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By J. Gebhardt, D. McBride, C. R. Bennett, Croft. N., M. Cross

A comprehensive model of solution flow through heap leach systems requires a numerical solution with the ability to predict variably saturated-unsaturated flow through porous media domains that contain materials with spatially variable properties. The types of flow associated with stockpile leach processes lead to flow problems, such as infiltration into dry soil, drainage, perched water tables and flow through heterogeneous materials. Computational methods for modelling this class of flow behaviour are conventionally based on the classical Richards' equation. However, the governing equations are highly non-linear, difficult to solve, and require iterative numerical solution methods. The pressure-based form of the Richards' equation suffers from poor mass balance, while the mixed form can possess convergence difficulties. An adaptive transformed mixed algorithm is described, which reduces the non-linearity of the problem, optimizes the time step size, and provides a fast, numerically robust scheme that significantly reduces computation (or CPU) time. This method is shown to give fast, accurate solutions on a number of complex flow problems. The utility of this algorithm is illustrated through its implementation within the PHYSICA computational modelling software, which incidentally, provides a framework for a comprehensive heap leach model.

Jan 1, 2005

Real time analysis of ore quality between the mine and mill provides major benefits to copper mining and processing operations. Prompt gamma neutron activation analysis (PGNAA) is a proven technique that has been successfully applied for real time conveyed flow multi-elemental measurement. The advantage of PGNAA is that it measures through the full conveyed cross section continuously and provides representative element measurement without the need to constantly sample coarse (primary crushed) conveyed flows. High specification PGNAA analyzers enable accurate measurement over time increments as short as thirty seconds. Elements such as copper can be measured to a precision of 0.02% copper which is sufficient for high confidence in decisions for bulk flow diversion. Increments of eight tonnes are being diverted through a bulk ore sorting application to remove batches of waste from mill feed as well as divert material to different stockpiles based on ore quality. Longer measurement increments of two to five minutes are suitable for blending control of ores to reduce feed quality variability and to control average ore quality within a target range. Feed blends can be adjusted as frequently as required but typically multiple measurement increments are composited to produce a rolling average ore quality. The paper details two case studies where analyzers have been successfully used to measure conveyed flows for blending and bulk diversion applications. The real time measurements of ore composition are also used for ore reconciliation, in metal accounting and providing process operators with advance warning of ore quality changes that may affect grinding performance and cause process upsets. Real time ore quality measurement has proven beneficial in improving copper processing performance through better utilising plant capacity in a leaching operation, optimising ore feed quality, and reducing unnecessary processing of waste. INTRODUCTION Representative real time elemental analysis of conveyed ore quality using fully penetrative technologies has been available to the minerals industry since the 1990s. The Prompt Gamma Neutron Activation Analysis (PGNAA) technique was developed into a conveyed material analyser and soon adopted by the cement and coal industries which recognised the benefits in real time quality management. These commodities were ideally suited to this measurement technique as operations generally involved conveying bulk material prior to processing. Measured quality was used to divert material to different destinations or used to control blending for improved quality consistency. Uptake in the minerals industry, however, has been slow until the last ten years, and particularly until the mid-2010s.

Jan 1, 2019

By H. Karakul

Determination of P-wave velocity (Vp), which is closely related to intact rock, is a nondestructive, easy and less complicated procedure. Due to these advantages, there is an increasing trend to predict the geomechanical properties of rocks from Vp. In addition to mineral content, cementing material and porosity, degree of saturation (Sr) are also other factors influencing geomechanical properties of the intact rock. However, up to the present, in the studies on the prediction of geomechanical properties of rocks from Vp, the effect of Sr has not been investigated. By considering this issue, in this study, it was aimed to correlate strength properties (uniaxial compressive and tensile strengths) and Young’s modulus with Vp of various rock types under different degrees of saturation. In addition, geomechanical properties of rocks were estimated from theoretical P- and S-wave (Vs) velocities, which were calculated based on their mineralogical compositions. For this purpose, fourteen different rock types were collected from several parts of Turkey and a comprehensive laboratory testing program was conducted. In the statistical analyzes, a series of different prediction relationships were developed by using independent variables such as Vp, Sr and effective clay content (ECC). Simple regression analysis results indicated that although prediction of the geomechanical properties of rocks from Vp at different degrees of saturation was possible, the equations developed would yield some under- or over-predictions. On the other hand, the multivariate equations developed have very high prediction performances and are very useful tools to estimate the geomechanical properties from the measured Vp at any Sr value. In addition to mineralogy, the variation in geomechanical properties with increasing Sr is also associated with the combined effect of porosity and clay content, which is first described in this study by the term Effective Clay Content (ECC). It is also noted that strength properties of rocks at any Sr may also be estimated using the empirical relations based on the theoretical Vp and shear-wave velocity (Vs) values, which are calculated from their mineralogical compositions.

