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By M. J. Beus

Many mines in Canada, the United States and South Africa are reaching the hoisting limit. Very little payload will be possible without compromising safety due to the excessive weight. It has been suggested (DeLorme, 2000) that one of the most attractive concepts to enable deeper hoisting is to reduce the allowable factor of safety in the wire rope. Researchers at the Spokane Research Lab are developing new technology to improve hoisting safety and productivity by providing new monitoring and analytical tools. A Shaft Conveyance Monitoring System (SCMS) has been developed which determines hoist rope end load, true conveyance position and acceleration, and rope safety factor, as well as other hoist operating parameters. This information is transmitted to the hoist operator display 20 times per second. Recent field measurements on 45 mm (13/4 in.) diameter hoist rope indicate that dynamic forces during loading of a 9000 kg (10 ton) skip could exceed the safety factor of the rope. To improve on the current understanding of the mechanical behaviour of hoist ropes, and to help interpret the results from field-testing of the SCMS, a new approach to computer modelling of stranded wire rope is also being developed. Particle Flow Code, PFC3D (Itasca, 1999), is used to simulate the structural behaviour of wire rope and the interaction between individual strands when the rope is subjected to static and dynamic end loading. Details of the SCMS, field results from the measured rope loads, and the results of numerical modelling on the wire rope will be discussed.

Jan 1, 2002

By Greg Rasmussen

"Huckleberry Mines Ltd is an open pit porphyry copper-molybdenum mining operation located 120 km south of Houston, British Columbia with a 18,000 tpd milling facility. Huckleberry Mines is owned 60% by Princeton Mining Corporation, the operator, and 40% by Japanese partners.The Huckleberry deposit is one of several porphyry systems located in the Tahts a district of the intermontane belt of British Columbia. The principal economic minerals are chalcopyrite and molybdenite. The ore deposit is split into two ore deposits, the Main Zone, consisting of24,241,000 tonnes of mineable reserves grading 0.484 %Cu and 0.013 %Mo, and the East Zone, consisting of 66, 131,500 tonnes of mineable reserves grading 0.523 %Cu and 0.014 %Mo.The milling begins with gyratory crushing. This sizes the product down to 100% passing 6 inches. This product is discharged onto a stockpile by a stationary conveyor. The stockpile was designed for a capacity of 144,000 tonnes with a live capacity of 20,000 tonnes. Two apron feeders draw the ore from the bottom of the stockpile and discharge onto a SAG mill feed conveyor which in turn feeds a grinding circuit consisting of one 32' x 15' SAG mill and two 30' x 16.5' ball mills. The grinding cyclone overflow feeds bulk flotation at 55 -65% minus 200 mesh.The bulk flotation uses conventional rougher and column flotation methods to float a bulk concentrate recovering 92.6% copper on the East Zone and 95% copper on the Main Zone with 75% recovery molybdenum on both zones. The bulk concentrate feeds the bulk thickener which produces a density of 60 %solids. This in turn feeds the molybdenum circuit, which separates the copper and molybdenum, by depressing the copper then using conventional rougher and column flotation produces a copper concentrate of 27 %Cu and 0.02 %Mo, and a molybdenum concentrate containing 1.5 %Cu and 54 %Mo at 67% recovery. These concentrates are separately thickened, filtered, dried, and shipped to the smelter for processing."

