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By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By J. Olsson

The paper describes and discusses the use of stainless steels for leaching plants emphasising the duplex family, i.e., austenitic-ferritic stainless steels. This group has generally twice the proof strength of the more common 300-series austenitic grades, which implies possibilities to reduce the gauge at construction of pressure vessels and atmospheric tanks and vessels and thereby possibilities to reduce the weight. The duplex grades have also higher surface hardness resulting in better resistance to mechanical wear, i.e., abrasion and erosion corrosion. The lower contents of nickel and molybdenum imply lower cost and a more stable price considering the present market situation for these alloying elements. Corrosion data from laboratory and pilot plant tests, as well as examples of applications of duplex and highly alloyed austenitic grades, are presented. Cu2007 - Volume IV (Book 1) The John E. Dutrizac International Symposium on Copper Hydrometallurgy Edited by P.A. Riveros, D.G. Dixon, D.B. Dreisinger, M.J. Collins Toronto, Canada,

Jan 1, 2007

By D. B. Johnson

Acidic, metal-rich waters generated at working metal mines and abandoned mine sites are generally considered to be major pollutants of the environment. However, the metals they contain often have significant value of their own, or as sources of useful mineral products. We have developed novel bioreactor systems that facilitate the selective recovery of various transition metals (e.g. copper, zinc and iron) as defined minerals that can be recovered and recycled. The bioreactors use novel species of acidophilic bacteria. Ferrous iron is oxidised by Ferrovum myxofaciens, a specialist bacterium that forms large amounts of exopolymers and grows as filamentous streamers in flowing mine waters, and the ferric iron generated is precipitated as the mineral schwertmannite, a small proportion of which is used to remove any arsenic present in mine water. Copper and zinc are precipitated as sulphides using H2S generated by consortia of acidophilic and acid-tolerant sulphate-reducing bacteria in a continuous flow, on-line low pH bioreactor. Transition metal sulfides can be segregated by precipitating them, either on-line or off-line, at different pH values. The modular units that have been developed can be configured to treat mine waters of different chemistries. A hypothetical acidic (pH 2.5) mine water stream containing 500 mg/L iron, 100 mg/L of copper and zinc, 50 mg/L of aluminum and manganese, 2 mg/L of arsenate, and discharged at a rate of 10 L/s, is used as an example of the potential application of the mineral-generating bioreactors. The environmental benefits and economic implications of considering mine waters as resources rather than wastes are discussed.

Aug 1, 2013

By Alessandro Navarra

Discrete event simulation provides a computational framework in which the use of smelting equipment can be analyzed and optimized, leading to the development of alternative modes of operation. Much of the complexity of copper and nickel smelters is centered on the converter aisle. These converters operate in parallel, produce batches, and set the tempo for the downstream operations. In practice, smelter staff schedule daily operations to coordinate the smelting furnaces and converters with downstream operations. Thus, a realistic simulation of smelter operations, over hundreds of days, should incorporate converter scheduling algorithms as presented in this paper.

Jan 1, 2014

By Bradford C. Wesstrom

An overview of the challenges encountered at the Freeport McMoRan El Paso Copper Refinery with higher concentrations of antimony electrolyte will be shared. The observations will cover the detrimental effects on copper starting sheets, commercial cathodes and anode slimes. The study will show negative effects on quality and productivity. Experimental work will utilize a test cell to study the effects on electrolytes by different Antimony, Arsenic concentration and anode molar ratio. Best practices will be shared for producing high quality cathodes while effectively managing the detrimental effects of higher antimony electrolyte.

Jan 1, 2014

By A. Fakhimi

The effect of porosity on mechanical behavior of rock has been studied in the past using both experimental and numerical techniques. One important aspect of this study that has not received much attention is the role of void size and distribution on the mechanical behavior of rock. In this study, the CA2 computer program that is a hybrid discrete-finite element program for two-dimensional simulation of geomaterials is used. Numerical specimens with different macro-void sizes are loaded uniaxially. The Young?s modulus, Poisson?s ratio, uniaxial strength and crack initiation stress are studied. The numerical results are compared with the database of experimental tests on Plaster of Paris specimens containing Styrofoam spheres with different void sizes and porosities. It is shown that the macro void spatial distribution is partly responsible for the scatter of the experimental data. It is also shown that not-only the porosity but also the pore size can affect the deformability, crack initiation stress and rock strength.

