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By A. K. Verma

This paper provides a brief overview of evolution of deformations, stresses, and pore pressures due to different excavation stages during construction of an URL. Excavation of a rockmass develops a damage zone of finite width around the excavated zone which is associated with changes in permeability and which affects the fluid flow mechanism. In this study, a coupled hydromechanical (HM) analysis has been conducted for a water saturated porous rock mass which has been created by sequential excavation and backfill of vertical disposal pit of an URL. For this purpose, an Atomic Energy of Canada Limited?s in-floor concept for a deep geologic repository suitable for Indian conditions has been used. Changes in rock deformations, stresses, strains and mechanically induced pore pressure in an undrained condition, during excavation, as well as those caused by mechanically induced rock deformations after backfill of the disposal pit, have been modeled. A three-dimensional finite difference tool FLAC3D has been used for the analysis.

Jun 1, 2012

By H. A. Steane

THIS BRIEF PAPER presents the information available on the use of Dorrclon?is in the middling re-grind unit at the lead-zinc mill of Canadian Exploration Limited. The plant throughput is 1,650 tons per twenty-four hours. The flotation feed is ground to 60 per ?Cent passing through 200 mesh. It contains some composite 11articles of sphalerite in calcite, and these reported either in the final zinc concentrate, thus lowering the grade, or in the tailing, with loss of zinc. The re-grind unit was set up in the zinc flotation circuit to liberate the sphalerite from these middling particles, to raise the grade of concentrate and improve recovery. Grinding through 325 mesh should give substantial liberation of locked sphalerite. The middling regrind unit consists of two Dorrdones and one ballmill arranged as shown in the -accompanying flow-sheet. The Hardinge ball-mill, size 7 ft. x 36 in., was free for this use as a result of recent plant expansion. The two Dorrclones were purchased, and the necessary pumps and pipe lines were installed to complete the regrind unit. The unit has been developed over a period of two years by several steps and various flow schemes until reaching tl1e present flow scheme. These steps are not elaborated here, because the changes were made to determine the best product to work on for flotation metallurgy, and not because of the Domrolone classifying ability.

Jan 1, 1956

By Normand Champigny

The Forces of Change ? The current business environment ? What can we expect for the future on management of physical assets ? The impact of maintenance on production costs ? What is RCM is doing is improving business performance ? The beginnings of RCM The RCM II Process ? RCM II is a structured process that involves employees in determining the best failure management tactics for systems and equipment in their operating context ? The method is an effective approach to risk and cost reduction as well as failure management

May 1, 2002

Overview n Why we audited the IRS n How we did it n What we discovered n What we learned n Where we are going next The unbroken chain of safety The Internal Responsibility System (IRS) The network of roles and relationships in a workplace, through which everyone works with mutual commitment to reduce or eliminate hazards.

May 1, 2003

By Barbara Kirby

Mining Industry Human Resource Council Who we are: National Sector Council for the Minerals and Metals Sector 18-person Board of Directors Over 100 Industry Volunteers PPP - Funded by HRSDC and industry What we do: Identify national HR challenges and opportunities for the Canadian mining industry Create national solutions through collaboration, partnerships and Synergy

Oct 1, 2010

M INE production requires the coordination of the talents of men and the use of equipment. Mine operators maintain a continual surveillance of equipment, looking for improvements and modifications that will benefit them. Few give similar attention to the advances made in the education of mining engineers since they themselves graduated. That is not surprising. Education lacks the advertising budget available to manufacturers. A modification to improve a mechanical contrivance is advertised, and an advertiser's press releases get attention by publishers. The whole program for mining engineering education could be revolutionized and no one, except a few professors, would know about it. The Canadian Institute of Mining and Metallurgy's newly established General Commit-tee on Education can improve that situation. Nine groups of engineers in Canadian universities are trying to give undergraduates an education that will make them useful to the mineral industry as mining engineers. The tabulation offered here (Table I) is an analysis of the distribution of the undergraduate-teacher contact time.

