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By A. Ghadyani

This investigation was undertaken to assess the possibility of ash and sulfur removal by microbial action of high sulfur-content coal. Thiobacillus ferrooxidans and Thiobacillus thiooxidans have been used for biodesulfurization of coal. Feed samples were provided from Tabas coal mine located in Yazd province, Iran. The sample contained 28.80% ash and 2.30% sulfur. Flotation tests were implemented to optimize the effective parameters in these cells which were constant during bio-flotation tests. According to the results, obtained from various tests using Taguchi orthogonal array design (L27), the values of optimized parameters were pH at 7, 1000 g/t gas oil as a collector, 10% solid content, 15 min conditioning time, 100 g/t MIBC as a frother and 800 rev/min rotor speed. Bio-flotation tests are carried out by means of laboratory double discharge cell and mesophilic bacteria as depressant reagent using above mentioned optimized parameters. The bio-flotation experiments were conducted based on a Taguchi orthogonal array design (L9) with four variables (bacteria type, bacteria count, rotor speed of mixer and bio-conditioning time). The collected data was analyzed by using DX7.0, Minitab14.0 and WinRobust1.02 softwares for evaluation the effect of each parameter on the optimization criteria. Considering the highest combustible recovery and the lowest ash and sulfur content, the value of optimized bacteria type, bacteria count, rotor speed of mixer and bio-conditioning time were Thiobacillus ferrooxidans, 5×107 cells/g(coal), 100 rev/min and 20 min respectively. Under this condition, ash and sulfur content and combustible recovery were predicted 12.39%, 2.08% and 82.03% respectively.

Sep 1, 2012

By Z. He

Based on full investigation of the characteristic of sphalerite in the residue obtained from cyanidation leaching process and the study of the mechanism of the interaction between flotation reagents and sphalerite with the aid of electrochemical analysis, the reagent named YO was developed for eliminating the depression effect of CN- on sphalerite and reducing the dosage of CuSO4. The achievements have been used in commercial production for the treatment of the cyanidation residue to recover the zinc minerals, obtaining a zinc concentrate with grade of 56.49% Zn and recovery of 86.63% Zn.

Jan 1, 2014

By A. M. Ozbayoglu

Gross calorific value (GCV) of coals was estimated using artificial neural networks, linear and non-linear regression techniques. Proximate and ultimate analysis results were collected for 187 different coal samples. Different input data sets were compared, such as both proximate and ultimate analysis data, and only proximate analysis data and only ultimate analysis data. It was observed that the best results were obtained when both proximate analysis and ultimate analysis results were used for estimating the gross calorific value. When the performance of artificial neural networks and regression analysis techniques were compared, it was observed that both artificial neural networks and regression techniques were promisingly accurate in estimating gross calorific values. In general, most of the models estimated the gross calorific value within ±3% of the expected value.

Sep 1, 2012

By M. Saghaeian, R. Hejazi, M. Mohammadinejad, M. Zare

"Water quality and quantity at the Tailing Thickening Section of processing plants is considered to be a crucial factor and impacts the performance of several sections. Therefore, gaining stable and effective performance at the Tailing Thickener Section is one of the principal goals of minerals processing plants. Different factors such as: qualitative and quantitative sustainability of plant feed, the balance between the mass of input and output water flow, the dissolving method and distribution of flocculant and the amount of dirt, solid percent of thickener inlet pulp, affect the performance of Tailing Thickener. The present study investigates the successful improvement of Tailing Thickener performance at Jalal Abad Hematite Iron Ore Concentrate plant through optimizing the above operational parameters. For this purpose, the following optimizations have been done: homogeneity and sustainability of plant input feed rates, fine pulp removal collected by the bag filters at the input of the thickener, adding an quietness box before moving the tail pulp into the thickener to reduce the pulp turbulence, replacing flocculant pump and injection pipes, improving water mass balance which leads to optimizing and stabilizing the concentration of input tail pulp into the thickener, adding a mixer to increase the flocculant preparation time, increasing the locations for adding flocculant to thickener from 1 point to 6 points. Applying the above modifications and monitoring the Tailing Thickener performance over the course of months, has led to the improvement of recovered water quality from 500 ppm to 200 ppm, increasing the solid underflow of the thickener from 40% to 48.5%, and similarly, reducing water loss by 60%. Of other important effects, due to improvement of water quality, grade of final concentrate 0.5% increased and because of 73% increase in monthly working hour, concentrate tonnage 55% increased. Finally, sludge thickener optimization has had a significant effect in selecting and designing the dewatering system from the underflow of the sludge thickener."