May 1, 2009

By T. G. Joseph, M. Welz

ABSTRACT: Joseph (2002) introduced passive seismic monitoring to measure mining equipment performance. This paper evaluates the potential of passive seismic monitoring to correlate mining equipment operation with oil sands surface response, with a mining hauler as the seismic source. When applied to moving haulers, this action–reaction approach is complex. Vibrations from on-board equipment, such as pumps and tires, dirty the signal with noise. To facilitate any correlation, the signal must be cleaned up. Existing geophysical analytical techniques were manipulated to evaluate the noise problem and to filter sufficiently to permit an evaluation of whether a mining equipment action–ground response relationships in fact discernable.

Jan 1, 2011

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By C. Bazin, D. Hodouin, M. Ounpuu

Sensors are now available in mineral processing circuits to monitor pulp flowrate and density, as well as ore characteristics and other process variables. The amount of information provided by these instruments is considerable but in many cases poorly exploited. This paper gives the results of the application of time series analysis techniques to signals generated by the sensors installed on an industrial Pb dezincing flotation circuit in New-Brunswick. Autocorrelation and cross correlation functions appear to be interesting tools for a preliminary circuit analysis, however the calibration of single input single output discrete transfer functions using collected sensors signals leads to conflicting results. For this reason a phenomenological approach, based on the kinetic and transport properties of the flotation process, is also considered. It has several advantages over the empirical transfer function modelling but also limitations in its applicability to industrial processes. A combination of the transfer function and kinetic modelling approches appears to be a promising avenue for better process modelling and control.

Jan 1, 1985

By G. V. Lewis

"INTRODUCTORY REMARKS""I believe we need to communicate as much as possible with the industry. I don't think that we should be a body that just goes around doing dust surveys and writing nasty letters. We should get together on these problems and try and solve them as a group. I've only been with the Department a little over 12 months. I haven't visited all of your plants. I've visited most of the major open pits and I have had a chance to observe a lot of problems that you have encountered and a lot of the problems that you have brought up this morning. I thought the best thing I could do is perhaps mention a few of the approaches to the problems that my superior has suggested to me and we have discussed in the Department, and then perhaps go over a few of the evaluating problems and what we are trying to do with our dust surveys and perhaps ways and means of improving the present setup."""

Jan 1, 1976

By Ken Major, Anita Marks, Craig Sams

In 2007 Copper Mountain Mining determined that there were sufficient resources to consider reopening the Similco Mine near Princeton, BC. The mill facility that had been built by Newmont Mining in 1972 was closed in 1996 and all of the process equipment removed. The mill had been built on the west side of the Similkameen River to facilitate mining of the Ingerbelle Deposit. In 1980 construction was completed on a primary crusher and cable belt to deliver ore across the Similkameen River from the Copper Mountain deposit to the Ingerbelle mill. With the decision to restart mining of the Copper Mountain deposit, the decision was made to design and build a 35,000 tpd grinding and flotation mill near the mining operations. This paper discusses the application of historical operating data for the selection of the mills for the new grinding circuit and provides an overview of the grinding circuit design.

Jan 1, 2012

By M. Lahtinen, H. Takala, B. Saxén

Oxidic zinc fume dusts are formed in electric arc furnace (EAF), Waelz furnace operations, and also in the Top Submerged Lance (TSL) furnace of Outotec Ausmelt. These dusts are normally considered as secondary raw materials for zinc metal production, as they are mainly originated from steel scrap recycling or zinc plant residue processing. The latest development in zinc fuming is direct smelting of zinc concentrates in the Ausmelt TSL furnace and hydrometallurgical treatment of produced fume dust. This technology is for primary zinc production like roasting and concentrate direct leaching, as concentrates are directly treated. The various oxidic zinc raw materials differ in composition and content of impurities. Thus, they require different hydrometallurgical processes to produce pure zinc metal. In addition to zinc these dusts typically contain also lead, silver and indium, which can be recovered and can increase recovered metal value significantly. From the impurity point of view the most relevant elements in the fume dusts are iron, arsenic, fluoride, chloride and cadmium. This paper describes hydrometallurgical processes to treat Ausmelt TSL fume dusts to extract valuable metals at high recovery and also to control and separate various impurities efficiently.

Jan 1, 2014

By H. J. Oterdoom

SMS Siemag (SMS) has always been the front runner in safety aspects of electric smelter plants for the ferro-alloy and non-ferrous industry. The awareness for safety increased significantly over the past decades and SMS contributed with its design features greatly to a safer design and operation. Today, safety aspects are not only part of the smelter design but also of the overall plant layout. Explosions in electric smelters are rare, but have a huge impact on peoples’ lives, on equipment and on production. For this reason, SMS wanted to have a better overview of explosions within the smelting industry in order to see if useful statistics could be extracted. Generally, there is a lack of statistics regarding explosions in the electric smelting industry, and not enough information is collected or published. A significant portion of the explosions seems to be water related. Many companies, both operating and engineering, are trying to handle the risks of water, and apply methods to detect water leakages. Installing such a system is a management decision and management has then to make sure the system is properly implemented. The disadvantages and limitations of these systems should be carefully considered and communicated to operators and authorities.