Jan 1, 1963

By Deni Côte, Michel Dagbert, Marcel Vallée

"Greater reliability of mineral deposit and reserve estimates can be attained through better quality control of the data and information acquisition, and the estimation processes. This paper reviews the following key requirements:1. greater awareness of the significant figures of both data and estimates, and better understanding of the probabilistic aspects of the estimates, their confidence limits and margins of error;2. greater reliability of the information that supports the estimates, by more explicit and more rigorous methods and standards for data acquisition and for interpretations;3. more quantitative estimations of geological/mineral continuity, based on improved three dimensional sampling patterns and the use of geostatistics; and 4. better integration at the project engineering and mine production stages, of the mineral deposit characteristics and mining method constraints, for more efficient mineral recovery and mine quality control.RÉSUMÉUne plus grande fiabilité des estimations des gisements et des réserves minières requiert plus d'emphase sur le contrôle de la qualité de I ‘acquisition de l'information et du processus d'estimation. Les exigences suivantes sont revues:1. le respect du niveau d'exactitude des données et des estimes en n'utilisant que le nombre approprie de chiffres significatifs des observations et mesures, et en exprimant le niveau de confiance et la marge d'erreur des estimations;2. l'amélioration de fa fiabilité des données par des normes plus rigoureuses pour leur acquisition et leur vérification, et par des méthodes plus systématiques d'interprétation et de modélisation;3. l'estimation plus rigoureuse de la continuité des minéralisations dans les trois dimensions des gisements, par des patrons échantillonnages mieux adaptes awe paramètres géologiquement minéralogiques, et par l'utilisation des méthodes géostatistiques; et4. l'intégration plus poussée, particulièrement lors de la planification de l'exploitation minière, des caractéristiques des gisements avec les contraintes des méthodes d'exploitation, pour améliorer la récupération et le contrôle de la qualité en exploitation."

Jan 1, 1993

By J. M. Skeaff

"The main solution, ore and residue pulp streams in the Rio Algom Quirke I uranium mill at Elliot Lake have been sampled and analyzed for radium-226. Analysis of the ore and leached residues indicates that Ra-226 dissolves and precipitates within the first pachuca tank. A maximum of approximately 0.2% of the Ra-226 in the ore remains in solution during leaching.IntroductionConcern over the acid drainage and radionuclide dissolution problems associated with uranium tailings disposal sites in Canada has prompted investigation into methods for improving current uranium processing practice.Present commercial practice usually involves leaching of the uranium ore with sulphuric acid, ion-exchange separation of the uranyl sulphate complex from the leach liquor and"" precipitation of the uranium as yellowcake. Daughter products of U-238, such as Th-230, Pb-21O and Ra-226 remain with the tailings and undergo long-term dissolution.Table I summarizes the probable behaviour of the radionuclides during milling. The concern here is with Ra-226, because it will deposit in the bones if ingested and is ""thus considered a serious health hazard(1), Similarly, Po-218 and Bi-214, which are daughter products of Rn-222, can be retained in the lungs and are considered to be the principal sources of radiation dosage(2) arising from the inhalation of Rn-222. Previous investigations(3-9l indicate or imply that Ra-226 undergoes redistribution during milling. However, detailed published information on the behaviour of Ra-226 in the uranium milling process appears to be lacking. A knowledge of the behaviour of Ra-226 in uranium mills, particularly during leaching, could lead to improved methods for its control.This paper reports the occurrence of Ra-226 in the Rio Algom mill. The main objectives of the study were to determine (1) the distribution of Ra-226 within the solids, (2) at what point, and how rapidly, redistribution occurs and (3) whether there are high concentrations of Ra-226 in solution."