Jan 1, 2018

By Dongyun Liang

Process mineralogy focuses on the chemical components and mineral composition of ore, dissemination size of valuable minerals, the occurrence of valuable and detrimental elements as well as the behavior of each mineral in the process. Through determining process mineralogy parameters and analyzing the characteristics of minerals, the results of process mineralogy study can provide mineralogy data for making a reasonable mineral processing technology program and optimizing the process. A detailed process mineralogy study is carried out for a complex rare metal ore in this paper and the results show that niobium mainly exists in the form of ferrocolumbite as well as nioboaeschynite and zirconium primarily occurs as zircon. The valuable minerals including Th-nioboaeschynite, ferrocolumbite, zircon, etc. have the characteristics of fine dissemination size, wide size range, complex chemical composition and variable physical properties, which mean it is a refractory ore. According to the results of mineral composition of ore, chemical composition of minerals, dissemination size of minerals, magnetism ranges of minerals and the distribution of niobium and zirconium, the process of ?desliming-Nb-Zr bulk flotation? is designed for this ore and the niobium-zirconium bulk rough concentrate with the grade of Nb2O5 9.43%, ZrO2 24.95%, Ta2O5 0.36% and the recovery of Nb2O5 77.66%, ZrO2 76.70%, Ta2O5 75.13% to crude ore can be obtained in the whole process closed-circuit test.

Sep 1, 2012

By P. Ying

An auxiliary system connected with SEM-EDX for rapid identification of mineral and rock sample has been developed. With the aid of a synthetic spectrum library created, using the compare and match techniques provided by INCA software in EDX the mineral or rock sample names for refer-ence can be given at the same time analyzed.

Jan 1, 2014

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014

By D. Y. Liang

Rare metal ores have those features of high industrial value and bad performance in ore separation. Most of rare metals ores are with low grade of valuable components, rareness of useful minerals, complicated combination of associated minerals and high difficulty in separation and enrichment of minerals. For those single (Ta, Nb) or (Ta, Nb, Sn) ore occurred in granite and pegmatite, the ways of gravity separation and magneto electric separation to concentrate (Ta, Nb) minerals are adopted. There are many mines being explored successfully both at home and aboard. While, for complex (Nb-Zr-REE) ores associated with Be and Ti minerals, they are commonly considered as rich rare metals ore but more difficult to process. One of rare metals mine in Inner Mongolia has the features as with large reserves and high grade of columbium and zirconium and accompanies with REE and beryllium, therefore with significant industrial value. After the utilization of research method of process mineralogy, detailed mineralogy research has been made on the rare metals ore. The test results show that there are abroad isomorphism replacements among such elements, such as Ti, Mn, Fe, Nb and Ta, between Be and REE in metallic oxide minerals of that ore, which makes the mineral composition of that ore extremely complicated. This research identifies clearly the mineral composition, and investigate at the technological property and the occurrence of those elements as Nb, Zr, Be and REE in the rare metal ore. The achievements of this research provide important mineralogy basis for ore dressing research of refractory rare metallic ores.

