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By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

Pillars are used in various forms in underground mining. For several decades pillar design has been an issue in both soft and hard rock underground mining. The major use of pillars is in room-and-pillar type mining. Pillars are critical structures in the production levels of block cave mines. With most mines leaning towards the use of block caving for ore extraction today, pillar design has become even more important. Empirical pillar design is popular. The use of numerical modeling is becoming more common in the design of underground mine pillars. A critical review of both the empirical and numerical modeling approaches to the design of underground mine pillars reveal some fundamental flaws. In general, pillar design approaches often assume the pillars are vertical, and are subjected to pure compression. Pillar failure criteria are then based on this assumption. Most papers on numerical modeling for pillar stability assessment use vertical pillars. This paper shows that where pillars are not subjected to pure compression the empirical pillar design approaches are inadequate, and that when using numerical models for the assessment of pillar performance, more care is needed in the determination of the average pillar stresses. The practice of relating field scale pillar strength to laboratory scale intact rock strength determined from conventional laboratory compression tests in empirical design equations is misleading when pillars are inclined or subjected to compressive and shear stresses. New data is added to the hard rock empirical pillar stability chart, and it is shown that it is misleading to conclude that failure of pillars with width to height ratios greater than 2.3 should not be anticipated. New empirical pillar design charts are presented for pillars at various degrees of inclination for different ko-ratios.

Aug 1, 2013

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By P. G. Hallof

The exploration staff of Campbell-Chibougamau Mines Limited has used past experience to delineate several areas of geologic interest under Lake. Chibougamau. Du• ring the winter of 1964-65, a reconnaissance induced polarization survey was carried out on the lake. First, several lines were surveyed over the known mu1.erahza-tion at the Henderson mine; the grid was then extended into the areas of interest. Several anomalous zones were located and drilled; one, of these proved to be of economic interest.

Jan 1, 1967

By Floyd Smith

Based on underground observations made in .the coal mines of the Dominion Coal Company Ltd., this paper deals with the stress phenomena in the approach roads and headways and in the gob areas associated with the longwall method of total extraction. The deformation of roadways during development and the deformation of roadways during the total extraction period is delineated and presented in graphical form .. Conclusions are made as to the feasibility of the introduction of the retreat method of longwall extraction in one of the colhenes. The importance of future studies are enumerated, especially. those pertaining to the determination .of the opti.m.um sizes of protective pillars and to increasing the efficiency of the current methods of artificial roadway support.

Jan 1, 1967

By Paul F. Grundy

The ever changing conditions in the coal-mining industry and the increasing competition of other fuels such as oil, natural gas, wood refuse, etc., have made it imperative that the coal operator be in a position to supply a constantly uniform and clean product. The old idea of putting on the market "anything so long as it's black" no longer holds good. Today's users of fuel have to consider the amount of heat per dollar they obtain from the fuel they buy. Burning of coal has become largely mechanical, at least so far as industrial coal is concerned, and industrial coal is the kind the bituminous operator is for the most part called upon to supply. When we get into things mechanical, the matter of precision has a mighty bearing on efficiency. Precision in coal means standardization of quality, or uniformity of preparation in size and also in ash and moisture content. The trend of coal mining is ever towards more and more mechanization. Mechanization means coal-cutting machinery, loading machinery, conveying machinery, etc. Although such methods cut the cost, the cleanliness of coal so mined and loaded is not controllable to the same extent as when each operation is by hand labour. The operator has therefore the problem of mining his coal as cheaply as possible, but at the same time preparing a product which will to the utmost satisfy his customer. The answer is a mechanical cleaning plant. Before installing a cleaning plant, however, the operator must take into consideration the cleansability of the coal from his particular mine. This is accomplished by taking representative samples of the seam or seams to be treated, and subjecting these to screen tests, followed by float and sink tests on each size product. From these tests, it can be readily found to what degree of cleanliness the several sizes can be prepared advantageously, and also what will be the percentage recovery of cleaned coal. The accompanying tables give the results of representative tests on Michel coals of minus-2-inch size. All coal over 2-inc.h was intended to be hand cleaned. The coal-cleaning plants in general use at the present time come under two broad classifications, namely, wet and dry.

