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By Sergei Decterov, Peter Hayes, Evgueni Jak, Taufiq Hidayat, Denis Shishin

Copper smelter operations around the world are under sustained pressure to reduce costs and increase output. Through the provision of reliable data on fundamental properties of the chemical systems the opportunities for improvements of industrial copper production can be identified. Experimental and modelling studies on phase equilibria, thermodynamics of copper slag/matte/metal/gas systems have been combined into an integrated research program undertaken at PYROSEARCH. Experimental phase equilibria studies involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of compositions of equilibrium phases with electron probe X-ray microanalysis (EPMA). Thermodynamic databases development and modelling is undertaken using the computer package FactSage in conjunction with advanced models used for complex solution phases. Progressive development of these research methodologies has brought significant advances in characterisation of these complex systems, including a new optimised thermodynamic database for the copper-containing slag system Cu2O-Al2O3-CaO-FeO-Fe2O3-MgO-S-SiO2.The new data and models can now be applied to assist in improvements of the processes. The effects of changes to chemistry and process conditions within the smelting reactor can be examined. Several examples of new descriptions of the phase chemistry of the Cu2O-CaO-SiO2 and Cu2O-FeO-Fe2O3-SiO2 systems in equilibrium with metallic copper showing calculated and experimental data are presented.

Jan 1, 2014

By R. Biss

"Niobium or columbium, as usually called in North America is becoming a more and more important metal in the industrial world because of its attractive properties.Eventhough discovered in the early nineteenth century, it was not until the 1930's that its use became more widespread. The discovery of large commercial deposits in the late 1950's and the demand of industry for steel with high strength and toughness further promoted its use. To assure its adequate supply new or-e processinr technologies had to be developed. So, beside the traditional gravity concentration, the flotation process was employed for the partial upgrading of pyrochlore concentrate at S8ve (Norway) plant in 1953. The flotation process was equally used at St-Lawrence Columbium plant in the province of Quebec, Canada. The new plants at Araxa and Catalao in Brazil and at St-Honore, Canada, which supply almost of all niobium used today in the non-Communist world, also adopted the flotation process. The processes using long chain aliphatic rnonoarnines, diamines or sulfonates as collectors proved to be difficult especially on weathered types of ores or on those having a substantial content of silicate gangue minerals. They almost completely failed in case of alkaline intrusive rocks as syenites, nepheline syenite, ijolites and pyroxenites, composed almost entirely of silicate minerals. A lot of effort was devoted all around the world on research of new, more efficient flotation processes. So in 1982, Les Services T.M.G. Inc. (Niobec), sole producer of pyrochlore concentrate in North America, developed the direct pyrochlore flotation process from carbonatites. In 1983, at about the same time, the Quebec Department of Natural Resources Laboratories and Les Services T.M.G. Inc. announced a successful recovery of niobium Minera1s from a low grade nenheline syenite ore."

Jan 1, 1984

?Why TSM in Canada ?How it was developed ?Architecture and Goverance ?COI panel ?Performance indicators and how they work ?External Verification ?Reporting ?The national organization of the Canadian mining industry ?Mining, smelting and refining of base and precious metals ?Mining of iron ore, diamonds, uranium, oil sands, coal and industrial minerals ?Many associate members ?www.mining.ca

May 1, 2011

By Louise Pearce

?Environmental and social impact assessments (ESIAs) are: ??process-driven and scientific processes ??The process entails a number of steps and procedures which result in obtaining a licenceto operate ?and moving more towards a social license to cooperate. ?However, the primary premise of ESIA is to facilitate the consideration of environment and the communities in planning and decision-making which would ultimately make it possible to arrive at decisions that are ?sustainable?. ?Hence, ensuring the development of the mining sector on a sustainable basis is a critical challenge that needs to be addressed by the global community.