Jan 1, 2015

By W. Abdellah

Underground mine developments, such as haulage drifts and cross cuts, play a vital role in providing access to ore extraction areas for mine production. The stability of mine developments is thus of crucial importance during the life of a mine plan. Many Canadian mines use longhole mining methods or one of its variants. These methods require access to the orebody through mine developments such as haulage drifts and cross cuts on multiple levels. This paper examines the stability of mine development access intersections with respect to the planned mining sequence. A case study, the #1 Shear East orebody at Vale?s Garson Mine in Sudbury, Ontario, is presented. A three-dimensional, elastoplastic, finite difference model (FLAC 3D) was created for a development intersection situated 1.5 km below ground surface. The stability, or performance of the intersection, is evaluated in terms of the strength-to-stress ratio. The ratio threshold is set at 1.4 for temporary openings. Unsatisfactory performance is defined as a strength-to-stress ratio less than this threshold value. The performance of the intersection stability is evaluated at various modelled mining stages and the probabilistic method of analysis is then invoked to study the probability of unsatisfactory performance of the intersection. The results are presented and categorized with respect to probability, instability, and mining stage.

Aug 1, 2013

By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

By Dalton Fowler

"Pressure vessels used in pressure leaching and pressure oxidation processes in the mining industry are often lined with acid resistant brick and membrane systems. Although the options available when it comes to selecting materials and linings designs for these vessels appear somewhat limited there are, nevertheless? several choices which must be made in order to successfully design, manufacture and construct these linings. These choices require careful evaluation of materials properties which include, among others, thermal conductivity, thermal expansion, chemical swell, and modulus of elasticity, as well as a variety of construction methods.Some of the options available, and some of the means of evaluating them objective of this discussion."

Jan 1, 1999

By Gulshan Kumar Pradhan, Yogendra Pratap Singh, Dhawanm Nikhil

"Potassium (K) is one of the essential elements for the growth of plants and thereby for humans. In fertilizers, potash demand has been steadily increasing at ~3.5% annually. Water soluble potash deposits are rare and highly localized. India is neither present on the world potash production map nor it has adequate potash rich rocks. The K-bearing minerals are recovered either by using conventional underground mining methods or though solution mining methods. India possesses a vast resource of silicate rocks such as glauconitic sandstone and Feldspar. These rocks are basically a group of alumino silicate of potassium, sodium and calcium (K2O%: 5-12, Na2O%: 3-10%, SiO2%: 52-65, Al2O3%: 15-20, Fe2O3%:, 5-7 and MgO%: 2-3.5).The K extraction from silicate rocks has received little attention probably due to the slow release, the locked structure of alumina-silicate minerals, and the unavailability of appropriate economic processes & their know-how. In fact due to this India imports all of its potash demand (about 3.5 million tons per annum) from different countries.In the present work, an attempt has been made to identify the structural and chemical alteration of desired K mineral phase in silicate rock (~K2O%: 10.5, Na2O%: 2%, SiO2%: 55, Al2O3%: 19, Fe2O3%, 5-6, MgO%: 2.5) under different conditions such as acid leaching, thermal treatment and chemical processing. Different treatments are aimed to increase K availability which is related to the modifications in mineralogical composition. The modifications in the feed sample and treated samples are studied through SEM-EDAX, XRD, EPMA and optical microscope. With the combination of treatments, it is possible to extract more than 90% K and the formation of sylvite phase (water soluble) confirms the dissolution of potash values."