Jan 1, 1934

By J. Nalaskowski

A study of the interfacial properties of the basal plane and the edge surfaces of talc is described in this paper. The isoelectric point measured at the two different crystallographic planes by the streaming potential method was found to be similar and exists at about pH 3.0. In the case of the edge surface the zeta potential increases at higher pH values which can be attributed to the hydration of magnesium ions at the edge surface. The atomic force microscopy (AFM) colloidal probe technique was used to measure interaction forces. For such experiments a 20 um talc particle was attached to the AFM cantilever and forces between the edge of the talc particle and two different crystallographic planes of talc were measured at various pH values. These measurements, while being qualitative due to the poorly characterized contact area, show differences between the properties of the base plane and edge of the talc and correspond to the results from streaming potential measurements. Finally, the differences in the hydration of the basal plane and the edge of talc are revealed from molecular dynamics (MD) simulations. The basal plane of the talc is much less hydrated than the edge, as can be seen from the water density distribution functions, which correlate quite well with the contact angle measurements at the basal plane surface and the edge surface of the talc sample.

Jan 1, 2006

By Rick Coleman, Chelvan (Chevy) Veloo

"P.T. Freeport Indonesia's lrian Jaya Operation has been producing copper concentrate continuously since 1972. Numerous ore discoveries and five mill expansion programs have seen the initial milling rate of 7,200 MTPD escalate to the present rate of 125,000 MTPD, producing 2.5 million pounds of copper and 3,500 troy ounces of gold per day. The latest expansion, commissioned in February 1995, incorporates a 34 foot Semi- Autogenous Grinding (SAG) Mill, two 20'x30' Ball Mills, conventional roughing, cleaner column flotation, and attendant upgrades to the existing concentrate pumping and dewatering facilities. This paper will describe the SAG Plant flowsheet, and focus on the key training issues which contributed to a successful plant start-up.IntroductionP.T. Freeport Indonesia's operations in the Ertsberg mining district are located in the Jayawijaya Mountains of Irian Jaya, the easternmost province of the Republic of Indonesia. P.T. Freeport Indonesia (PTFI), the operator, is owned by Freeport MacMoRan Copper and Gold (81.3%), the Government of Indonesia (9.4%), and private Indonesian investors (9.4%). Geographical location, and sailing distances are provided on the attached location map.The operation stretches over 7 4 miles ( 114 km) from the dewatering and concentrate shipping facility at the Port of Amamapare on the Arafura Sea to the Grasberg open pit located at 3400m. The regional geology is covered in detail by Van Nort et al (1991 ), with current proven and probable reserves estimated at 1.13 billion metric tonnes grading 1.30% Copper, 1.42 ppm Gold, and 4.06 ppm Silver. The Grasberg open pit mining operation provides 92% of the mill feed, and is described in detail by Hickson (1991). The remainder of the mill feed is derived from several underground block caving operations. Current production rates provide a mine life in excess of 25 years. However, very favorable geology in the area leads to expectations that additional reserves will extend the life of the operation considerably."

Jan 1, 1996

By T. E. Morimoto

Summary The Research Council of Alberta has made a series of tests with the cyclone washer to investigate the influence of the following operating variables: underflow apex diameter, .specific gravity of medium, pulp ratio, density distribution of the feed, and size analysis of the feed. The results obtained for all the variables studied, except size analysis of the feed, are included in this paper. The tests were made with smaller underflow apex diameters and lower specific gravity .suspensions than have been recommended by Cerchar for the sharpest separations. However, what is considered to be sufficiently good cleaning was accomplished with a suspension of 1.30 specific gravity and an underflow to overflow diameter ratio of 0.56. It was found that the sharpness of separation was not affected appreciably by variations in specific gravity of suspension or underflow apex diameter provided that the density of separation was within the normal range of washery operation. Cyclone performance was not too adversely affected by decreasing the pulp ratio. The minimum figure which gave reasonable separation was 4 to 1. The tests with various density distributions of feed revealed .that the degree of washing difficulty had no detrimental effect on the .sharpness of separation given by the cyclone. Introduction A major problem of the bituminous coal industry today is that of reducing the ash content of the finer sizes (minus 1/4-inch) of coal. This problem is particularly acute in Alberta, where, because of tectonic movement subsequent to deposition, the coals have been rendered friable, and bands of impurities have been intimately mixed with the clean material. As a consequence, most Alberta coals, as mined, contain a large proportion of fines and have a high inherent mineral-matter content. The advent of mechanized mining and stripping operations ?has further aggravated this problem.