May 1, 2011

By J. B. Brodie, C. Pelletier

"The vulnerability of Canadian and U.S. companies, their directors, officers and employees to onerous penalties associated with violations of environmental statutes and common law actions has provided the impetus for the increasing use of environmental audits. This trend is developing in direct proponion to the cost and difficulty of obtaining liability insurance. Companies operating in British Columbia should be cognizant of developing legislative and enforcement trends and their implications for individual and corporate responsibility. Canadian mining companies doing business in the U.S. should be particularly aware of the environmental exposure which may be assumed with property acquisition or by operations which produce or use any of an ever-increasing list of regulated substances.The environmental audit is now a key component of prudent business planning which will identify noncompliances and environmental liabilities, outline defensive strategies, and assist in a legal defence should charges be laid. This paper will discuss the purpose and mechanics of an environmental audit with emphasis on those features which will maximize protection against statutory and common law actions.IntroductionThe environmental audit is but one weapon in a comprehensive defensive strategy for corporate and individual survival in an increasingly litigious world. The principles of the environmental audit have been formulated as a logical response by management to an ever-growing list of environmental vulnerabilities, which often have the potential to result in plant shutdowns, prosecutions or fmancial liability of major proportions. Accordingly, the audit may play a critical role in maintaining profitability as well as assisting in the defence of a company and its employees against actions taken by regulatory agencies and citi7.cns under statute and common law. Should convictions result from these actions, the penalties are likely to be ameliorated by the demonstration of due diligence through management policy supporting the audit procedure.An awareness of environmental sensitivities, strict adherence to licensing requirements, and planning for environmental emergencies are now generally considered to be as important to profitable performance as operating costs, metal prices, and labour peace. Why is this so? The increased priority given to environmental matters is partly a result of changing attitudes amongst the mining profession, but perhaps more importantly, it is also a direct consequence of the proliferation of ever more stringent environmental legislation, the targeting of management for responsibility and the draconian penalties imposed for violations of such legislation. Contributing to this trend are recent court decisions involving disputes of an environmental nature in which the standard of care required for a successful defence now requires almost super-human diligence in environmental management. The principle of ""strict liability"" (in which negligence or permit violation does not have to be shown) is also being increasingly applied in the resolution of civil actions."

Jan 1, 1988

By K. Spence

"The notion of “value” has always been a subjective and contentious issue. Indeed, value is in the eye of the beholder. There are as varied methods and practices for valuing property, as there are industries in which they are applied. For example, there is replacement value, insurance value, salvage value, appraised value, book value, and fair market value, to name a few, although in the mining industry, valuations usually refer to fair market value.In the Canadian mining industry, at present, there are no comprehensive regulations or guidelines that specify which approaches or methods are appropriate for use in the valuation of mineral projects. In January 1999, The Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission recommended that the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) establish a committee to review and advise on approaches and methodologies for the valuation of mineral properties. Among the approaches to be considered are included the following: the discounted cash flow approach, the cost approach, the option pricing approach and the market comparables approach. In addition, methodologies differ depending on whether the project is at the exploration stage or the producing stage.The CIM Special Committee on the Valuation of Mineral Properties (CIMVal) expects that its final report will form the basis for a Canadian code or standard for the valuation of mineral properties."

Jan 1, 2002

Leadership "Organizing a group of people to achieve a common goal" Paradigms ? Rush to produce or cut costs. ? The most important thing after safety is production. ? We?ll take care of ??this?? once in production. ? I know what to do, 30 years of experience in mining. ? I want a 100% reliable operation.

Aug 1, 2013

By Peter Waggitt

Northern Australia has been home to uranium mining for over 70 years, more or less continuously. In the early days, post World War 2, there was little effort made to remediate workings at the end of operations. The three “campaigns” of uranium mining (1951-55; 1960-70; and 1979-present) are all now in various stages of remediation. This includes not only the large legacy site at Rum Jungle but also smaller fields like the South Alligator Valley, as well as contemporary works at Nabarlek and the ongoing closure at Ranger– Australia’s longest operating uranium mine. This paper briefly describes some of the past remediation activities before providing an update on the Ranger closure programme and future timetable.

Jan 1, 2020

By Ken Dyck, Chuck Edwards

"Cameco's McArthur River is the world's largest high grade uranium mine. Production started in late 1999. Cameco carried out the engineering design and construction management for the McArthur River project, including all aspects of mining, ore handling and ore transportation. The ore composition was expected to vary dramatically (0 to 30% U3O8; 0 to 25% clay; etc). To cope with the composition swings, sizing screens were selected to provide classification in the grinding circuit. The grinding circuit started up close to the design to provide minus 500 micron slurry. The 50% solids (wt) ground ore slurry proved to be difficult to transport to and process at the Key Lake Mill. Slurry containing high concentrations of high density pitchblende (about spgr 8.0) and low concentration of stabilizing clays, would settle in containers. Ore transport efficiency to Key Lake was found to be unacceptable.A test classification cyclone was installed in the grinding circuit at McArthur River early in 2002. The cyclone operating parameters were not typical, but the cyclone was made to work very successfully. Transportation efficiency to Key Lake increased due to more stable slurry. Preferentially ground (fine) pitchblende particles were easier to leach at Key Lake. The radiation exposure for operators and maintenance personnel to handle the more stable slurry was also reduced.The classification sizing screens were removed from the McArthur River grinding circuit and replaced by permanent classification cyclones late in 2002.INTRODUCTIONThe McArthur River mine and Key Lake mill operations are located in northern Saskatchewan, approximately 650 and 720 kilometres from Saskatoon, respectively. Figure 1 is a location map. McArthur River is the world's largest, high-grade uranium mine, with a production capacity of 18.7 million pounds U3O8 annually. (Rosner and Edwards 1998, Dyck 2000, Jamrozek 2000, Rodgers 2001) Proven and probable reserves are more than 473 million pounds U3O8. McArthur River ore, grading on average 21% U3O8, is milled at Cameco's Key Lake operation, 80 kilometres southwest by road. McArthur River production began in December 1999."