Jan 1, 2014

By M. Rehor

The importance of brown coal as a raw material is currently given by growing energy needs of Czech Republic. More than 70% of mined brown coal comes from North Bohemian Basin these days. Mining of brown coal is run in four mining locations. They are geologically different and the parameters of mining coal are quite different too. This requires a little bit different methodology of both extraction and reclamation. Methods of reclamation works in the region are given mainly by the characteristics of overburden rocks appearing in the upper horizon of recuperated localities. The difficulties of the North Bohemian mine dumps reclamation works are caused by extremely unfavourable properties of rocks poured down to the majority of mine dumps. These are mainly rocks of the overlaying strata and the rocks strata of brown coal bed. Main materials poured down to the mine dumps are sands, clayey sands and kaolin ? illitic clays. Admixtures in filled rocks consist of organic (coal) mass, siderite and pyrite. These rocks are mechanically instable with respect to the wind and water erosion and during weathering they are getting unfavourable, acid (phytotoxic) nature, due to the influence of SO3 and Al ions. External and internal dumps of open pit mines are significant part of the North ? Bohemian landscape sustained by excavation. Their as fast as possible preparation and gradual integration into ecosystem of the area is interest of both citizens of region and mining companies. The paper briefly summarizes the methodology of restoration of the largest dumps of the North Bohemian Brown Coal Basin and the results of analyses and evaluation of samples taken on restored localities Rado-vesice dump, Strimice dump, Ru?odol dum pand internal dump of Bilina mine. An example of modern non-tradicional restoration methods is the restoration of internal dump of Bilina mine (application of power plant stabilizer). According to observations and results of sample analyses the methods of restoration were selected to limit the erosion influence, adjust the chemical and physical composition of surface of Radovesice and Strimice dumps. The application of marlites and bentonite prevent the unfavourable weathering processes on dump surface. Compensation of Quaternary sediments was artifically formed here. The need of marlite ploughing in, application of organical substrates and vegetation preparation was proved on Radovesice dump. The conception of landscape reclamation of the largest dumps after finishing of mining, methodology of technical reclamation and well considered using of fertilizable soils are main results presented in this article.

Jan 1, 2014

By G. Belardi

This paper presents the preliminary results of a research programme conducted to assess the feasibility of a flotation technique in the remediation of soils severely affected by heavy metal contamination. The use of flotation in soil remediation is a recent practice. The main difficulties are given by the variety and peculiarity of the heavy metal containing species, and also by the grain size. Most of the studies reported in the literature concern the use of conventional collectors, such as xanthates, after a preliminary chemical modification of the metal bearing species through sulphidization. On the basis of the minera-petrographic characterization and of speciation, some classes of reagents have been selected, capable of acting both on metal-bearing species and all metallic cations to be separated. The design of the synthetic molecules has been based on the coordinative properties of the metallic centres and functionalized in order to act as collectors for a wide range of metals independently on their surrounding atoms. In laboratory experiments a sample of stream sediment has been utilized, whose contamination is caused by the runoff from Sardinia mine waste dumps and overflow from the settling ponds. The material showed contamination mainly from Zn, Pb and Cu and to a lesser extent from Cr, Ni, Cd, and Sb associated in mixed particles of Fe and Mn. Flotation tests on a laboratory scale have been performed on grain sizes less than 355 µm in laboratory cell Minerais & Metaux. The effects of the structure of collectors (functional group, chain configuration) as well as of the principal flotation parameters (such as pH, concentration of reagent) on the grade and recovery of heavy metals in the concentrate and in the tailings (remediated soil) have been investigated. The results of the laboratory tests substantially confirm the theoretical premises, and the most effecive reagents found belong to the classes ATP, MBT, MBO, fat acids and phosphates.

