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By Georges Croisé, Les-Lee Thompson, Adrien Debergé

Membrane filtration systems have regained focus in recent years as an effective means of liquid-liquid separation to increase the concentration of valuable elements, recover reagents or remove impurities. ORANO Mining (formerly AREVA) investigated this cost optimization process opportunity as early as 2011 for implementation at the Trekkopje project (Namibia). The key focus was to separate and recycle bicarbonate from the uranium bearing eluate solution. The performance targets were successfully achieved at lab- and pilot scale with an ultrafiltration and nano-filtration configuration system. Early 2015, ORANO Mining further launched an investigation into the use of membranes for acid recycling at the KATCO In Situ recovery mine in Kazakhstan based on the favorable results from the original bicarbonate application. KATCO is the world leader in ISR uranium mining with an eluate processing capacity of 80 000 m3/yr. This site consists of two processing plants namely, Muyumkum and Tortkuduk, located 40 kilometers apart, both operating under acidic conditions whereas precipitation and packaging are based in Tortkuduk only. This paper serves to present the results from the integration of a nano-filtration system at the Muyumkum satellite processing plant. The project consisted of screening laboratory bench studies conducted at ORANO-CIME followed by process validation at KATCO through further bench and pilot test work. The feasibility study assessments were successfully concluded which led to the implementation at an industrial scale in Muyumkum of a nano-filtration process to reduce eluate volumes being sent to the uranium precipitation section whilst achieving effective separation of uranium from sulfuric acid. Nano-filtration technology has drawn significant attention due to the efficiency and reproducibility of the process and its moderate capital cost relative to operational savings. The reliability of the previous results is a great opportunity to reduce operative expenditures within ORANO’s next ISR mining project in Mongolia.

Jan 1, 2020

By G. Bonnivard

"A complete laboratory process for the treatment of lateritic ores containing a high proportion of iron, as well as chrome and alumina, has been established. The ores treated originate from the tropical zones and result from superficial climatic alteration. According to recent estimates, the known reserves of such ores reach many billions of tons, thus representing huge potential reserves for the elements they contain.The process used is based on the alkaline roasting of pelletized ore in the presence of sodium carbonate. This treatment results in the separate recovery of pellets of upgraded iron ore, pure chrome oxide and hydrated alumina. The research described in the paper aims at determining the best experimental conditions for obtaining the highest extraction of the required oxide from this type of ore."

Jan 1, 1967

By M. Maley, S. Burling, R. Ring

ABSTRACT The numerous global uranium deposits vary significantly in mineralogy, grade, and textural characteristics; therefore, information from traditional (or conventional) sources on the fundamentals of leaching uranium and gangue minerals is not always applicable when studying particular ores. Empirical studies can be effective in understanding leach systems and can lead to improvements in process design but there remains a lack of fundamental understanding necessary for ongoing process optimization as ore bodies continue to vary. ANSTO Minerals has undertaken a work program to address several fundamental questions about uranium leaching, including the unexpected impact for some ore types of leaching at high oxidation potential.

Jan 1, 2012

By K. Soldenhoff, D. Wilkins, E. Ho

In the processing of rare earth ores, a pure, mixed rare earth chloride solution is usually produced and used as the feed to solvent extraction circuits to separate the individual rare earths. Cerium(III) may be separated from the other rare earths by oxidising it to cerium(IV), which precipitates as cerium(IV) hydroxide in chloride liquors. This oxidation step may be inserted either before rare earth separation by solvent extraction or between solvent extraction circuits. Although oxidation of cerium by sodium hypochlorite has been known for many years, detailed conditions for oxidation are not readily available. The effect of hypochlorite addition, temperature, pH and cerium concentration on oxidation of cerium(III) from synthetic solutions was investigated