Jan 1, 1952

By L. Tong, D. Robinson

"The stirred milling of nickel laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a netzsch™ lME4 stirred mill on siliceous goethitic, goethitic, and saprolitic nickel laterites. Tests on the -2,000 µm sample displayed the effects of selective comminution. The -38 µm product of grinding the -2,000/+38 µm feed confirmed the effects of selective grinding and nickel upgrading. Size classification followed by stirred milling is recommended for nickel upgrading. The energy requirement in the stirred milling was also investigated.RÉSUMÉ le broyage par billes de latérites comportant du nickel offre des possibilités d’amélioration de la libération et de la réduction sélective de la taille des minéraux nickélifères tendres dans les latérites. Des essais de broyage en vrac ont été effectués dans un broyeur à billes netzschMD lME4 sur des latérites nickélifères à goethite siliceuse, à goethite et saprolitiques. Des essais sur l’échantillon -2000 µm présentaient des effets d’une comminution sélective. le produit -38 µm de l’alimentation -2000/+38 µm confirme les effets d’un broyage sélectif et du rehaussement de la teneur en nickel. Pour améliorer la teneur en nickel, il est recommandé de classifier le minerai en fonction de sa granulométrie, puis d’effectuer un broyage à billes. l’énergie requise pour le broyage à billes a aussi été étudié."

Jan 1, 2015

By M. R. Khalesi, S. Bellec, C. Bazin, D. Hodouin

Batch grinding tests conducted on a gold ore indicated that gold is not randomly distributed within the size fractions of the ground ore. Since gold leaching performances were found to be dependent of the size of the gold carrying particles an integrated gold ore grinding-leaching simulator should incorporate a method to predict the gold size distribution of a ground ore. The paper describes the results obtained from batch grinding tests showing the non random distribution of gold within the size intervals of a ground ore and the initial developments of a grinding model to predict the gold size distribution in a batch grinding product.

Jan 1, 2011

By Raj Rajamani

In general, many past works examine mill load, mill power, shell lifter design etc with a view to improving the mill capacity. On the contrary, only a handful of papers have addressed the transport of fine slurry through the pulp lifters. We present the flow dynamics of pulp lifters via laboratory scale experiments, high speed photography and modeling with computational fluid dynamics. Next, the flow behaviour in ArcelorMittal?s Mont-Wright autogenous mill discharge flow is examined. In an effort to improve mill throughput, a comprehensive simulation and plant scale study of the mill was taken up with a focus on the shell and pulp lifter design. The shell lifter was found to be at its optimum limit for breakage of ore particles given the constraints of wear life and occupied volume. Next, the pulp lifter study was taken up with computational fluid flow code and discrete element code. The simulations directly showed that there was considerable carry-over of slurry. This effect was traced to the area restriction in the pulp lifter channels. Further, crash-stop studies confirmed slurry pooling within the mill. Thus it was readily apparent that mill throughput can be increased if the pulp-lifter could be redesigned. Consequently, the discharger section of the pulp-lifter was redesigned. First, this paper outlines the modeling in laboratory scale studies and plant scale studies leading up to the discharger design. Next, the discharge flow in seven different published mill surveys is predicted with computational fluid dynamics (CFD) methodology shown here. Finally, Mont-Wright mill circuit performance before and after the discharger redesign is described. The usefulness of fluid flow simulations in the design of pulp-lifters is emphasized.

