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By C. J. Brown

Regeneration of hydrochloric acid steel pickle liquors has traditionally been accomplished by pyrohydrolysis. However, a number of factors have recently conspired to reduce the attractiveness of this approach. Moreover, the process is not amenable to small-scale operations. On the other hand, the standard technique for regeneration of sulfuric acid pickle liquors, which is the low-temperature crystallization of ferrous sulfate is applicable to any size operation. A similar technique has recently been developed to regenerate hydrochloric acid. Sulfuric acid is added to the ferrous chloride-bearing spent HCl pickle liquor. The temperature is then reduced to below 0°C, resulting in the crystallization of ferrous sulfate heptahydrate and liberation of free hydrochloric acid. Depending upon the crystallization temperature, variable concentrations of sulfate are left in the regenerated acid. Although this residual sulfate has an impact on the pickling characteristics of the regenerated acid, tests have shown that by adjusting the conditions, pickling rates will be at least equal to those using pure HCI, and an acceptable surface finish will be produced.

Jan 1, 2006

By F. M. Waldie

THE 2,538-foot belt conveyor recently installed underground at the Sullivan mine hoists ore from the 3,350-foot level to the 3,900-foot or main haulage level, a vertical distance of 680 feet. The design and planning of development work, under the direction of Mr. R. H. Stewart, Consulting Engineer, was begun in the spring of 1941. Development work was started in July of that year from the 3,350-foot level, and headings were started on the 3,650-foot and 3,900-foot levels later in the same year. It was the intention at that time to keep three headings going on development work necessary for the installation of the system: two on the conveyor incline, and one on the 3,900-foot level. This programme was modified in 1942 when there was some doubt whether the material for construction could be obtained. This problem of supply was eventually solved and the development work was pushed to completion in December, 1943. Construction was started in December, 1943, "'under the supervision of Mr. G. H. McKay, Superintendent of Construction and? Maintenance, and was completed in November, 1944.

Jan 1, 1945

By W. S. Tremaine

When the Hedley Mascot mill was built in 1935, it was designed as a straight flotation plant. The ore to be treated at that time was a gold ore in which the gold was intimately associated with arsenopyrite and pyrrhotite in highly silicified and garnetized limestone gangue. This material was ground to 85 per cent minus 325 mesh in two-stage grinding and floated in standard flotation cells to produce about a 5-ounce concentrate, which was shipped to Tacoma smelter for refining. This arrangement gave us a recovery of about 89 per cent. Test work indicated that the best way to improve this recovery would be to build a cyanide plant to treat our flotation middling. Arrangements for the construction of this plant were finally approved and work on it was started in the spring of 1940. This plant was of the conventional type in which the flotation middlings were thickened, filtered, and then put through the usual cyanide process. Its capacity was 50 tons of middlings per day. This arrangement worked quite satisfactorily and gave us an increase in overall recovery of 4 per cent. Unfortunately, about the time the plant was completed, we developed, and started to ship to the mill, ore that differed entirely from that met with up to that time. Instead of being hard, it was very soft, the orebody from which- it came being much faulted and brecciated. In many sections, the sulphides were oxidized and the breccia was filled in with a very soft, hydrous iron silicate known as chloropal. When this new ore was mixed with the old ore and sent to the mill, the whole operation was disrupted. The chloropal slimed so badly that the classification, flotation circuits, and cyanide plant would not handle it. The difficulty in the cyanide plant was at the head end, where the 10 ft. by 20 ft. thickener and the 8 ft. by 8ft. drum filter would not handle the middlings containing a large percentage of primary slime and chloropal. This material would not thicken to more than 30 per cent solids in the thickener and, when pumped to the filter, would forma very thin, slimy cake. Overall recovery dropped to between 83 and 84 percent and it was quite apparent that some extensive changes would have to be made in our flow-sheet before this ore could be treated successfully.

Jan 1, 1947

By T. Fekete, D. L. Flocks, R. T. Hart

The plugging effect of bacteria was investigated by injecting various concentrations of dead bacteria cells though sandstone cores. Pressure profiles along the cores were recorded periodically during the injection cycles. The plugging effect was analyzed using a plot of the ratio of reduced permeabilities to the initial permeability versus input volume. Results indicated that Tock permeability has little effect on plugging, but that the concentration of bacteria in the injection water has a significant effect on plugging characteristics. The pressure profile curves showed that bacteria penetrated several inches through the core but that the greater portion of the bacteria accumulated at the in-put end of the core.