Jan 1, 2014

By D. J. Wesolowski, D. A. Palmer, P. Bénézeth, S. Hilic

The equilibrium solubilities of gibbsite, Al(OH)3, and boehmite, A1OOH, have been extensively studied in our laboratory from 30 to 90°C, and 100 to 300°C, respectively, to ionic strengths of 5 mol.kg-1 (NaC1) over a wide range of pH. The resulting solubility constants have been treated with consistent empirical models that incorporate appropriate experimental data taken from the literature. These studies were initiated in part to understand and quantify scale formation in geothermal fields as a result of fluid re-injection from electric power generating plants. Most of the experimental results were obtained through application of a unique potentiometric method that allows for rapid, precise measurement of the in situ pH and allows the approach to equilibrium to be monitored from under- and super-saturation. The experimental program was extended to deal with more basic solutions (e.g., five molal NaOH), in which the dissolution of boehmite was measured for application to the refining of bauxite by the Bayer process. More recent results in strong caustic solutions at temperatures below 90°C were obtained to investigate the dissolution of aluminum-containing sludge from holding tanks at the Savannah River waste reprocessing site. In this case the solubility enhancing effects (kinetic and equilibrium) of triethanolamine were also established and quantified. Finally, potentiometric solubility experiments were conducted (50°C in 0.l mol-kg-1, NaCl) on aluminum alloy sheets to identify mainly the nature of the aluminum oxide/hydroxide surface layer formed under these conditions.

Jan 1, 2004

By Robert Dickson

Princess colliery is operated by Old Sydney Collieries, Limited, a direct descendant of the General Mining Association of London, England, which, in the first quarter of the nineteenth century, pioneered in coal mining in Nova Scotia. The coal worked is a 5 ft. 6 in. seam known generally through the Sydney coalfield as the Harbour seam but referred to locally as the Sydney Main. Entry is made by shafts, 680 feet deep, sunk in 1871 on a headland forming the northern entrance to Sydney harbour. From them extend the main roadways of the colliery, a distance of 700 feet to the shore line and a further distance of 14,700 feet in submarine areas to a total length of 15,400 feet. It was the first colliery in Nova Scotia designed to work submarine areas. Lateral development extends across a frontage of 16,000 feet and the submarine area from which the coal has been extracted is slightly over 6 square miles. There yet remains sufficient territory ahead of the workings to assure a future life to this colliery estimated at over 80 years at the current rate of production. In this area the seam dips at 6 to 7 per cent and face workings have reached a depth of 1,690 feet below the sea level. Until 1923 extraction of the coal was by room-and-pillar, followed by the drawing of the pillars. At that date the superincumbent strata had reached a thickness of 1,400 feet, resulting in heavy weighting on the roof and severe side pressure on the coal ribs. In combination with a soft, heaving pavement this created a set of conditions involving great difficulties and expense in keeping open places driven in the solid sufficiently long to permit recovery of the coal in the pillars by methods and equipment then available. The operator was forced to resort to extraction by longwall as the only economical method of winning the coal.

Jan 1, 1948

By S. Kaiman

This paper describes flotation test work conducted over the past several years at the Mines Branch, Ottawa, on the radioactive quartz-pebble conglomerate ores of the Elliot Lake area of Ontario. The purpose of this work has been to produce a uranium flotation concentrate for sub-sequent leaching operations. The results of earlier investigations are summarized and correlated with the results of mineralogical studies of the ores and flotation products. The results of recent pilot-plant investigations by flotation, as well as by gravity concentration followed by flotation of the gravity tailings, are given. The principal collector used for uranium flotation was a tall oil fatty acid, and the indicated total cost of all reagents ranged from 21 to 31 cents per ton of ore treated.