Jan 1, 2014

By Gerke Gilian, Pretz Thomas, Pehlken Alexandra

"The evaluation of health hazards within the treatment of mineral and waste materials is gaining more and more importance in industrial countries. The need to control occupational health and safety has been recognised, and regulations which describe general protective measurements for personnel provide a tool to protect their health. It is the aim of the paper to give an outlook for practical approaches to risk assessment and to present measures for exposure reduction in accordance with the state of the art in Germany.Both the treatment of minerals and of waste materials are described in relation to the risk assessment. The method of evaluating health hazards in the two industries is similar and therefore both examples are presented next to each other.The example presented in the paper is the German “Biostoffverordnung” (the regulation for biological materials) which is important for the waste treatment industry. All kinds of waste treatment facilities (like composting facilities, waste dumps, sorting facilities for packaging materials) are obliged to carry out an assessment of health hazards for a variety of working areas and working places. The possible safety requirements deriving from this regulation are presented and discussed under the aspect of biological hazards."

Jan 1, 2003

By H. G. Hedlund

Tailings in Mining Industry can be handled in different ways. Today tailings disposal is in focus by projecting new plants as well as treating and handling of old Tailings dams.The trend today is to process minerals, detoxify the Tailings and place them as dry surface Deposition or Underground Backfill. This paper will briefly present five different Mining plants in North and Central America, where Tailings have to be dewatered for dry depositing. The Metso-Sala VPA is a filter especially developed for dewatering and drying of Mineral Concentrate and Mineral Tailings. Keywords: tailings disposal, dewatering, drying, mineral tailings

Sep 1, 2012

By P. Vijay Kumar

Phosphate minerals are conventionally concentrated by flotation process using soap or soap- light diesel oil emulsion as collector. Some plants use detergents such as sodium petroleum sulfonate or alfa olefin sulfonate to enhance efficiency of soap flotation. It is reported that urea a known hydrotrope enhances flotation efficiency of soap as efficiently as alfa olefin sulfonate or linear alkyl benzene sulfonate at bench scale tests. In the present study tri sodium citrate also a known hydrotrope is tested as promoter in the flotation of phosphate mineral from Eshidiya ore.

Sep 1, 2012

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

By G. Bonifazi

Mining activities belong to human history, they are lost in the mists of time. They usually impact on large portions of the territory, both directly (exploitation areas and logistic activities directly related to exploitation) and indirectly (exploited material handling, processing and storage areas). As a result, at the end of mine life cycle, dismissed areas usually cannot be directly re-utilized without efficient and well addressed rehabilitation actions. Main goal of the proposed approach was to analyze the results obtained when a set of procedures, based on the collection and the analysis of remote sensed data, is developed to evaluate the effect of rehabilitation of land contaminated by extractive industry activities and to perform a monitoring and registration of the environmental impact of such operations by the application and the integration of modern information technologies, as Earth Observation (EO) and Geographic Information Systems (GIS). The study was developed in the framework of the EU-Asia program of the European union (EXTRACT-IT Project-Contract No: CN/ASIA IT&C/006 (89870): Application of Information Technologies for the sustainable management of Extractive industry activities) and it was addressed to three different dismissed mine areas in India, Thailand and China, respectively. The results, in terms of methodologies selected, strategies applied and results obtained, are described with particular reference to Fuxin coal mine area in China.

Jan 1, 2014

By M. L. Cao

In this study, a montmorillonite organo-intercalation compound (MOIC) was synthesized by using a Na-modified bentonite (NaB) as a matrix and hexadecyltrimethylammonium (HDTMA) bromide as an intercalating reagent under microwave irradiation. The synthesized products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), organic carbon content measurement, and adsorption density determination. The results show that, at 10% suspension concentration and 10 minutes irradiation in a 130-W microwave oven, the basal spacing d(001) of the synthesized MOIC increases to 2.209 nm from the original 1.218 nm of NaB. The MOIC has much higher adsorptive densities to nitrobenzene and aniline from aqueous solution than the NaB. The adsorption isotherm of nitrobenzene on the MOIC is linear, and the adsorption is mainly the result of nitrobenzene?s preferred partition in MOIC over aqueous solution due to MOIC?s hydrophobicity. The adsorption isotherm of aniline on MOIC follows the Freundlich equation and the increased adsorption is not only the result of aniline?s preferred partition in MOIC over aqueous solution but also that of the MOIC?s surface adsorptions.