Jan 1, 2016

By L. Veleva, Garcia. A., G. Perez

Aluminum is a metal used for the transmission of electricity of high voltage, in the construction industry and other areas. In atmospheric conditions aluminum forms an oxide layer (Alz03'H20) as a result of its corrosion, entering the passive state. The oxide layer can be destroyed by the presence of ions (Cr, SOx-n) developing localized (non uniform) corrosion attack by pitting, difficult for evaluation. The concepts of fractals and self-similarity were used in this study for the characterization of the development of localized corrosion. Images obtained with a scanning electron microscope (SEM) of samples of electrolytic aluminum wire that have been exposed during one year in ruralurban and marine-coastal environments of the humid tropical climate of Mexico, have been processed. The development of pitting has been studied as a function of time, making a statistics of the frequency of appearance of pits versus the area occupied by them. The data show that the distribution of the pits follows a power law. Therefore, the concept of self-similarity can be applied for the study of the phenomenon of localized corrosion, describing their development with time.

Jan 1, 2006

By G. R. Webber, L. M. Azzaria

"The wide interest in the application of the geochemistry of mercury to mineral exploration is leading to the continued development of a variety of analytical methods for the determination of nanogram quantities of this element. The various methods have different degrees of reliability, sophistication and portability. In this investigation, two simple portable instruments were used in geochemical prospecting surveys -an ultra-violet absorption instrument and a similar one modified with gold for the removal of interfering substances. The results show the application of the method to the determination of mercury in soils of different organic content, and in rocks, sulphides and air."

Jan 1, 1969

By The Hollinger Mill Staff

ALTHOUGH cylindrical grinding mills have long been used, there is wide divergence of opinion as to what constitute best operating conditions. Questions such as mill diameter, diameter-length ratio, revolutions per minute, type and size of grinding media, volume of charge, circulating load, pulp level, pulp consistency, liner design, and size of feed, have all been given serious consideration by competent scientific investigators as well as by operators. While many laboratory and plant tests have been made that would seem to justify certain definite conclusions, there is a dearth of definite data giving actual results obtained when a grinding mill working between fixed limits is operated at its maximum capacity under varying conditions as to ball load, circulating load, speed, etc. In tests conducted recently at the Hollinger, extending over a period of thirteen months, to determine the best operating conditions for a ball-mill 6 ft. 6 in. diameter inside the liners, some very interesting facts have been ascertained. This paper is presented in the desire to make public the results of these tests and not with the idea that the last word has been spoken in regard to grinding. We feel, however, that these facts justify certain definite conclusions and hope that, by the fullest and frankest criticism and discussion, the essentials necessary for the correct design and operation of grinding mills will become better known.

Jan 1, 1937

By John G. McCamis

The Maritimes Carboniferous Basin is the largest intermontane basin in the Appalachian Mountain System, occupying a total area of 57,200 square miles and containing up to 30,000 feet of late Devonian through Permian .sediments. Deposition began with continental elastics in late Devonian and early Mississippian. Marine deposition is represented by a limestone-evaporite sequence of late Mississippian age. Pennsylvanian and Permian continental rocks deposited largely in flood-plain and swamp environments complete the succession. Marine seismic data disclose several varieties of structure, both halokinetic and tectonic in origin. Recent exploratory drilling in the offshore part of the Basin encountered good reservoir rocks in the Riversdale sandstones, which also provided encouraging shows. The most likely source rocks of hydro~ arbons in the Maritimes Basin are shales in the Horton and Riversdale groups. Potential recoverable reserves of the Maritimes Basin are estimated to be 400 million barrels of oil or 7.8 trillion cubic feet of gas, based on the volume-of-sediment method of calculation.

Jan 1, 1973

By M. E. Holuszko

Although there is no widely accepted rigorous definition of handleability, the handling coal characteristics often referred to as handleability define whether a coal has the ability to flow unhindered through the processing and transportation systems. The handleability may be severely affected if fine coal particles tend to aggregate. In the pelletization process, the rolling action of the drum is applied to bring the individual particles into proximity with each other so that they can aggregate and form pellets. Because of apparent similarities between these two processes, the pelletization tests are carried out in parallel to the handleability tests in this project, and the pelletization results are used to explain coal handleability properties.