Jan 1, 1960

By W. Hardtke, B. Perry

Model reconciliation problems at the low-grade, high-nugget Phoenix gold-copper deposit led to an examination of the influence of production decisions on ore-waste classification. A conditional simulation study of the deposit was used as the basis for: 1) quantification of dilution at different bench heights, 2) quantification of ore-waste misclassification relative to bench heights and cut-off wades, and 3) determination of an appropriate number of samples to optimize ore-control polygon definition. Actual reconciliation data were empirically used to support conclusions. Simulations of both gold and copper were combined through net revenue modelling. These simulations increased understanding of the nature of the deposit and provided insight for resource modeling and mine planning.

Jan 1, 2011

By D. Laguitton

The basic chemistry of a1•senic related to its dissolution and subsequent precipitation in gold-mine waste waters is discussed. The lime addition methods provides the most economic treatment of arsenical slurries, but requires a careful control of the oxidation of Asm into Asv, of the pH (>12) and the filtration of the precipitate. If arsenic levels below 0.5 mg/ l are required, a modification of the method by phosphate addition must be considered.

Jan 1, 1976

By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By G. M. Castillo

Newmont?s Phoenix mine started production in March of 2006. Due to the extreme hardness of the ore, the mill has struggled to meet throughput projections. Grinding studies showed that optimizing the existing circuit would not achieve budgeted throughput. These studies also showed that the pebble crusher was being underutilized due to the inability of the SAG mill to break the rock. The concept was developed to supplement the feed to the existing pebble crusher with a secondary crusher. Models of this process looked favorable so a portable crusher was installed to test the process. The temporary crusher was successful at increasing the throughput by 7% and based on the operating data, plans are currently being developed to install a permanent secondary crushing system in front of the SAG mill. This paper will review the results from the test crusher and the flow sheet for the permanent secondary crusher.

Jan 1, 2012

By R. L. Veenstra

This paper explores the connection between the stresses observed and the failure mechanisms present in the modelled cemented paste backfill. In order to look at this connection, the authors have used a previously developed model to conduct a sensitivity analysis of the model?s strength and permeability input parameters. The results from the sensitivity analysis were then compared to determine what causes modelled stresses and failure mechanisms to vary. Increased insight into the behaviour of the modelled paste will help clarify how paste behaves in the field.

Aug 1, 2013

By H. A. Steane

THIS PAPER describes the re-grind section in the 2,000-ton per day, lead-zinc flotation mill of Canadian Exploration Limited, near Salmo, B.C. There are two re-grind units in operation, one in the lead circuit, and one in the zinc circuit. In each unit, the rougher concentrate is re-ground ahead of the cleaning circuit. These re-grind units have made valuable improvements in the concentrate grade, and with no loss in recovery by over-grinding galena or sphalerite. Since the initial installation of this re-grind section, the plant throughput has been increased gradually from 1,600 tons to 2,000 tons per twenty-four hours, and, as shown by the screen analysis of mill tailing, a coarser overall grind has been accepted, from 55 per cent to 45 per ?cent minus 200 mesh. There has been no increase in grinding capacity, but two mills have been taken from the main grinding circuit and used for the re-grind circuit.

Jan 1, 1958

By Erwin L. Zodrow

"This paper is based on a statistical analysis of the Smallwood iron ore mine (6). In this mine, the prediction of magnetite is especially difficult because of strong trends. Recognizing the statistical limitations of the sample data, the paper approaches the basic statistical analysis of the magnetite by endeavouring to obtain a first approximation of its sample density function. The knowledge of the distribution of a random variable is essential for several reasons, but particularly: (1) to obtain reliable estimators of the population parameters -for example, mean and variance; and (2) to use these estimators in hypothesis-testing concerning future experiments -sample points and sample intervals."

Jan 1, 1968

By S. G. Shabestari

Thermal analysis is a tool that is generally employed to predict the structure of the alloy before the actual casting is carried out. By cooling a sample of the molten alloy and recording the temperature-time curve, important solidification events may be analyzed by using the first derivative-cooling curve. In this research, strontium is added to (AS5U3G) 319 aluminum alloy and its influence on the formation of intermetallic compounds e.g. Al15(Mn,Fe)3Si2, Al2Cu, Al5Mg8Cu2Si6 formed during pre- and post-eutectic reaction have been investigated. Also any changes in solidification parameters such as temperature of Al-Si eutectic under cooling and temperatures of nucleation and growth of each phases caused by strontium addition, have been determined via the first derivative cooling curves. The effect of strontium on the formation of various intermetallic compounds has been studied by using very accurate thermal analysis equipment and the microstructures were analyzed using an optical microscope. The various phases reported in this paper were identified using Scanning Electron Microscopy (SEM) and linked to Energy Dispersive Spectroscopy (EDS). Formation of all pre- and post-eutectic phases was interpreted by comparing the phases formed in the microstructure and the reactions detected by using cooling curves. The results of this research indicate that thermal analysis technique can be used as an on-line process control in the production lines in aluminum casting industries.