Jan 1, 2012

By D. Berkley

Off-gas systems often become the limiting factor in production increase and environmental projects. Any upgrade or new off-gas project needs to address control instability issues, instabilities that can result in safety hazards, significant loss of system capacity and/or emissions to the environment [1]. In addition, the design engineer must optimize system configuration and equipment size for the new operating conditions, to have a technically feasible and economically viable project. Dynamic simulations can be used for addressing both the control stability and the design optimization issues. This paper illustrates how the dynamic simulation of transient processes and of their control system can be used in "real life" situations for these purposes, presenting the example of an electric furnace off-gas system design.

Jan 1, 2005

By B. Caldwell

"The CompanyCardinal River Coals is jointly owned by Luscar Ltd. and the Consolidated Coal Company of Canada (Consol). The Luscar mine is operated by Luscar Ltd. and is located 40 km south of Hinton near Cadomin, Alberta (Fig. 1). The plant sits on the old townsite of Luscar, Alberta, which was founded in order to develop the coal in 1912 (Fig. 2). Initially, the coal was mined by Luscar Ltd. for heating and steam generation and used quite heavily by the railways for their steam locomotives. In 1955, the mine was decommissioned as the demand for coal for tl1ese purposes had dropped off. In 1969, the mine was re-established by Cardinal River to provide metallurgical coking coal for its customers in Japan. The coal is mined from the 13m thick Jewel Seam by open pit methods at a 10 to 1 stripping ratio. The run-of-mine coal is then cleaned to meet customer demands.The PlantThe clean coal preparation facilities at Cardinal River were extended in 1980 in order to increase the feed rate from 450 t/h to 800 t/h. The extension is a separate plant which can be operated on its own or in parallel with the old plant. In addition, modifications have been made to the fine coal circuit (hydrocyclones added), the coarse refuse circuit, (refuse bucks replaced by a refuse conveyor which backfills a pit), and the fine refuse circuit (solid bowl refuse centrifuges, refuse classifying cyclones, and hydra-rake thickener no longer utilized) since the plant was built in 1969. The plant production of 3 M t per year with a yield of 78% is achieved by first screening and breaking the run-of-mine material to a top size of 1 ½ in. The feed is then slurried, sized, and processed in three different washing circuits. The washed coal is mechanically dewatered, thermally dried, and then stored in a 14 500 t capacity silo or on a 300 000 t stockpile. The fine refuse is thickened and pumped to the same pit to which the coarse refuse is being conveyed"

Jan 1, 2000

By E. Wright

"INTRODUCTIONThe Ruttan Mine is located twenty-two km east of Leaf Rapids in northwestern Manitoba. The copper-zinc exhalative massive sulphide deposit is comprised of a series of individual and interconnected en echelon lenses which strike east 20 degrees north and dip south 70 degrees. The mine has been owned and operated by the Hudson Bay Mining & Smelting Company since July 1987. Sherritt Gordon Mines Limited began mining the orebody in 1973 from an open pit, but production has been entirely from underground since 1980. HistoryDuring the progression from open pit to underground mining, it was recognized that manual methods of ore reserve calculation were inadequate for responding to changing metal prices and evaluating alternative mine plans. The mine planning system that was developed is described in the paper, ""Computerization of Ore Reserves and Mine Planning Functions at Ruttan Mine"", presented by B.C.W. Haystead at the 1984CIM Annual General Meeting. At that time, programs for core logging, diamond drill hole plotting, grade interpolation, ore outline digitizing, and reporting had been developed by the Systems Department for use on Sherritt's UNIVAC 1100 mainframe computer. Telecommunications linked terminals at the Ruttan coreshack and office to the UNIVAC in Fort Saskatchewan, Alberta. The same mine planning system was also used at a second property.Operation of the mine planning system was expensive, and it was evident that increased use required a costly upgrading of the UNIVAC in order to maintain an acceptable service level to all users. The system was re-evaluated,' and it was concluded that: core logging was not easily adaptable to a new property, nor flexible enough for exploration; plotting, grade interpolation, and digitizing required considerable manual effort; and that the UNIVAC operating system was difficult to learn.It was recommended that a study should determine if: core logging could be redesigned and/or implemented on a microcomputer; interactive graphics be used to reduce the effort for functions requiring visual interpretation; and the creation of input processors would assist users in setting up parameters for guiding the programs."