Jan 1, 2014

By B. Q. By

TiO2 is an ideal material for catalytic technology due to its unique properties. In this paper, Sm3+ doped TiO2 photo-catalyst was developed to improve the efficiency of TiO2 and to use the natural light as irradiation source, which was made from Titanium Tetrabutoxide and Samarium Oxide with the Sol-Gel process. The Sm3+-TiO2 photocatalyst was used to degrade reactive orange 4 (RO4) in Azo Dyes. The effects of solution pH, Sm3+ concentration and catalytic time on the degradation rate of RO4 were studied. The characteristics of the catalyst were analyzed with XRD and TEM. The experimental results show that the catalyst has high activity in the degradation of RO4. The Azo bonds of RO4 are active and easily broken by oxidation. The catalytic activity of the Sm3+ doped catalyst greatly depends on the pH of solution. The catalyst has high photo-catalytic activity at both neutral and alkaline conditions. The degradation mechanism of the Sm3+ doped TiO2 photo-catalyst was also discussed.

Jan 1, 2014

By A. Gül

This investigation was carried out with low grade Murgul-Cakmakkaya copper ore once used to be dumped away as waste material. Sulphide minerals in the ore sample observed are chalcopyrite, pyrite, sphalerite and to some extent molibdenite; quartz, calcite and dolomite are the gangue minerals. The ore sample assays 0.28% Cu, 2.94% Fe and 3.36% S. Mineralogical study of the ore sample showed that adequate liberation of chalcopyrite for flota-tion was achieved below 100 µm. In flotation tests Aerophine 3418-A was the collector employed, NaOH or Ca(OH)2were the pH modifiers. Deactivators used were sodium meta bi-sulphide, starch, dextrin and lime. MIBC was the frother used throughout the tests. Test results showed that starch alone was the most suitable depressant to give the optimum metal content and recovery val-ues. Activated charcoal was used to adsorb excess collector species in the flotation pulp during cleaning stages After two stages cleaning of the rougher concentrate using starch as the depressant a copper concentrate assaying 21.2% Cu was obtained with 79.5% recovery while the tailings contained 0.01% Cu and metal losses were about 3%

Jan 1, 2014

During incineration of municipal solid waste (MSW), various environmentally harmful elements and heavy metals are liberated partly into bottom ash, and partly carried away with the off-gases and subsequently trapped in fly-ash. If these waste incineration residues are not properly processed and immobilized, it can lead to secondary environmental pollution to the air, soil and water. The stricter environmental regulations require a higher immobilization efficiency of the waste incineration residues, which is the main objective of the present cooperation research. Within the present project, a systematic scientific research on various MSWI residues has been carried out, including sampling, low or high temperature processing and leaching tests. In the present paper, the major results have been summarized. The research results reveal that through appropriate combined pre-processing and high temperature vitrification, the bottom ash and fly ash can be efficiently stabilized. The results achieved provide a valuable alternative route to treat the solid residues from incinerators, and to make efficient recycling and safe utilization possible.

Jan 1, 2014

By Kyoungkeun Yoo

A citric acid leaching test after heavy medium separation process was performed to remove the heavy metal contaminat such as Pb, Cu, and Zn from contaminated soil. The lead component was removed from soil by heavy medium separation whereas zinc component shows 0 % - 37.9 % removal ratio with particle size. The citric acid leaching was conducted to remove the remained zinc component. The removal ratio of Zn reached to more than 95 % under the conditions; 10 % in pulp density, 200 rpm in agitation speed, 50 °C, 2 mol/L in citric acid concentration at 2 hrs in leaching time. These results suggest that the heavy medium separation method followed by citric acid leaching is effective for treatment of soil contaminated with various chemical forms of heavy metal. Keywords: metal contaminated soil, citrate, heavy medium separation, zinc

Sep 1, 2012