Jan 1, 1981

By L. A. Homeniuk, R. Bonnar

"The Athabasca Basin has been the scene of an intense exploration effort since the late 1960s, resulting in the establishment of this area as one of the major uranium districts in the world.The A thabasca Group is of Helikian age and unconformably overlies metamorphic rocks of Aphebian and Archean age. Most of the known uranium deposits have a close spatial relationship with the unconformity, graphitic meta-sediments, major northeast-trending structures and the basin edge. It should be noted that, in regard to the latter, some of the Cluff Lake deposits are exceptions.The pre-Helikian rocks underlying the Athabasca Group have been divided into six Iithostructural domains. The known uranium deposits are concentrated in the Wollaston and Mudjatik domains in the southeastern portion of the basin.The orebodies typically have a narrow high-grade portion below the unconformity and a broader, lower-grade disseminated zone in the overlying sandstone. Over-all grades average over 1% U3O8 and our estimate of known reserves totals more than 400 million pounds of contained U3O8. Some of the deposits have high concentrations of other metals, including nickel, arsenic, cobalt and gold. Ubiquitous chlorite and clay alteration is characteristic of the orebodies.Other Proterozoic basins in Canada of similar ages and having analogous geological settings to the Athabasca have received far less attention. Although little of the known uranium mineralization in these basins is related to the Helikian unconformity, there may be an exploration potential for deposits similar to those of the Athabasca basin.IntroductionThe Athabasca sedimentary basin is located within the Churchill Structural Province of the Canadian Shield in Northern Saskatchewan. The basin is elliptically shaped and is approximately 800,000 square kilometres in area.The objective of this paper is to summarize the various elements in the genesis of the unconformity-type uranium deposits of the Athabasca Basin and to evaluate the comparative potential of other Proterozoic basins to host similar unconformity-type deposits."

Jan 1, 1982

By Georges Houlachi, Raynald Labrecque, Jean-Noël Cloutier

"Electrodialysis (ED) is an electro-membrane technology based on electrochemical process using electrical energy for the production of chemicals. The process can be used for concentrating, extracting, separating products, modifying molecules, purifying solutions, pH adjustment and regenerating salts into their base and acid. This paper reviews the principle of ED, present some of the different options and discuss applications that are relevant to the hydrometallurgy and mining industries for the treatment of effluents focusing on recovery of chemicals (acid and metals) and recycling of water minimizing the environmental footprint.INTRODUCTIONElectrodialysis (ED) is usually defined as an electrochemical separation process in which electrically charged membranes and an electrical potential difference are used to separate ionic species from an aqueous solution and other uncharged components [1]. ED technology consists of an electro-membrane technology based on an electrochemical process using electrical energy for the production of chemicals. It is a method combining electrolysis and dialysis was proposed for the first time in 1890 by Maigrot and Sabates [2]. In the late 1930s Teorell, Meyer and Sievers discussed membrane phenomena, revealed membrane potential, electric conductivity, transport number [3]. Meyers and Strauss introduced a multi-compartment ED apparatus consisting of two electrodes and a stack of ion-exchange membranes between them [1]. They succeeded to double the concentration of a KCL solution [3- Tarleton]. In general, ED consumes less energy than electrolysis to perform salt splitting. In that regard, one can expect an energy reduction of about 30% [4–5]. ED offers a great versatility in the domain of separation processes. Indeed, it can be used for concentrating, extracting, separating products, purifying by desalination, pH adjustment and regenerating a salt to acid and base components. This paper reviews the principle of ED, presents various options available and discusses potential applications relevant to the mining and metallurgy industries with economics of some successful industrial applications."