Jan 1, 1966

By Thomas Genty, Pascal Marcotte, Matthew Gillman, John Baechler

Elevated concentrations of ammonia nitrogen is a common characteristic of mine impacted water and generally results from the dissolution of undetonated explosives (i.e., Ammonium Nitrate and Fuel Oil and emulsion explosives) by contact water. Several active water treatment technologies are commercially available to remove ammonia nitrogen, but reduction of active treatment demand by promoting natural attenuation is considered best industry practice. In this paper, the results of laboratory-scale and full-scale trials of a semi-passive approach (i.e., enhanced algae growth) to remove ammonia nitrogen at the Meliadine mine are presented. Phosphorus was found to be the limiting factor to algae growth at the mine site. The addition of various concentrations of phosphorus was first tested at a laboratory scale. The samples were exposed to in-situ conditions, and ammonia nitrogen removal rates ranging from 40% to 93% were achieved over a period of 24 days. This paper also presents the methodology and results of an in-pond treatment during which a 50% ammonia nitrogen removal rate was observed after 68 days. The studied mine site uses breakpoint chlorination as its primary treatment approach for ammonia nitrogen removal. The results presented in this paper show the potential of using enhanced algae growth as a pre-treatment method, subsequently reducing the quantity of chemicals required for operating the breakpoint chlorination plant. This potential requires further investigation and additional trials are currently under evaluation.

Jan 1, 2023

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By H. Chaouki

The aim of this work is to simulate the forming process of a green anode. For this purpose, a nonlinear compressible viscoelastic constitutive law is presented. The concept of natural reference configuration is considered. Within an isothermal thermodynamic framework, a Helmholtz free energy is proposed to take into account the nonlinear compressible deformation process occurring between natural reference configuration and current configuration. A dissipation potential is introduced in order to characterize the irreversible aspect of compaction process. Thus, the constitutive law is formulated through two equations: 1) an expression of Cauchy stress tensor and 2) a differential equation characterizing the evolution of the natural reference configuration. Material parameters are assumed to be a function of the bulk density. This allows capturing the micro-mechanical phenomena within the chosen macroscopic approach. An experimental study based on compaction tests is carried out in order to characterize the mechanical behaviour of the anode paste. A user's material VUMAT subroutine for finite element dynamic explicit analysis has been developed and implemented in the ABAQUS commercial software. To evaluate the model predictive capability, numerical simulations of the compaction forming process of anode paste were performed. Simulation results show that the constitutive law predicts the experimental trends and gives interesting physical responses. This constitutes a first step toward making a benchmark with experimental results on the forming process of anode paste.

Jan 1, 2011

By C. Gravel, A. Fathi, P. Rivard, G. Ballivy, Z. Moradian, M. Quirion

Knowing shear mechanism of discontinuities under monotonic and cyclic loading conditions is a key factor in stability analysis of rock slopes and rock foundations. In this paper, the effect of cyclic loads on the shear mechanism of joint asperities is described. For this purpose, a fresh tension-split joint from a granite block was used as a reference and thirty five mortar replicas were fabricated. Cyclic shear tests were conducted on replicas under low values of constant normal load (CNL) using a servo-controlled loading system. Tests were performed in two consecutive steps; load-controlled and then displacementcontrolled. In the load controlled part, after initial increase of shear stress to 0.25 MPa, the test was stopped for 2 minutes, then increased to 0.5 MPa, and finally decreased to 0.25 MPa. This process was repeated ten times. At the end, the test was continued up to 10 mm shear displacement under displacement-controlled loading in order to pass the peak shear strength and reach the residual strength. Characterizing joint surface and modeling of involved asperities during the tests was undertaken using a Matlab code developed with new mathematical expressions. The algorithm used in the code is based on three-dimensional coordinates of the scanned joints’ surfaces before and after the test. It was found that a high percentage of degradation happens during the first cycle of loading and during the other cycles, degradation occurs gradually. While comparing tests conducted in monotonic and cyclic loading conditions, it was observed that under low number of cycles, the pronounced mechanism is consolidation of the joint surfaces. This consolidation increases contact areas and, therefore, shear strength parameters.

