines has fostered the development, use, and improvement of portable electric mine lamps. Although there is still need for better illumination in mines and the replacement of open lights has been slow, improvement in electric cap lamps and increase in their use indicate one phase of recent progress toward safer and more efficient mining This report is the result of a recent survey of electric-lamp installations in the Alabama mining; district; it shows the misuse, increase in use, and relation to certain classes of accidents of these installations.

Jan 1, 1935

By B. J. Moore

This publication contains analyses arid related source data for 274 natural gas samples from 20 States. Of the total samples, 269 were collected during calendar year 1985; the reminder were collected earlier, but releases granting permission to publish were not received before 1986, All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1987

By J. D. Lane

The U.S. Bureau of Mines is conducting research on guidance systems for computerized haulage in underground mines. This report describes the process of component selection, installation and testing, perception algorithm development, and steering control algorithm development, to produce a real-time steering control system for an articulated haul truck for underground mining. Ultrasonic transducers were mounted on the truck to provide perception data by measuring the distance to the ribs. Linear potentiometers mounted inside the steering cylinders measured the steering angles. Algorithms, implemented on an inexpensive, robust onboard computer system, analyzed the data and controlled the steering via an electro-hydraulic proportional valve. The steering algorithm presented follows a zone defined by the relative position between the truck and a rib. Experimental verification of the ability to follow the zone in a test corridor on the Colorado School of Mines campus is presented. The automatic steering system successfully negotiated straight sections, curves, and the transition zones between straight and curves with the truck in first and second gears. The resulting real-time automatic-steering system can be applied to many underground articulated machines.

Jan 1, 1994

By Hanns J. Billmayer

Optimized Operator Compartment layouts based on previous Bureau of Mines activities in standardization and optimization of controls were designed and installed in three operating vehicles. Two National Mine Service 48A-36 TorKars were modified in production prior to delivery to the Quarto Mining Company. An Elkhorn AR-4 scoop owned by Adanac Coal Company was modified in a local rebuild shop. The modified vehicles were then evaluated underground under normal production conditions for a 60 day period. Vehicle operators and management appear well satisfied with the compartment modifications.

Jan 1, 1976

By Francis E. Federspiel

A mineral purvey of the Granite Chief RARE II area (A5-261), covering about 23,400 acres (9,470 ha) of Tahoe National Forest and the Like Tahoe Management Unit, was conducted by the U.S. Bureau of Mines and the U.S. Geological Survey in 1979 and 1980 (fig. 1). The investigation by the Bureau of Mines indicates that the area has a low potential for mineral resources. Samples taken from prospect pits and favorable outcrops indicate no minable quantities of precious or base metals. Placer deposits are too small and low grade to be considered a resource.

Jan 1, 1981

By McMillan W. D.

Vermiculite is the name of a group of micaceous minerals characterized by their property of exfoliating when heated and thereby increasing many times their original volume. The resulting product has excellent heat-and sound-insulating properties, is used as a lightweight aggregate, and has numerous other industrial applications. Deposits of vermiculite occur in areas of pre-Cambrian rocks of the Llano uplift of central Texas, particularly in Burnet and Llano Counties. Because of the growing economic importance of vermiculite products, the Bureau of Mines undertook a detailed investigation of several deposits in Llano County. This investigation was completed in February 1947. The work comprised topographic surveys of five deposits, drilling with a 4-1/4 inch Parmanco power auger drill, and laboratory evaluation of samples. 342 drill holes, aggregating 4,905.5 feet, were completed, and 377 samples were taken. Laboratory evaluation of the vermiculite comprised expansion tests on both crude and beneficiated samples. The products obtained were compared with commercial-grade vermiculite from Montana.

Jan 1, 1949

By John W. Moore

The discovery of porphyries in petroleum by Treibs (17-19) is one of the most significant achievements relating to the origin of petroleum. The presence of these remnants of chlorophyll and hematin in petroleum has immediate practical interest in several aspects of the petroleum industry. Because of their interfacial activities and film-forming tendencies, the metal-porphyrin complexes may be expected to affect the wettability of petroleum-reservoir rock surfaces and influence the flow of fluids in these reservoirs. Also, studies of the relationship of trace elements and porphyrins in petroleum may be expected to yield valuable information on source beds and petroleum migration. Finally, the extreme stability of several metal-porphyrin complexes complicates removal of these metals from some petroleum stocks where they exert deleterious effects on processing and utilization. Metal-porphyrin complexes are commonly associated with the asphaltic residues of crude oils in which they occur (8, 9, 15). However, investigations in this and another laboratory (15) show that small amounts of these complexes often remain in partly refined petroleum products, such as thermally cracked distillates and deasphalted stocks.

Jan 1, 1957

By Joseph D. Davis, G. S. Scott, Palmer B. Place

In the course of investigations made by the Bureau of Mines in cooperation with the Trent Process Corporation, into the properties of mixtures of oil and coal, a comparative study was ma.de of the 'behavior of these mixtures and their cons ti tuents on destructive distillation. Mixtures of a petroleum oil and bitminous coal were first distilled under carefully controlled conditions, and then charges of the eame oil and coal were distilled separately under similar conditions. The quantity and quality of the distillation products were determined, and. resul. ts were compared. This comparison furnished a basis tor judging whether grea, ... er values in products can be obtained by distillation of oil and coal in mixtures than· b:, their separate distillation. In making the mixtures, the method used in t~e Trent process for cleaning coal was followed. The paste or plastic emulsion of oil and coal obtained is called "amalgam".••• When finely pulverized wet coal is mixed with approximately one-third its weight of. oil and agitated with a large excass of waj;er, the coal and oil agglomer-. ate to form a paste or amalgam. A large portion of the extraneous ash original.17 in the coal remains suspended in the water, with which it can be decanted from the amalgam. Ir the latter is now thoroughly drained and kneaded after the manner ot working butter, most of the excess water enclosed can be removed. This, .in brief, constitutes the Trent process for cleaning coal, The effectiveness of the process for cleaning coal has been studied••••. by the Bureau, and the results of the study show, in general, a high ash reduction an:l good recovery of combus ti bl e f'rom coals of medi ,mi and hi~ rg,nk. With coals of tht lowest rank, such as li@!Rlites, the process is only moderately auccessf'ul, owing to the difficulty attending the preparation of coherent amalgams, Oil losses to wate~ and refuse are small, and apparently it would be practical to rotate the same oil in the cleaning process if some efficient method were devised for recovering it from the amalgam, so a distillation process naturally suggested itself.

Dec 1, 1921