Jan 1, 2004

By Yan Yang

The Jinfeng gold mine is one of the three gold mines that Eldorado Gold has in China and it is the second largest gold mine in China. The mine is located in a relatively remote and mountainous area in the southwestern Guizhou province. The orebody is similar to the Carlin type deposit in Nevada. The mill throughput was designed to treat 3,600 tones per day. The ore comes from open pit mining and underground mining, and is fed to one-stage jaw crushing. The crushed ore is stockpiled, reclaimed and then fed to the SABC grinding circuit. After classification with hydrocylones, the ore is floated, and the resultant concentrate is oxidized biologically in a process known as BIOX®. The oxidized concentrate is then washed in a CCD circuit and finally leached with cyanide in a CIL circuit for gold extraction. Jinfeng produces about 180,000 oz of gold per year. This paper introduces operations and modifications of SABC circuit over the past three years, and then describes some technical characteristic of the SAG mill and other circuits in the processing plant. Major modifications and improvements on the SABC circuit are described in the paper, including: 1. Impacts of grinding ball and mill liner with respect to material selection, quality, hardness, manufacturing methods, and interactions between mill liner and grinding ball. 2. Effect of milling operation parameters on milling efficiency. 3. Impacts of SAG mill scats and modifications of grate size to improve mill throughput. 4. Design and construction of a pebble crushing system, and recycle the crushed scats to the SAG mill to improve mill throughput. With the above-mentioned modifications, 20% increase over the design in mill throughput has been realized over the past three years, and operating cost has been significantly reduced. However, some issues still remain, and thus process modifications and technical innovations are still needed.

Jan 1, 2012

By R. A. Hemstock

AREAS in which the surface de-posits consist of organic material -known in some parts of Canada as muskeg and in Europe, more generally, as peat lands -have long been some of the least rewarding of lands of the north temperature zone. Even in such countries as Great Britain, Holland, and Denmark where a good deal of incentive exists to develop all available land, the use of peat land has been negligible except as a source of fuel. Only recently have efforts shown promise in re-claiming these lands for farming or for forestry. Russia has large areas of peat and use is made of it for power generation. The Russian people have also ?developed a variety of machines for handling peat, which would indicate that they are well ahead of the Wes tern World in their technical and physical ability to solve some of the problems. Certainly in Canada, where there are over 500,000 square miles of muskeg, the economic aspects of this problem are important. This is especially true in considering the shifting emphasis to northern development. Not only is muskeg in possession of great stretches of terrain, thereby rendering it useless for agricultural purposes, but it is apparently moving into forested areas and reducing their productivity. In addition, it lies as a great barrier to movement in the search for and development of such natural resources as petroleum, natural gas and minerals generally. This situation has long been recognized in Canada but only recently have organized efforts been made to study the problems and search out ways of overcoming them.

Jan 1, 1958

By Ralf M. Kleine

THE property of Consolidated 1 Discovery Yellowknife Mines Limited, (Figure I) is situated in the Northwest Territories, approximately 50 air miles north of the town of Yellowknife. The mine is reached by a shaft which extends from surface to a depth of 4,000 feet, with working levels established at 1 50-foot intervals. Stopping operations are carried on throughout a vertical range of 2,000 feet, with both shrinkage and cut and fill methods being used, depending on the ground conditions. Production started in 1950 and milling is done in a 1 65-ton per day cyanide plant. During ten months of the year, the property is serviced entirely by air, utilizing charter aircraft from Yellowknife. A 4,000-foot runway near the mine was constructed from mill tailings. This strip is adequate to receive Bristol freighter planes carrying heavy loads. Other servicing is done by Otter aircraft, equipped with skis or wheels for winter and with pontoons for summer operations.