Jan 1, 2004

By Thomas Clark

This report presents a review of the distribution and exploration potential of platinum-group elements (PGE) in Québec; it is based on published and unpublished analytical data. This qualitative evaluation of the PGE potential, whether in PGE-dominant deposits or in Ni-Cu-dominant deposits with co-product PGE, is based on interelement ratios such as Ni/Pd, Cu/Ir, Cu/Pt, and Cu/Pd. Good PGE targets, i.e., deposits associated with magmas fertile in PGE, are identified. Less favorable PGE targets, i.e., deposits associated with PGE-depleted magmas, are also mentioned. The importance of exploring for deposits similar to those at lac des Îles and East Bull Lake (Ontario) is emphasized.

May 1, 2001

By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

Numerous data in the literature confirm that the chemical composition and consumption of grinding media influence electrochemical properties of flotation suspension as well as effectiveness and selectivity of upgrading processes. During a milling process, attrition of grinding media is observed. Depending on the susceptibility to abrasion, the grinding media influence, to a different extent, the redox potential, pH as well as flotation efficiency. As a result, different upgradeability of sulfide minerals is observed. The paper presents laboratory scale flotation results, obtained for the copper sulfide ore from Polkowice Region of KGHM Polska Miedz S.A. in Poland ground in the presence of forged steel, highchrome iron and stainless steel as the grinding media. The investigated flotation feed contained 36 g/t (ppm) of silver and 1.86 % of copper. Several flotation tests were conducted using fixed amount of frother and a mixture of sodium ethyl and isobutyl xanthates as the collector at three different doses of 75, 100 and 125 g/t. A comparison of the obtained results confirmed that the application of grinding media with different chemical compositions influenced the electrochemical properties of the suspension and recovery of silver and copper in the final concentrate. The highest values of redox potential were observed for the stainless steel as the grinding medium. Moreover, in the presence of this type of grinding media, regardless of the collector dosage, the best silver upgrading was observed. For the forged and high-chrome iron media, the recovery of silver depended on the collector dosage. It is indicated that higher levels of the redox potential, together with smaller amount of iron released from the grinding medium, improve the flotation of the silver-bearing mineral compounds from the copper sulfide ore.

Jan 1, 2016

By Michael Davies

Mined Material Management Meeting or Missing the Mark? o you agree that we have the technology to consistently design robust M3 facilities? ?YES your experience do these M3 facilities perform as expected during operations? ?USUALLY hat can be done to improve performance, e.g. better communications between project and operating teams, discontinuity between design and operational input by designers, others? ?UNDERSTANDINGWHY THINGS GO WRONG an we identify the key characteristics of ?good M3 facilities?, i.e. ones that are performing well? Can we identify ?good M3 facilities?, i.e. ones that perform well and can be held up as examples? ?WITHOUT QUESTION?? your opinion, for what reason do they not perform as expected? ?NO SINGLE REASON??..

May 1, 2010

By Jorge M. C. Soares

The CO oxidation reaction has been studied on Au/TiO2 catalysts prepared by incipient wetness (IW) and deposition-precipitation (DP) methods. Additionally the assessment of activity was also conducted on simple gold compounds (Au2O3 and Au(OH)3) and their physical mixtures with TiO2. We have found that there are three types of CO2 production from fresh catalysts, which are only dried, namely: Non-catalytic Type I (low temperature CO2 production); Non-catalytic Type II (higher temperature CO2 production) and Catalytic Type III. The DP catalysts are far more active for Type III reaction, showing activity already at room temperature, whereas the IW catalysts generally do not show steady state conversion until T>673 K. This is due to both large particle size and the presence of residual chlorine for the latter. No truly catalytic activity was found for low temperature CO oxidation on gold precursors on their own, although both Au2O3 and Au(OH)3 react well with CO even at room temperature in an irreversible manner (Type I reaction). Despite that, catalytic activity was obtained by mixing Au(OH)3 or Au2O3 with TiO2 which gives further emphasis on the importance of a good contact gold/support and the absence of chlorine.