Jan 1, 1998

By J. E. Nesset

"I had been requested earlier this year by MetSoc, our sister society of CIM, to contribute a chapter on technical developments in Canadian mineral processing over the past 50 years to their 50th Anniversary volume. Accepting the challenge of assembling such a chapter seemed at first a reasonably straightforward task, until one realises that the list of contributions by Canadians to mineral processing over this period has been more than just significant. It turns out to have been an extraordinarily fertile time for innovation and impact for Canadian-based technology. The list is necessarily a subjective one, however I had no trouble identifying twenty technology developments that are clearly outstanding, and there are undoubtedly others. As much as possible, I approached the individuals themselves who played key roles in each technology and asked that they tell the “story”. Without exception, all who were invited accepted eagerly and delivered more than I had hoped for. The technologies have been grouped into those that are truly Canadian innovations, such as the Knelson gravity concentrator and the McGill gas dispersion sensors in flotation, and technologies where Canadians and Canada played a very significant role in their success and implementation, such as AG/SAG grinding and ion-beam surface analysis. Also included are what may be termed technology transfer initiatives and institutions that have risen to a world class level, such as SGS Lakefield and the Canadian Mineral Processors Society of CIM. The challenge is now for the coming generation to continue this record of innovation and contribution to the industry, and that includes the (mostly) Canadian mining and metallurgical companies who have taken the longer term view and supported many of these initiatives, through their critical early years, with both financing and project sites for these ideas. Let us hope that the current trend of mining company globalization will not dampen their enthusiasm to participate. This plenary presentation will highlight many of these technologies, the individuals behind them, and their significance to the mineral processing industry."

Jan 1, 2012

By H. M. Lewis

The current status of the international zinc market is summarized, and a supply /demand outlook is presented for the next five years. A number of technical problems facing the industry are outlined. Introduction ZINC has sometimes been called the unknown metal. Considering that on a world basis it ranks third among non-ferrous metals in production and consumption, zinc retains a certain modesty. It has no distinctive colour like copper, lacks the low density of aluminum or magnesium and is not always easy to identify as a product. The 'spangle' of galvanized steel is probably zinc's most distinguishing feature. The purpose of this article is to develop an over-all review of zinc. Starting with the current position of the metal, the major factors that will shape its future will be described so that an assessment of the outlook for zinc can be made.

Jan 1, 1978

By W. Rostoker

Packing Experiments The porosity and most of the other physical properties of a coherent mass of any material built up by the packing together of discrete particles will obviously vary with, and be governed by, the manner of association of the particles. The relation of packing to powder metallurgy has been discussed in some detail by at least two authors. Packing Theory Theories of particle packing have been put forward by C. C. Furnas and A. E. R. Westman. Although their approach to the problem is not the same, their conclusions are similar. In the process of packing, they visualize the voids of a uniformly sized material becoming filled with particles of a smaller size, and the voids between these being filled in turn with still finer particles. Obviously, if this process is carried ad infinitum, the resultant mass will have the same density as the constituent particles. In practice, of course, such a density of packing is never attained. In addition, the premise is made that successive particle sizes must fit into the voids left by the immediately larger particles- an assumption requiring definite size gradations and also particle shapes. It remained, then, for theory to correlate relative diameter ratios, and proportions and numbers of sizes of particles, for requisite packed densities. Briefly, the following principles were postulated: (a) For an infinite diameter ratio between largest and smallest sizes, an infinite number of particle sizes in proper proportion is required to give natural density. (b) For a given diameter ratio, there is a maximum number of permissible particle sizes for maximum packed density (Furnas). (c) Provided the particle shape is spherical, or approximately so, the proportions o particle sizes can be calculated. (d) The ratios of successive diameters of particles are in geometric progression.

Jan 1, 1947

By Dale Lens, W. S. (Wayne) Cusitar

"The use of continuous loading and conveying technology for mining is currently practiced in relatively few mining environments and, even in these cases, on a non-exclusive basis. For the most part, and particularly in hard rock mining, appropriate equipment technology has only recently been developed for continuous loaders, mobile low profile crushers and flexible face conveyors. Mining R&D work by Inco Limited has promoted the development and proving of a loader suited to hard rock conditions and capable of sustained loading rates of500 tonnes per hour. Current R&D work at Inco will test the production capabilities of a low profile mobile crusher by CMS/Eagle and a flexible/ mobile face conveyor system by DME. This follows successful production testing of the Belt Bender concepts in potash mining in Saskatchewan and the development of enhanced extensible conveyor equipment features by DME. Numerous applications are seen for variations of the LCC technology in soft rock, hard rock and surface mining environments. Introduction In some respects, this paper is an announcement of new technology which has the potential to bring revolutionary change to the mining industry. It is also the story of technology transfer, in which mining concepts that have developed independently in underground soft rock and hard rock mines and in surface mining operations are being brought together for a common benefit. It is also the story of key developments in equipment technology which 'complete the cycle' of cooperating technical capabilities to enable the revolution to begin. The phrase ""technological revolution"" requires some defmition: an equipment innovation, or invention, or improvement, will only be revolutionary if its use gives rise to a significant new mining practice."