Jan 1, 2014

By O. A. Ojo, R. G. Ding, M. C. Chaturvedi

In this study, the fusion zone microstructure of tungsten inert gas weld of a directionally solidified NhAl-base alloy was examined by the standard metallographic techniques involving the use of optical, analytical scanning and transmission electron microscopes equipped with energy dispersive spectrometer. Fusion zone cracking was observed to be closely associated with interdendritic secondary solidification microconstituents identified as consisting of y, y' and NiMo (Y) phases. Depression of solidification temperature to the terminal ternary eutectic reaction temperature of the system during cooling is suggested as an important factor contributing to the fusion zone cracking.

Jan 1, 2006

By A. Scheltema Beduin, M. Kalisch, E. Floch, R. J. Dijkhuis, H. J. Oterdoom

In metallurgical copper production, the traditional aim is to increase recovery of copper to the maximum. SMS Siemag (SMS) has supplied numerous furnaces for this application. New targets are to make sure end of line products are as safe as possible with respect to health and environment, and to maximize raw material utilization. This means a for example a minimization of leachable metals in slag, so it can be safely used as a construction material, and either a targeted concentration or fixation of volatile compounds, such as arsenic. Currently, 2 process routes are generally applied for slag cleaning. The first is grinding followed by flotation, and the second is slag cleaning in an (electrical) furnace. Popularity of both options has fluctuated over the years, and currently the milling-flotation seems to be the more popular option. In this article some of the advantages and disadvantages of both methods are described, and especially how long term environmental policies could have an impact on the decision which process route to choose. Finally, this article will describe some of the developments SMS is working on in pyrometallurgical slag cleaning that could influence the direction for the design of the copper plant of the future.

Jan 1, 2014

By D. Naden, D. J. King

"The high capital and operating cost of liquid-solid separation circuits in hydrometallurgical plants has led to an increased focus on the use of in-pulp systems for metals recovery in order to eliminate the need for solids washing and to reduce the need for liquid-solid separation.Carbon-in-pulp (CIP) has now been accepted in Canada and around the world as the leading process for recovery of gold and silver, replacing the Merrill-Crowe process and thus removing the need for CCD thickeners or belt and drum filters. The overall design of conventional CIP adsorption circuits was established in the late 1970s and it has remained substantially unchanged until now. Most of the development work since 'hen has been concentrated on improving methods of separating pulp and carbon and on reducing carbon losses during transportation and agitation.Resin-in-pulp (RIP) has been used for many years in uranium mills in the USA. However, most of the plants were built in the 1960°s and RIP was only chosen when liquid-solid separation of leach pulps proved very difficult. The plants are far from ideal as they have high resin losses and high maintenance costs. Consequently, there is room for improvement.Davy McKee has taken a fresh look at the engineering development of in-pulp contactors leading to a fundamental redesign of the adsorption units. The improved in-pulp technology uses a modification of the proven air-swept screen techno1ogy together with a new technique of process operation. The new contactor operates at high pulp throughput rates with high concentrations of carbon or resin in the recovery stages, resulting in a significant reduction in the contactor size over conventional design. As a result of this reduction in the size of the contactor by up to 80%, significant savings can be made in equipment and building costs. In addition, the plant 1s easier to operate than a conventional CIP plant."

Jan 1, 1987

By Mitchell Gordon

"In almost all thickener applications the highest possible solid/liquid separation efficiency is what is desired by the user. There is a trend in the industry due to monetary restraints and environmental pressures to look at ways to extract this maximum performance by either retrofitting existing thickeners or installing the most cost effective new thickener. This paper looks at some of the common problem areas and presents a range of solutions developed by Outokumpu Mintec in North America and outokumpu's subsidiary Supaflo Technologies Pty. Ltd.The Emerging PictureAfter many hours of discussions with a large number of plant personnel over the last two years a picture began to emerge regarding current thickening operations in the industry. Initially, it seemed that everybody had their own unique process problems and therefore needed a correspondingly unique solution. Looking more closely at all the cases and the ideas that we had either implemented or suggested, it gradually became apparent that the majority of operators all had one and the same process need ....""Better Separation Efficiency""The range of operational problems that were uncovered in the survey were much more varied than expected and often were not even considered initially to be thickener problems. Often, it was only after the rejection of many solutions to the problem, generally due to capital cost, that the actual cause of the problem was looked at and found to be a thick-ener.A summary of the problems that have so far been identified is presented in Table 1. They are subdivided under three major categories of environmental, process and paste fill to highlight the wide range of mining activities that can be affected by poor thickener performance. These seem to be the major areas where the need for better separation efficiency is rooted."