Jan 1, 1962

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012

By R. F. Robertson

"Adsorption isotherms of hexyl mercaptan vapour on synthetic sphalerite, zinc sulphide and zinc oxide were de-termined with a gravimetric McBain-Baker micro balance incorporated in the B.E.T. apparatus. Isotherms are given for hexyl mercaptan on synthetic sphalerite at 25°C, 0.5°C and 50°C; on zinc sulphide at 25°C and 1.5°C; and on zinc oxide at 25°C. All these isotherms are sigmoidal, with a definite change in slope at or close to the mono-layer. The amount of mercaptan adsorbed below the monolayer increases almost linearly with relative pressure to P/P0 = 0.8.Above this value, the amount adsorbed increases very rapidly with relative pressure. Hysteresis loops appear in the isotherms for all adsorption-desorption cycles. These loops are completely reversible. It is not possible to desorb the mercaptan monolayer from any of the adsorbents, even at elevated temperatures."

Jan 1, 1966

By E. Gaucher, D. C. Gagnon

"The paper refers to methods and concepts used in the computer treatment of banks of geophysical, geochemical and geological data, relating to the exploration of massive sulphides. In particular, a data bank of 400 drill holes on independent conductors can be used to calculate probability levels of intersecting a certain quantity of sulphides according to the characteristics of the conductor. Inversely one can, using the data bank and some cost assumptions, simulate and optimize the cost of intersecting a certain quantity of sulphides by selecting drill targets among conductors according to conductivity, magnetism or gravity. Problems of noise, inherent in any simulation, are illustrated in this paper by the results of a study of the nomenclature of volcanic rocks of 27 drill holes by forty geologists. Compilations of data banks are long and timeconsuming, and it would help to standardize to allow exchange of data. We believe that such efforts may result in the discovery of more mineral deposits and at a lower cost. The present study is supported jointly by SOQUEM The New Jersey Zinc Co. and Cominco Ltd."

Jan 1, 1973

By C. C. Walden, D. W. Duncan, P. C. Trussell

Thiobacillus ferrooxidans released copper from -400-mesh chalcopyrite at a rate of 54 mg/I/hr. Any flotation chemicals remaining on the concentrate did not inhibit the leach rate. Zinc rougher tailings were also leachable. With bacteria, 75 per cent of the zinc and 68 per cent of the copper came into solution. In the sterile controls, only 16 per cent of the zinc and 10 per cent of the copper were released; 100 per cent of the copper and 36 per cent of the zinc were leached from pyrite cinders through the action of bacteria, and 17 per cent of the copper and 10 per cent of the zinc were solubilized in the sterile controls. Less than 0.027 per cent of ~he iron came into solution. The majority of the copper in a converter slag was acid-soluble, but a reverberatory slag responded to microbiological leaching. About 62 per cent of the copper came into solution, compared to 12 per cent in the sterile control. The various factors influencing the rate and extent of microbiological leaching are discussed.

Jan 1, 1966

By L. Voisin, E. Díaz, V. Montenegro, W. Kracht

Grinding media is of great concern in the mining industry mainly because its consumption represents an important part of the costs during mineral processing and consequently, of the total mining business OPEX. In addition, grinding media consumption impacts directly on flotation performance through negative contamination by corrosion, affecting the pulp chemical potential, complicating the understanding and control of the process, as galvanic interactions between mineral species also occur. In addition, during the process there is also a physical consumption of the grinding media through erosion and impact. In both cases, mineralogy has an important role because pulp abrasion power, chemical reactivity, rheology, hardness and other variables depend on the minerals contained in the pulp and their interactions. In the present study, a geometallurgical and phenomenological model, which describes the grinding media consumption and its relationship with mineral hardness expressed by Bond Work Index, was obtained based on advanced mineral characterization techniques such as Hylogger3TM, X-ray diffraction, X-ray fluorescence and experimental grinding tests using a laboratory mill applied on Chilean copper pulps. The results obtained show that pH has an important effect on grinding media consumption, because corrosion varies with hydrogen ions availability. Also, mineral hardness depends on mineralogical composition, but textural analysis must be performed to have a better description of this property. Finally, minerals present in a sample define the grinding media consumption mechanism, because a sample with harder minerals and a greater value of Bond Work index is capable of protecting grinding media from impact wear, while a sample with lower hardness but with a big sulfide minerals content would be more aggressive with grinding media because corrosion is more important in this case. The geometallurgical model obtained is capable to relate the grinding time, mineral hardness, content of sulfide minerals and grinding pH to estimate the grinding media consumption.

Jan 1, 2017