Jan 1, 1987

Ontario Operaations Mining Garson Stobie Copper Cliff North Copper Cliff South Creighton Mcreedy East Milling Clarabelle Mill Smelting Smelter Matte Processing Anode Casting Refining Copper Cliff Nickel Refinery Port Colborne Cobalt Refinery

May 1, 2007

By Keila Gonçalves, Aline Tavares, Danielly Couto

"The sulphide copper deposits from the Carajás area (North region of Brazil) were generated by the percolation of hydrothermal fluids in volcanic and granitic rock and are denominated as IOCG deposits (iron oxide copper-gold deposits). During these hydrothermal events a wide variety of gangue minerals such as amphiboles, biotite and fluorite were formed. These gangue minerals are enriched in fluorine and chlorine which are deleterious elements in the copper concentrate. Chalcopyrite and bornite are the main copper-bearing minerals and they can occur in veins, in brecchia or disseminated in gangue.The study, which included bench scale flotation tests and minipilot plant tests was aimed at improving the fluorine rejection in the flotation process during the flowsheet design for one of these Carajás sulphide copper deposit. All of the study was supported by quantitative mineralogical techniques such as QEMSCAN and the use of a scanning electron microscope (SEM).This paper describes and discusses the results obtained in the metallurgical tests and emphasizes the importance of the quantitative mineralogical characterization during the process conditions optimization and flowsheet design.INTRODUCTIONIron oxide copper-gold (IOCG) deposits encompass a wide spectrum of sulphide-deficient low-Ti magnetite and/or hematite ore bodies of hydrothermal origin and normally have important copper sulphide reserves. In the Carajás mineral province, located at the southeast part of the Amazon Craton in Pará State (Brazil), there is a variety of world-class (>200 million tonnes) Fe-oxide Cu-Au deposits (e.g. Salobo, Cristalino and Sossego), whose genesis has been assigned to hydrothermal fluid percolation in volcanic and granitic rocks. Figure 1 displays the location of the Carajás area.The hydrothermal thermal fluid composition was extremely variable. It may have contained gases, salts (brine) and metals. The metals were carried as various complexes and it is thought to have involved sulphur, chlorine and fluorine containing species. This resulted in some minerals formed during the hydrothermal alteration having high fluorine and chlorine contents. These elements result in smelter penalties in a copper concentrate because they cause the smelter off-gases to be more corrosive."

Jan 1, 2011

By Chris Fleming, John R. Goode, James Brown

"Data will be produced from two uranium feasibility studies that were conducted in 2008, both involving uranium recovery from leached slurry by resin-in-pulp (RIP) with strong base resins. Excellent metallurgical results were produced in RIP pilot plants in both studies, and the loaded resins were eluted with strong sulphuric acid and recycled to RIP in an integrated process. Resin losses by either abrasion or mechanical breakage were immeasurably low.Metallurgical results from these two campaigns will be presented, along with an economic analysis of RIP versus the alternative process of CCD or filtration and solvent extraction.INTRODUCTIONThe recovery of uranium directly from pulp with strong base resins in RIP contactors was practiced commercially in the USA in the 1960s, but the process never established itself as a viable alternative to solid/liquid separation and solvent extraction. This was due mainly to the necessity to do a sand-slime separation partially resulting from the unavailability of coarse resin beads, inadequacies in the design of the RIP contactors and screens to separate resin from pulp, as well as problems with the strength and durability of resins in agitated pulps.There have been significant advances in the last 30 years in each of these areas. All the commercial resin manufacturers are now producing very tough, durable, strong base resins, and are manufacturing them in a large bead size that is better suited to RIP applications. In addition, with the emergence and wide spread implementation of the carbon in pulp process in the gold industry in the 1980s, many innovative techniques for preparing leached slurries and separating carbon from pulp have become firmly established. These techniques have proven to be equally applicable to resin separation from pulps in RIP contactors."