Jan 1, 2016

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By James Tuer, John R. Goode, Jim Cambon

"Hudson Resources Inc. (Hudson) has defined a major resource of high purity anorthosite (calcium feldspar) assaying about 30% Al2O3 at the White Mountain (Naajat) deposit in Western Greenland. Extensive beneficiation and evaluation testwork has shown that the material can be simply beneficiated to produce a feed material ideal for the production of low-alkali E-glass used for making glass fibre. An offtake agreement is in place with a major US fibreglass manufacturer and, subject to the mine construction schedule, shipments are scheduled for late 2016 or early 2017. In parallel with the E-glass program, Hudson has completed an initial program of metallurgical testwork which shows that the White Mountain anorthosite can be processed by hydro- and pyro-metallurgical processes to yield either smelter-grade alumina (SGA), suitable for conversion to aluminium metal, or a high purity, chemical/specialty-grade alpha-alumina (CGA) commanding a premium price. The process includes dissolution of the anorthosite in hydrochloric acid, HCl sparging to precipitate aluminium chloride hexahydrate (ACH), recycle of the ACH filtrate to leaching with a bleed stream processed for HCl regeneration from CaCl2, and two-stage calcination of the ACH to regenerate HCl and produce SGA and/or CGA. Calcium silicate and amorphous silica are marketable by-products. This paper discusses the White Mountain anorthosite deposit; the process testwork completed to develop production processes for SGA and CGA; production plans, and indicative economics.INTRODUCTIONHudson Resources Inc. (Hudson) holds a 100% interest in the Naajat Exploitation Licence in Western Greenland that cover the White Mountain high-calcic anorthosite deposit. Anorthosite is a calcium aluminosilicate of slightly variable composition but generally containing about 30% Al2O3. The alumina content is similar to that in bauxite and anorthosite has long been studied as a feedstock for the production of alumina. Other potential uses include feedstock for the high-end fiberglass (E-glass) industry and as a filler for use in paint and plastics."

Jan 1, 2016

By S. E. Malouf, W. Thorpe

"The Chibougamau Explorers property comprises 35 claims or 1,726 acres in La Dauversiere and Rohault Townships along the west shore of Norhart Lake. The property is serviced by a twelve-mile all-weather high-way leaving the main St. Felicien-Chibougamau highway at mileage 121. This road junction will be a railway siding on the C.N.R. St. Felicien-Chibougamau branch line in early 1957. The property lies 30 miles due south from the town of Chibougamau. The mine-sponsored Chibougamau Explorers town has a population of 250 with 28 residences and a well equipped recreation centre.The original showing was found by Rider Storn, a prospector financed by Val d'Or interests during the 1950 field season. This showing did not stand up to detailed prospecting but it did lead to the discovery of the main zone by A. Oakley during the following winter.The company was incorporated in I 950 under the presidency of E. Ayrhart. Financing following the initial drilling involved an increase of capitalization from 3 to 5 million shares and the advent of financing and management control by Anacon Lead Mines Limited.Exploration and development to Jan. I, 1956, has included 42,331 feet of surface diamond drilling; 31,363 feet of underground drilling; a 3-compartment shaft to 1,245 feet, with 8 levels at 150-foot intervals; and I 1,054 feet of drifts, crosscuts, and raises. Ore reserves to the 900-foot level, proven and partly developed, total 546,725 tons averaging 0·30 ounces gold and 0·93 per cent copper. A mill with capacity of 500 to 750 tons will be installed by January 1956.GeologyThe Chibougamau Explorers property lies along the belt of Keewatin volcanics striking through Bachelor Lake, Opawica Lake, Doda Lake, Coapatina, Norhart Lake, and Rohault Lake, where it is in close proximity to the paragneisses of the Grenville series. The boundary of the paragneisses, a gradational contact, lies within a mile of the Chibougamau Explorers shaft collar."