Oct 1, 2003

By Rodolfo Zanella

Au/TiO2 catalysts prepared by deposition-precipitation with NaOH (DPN) (~3 wt%) and urea (DPU) (~8 wt%) were tested in crotonaldehyde hydrogenation at atmospheric pressure. There is no differences in activity (mole.gAu -1 s-1) and selectivity between both DPU and DPN samples for a given activation treatment. This is due to the fact that DPU and DPN samples exhibit similar gold particle size distribution, although the gold loading in DPU is much higher that in DPN. The DPU samples were reduced under H2 at different temperatures (120-500 °C) or under air at 300 °C with various flow rates, to vary the average particle size within a large range, 1.7 to 8.7 nm. The selectivity to crotyl alcohol (selective hydrogenation of the carbonyl bond) is high, 60-70 %, and almost constant as a function of the particle size. The selectivity to crotyl alcohol is also constant for conversions between 10 and 50%. These results suggest that the adsorption mode of crotonaldehyde is of ?3 or ?4-type. In contrast, the TOF depends on the gold particle size, it drastically increases when the gold particle size is ~2 nm. Our results are in agreement with former studies that suggest that the gold atoms involved in the hydrogenation process are those of low coordination.

Oct 1, 2003

In the present work, the effect of pH, non-ionic polyacrylamide flocculant and anionic polyphosphate on rheology and settling behaviour of colloidal TiO2 suspensions (15 ? 50 wt% solid) is investigated. Maximum particle aggregation, reflecting in the highest suspension settling rate and maximum shear yield stress was achieved at pH 7.2, the isoelectric point (iep), consistent with DLVO expectation. However, the maximum aggregation condition at the iep also resulted in the poorest suspension consolidation behaviour. Significantly enhanced consolidation was achieved for a more dispersed suspension at pH values away from the iep but at reduced settling rate. Thus, when pH alone is used to control conditions which facilitate strong interparticle attraction, a high settling behaviour which is not conducive to compact consolidation results. Improved suspension consolidation may be achieved at the iep via anionic polyphosphate addition which leads to attenuation of the strongly attractive van der Waals forces and emergence of "soft" repulsion due to weak inter-particle electro-steric forces. The weak repulsion act to lubricate particles involved in the hydrodynamic interactions which controls the compressibility of the sediment bed, allowing a compact consolidation of solids to be obtained. Alternatively, non-ionic polyacrylamide homo-polymer (Magnafloc 333) was fairly effective in flocculating titanium dioxide suspensions leading to high settling rate and acceptable pulp consolidation at the iep.

Jan 1, 2006

By Clifford S. Gibson

THESE troubled times suggest three reasons for maximum effort to control silicosis: (1) To keep to a minimum the ever-increasing burden occasioned by past deficiencies in this respect. (2) To effect the greatest production with maximum efficiency, which means at the least cost. (3) To preserve man-power in every way. Good control of the silicosis problem aids these aims. Inadequate control hampers all three. Insofar as our knowledge goes, silicosis in Ontario mines is caused by the inhalation of finely particulate quartz. It follows, therefore, that removal of dust containing this mineral automatically erases the cause. The achievement of this ideal is the aim of the mine operator. His best tool to this end is ventilation. This paper discusses mine ventilation from the viewpoint of dust control and it is hoped that in so doing there may result a better understanding of the part played by air in silicosis prevention. No attempt will be made to treat the subject fully. Instead, there will be presented certain salient aspects culled from field observations, the data in all cases referring to gold mines, unless mention to the contrary is made.

Jan 1, 1942

By S-E. Vandat

The goal of this work was to select an appropriate electrode for dummy load of diesel engine in fully salt-water in the DESA factory. The electrochemical corrosion rate of general structural steel, commercial pure aluminum and cathode copper calculated as weighting, volumetric and commercial in fully salt-water by city power. After several tests and then applying the fuzzy logic method, it was determined that general structural steel is the best selection for this purpose.

Jan 1, 2005