Jan 1, 2010

By L. Vollert

In August 2018, the first full-scale HydroFloatTM cells for the recovery of coarse composited copper and gold were commissioned at Newcrest’s Cadia Valley operation in New South Wales, Australia. The primary objective of the installation is to recover coarse value-bearing composites that are lost to conventional flotation tailings, without the need for additional power input for particle size reduction to improve mineral liberation. This paper examines the application of Eriez HydroFloatTM technology for the recovery of coarse, poorly liberated copper sulphide particles drawing on recent experience from lab scale testwork through circuit design and commissioning of the full-scale installation at Cadia Valley. INTRODUCTION In the face of declining copper head grades and a tightening regulatory environment around the use of wet tailings dams, the processing of copper ores at coarser particle sizes has become a focal point for the industry. Sulphide flotation using the Eriez HydroFloatTM is one of the emergent technologies that sits under this umbrella of coarse pre-concentration. It has been demonstrated through numerous lab and pilot scale testwork programs carried out by Newcrest and others (Awatey, Kohmuench, Thanasekaran, Skinner & Zanin, 2013), to improve the flotation recovery of sulphide-rock composite particles with low surface liberation, relative to conventional flotation technology. The HydroFloatTM technology has been used widely for the recovery of coarse potash, phosphate, coal, vermiculite, spodumene and diamonds but has never been applied at full scale in either gold or sulphide flotation. In August 2018, the first full-scale 3.4 m diameter HydroFloatTM cells for the recovery of coarse composite copper and gold were commissioned at Newcrest’s Cadia Valley operation in New South Wales. The primary objective of the installation is to recover coarse value-bearing composite particles that are lost to conventional flotation tailings, without the need for additional upfront power input for particle size reduction to improve mineral liberation.

Jan 1, 2019

By D. E. M. Plaumann, B. S. Fee, R. D. Hansen, R. R. Klimpel

"The steps from experimental curiosity through to commercial product can be slow and tortuous in spite of the quality of the technological advances offered by the new development. Data generation and interpretation need to be done in lab tests as well as full-scale evaluations and, in each, the advantages of the new reagent must be clearly identifiable and measurable.The Dow Chemical Company has patented a novel new collector for the flotation of zinc. Fl (2-hexylthioethylamine hydrochloride) has several unique structural features that suggest atypical mechanisms for zinc collection. Laboratory data have demonstrated significant flexibility with respect to grade and recovery balance at dosages lower than those typically used for xanthates.In mill trials, the same phenomanon is evident - the choice between high grade and high recovery allows one to select the desired quality of zinc concentrate. One trial in particular was run over a three month timeframe and Fl gave improvements in recovery of 2.5% and a reduction in lead levels with less than 0.5% loss in grade. The dosages of other reagents in the flotation circuit were also reduced.Data demonstrating improved recovery and grade in lab trials will be discussed. Extensive data from the mill trial will illustrate how Fl works in both rougher and cleaner circuits."