Jan 1, 1949

By I. Stanoev, V. S. Stoilov, I. Gradinarov, E. D. Visariev, I. A. Bonchev, Aurubis Bulgaria

"Aurubis is the leading integrated copper group and the world’s largest copper recycler. In Copper smelter Aurubis Bulgaria (Pirdop), the residual copper in the slags from Flash furnace and Converters is recovered by flotation. The slag processing comprises: pit cooling, crushing, two stages grinding (autogenous and ball) and flotation. The copper concentrate is thickened and then is filtrated by vacuum disk filter. The thickener overflow is sent to settler for additional clarification. A resent throughput increase resulted in higher solid content in the thickener overflow due to insufficient thickener area. Different scenarios to overcome the issue were evaluated (new thickener, reagents and reconstruction). An increase of the thickening area by installation of lamella modules was chosen as the most promising option. Three lamella modules (1 m3 each) were installed in conventional thickener for the test. Number of sampling campaigns was done to evaluate the effect on solid content in overflow. Parameters of the dewatering cycle were collected during sampling campaign. The products grain size distribution was defined - thickener feed, thickener overflow with and without lamella. The thickener overflow with lamella modules has 2.12 g/L less solid content. The decrease was 71.8%. According to the tests results, the whole conventional thickener was reconstructed with lamella modules. The thickener area was increased by more than 400 m2.INTRODUCTIONIn Copper smelter Aurubis Bulgaria, the copper in slag from the Flash furnace and the Converters is recovered by flotation. The scheme of slag processing is crushing, two stage grinding (autogenous and ball) and flotation. Till 2010 the grinding cycle in the plant was in two stages: the first stage was AG Mill 70×23 working with a classifier and the second stage was ball mill 3.6/5.5 working with a hydrocyclone. In 2010 a new AG Mill 65×78 with hydrocyclone was put in operation in order to increase throughput of the plant. The second stage of the grinding cycle was not changed."

Jan 1, 2016

By R. J. McLeod

"Grinding at Giant Yellowknife is done in two stages. The first stage consists of two ball mills in closed circuit will: mechanical classifiers, the classifier overflow goes to flotation. The tailings from this flotation circuit are separated into slime and sand portions, the slimes go to an additional flotation circuit while the sand portion goes to the secondary grinding mills.Milltronic automatic sound control units were installed on each of the two primary ball mills and put into operation September 3, 1966. After about two months adjustments to the control units the operators were taken off the grinding circuit on November 1, 1966. The operators duties were taken over by the automatic control units while miscellaneous work was taken over by the helpers in the mill. The labour saving by the installation is approximately $2250.00 per month.After a short period of operation it was apparent there was a slight change in grind. The screen analysis of the primary classifier overflows for the period May to August 1966 averaged 62.23% minus 200 mesh while for the period September to December 1966 averaged 62.0% minus 200 mesh. This is a slight coarsening of the grind. The change in the primary grind has manifested itself also in the screen analysis of the final grind. Before automation the final grind was 80% minus 200 mesh, while after automation it was 7 5% minus 200 mesh. A change of grind was also noted in the flotation concentrates. Before automation the screen analysis of the concentrates was 35% plus 200 mesh and 50% minus 3 25 mesh. A ft er automation it was 35% plus 200 mesh and 47 .5% minus 325 mesh. In other words the grind got coarser or perhaps we should say there was less overgrinding. Another significant change took place in the assays of the slime and sand portion of the primary flotation tailings. It was usual under manual control for the slime portion to assay higher in gold than the sand portion. The reverse is now true."

Jan 1, 1967

By M. E. Stutt, R. H. Rehder

"The mining industry is taking advantage of the increased performance resulting from the use of variable speed A C drives for large motors. This technology provides increased efficiency under the variable speed and torque requirements of such drives as mine hoists, conveyors, and air moving equipment. The technology does introduce voltage spikes on the voltage wave form that stress the insulation system to a greater degree than would occur with a constant voltage source. These voltage spikes must be considered in the design of the insulation system used for these motors.BackgroundHistorically the insulation systems for large AC motors were designed to withstand with reasonable life the voltage stresses of a 60 Hz constant sinusoidal voltage. One of the design tests is a voltage endurance test that requires the application of a 60 Hz voltage from conductor to ground equal to four to five times normal and establishing a time to failure. These higher than normal voltages accelerate the normal aging process by causing extensive partial discharge activity (corona) within the insulation system and the time to failure is a relative indication of insulation life.In addition to the voltage endurance test at 60 Hz, the individual coils are subjected to a surge voltage test to establish the withstand capability of the turn to turn insulation under switching surge conditions. The surge voltage is a fast rise time, 0.2 microsecond to crest value, voltage spike that can be caused by a circuit breaker or contactor closing operation. These voltage spikes can have a crest value of greater than 3.5 times the normal line to ground crest voltage of the normal 60 Hz power supply. The standard withstand test value is thus 3.5 times normal line to ground voltage. Because the voltage surges or spikes occur mainly during start and stop switching conditions, voltage endurance under these conditions has not been a major factor in insulation system design."