Jan 1, 2015

By D. M. Aloi

In today's evolving and globalized world, mining companies are being pressured to move beyond compliance towards long-term sustainability and sustainable development. Companies are expected to "engage" with communities and measure the success of these engagements without a clear understanding of "how" to do this. This move, away from "Corporate" Social Responsibility (CSR) and compliance, develops more of a focus on "Community" Social Responsibility and sustainability. This shift in focus leads to the development of world-class projects that provide sustainable development for people, reduces the incidence of costly delays, and promotes good global citizenship for corporations. The process of "engaging" communities in mining project design and development leads to a stronger license to operate and sustainable development. To create this mutually beneficial relationship between communities and companies, communities must be "engaged" in the mining process as early as possible, preferably during the exploration or the concept phases. How to create this "engagement" remains elusive. How to measure the progress of this engagement is also problematic. The quantitative and qualitative metrics needed to measure both positive and negative impacts of the mining and community relationship will be discussed.

Jan 1, 2007

CSIRO Minerals, in association with the AJ Parker CRC for Hydrometallurgy, has an active program of hydrometallurgical research in which physical and computational modelling are used to better understand and improve a range of different unit operations. The modelling is based on flow simulation (Computational Fluid Dynamics or CFD), but incorporates other physical and chemical phenomena of importance, such as droplet break-up and coalescence, species transport and reaction. This paper reviews some of the major projects that have been undertaken at CSIRO Minerals and will illustrate the critical importance of hydrodynamics to the performance of unit operations and the improvements that can be made to performance using such modelling techniques. Unit operations that are discussed include solvent-extraction, gravity thickeners, flotation cells, bio-heap leaching and stirred tanks.

Jan 1, 2005

By Q. Han, W. Dai

Al-Ti-B type master alloys have been widely used in the grain refinement of aluminum since 1940s. The introduction of Al3Ti and TiB2(AlB2) particles reduces the grain sizes down to about 200 micrometer level and makes cold work possible. However, the mechanism for the grain refinement is still not clear, though it is believed that TiB2 in the presence of Al3Ti nucleate a-Al grains in solidification. This paper presents our finding on the formation of (Ti,Al)B2 solid solution, which leads to a proposed theory on grain refinement by Al-Ti-B type master alloys that upon addition into aluminum melt stable TiB2 particles react with aluminum slowly and release titanium into the melt. The titanium thus released in combination with titanium in the melt through dissolution of Al3Ti maintains a transient titanium-rich layer on the surface of (Ti,Al)B2. This layer offers a low crystal mismatch with a- Al and promotes the nucleation of aluminum grains.

Jan 1, 2014

By S. Joshi, E. Asselin

An electrochemical quartz crystal microbalance (EQCM) was used to study the leaching of pure gold in deaerated 1 M Na2S solution. Multiple cyclic voltammograms were measured between -0.76 and 1.242 V (SHE) at 20 mV/sec and 2 mV/sec and the frequency shift of the quartz crystal was simultaneously measured. Both the forward and reverse scans showed oxidation occurred between -0.40 to 0.20V. The frequency shift increased during both the forward and reverse scans in the potential range of -0.40 to -0.06 V indicating electrode mass decreased. Since at -0.40 to 0.20 V oxidation peaks were also observed, part of the oxidation was due to oxidation of gold. Eh-pH diagrams were constructed and showed soluble Au(I)-S(IV) species formed between -0.30 and 0.10 V (SHE). Atomic absorption spectroscopy of the test solutions and the mass change recorded by EQCM both showed about 0.015 mg of gold leached. Since the majority of the frequency shift increase corresponding to gold oxidation occurred at -0.40 to -0.06 V during multiple cyclic voltammogram measurement, the total leaching of gold could be approximated to occur at this potential interval to give a leaching rate of ca. 6.4x10-5 mg/s-cm2.