Jan 1, 1989

By L. E. Young

"The Red Dog deposit of the western Brooks Range, Alaska was discovered in the 1970s. Two mineralized areas are present, the Main and Hilltop deposits. With indicated and inferred reserves of 77 million tonnes of 17.1% zinc, 5.0% lead and 82 g/ tonne silver, the Main deposit of Red Dog represents one of the world's largest zinc-lead deposit s. Since serious evaluation by Cominco commenced in 1980, a better understanding of deposit geology has been gained through 10 715m of diamond drilling and concurrent geologic, geophysical and geotechnical studies. The Red Dog deposit is of Mississippian to Pennsylvanian or Early Permian age, and straddles a redox transition in fine-grained and chemical sediments of the Red Dog structural sequence.The Main deposit has been modified by regional Mesozoic thrust faulting and isoclinal folding, resulting in complex interrelationships between silica rock, sulphide rock and barite. Multiple lines of evidence suggest the Main deposit contains both a syngenetic stratiform and a replacement component. Ore fluids were probably derived by regional lateral movement of brines through a coarse clastic footwall aquifer, then upwards along block faults to the site of the Red Dog deposit.Historical PerspectiveThe region in the vicinity of the Red Dog deposit (Fig. 1) was first prospected by J. W. Kelley in the late 1880s (Orth, 1967). The first coordinated inland exploration was conducted by the U.S. Geological Survey in 1910-1911 and 1923-1926 (Smith, 1913; Smith and Mertie, 1930). The earliest reports of zinc-lead mineralization in the region include reference to samples collected at unknown locales by Eskimo prospectors (Anderson, 1944). In 1955 stratiform pyrite was discovered 19 km west of Red Dog by I.L. Tailleur of the U.S. Geological Survey (Tailleur, 1970). The first reported visit to what is known as Red Dog was by I.L. Tailleur in 1968, who was field checking a colour anomaly noted by B. Baker, a local bush pilot (Tailleur, 1970; Moore et al., 1986) ."

Jan 1, 1989

By M. K. Abel

"The Strathcona Mine is located in Levack Township on the North Range ofthe Sudbury Basin. The main orebody consists of pyrrhotite-pentlandite-chalcopyrite mineralization associated with an embayment of the footwall of the Sudbury Irruptive. A zone of massive chalcopyrite-cubanite-pentlandite mineralization occurs in a complex vein system in a series of mixed gneisses and breccias in the footwall. Vein widths vary from a few millimetres to 6 metres. In December 1979, this zone was estimated to contain 976,000 metric tonnes, with a grade of 9.31% Cu and 0.46% Ni. The vein system has a general strike of N 68°W at an angle of 60 degrees to the average strike of the footwall contact of the Irruptive. The dip of the vein system is 45 degrees sw. The strike and dip of individual veins in the system coincide with the directions that would result if a compressive stress had acted in a direction normal to the footwall of the Sudbury Irruptive, producing a conjugate set of fractures. The strike of the Irruptive at the Strathcona Mine is parallel to the long axis of the basin.IntroductionThe Strathcona Mine, owned and operated by Falconbridge Nickel Mines Limited, is located in Levack Township on the northwest rim of the Sudbury basin (Fig. I) . It is one of a group of nickel-copper sulphide ore deposits present along an 8.2-km section of the North Range of the Sudbury Irruptive. In the mines of the North Range, subunits of the Irruptive, going from hanging wall to footwall , include felsic norite, dark norite and dark norite breccia. The footwall complex at Strathcona includes the late granite breccia, which hosts a large proportion of the nickel-copper ores, and a compositionally variable group of brecciated and migmatized rocks, herein referred to as the feldspathic gneiss complex. It is within this latter group of rocks that the vein system of the Copper Zone occurs."