Jan 1, 1995

By C. C. Allen, H. H. North

"The Young-Davidson mine is in the southeastern part of Powell township, in the district of Matachewan. It is 32 miles southwest of Kirkland Lake, 48 miles southeast of Timmins, and 25 miles by road Northwest of Elk Lake. The Young-Davidson and its neighbour, the Matachewan Consolidated mine, are the two present producing properties in the district. The Matachewan area is the southwestern extension of the Kirkland Lake belt or 'break'. The Young-Davidson mine since coming into production in 1934 has been operated by Hollinger Consolidated Gold Mines, Limited. ""Desultory prospecting(1) has been carried on in the Matachewan area from time to time since the discovery in 1906 of silver in James township at Elk Lake, and some gold has been found in the southeastern part of Alma township and in the central part of Cairo township. The first real interest in the area, however, was started by Jake Davidson's discovery in 1916 of gold on Davidson creek, on what is now part of the Young-Davidson property, and by Sam Otisse's discovery shortly afterwards on claims a short distance to the east, now part of the Matachewan Consolidated property. In subsequent years both of these properties were investigated by various companies; the Young-Davidson chiefly by the Porcupine Gold fields Development and Finance Company, Limited, and the Matachewan Canadian by the Colorado-Ontario Development Company, Limited, which in 1919 was reorganized under the name of Matachewan Gold Mines, Limited. Work was discontinued as the ore was considered too low in grade to be mined"". However, in 1933 Hollinger Consolidated Gold Mines, Limited, undertook to bring the property into production and this became a reality in 1934.The total production to the end of year 1945 was 319,185.59 oz. gold and 73,541.94 oz. silver from 3,228,845 tons of ore. This represents an average grade of $3.67, including exchange and premiums."

Jan 1, 1954

By D. J. Bowen

"The Great Dyke extends for 540 krn along strike, to unknown depth, and varies in width from 3 krn to 11 krn. Rb/Sr age determinations gives values of approximately 2470 Ma.The Dyke consists of a variety of mafic and ultramafic rocks, many altered to serpentinites. These include, from top to bottom, successions of gabbro/norites, pyroxenites, peridotiteslharzburgites, and dunites/picrites.The layers dip in from either margin, steepest at the edges (20°) and flattening toward the central sections. Four separate complexes are present. From north to south these are termed the Musengezi, Hartley, Selukwe and Wedza Complexes, and are described as 'boat-shaped' or 'pig-troughed'. All are similar in petrological sequences. Physiographically, the Dyke is spectacular in the north, where as a mountain range it meets the Zarnbezi Escarpment. Elsewhere in the central parts there is little surface expression and wide open treeless vleis. Dyke rocks cut through granite and schist belt terrain and are termed 'The Magnesia Belt'.Vast mineral resources exist. These include chrome, asbestos, platinoids, nickel, copper and gold. Up to eleven chrome seams numbered from top to bottom occur in the lower ultramafic sequences. Seams are narrow at 10 em to 30 em but of high grade. The platinum occurs 10 m to 40 m below the norite/pyroxenite contact.A 60 m wide zone of Light Sulfide Mineralization (LSM) of less than 1070 sulfides extends from the lower gabbronorites into the upper pyroxenites. In this LSM, four enriched zones carry up to 5% sulfides. The most widespread is termed the Main Sulfide Zone (MSZ), below which is No. 2, No.3 and No.4 Sulfide Zones. The MSZ carrying pyrite, pyrrhotite and chalcopyrite is a multielement ore with components of PGE (pt-Pd-Rh), nickel, copper and cobalt, and gold and silver.Extensive exploration programs have been carried out and the intention is to begin large-scale mining. However, with Russia supplying metals to the western markets, South Africa's cutback on production, and an end to the Cold War, delays have arisen."