Jan 1, 1990

By Paul Grady, Martin Froehling, Curtis Mohns, Eliab Roman

"Since the idea of processing rock to unlock the valuable minerals inside was put into practice, efforts to improve production began. Methods have been learned that allow for operation in environments and under circumstances where it would not have been possible until now. All existing operations have experienced at least some form of productivity improvement measures. The objective is simple: generate more product of better quality in less time and at lower unit cost. Since the year 2000, various modifications have been made at the Kemess Concentrator in efforts to improve productivity. The following is a discussion of these modifications and their contributions to the success of the operation.INTRODUCTIONThe Kemess South Mine, a major producer of gold and copper, is located in north-central British Columbia. Kemess was brought into production in May 1998 by Royal Oak Mines with a modern mill controlled by a fully integrated Foxboro IA DCS system and employing 134 people. On February 11, 2000 Northgate Exploration Limited (now Northgate Minerals Corporation) acquired Kemess Mine from receivership. Since acquisition in 2000, Kemess has seen many accomplishments, including the reduction of costs by 40% site wide.The mill has a nameplate capacity of approximately 56,000 tonnes per day which is processed through a Metso (Svedala) 60” x 89” Primary Gyratory Crusher and then conveyed by a 60” conveyor to a stockpile with 48 hours of total storage capacity. The nominal minus 6” rock from the stockpile is fed to two parallel grinding circuits (A & B). Each section consists of a 10.4 m F x 4.7 m SAG mill with dual drive motors (4,480 kW apiece) discharging onto a 2.4 m x 7.3 m Metso (Svedala) single deck vibrating screen to remove the coarse material for recycle to the SAG mill by a Continental 45º high angle sandwich conveyor. Screen undersize is pumped along with ball mill discharge to a cyclopac consisting of twelve Krebs 66 cm F cyclones to classify flotation feed to a size of approximately 65% minus 200 mesh. Cyclone underflow feeds a Metso (Svedala) 6.8 m F x 11.0 m ball mill, also with dual drive motors (4,480 kW apiece). The primary grinding circuit has 35,840 kW available for grinding."

Jan 1, 2005

By James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity ? up to 45 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonnes of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle ? particle contact. The small gap, high electric field, counter current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in the US and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Nov 1, 2011

By C. O. Aksoy

There is a long history of coal production in Turkey with electric energy generated from power plants since the 1950s. However, the cost of power generation is high. Therefore, it has become necessary to find a means of decreasing production costs to become more competitive in a global market. This paper attempts to economically minimize the overall operating costs of a dragline-shovel-truck system applied at an open pit mine that has fed the Yatagan power plant since 1979, lowering the lignite production cost, and indirectly, the overall electricity generation unit cost. Systems currently in place, as a result of former optimization studies, are time-consuming and expensive to re-implement to comply with today’s very different geometric and economic conditions affecting mining operations. In such cases, rather than re-optimization, it is more viable to identify the parameters that affect the minimum unit cost, via a cost minimization study, allowing present mine equipment to be utilized more efficiently. Unit cost minimization analyses are subject to the capacity of the pool of mining equipment available, combined with the mining block geometry from pre-stripping onwards. In this overall unit cost minimization study, P&H shovels and CAT 777 trucks with capacities of 15 yd3 and 77 tons, respectively, were used in truck-shovel pre-stripping operations. A 65 yd3 Marion 8050 dragline was used to expose the overburden immediately over the coal seam. Pre-stripping bench heights varied from 8 m to 20 m and dragline bench heights from 20 m and 25 m were evaluated to minimize the unit cost of field operations. Total overburden extended to a depth of 60 m (35 m to 40 m for pre-stripping). Minimization analyses performed on the pre-stripping truck-shovel operation, prior to dragline operations, determined that the shovel bench height should be 15 m requiring a dragline bench height of 25 m.