Jan 1, 1995

By T. Saksala

In this paper, the embedded discontinuity approach is applied to finite element modeling of rock fracture. A rate-dependent constitutive model based on the embedded displacement discontinuity theory is developed to describe the mode I, mode II and mixed mode fracture of rock in tension and compression. The bulk material is described as linear elastic until reaching the elastic limit. Beyond this limit, a ratedependent exponential softening law governs the evolution of the embedded displacement jump. The present approach incorporates the rock heterogeneity by random description of the mineral texture of rock. Moreover, the inherent initial microcrack populations of natural rocks are accounted for as randomly oriented embedded discontinuities. Numerical examples demonstrate the model behavior in uniaxial compression and tension. The effect of loading rate and confining pressure is tested as well in 2D numerical simulations. These simulations show that the model captures the main features of rock in confined compression and uniaxial tension. The developed method has the computational efficiency of continuum plasticity models. However, it has an important advantage of accounting for the orientation of introduced microcracks.

Jan 1, 2015

By Wei Ye, Lei Li, Xianjian Guo, Feng He

The purpose of the paper is to study the smelting process of copper concentrate with high Cu/S ratio produced in Africa or other areas around the world and theoretically analyze the influence of slag type on the smelting process. The paper has compared the processes used successfully in smelters, including CAPEX and OPEX and other factors, to provide reference for the industry to select the best process under specific conditions. INTRODUCTION At present, a great amount of copper concentrates with high Cu/S ratio, with chalcocite being the major source of copper, have been produced or are about to be produced in the Copperbelt in Africa and other countries in the world. The copper concentrate is usually high in copper (~30–55wt.%) and low in sulfur (~10–15wt.%). The conventional processes of smelting-converting and roasting-leaching-electro-winning for treating this type of concentrate is high energy and materials consumption such as electric power\fuels\flux et al. The direct-to-blister (one-step) smelting process can be considered favorable due to a reduction in processing steps. Up to now, there are four copper smelters in the world operating with the direct-to-blister smelting process. There certainly are problems in the process such as high copper content in the slag, strict operation requirement of slag cleaning electric furnace, etc. Except technical issues, the impact of factors on economical aspect such as power and material cost needs to be considered comprehensively in process selection. In this paper the technical issues of direct-to-blister smelting process, including slag treatment process, were analyzed and the comparison to the conventional processes and economic analysis of direct- to-blister smelting process to treat high Cu/S ratio concentrate were done.

Jan 1, 2019

By A. Probst, N. Moores, J. A. Finch

"In 1994 McGill and INCO (Sudbury operation) initiated transfer of technology originally developed to detect level in flotation columns to thickeners. A conductivity probe was installed in a concentrate thickener to monitor the mud-line and solids load. The probe consisted in a vertical tube with 32 equally-spaced electrode rings connected in pairs to give 31 conductivity cells. Conductivity was measured as a function of depth (so-called conductivity profile) from which the mud line and % solids could be inferred. The probe was installed in October 1994 and has been successfully detecting profiles since then. This communication includes a description of incidents and experiences during this technology transfer process including: probe installation and start-up; software modifications to accommodate operating conditions and operators' needs; calibration procedures to adjust to changes in performance as a consequence of long term use; and preliminary observations on the last stage, still in progress, signal interpretation and use to facilitate operation, particularly by providing early reaction to upstream disturbances.IntroductionThickening is one of the basic unit operations in mineral processing and hydrometallurgy used to separate suspended solid particles from a solid-liquid dispersion by gravity settling. As the dispersion enters the thickener, the solids settle and clarified water overflows the top. A thickener, which may be continuous or batch, is basically a large vertical cylindrical tank provided with devices to feed the dispersion and to remove the settled solids. The tank provides residence time for the particles to settle. The dispersion enters the thickener through the feedwell whose function is to dissipate the momentum of the feed stream and to create relatively quiescent conditions around the entering point. Rotating rake arms move the settled solids towards the discharge point located at the bottom centre of the tank.There are normally three distinct zones in a thickener: a top layer of clear water, a middle layer called a sedimenting zone in which particles are settling, and a bottom layer called a compression zone in which particles are pressed together as a consequence of the weight of accumulated particles. Proper operation of a thickener requires two simultaneous conditions: no solids in the water overflowing the top and the target solids content in the underflow pulp. To achieve these conditions is difficult because sensors for detecting the sediment line (interface between clear water and sedimenting zone) and the solids content in the compression zone are not commercially available."

Jan 1, 1998