Jan 1, 2011

By R. Heikkilä

Fluent information exchange between different work phases, software and systems used in infra construction is a key for successful execution of infra construction projects. Open and publicly available information formats with the determined data models aim to facilitate the interoperability between different software and systems developed by competitive vendors. While building and construction industry has developed and used IFC format for years, infrastructure sector has just recently started to target clear efforts on the development of open information formats for infra construction processes. In the paper, a new Inframodel3 extension just developed in Finland and based on the LandXML1.2 international standard is to be introduced. The aim of the Inframodel3 was set to meet the requirements of information transfer needed especially between BIM based design software, measurement systems and 3-D machine control systems used in road, railway and watercourse construction projects. Some test results are reported and evaluated in the paper. In the field of bridge engineering, the IFC format and IFC Bridge extension have been tested and evaluated in Finland. The results from the experiments show and verify as well the applicability of these open formats to the information exchange requirements in bridge engineering. The current limits for open information transfer of these formats are shown. The active co-operation with the International Building SMART Organization has led to the achieved status and position for both the Inframodel3 and IFC Bridge formats and hence the continuing international support provided by Building SMART.

Aug 1, 2013

The Buzwagi Project is owned by Barrick Gold Corporation and located in the Lake Victoria Goldfields of central Tanzania in the District of Kahama in the Region of Shinyanga. The property is 6 km Southeast of the town of Kahama, 3 km South and adjacent to the road between Nzega and Burundi. The Buzwagi property is 97 km South of Barrick?s Bulyanhulu Mine. There is access to the rail line which connects from Isaka to the Indian Ocean coastal ports of Dares Salaam and Tanga. The Feasibility Study and permitting were started in early 2006. Project Execution commenced in August 2007. Process Plant commissioning started in January 2009 and the first gold pour is scheduled for Q2 2009. The reserve has been established as 3.3M oz of gold plus 177M lbs of copper. The project has been developed to include a 30Mtpa Open Pit Mine and 4.4 Mtpa Process Plant. Over an expected 15 year mine life, Buzwagi is anticipated to produce approximately 3.02M oz of gold and 220,000 tonnes of copper concentrate. Infrastructure associated with the project includes a 107 km 220kV power line, site accommodation, water harvest and extensive security facilities. The project is expected to be built on budget and on time during a period of extreme market volatility. This paper reviews the initiatives taken to achieve community support, control cost escalation, maintain schedule and manage logistic challenges, plus ensure security and safety of all workers.

May 1, 2009

By D. Stone, N. J. Aslin, W. Webb

In today's modem copper electro-refineries, increasingly higher average current densities are being employed. With these increases many refineries are approaching their limiting current density. The nearness of the average operating current density to the limiting current density has placed increasing emphasis on the need to maintain an even current distribution. This paper explores the importance of maintaining even current density and discusses the factors, processes and practices that are necessary to achieve and maintain high quality production at high operational intensity.