Jan 1, 1994

By L. Avramovic, B. Han, R. Jonovic, Z. Stevanovic, K. Haga, S. Dimitrijevic, A. Shibayama, L. Godirilwe, Y. Takasaki

Pyrite (FeS2) and chalcopyrite (CuFeS2) which could not be recovered, are present in mine tailings discharged from Bor copper mine. About 0.3% of copper (Cu) is contained in these tailings, therefore it can be considered as a useful copper resource. At the same time, pyrite is known to promote acid mine drainage, therefore it is necessary to detoxify the tailings. An efficient method has been proposed to recover copper and reduce the environmental impacts of tailings by a combined hydrometallurgical process of high pressure leaching (HPL), solvent extraction (SX) and electrowinning (EW) process. HPL process yielded high copper leaching rate (>95%) when water (H2O) was used as a leaching media. On the other hand, pyrite contained in the tailings was converted to iron oxide by high pressure leaching. Stability evaluation of the residue obtained from high pressure leaching, confirmed almost no elution of metal ions. The percentage of copper extracted and stripped from the Cu-loaded organic phase reached 97.4%. Moreover, it was confirmed that a low iron concentration in the electrolyte of copper electrowinning, resulted in the improvement of current efficiency of copper electrodeposition. INTRODUCTION Mine tailings are a by-product obtained from the flotation process and there are billions of tons of already existing tailings all over the world. Moreover, several billion tons of additional copper tailings will inevitably be produced in the coming years (Onuaguluchi & Eren, 2012). With the declining average copper ore grade, alternative sources of copper are highly sought, mine tailings have a comparable copper grade to that of low-grade ores (0.2–0.3%) therefore, it can be said that copper mine tailings present a very important source of secondary raw material for copper production (Antonijevi´c et. al., 2008). Consequently, it is necessary to confirm the possibility of the valuable metals (such as copper) recovery from mine tailing in which copper content is about 0.2–0.3%. Our group investigates the flotation and high pressure leaching processes for recovering of copper from mine tailings. Previous work on related samples include copper and nickel flotation tailings from Botswana, and a low–grade copper ore sample from Chile. Impurities, which are associated metals in mine tailing such as iron (Fe) and aluminum (Al) co-dissolve into the solution during the HPL treatment process. Therefore, separation of copper from impurities is necessary for selective extraction of copper from mine tailings and upgrading the copper concentration in the leachate to enable further purifying of Cu by electrowinning. Thus, it is important to investigate the possibility of applying solvent extraction for concentration of copper from leachate solutions of mine tailings (Onuaguluchi & Eren, 2012; Antonijevi´c et. al., 2008). In this study, LIX-84I was used as an extractant of copper from the leachate of high pressure leaching of mine tailing. As a fundamental solvent extraction investigation, the extraction behavior of copper was studied using a simulated solution of the leachate from the high-pressure oxidative leaching of mine tailing. The effects of; solution pH, extraction time, extractant concentration and phase ratio on copper extraction and sulfuric acid (H2SO4) concentration on stripping were investigated.

Jan 1, 2019

By Steve Scott

Green Economy Toyota Prius Hybrid contains about 50 kg of copper. All-electric cars have about 100 kg of copper. From where will all the copper come? Wind turbines have 1 metric ton of copper China is building 221 cities of 1 million people by 2025 (13 cities per year from 2008) = 10 New Yorks. The Greater Toronto Area has 5.6 million people, so a new GTA every 22 weeks!

May 1, 2013