Jan 1, 2005

By Gregg S. Hill, Bert J. Huls

"This paper on coarse particle recovery (CPR) summarizes a process to capture coarse particles that are not recoverable by regular flotation. Several porphyry copper operations in the world operate analogous circuits that recover non-floated copper from tailings; however, the case presented here is unique in that extensive underlying test work has allowed us to elucidate some fundamental principles behind recovery enhancement. This paper discusses an overview of the flow sheet that is proposed to Minera Escondida Ltda., the nature of copper in the feed to the CPR circuit, and the various unit operations within the recovery circuit. Details of the technology behind each unit operation will be presented in later publications.INTRODUCTIONSince 1996 BHPBilliton and MEL (Minera Escondida Ltda.) have developed a process to recover copper from coarse particles in the rougher tailings. Copper recovery from fresh tailings is not new. Several operations in Chile, such as Chuquicamata, El Teniente (AMEC, 2003), Mantos Blancos and others have operated various forms of tailings circuits. Both Chuquicamata and El Teniente practice cascade flotation scalping off froth containing fine copper particles after allowing sufficient retention time, air inducement and, sometimes, additional reagent addition. Chuquicamata tailings are not segregated but floated in sequential cascade and conventional large cell arrangements. At the Valle Central operation of El Teniente a coarse fraction of mill tailings is ground and floated, with the rejects recombined with fine tailings and subjected to cascade flotation through a sequence of concrete launders as the tailings flow towards their final deposition area. Mantos Blancos cyclone the rougher tailings and blend the underflow with scavenger concentrate from elsewhere in the principal circuit prior to flotation in Wemco Cells. Kemess in BC, Canada operates a 160 m3 Outokumpu cell to reduce the tailings sulfur content (Rasmussen, et.al, 2004)."

Jan 1, 2005

By John Lindsay

Outline ??Recovery plant requirements and concepts ??Common recovery plant unit processes ??Recovery plant design considerations ??Peripheral issues Process Design ??Liberation ??Separation ??Recovery Processing ??Density 3.5 g/cm3 ??Luminescent under x-ray ??Hydrophobic (non wettable) surface ??Non-magnetic ??Inert to strong acids / bases

Apr 1, 2005

By Charles "Chick" Rodgers

"The Key Lake uranium mine is the largest single uranium producer in the world. It is owned 2/3 by Cameco Corporation and 1/3 by Uranerz Exploration and Mining. Cameco is the operator. Current production is fourteen million pounds per year of uranium oxide (U308).The mine's location is 570 kilometres north of Saskatoon on the southern edge of the Athabasca Basin approximately at latitude 57° 11 'north and longitude 105° 34' west. Access to the mine is by an all-weather road and a private airstrip.The mill was commissioned in 1983. A molybdenum plant was constructed in 1989 in response to increasing molybdenum content in the yellowcake or final product. Early test work had showed that the first ore body to be mined, the Gaertner deposit, would present few problems with regards to molybdenum in the product. However, the test work also showed that the higher molybdenum content of the Deilmann ore, the second Key Lake orebody to be mined, would result in increased molybdenum concentrations. Without the molybdenum plant, penalties would become excessive and some product might not accepted by the refineries.This paper will describe the current Key Lake mill process with emphasis on the molybdenum solvent extraction process. It will cover the chemistry of the process, process development in the mid 1980's, and current operating practices.The Key Lake milling process consists of five individual plants, crushing and grinding, leaching -counter current decantation (CCD), solvent extraction, yellowcake/crystallization and bulk neutralization (Figure 1. Simplified Mill Flowsheet). A detailed mill flowsheet can be found in the appendix."

Jan 1, 1996

By E. M. Watkin

"Land directly disturbed by hard rock mining activities in Ontario and Quebec was surveyed in 1974 as part of a country-wide assessment, (Murray 1977). Some 15, 000 hectares, or 5 7 square miles, are listed as having been disturbed by overburden removal, waste rock and tailings deposition (Table 1) in the region. That area represents sixty-eight per cent of the total area which ha1; been disturbed by mining in central and Atlantic Canada. Assessment of disturbed areas was undertaken using LANDSAT-1 and LANDSAT-2 satellite imagery. Certain limitations of the technique were recognized but the data obtained were considered a relatively acceptable assessment of the extent of disturbed areas larger than ten hectares.Approximately ten per cent of the land disturbed by mining in the two provinces has been reclaimed to varying degrees. Indeed, this proportion is correct for the country as a whole. As pointed out by Ripley, Redmann and Maxwell (1978), some of the land was disturbed long before environmental concern 01· reclamation were ever considered. In numerous instances reclamation will remain impossible until presently active operations are closed. Nevertheless, these authors feel such figures make it clear that reclamation has not been a high priority in Canada in the past. Canada is a vast country, and there has been little pressure toward efficient use of all land space. Most mining operations occur in areas distant from the country's population centres. Under these circumstances, therefore, the pressure to reduce the environmental impact of mining is much less than in the more densely populated areas of Europe and the eastern United States, where such activity can occur in or adjacent to large metropolitan areas."