Jan 1, 2005

By M. A. Tomlinson, A. Di Feo, T. C. Cheng

"Goldcorp is evaluating the potential for economic reprocessing of historic tailings at several sites, including the Aunor A facility located in Timmins. The overall project is investigating the ability to recover value, remove sulphide minerals and alternative tailings re-deposition strategies. Desulphurization of tailings will eliminate potential acid generation while improved tailings re-deposition could reduce long-term liabilities and closure costs. Through a task-share project between CanmetMINING and Goldcorp, tailings obtained from Aunor A site have been characterized using mineral association analysis and diagnostic separation techniques. The selected tailing samples contain about 2 g/t of gold. Mineralogical analysis has identified coarse agglomerates bound with gypsum and significant free gold, confirmed by high recoveries in cyanide leach tests. However, despite no evidence of surface passivation on the minerals, conventional flotation techniques were found to be ineffective in concentrating gold or sulphides due to the high fines content and highly agglomerated particles.INTRODUCTION Aunor Mine is one of the historic mines that belongs to Porcupine Gold Mines (PGM) in Timmins, Ontario. PGM has undertaken an extensive mine closure program to remediate the legacy and closed mines with the funding supported by operating mines since 2006. Over the course of 100 years of operation in the Porcupine camp, it is estimated (Stevens et al., 2013) that about 130 million tonnes of tailings have been generated. Aunor Mine produced 2.5 million troy ounces of gold between 1940 and 1984, while processing over 7.6 million tons of ore. The original gold grade of Aunor Mine ores was about 10 g/t. With 95% gold recovery at the time, an estimate of 0.5 g/t of gold remains in the Aunor Mine tailings. Aunor Mine has two tailings impoundment areas: designated as Aunor A and Aunor B. The two sites are similar in size, about 7 hectares each. The amount of tailings in the Aunor A site alone is about 3.2 million tonnes. In 2017, bulk tailings were sampled from five designated locations in Aunor A. They were characterized using mineral association analysis and diagnostic separation techniques. The bulk tailings samples contained about 10% total sulphur, 10% iron, 2% arsenic and 2 g/t of gold. The prime objective of this collaborative work between CanmetMINING and Goldcorp is to facilitate the timely development and deployment of innovative tailings reprocessing solutions, specifically in the areas of desulphurization, and recovery of metals. This work targeted specific tailings of interest to Goldcorp which goals are to improve its environmental footprint and to reduce long-term liability. Thus, it is imperative to look for innovative reprocessing options that can overcome not only technological challenges but also achieve economic benefits to offset the costs associated with reprocessing the tailings. Moreover, the greater goal is to demonstrate and deploy tailings reprocessing solutions to solve one of the industry’s most difficult challenges for a sustainable mining industry in Canada."

Jan 1, 2019

By R. C. Gilmore, J. F. Brune

"Pulverized limestone rock dust used in United States underground coal mines to prevent and suppress coal dust explosions must easily disperse by forces of a methane or coal dust explosion. Moisture in the mine environment causes caking of the dust. Colorado School of Mines researchers performed dispersibility tests in a full-size explosion test drift. Tests included conventional, hydrophobized, and rock dust approved for German mines. Conventional and German standard rock dust products partially agglomerate, which may not be effective in suppressing a coal dust explosion, while hydrophobic rock dust retains better dispersibility.INTRODUCTIONA coal dust explosion devastated the Upper Big Branch mine in 2010 resulting in the death of 29 miners, the worst mining accident in the United States since 1972. The explosion propagated through approximately 65 km of active mine workings, but was extinguished in areas that had been properly rock dusted (Page, 2011). Researchers have long studied and established the ability of inert limestone rock dust to suppress coal dust explosions, see Richmond et al. (1975), Cybulski (1975), and Sapko et al. (2000).To be effective, rock dust must contribute to a total inert content of > 80% by weight and 100% of rock dust particles must pass through an 850 µm sieve, while 70% of the rock dust must be finer than 74 µm. This is established in US regulations 30 CFR §75.2. Dry rock dust is a nuisance that prevents mining work downwind from rock dusting activities. To overcome this problem, dust manufacturers have proposed applying the rock dust as a wet slurry or foam. After drying, manufacturers expected the slurry or foam-applied dust to have the same explosion suppression capabilities as dry-applied rock dust.Researchers at the Colorado School of Mines (CSM) designed and built a full-scale, underground Explosion Test Facility (ETF) at the CSM Edgar Experimental Mine in Idaho Springs, Colorado about 20 miles west of the CSM Golden, Colorado campus. To disperse the different rock dust products, researchers produced an air pressure pulse using a mesh array of PETN detonation cord. This method is simpler, more reproducible and safer than other methods considered, including methane-air explosions and a compressed air cannon. The detonation cord blasts produce a wind velocity of 30 to 50 m/s, the minimum velocity at which coal dust explosions can propagate, based on research by Nagy (1981) and Cybulski (1975)."

Jan 1, 2019