Jan 1, 1981

By K. MacMaster

"This paper deals with the history, development, present and future of the Employee Assistance Programs in place at the Inco Ltd. operations in Thompson, Manitoba. It should be noted that, although many similar programs exist in various industries and jurisdictions, these programs had to be fine-tuned to meet the needs of Inco employees, having in mind the helping professional resources available in Thompson and its geographic location. IntroductionIn the late 70s, many Canadian industries and the Canadian Labour Congress and their affiliates commenced discussions on the value of the Employee Assistance Program (E .A.P.) philosophy to both management and labour.In the contract signed between Inco Ltd., Manitoba Division and Local 6166, U.S.W .A. in 1981, a commitment was made to establish a joint E.A.P. for the hourly workforce in Thompson, Manitoba. With this background and sequence of events in mind, it is appropriate to explain the methodology and the steps that were taken for the implementation of the hourly program. Development of Hourly ProgramIt was agreed by the company and the union that the committee to develop the program should consist of equal numbers from both sides: three active union members plus an advisor representing the Union and three supervisory personnel plus an advisor representing the Company; in addition, a person familiar with E.A.P.s from the Alcoholism Foundation of Manitoba was to act as a facilitator. The Union appointed a social worker who was working as a counsellor for union members as their advisor , and the company appointed a staff employee who had worked voluntarily in the field of alcohol and drug abuse for many years. The makeup of the committee was extremely important in order to give credibility to the entire process. The makeup of the committee is shown in Table 1.The facilitator selected from the Alcoholism Foundation of Manitoba was well known in the community and highly respected in his profession."

Jan 1, 1989

By Sigmund J. Andersen, Eva A. Mørtsell, Jostein Røyset, Randi Holmestad, Oddvin Reiso, Yanjun Li, Øyvind Paulsen, Calin D. Marioara

"With the purpose of increasing the extrudability of lean alloys, we reduce levels of the alloying elements Mg and Si in a 6xxx extrusion alloy. To avoid sacrificing strength, we investigate the compensating effect of smaller amounts of lithium and germanium, alone and in combination. Recent studies by atomically resolved high angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) together with density functional theory (DFT) calculations have demonstrated that while Li replaces Mg, Ge substitutes Si in the columns in the hardening ß’’-phase. Several studies have shown that Ge replaces Si in other precipitates as well, and that both Li and Ge promote precipitation and can improve macroscopic properties, like strength and thermal stability. The scope of the current work has been to investigate and document the combined effect of the two alloying elements. Of the investigated alloys, the one containing both elements displayed highest hardness, corresponding with a significant increase in precipitate number density. We used HAADF-STEM to determine the extent of Li and Ge in the precipitate structures.INTRODUCTION The two most important alloying agents, with respect to age hardening of the 6xxx alloy series, are Mg and Si. In general, 6xxx alloys are formed into their final shapes by rolling or extrusion, before being age-hardened at elevated temperatures around 180°C. The hardening effect during this stage is due to the formation of metastable, semi-coherent, precipitate needles along the three < 001>Al directions generally following the precipitation sequence (Marioara, Nordmark, Andersen, & Holmestad, 2006): Supersaturated solid solution ? atomic clusters ? Guinier-Preston-zones (pre-ß”) (Edwards, Stiller, Dunlop, & Couper, 1998) (Marioara, Andersen, Jansen, & Zandbergen, 2001) ? ß” (Andersen, et al., 1998) (Hasting, et al., 2009) ? ß’ (Vissers, Huis, Jansen, & H. W. Zandbergen, 2007), U1 (Andersen, Marioara, Vissers, Frøseth, & Zandbergen, 2007), U2 (Andersen, Marioara, Frøseth, Vissers, & Zandbergen, 2005), B’ (Vissers, Marioara, Andersen, & Holmestad, 2008) ? ß, Si (stable)"

Jan 1, 2018