Jan 1, 1980

By Stephen L. Chryssoulis, Daniela Venter, Stamen Dimov

"Comparative surface analysis of floated and rejected free gold grains from a number of full scale benefication plants and from pilot plant testwork, has shown silver (the most common impurity in gold) and sulphur invariably in greater concentration on floated gold grains, implying that they assisted gold flotation (gold activators). Collector loading measurements on individual gold grains from concentrates of staged rougher flotation tests on a cyclone U/F product of a pyritic gold ore, revealed first progressively lower concentrations of the collector monomer on gold from each follow-up concentrate and secondly a direct proportionality between the surface concentration of silver and the collector monomer. These two observations leave no doubt that silver activates gold and that collector monomers play a significant, previously not fully recognized role in gold flotation.INTRODUCTIONGold to some degree is naturally floatable in industrial systems, which means that it can be recovered without collector addition (Marsden and House, 1992). This is due to the adsorption of hydrocarbons and deposition of sulphur, which are dependent on the metallic properties of gold, particularly its high electrical conductivity, which allows surface electrochemical reactions to occur catalytically and selectively. Cyclic voltammetry has shown that gold can be rendered hydrophobic by deposition of a surface layer of sulphur (Sº) from S2- and HS- solutions (Walker et al., 1984). Twenty monolayers of sulphur were required to produce a hydrophobic gold surface.However, no sulphide flotation plant relies solely on the natural floatability of gold for its recovery. Gold hydrophobicity is enhanced by the addition of flotation collectors such as xanthates (X), dithiophosphates (DTP), dithiophosphinates (DTPI), mercaptobenzothiolates (MBC) etc., as used in sulphide mineral flotation (Dekok, 1973: Adams et al., 1986). The mechanism invoked in enhancing the hydrophobicity of pure gold with the aforementioned four groups of collectors is similar to that of pyrite, whereby collector anions are oxidized at the gold surface to form dimers (Groot, 1987; Marsden and House, 1992; Basilio et al., 1992) As an example, xanthate ions are oxidized at the gold surface to form the neutral dimer dixanthogen (X2):"

Jan 1, 2003

By Huilan Yang, Feng He

This paper intends to introduce the development of copper smelting and converting technologies in China in recent years, with a particular emphasis on the introduction of various continuous converting technologies, and moreover, it analyzes the advantages and disadvantages of those technologies, including their impact on the downstream anode refining from different points of view. INTRODUCTION At present, many converting technologies are used in copper pyro-metallurgical plants in China, including Peirce-Smith (PS) converter, flash converting furnace, multi-lance based top blowing, bottom blowing and so on. These technologies have spanned a wide range of time. PS converter technology has been applied in copper smelters for many years and most of the blister copper have been produced by this technology; flash converting technology has been developed since 1990s and been maturely applied in several plants up until now; top blowing and bottom blowing technologies have been revived in China in the past decade and boast good environmental protection performance, energy efficiency, throughput capacity and short process flow. All of the said technologies have reference operations in treating high-grade matte. As more and more attention is paid to environmental protection globally and copper smelters continuously seek for cost reduction, it is necessary to share those converting technologies, especially those new converting technologies derived in China, with copper smelting practitioners in the world. This paper aims to analyze the advantages and disadvantages of various technologies from a macroscopic view and discuss their actual application effects, current developments and future improvements. BRIEF INTRODUCTION OF VARIOUS CONVERTING TECHNOLOGIES IN CHINA China has seen a rapid development in copper smelting industry in the past 30 years and has become the largest gathering place of copper smelters in the world, most of which are operating with PS converting furnace technology, however, with the increasingly strict environmental requirements of the Chinese government in recent years, the low-level pollution issue and the disadvantage of large gas exhaust amount per unit of copper of converting furnaces are particularly prominent.

Jan 1, 2019