Jan 1, 2004

By Jacob Masliyah, Zhiang Zhou, Tshitende Kasongo, Jianjun Liu, Zhenghe Xu, Jeawon Choung

"Slime coating is a recognized challenge in fine particle flotation, not only in decreasing recovery, but also in reducing the selectivity and hence froth quality. In this presentation, a novel method based on electrophoretic mobility distribution measurement to study slime coatings is described. By measuring electrophoretic mobility distribution of individual minerals and their mixtures, the interactions between these minerals can be evaluated.For illustrative purposes, a model system of fine coals, or oil sands with two different types of fine clays was studied. Flotation tests showed a significant decrease in coal (bitumen) flotation recovery with montmorillonite but not with kaolinite clay addition. When electrophoretic mobility distribution of a fine coal/montmorillonite clay mixture was measured, a single modal zeta potential distribution was obtained, in contrast to a bimodal distribution for fine coalkaolinite clay mixture. This finding suggests a stronger adhesion of montmorillonite than kaolinite clays on fine coal surfaces. In the case of bitumen, the bimodal zeta potential distribution was measured for the mixture of bitumen emulsion and kaolinite or montmorillonite, indicating a weak attraction of the clays by bitumen. In the presence of calcium, however, a single modal zeta potential distribution was obtained in the mixture of bitumen emulsion with montmorillonite but not kaolinite clays. These findings are in excellent agreement with bitumen flotation results, demonstrating that the electrophoretic distribution measurement is a powerful tool to study slime coating phenomenon in a complex fine particle flotation system."

Jan 1, 2002

By Derek Ettie

"In the Hydrometallurgical processes, the presence of the so-called "crud" is a constant challenge in solvent extraction. Crud is a stable emulsion which forms along the interface between the aqueous and organic phase. The spread is influenced by the following parameters: first, wind blows the dust and impurities into the open sedimentation tanks. Second, the undissolved solids such as sand transported in the PLS causing problems in conjunction with incorrect agitator design.The crud fraction can decisively impact the efficiency of the hydrometallurgical extraction because the phase interface can constitute a large fraction and the sedimentation tanks cannot react flexibly to it. In the downstream process of the series-connected sedimentation tanks, they are thus all contaminated with crud. At the same time, the necessary mass transport is significantly impeded at the phase boundary between organic phase and aqueous phase due to the crud formation.The transfer of the organic phase into the electrolysis cell can result in a "burnout" of the cathode. The carryover of this electrolyte into the extraction can cause problems with the pH regulation. The carry-over of the organic components into the raffinate also leads to contamination of the leaching circuit. The continuous treatment of the crud with a 3-phase decanter centrifuge is extremely effective in combating this problem. This technology splits all three phases from each other and they are consequently continuously separated. All subsequent process steps exhibit a stable, uniform effectiveness. The main advantage for the customer is that fluctuations in the process are eliminated and the organic phase can be recirculated back to the extraction. The recycling of the solvent alone justifies the investment in less than 6 months as examples from South Africa and Chile show.To operate solvent recovery in daily operation fully automated online at the optimum limit, the decanter centrifuge is equipped with a concentration-dependent pond adjustment called DControl® by this means, we can guarantee our customers the maximum possible solvent recovery and minimize the solvent costs in this process step. This system is presented in detail in this paper."

Jan 1, 2014

By R. Cotton

"1. INTRODUCTIONTo say that the environment will be a dominant issue in the 1990' s is an understatement. A world-wide ""green revolution"" is taking place not only with the general public and politicians, but in the boardrooms and plant facilities of corporations around the world. There is probably not a plant manager who has not been requested by his corporation to assist in some way on environmental issues by providing advice and strategy, by dealing with customer or community concerns, by considering environmental matters in transactions, by developing new environmental compliance policies and requirements, and so on.There are, in the author's view, three main challenges for the mining industry in the environmental area in the 1990's. This paper will discuss each in turn. The first challenge is the concept of ""sustainable development"". Whatever the meaning of this much-debated phrase, we are rapidly moving beyond the buzzword, and into the specifics. It will clearly impact on the way we manage our companies, our communities and our personal lives.The second is the challenge of personal liability; particularly for officers, directors, supervisors and managers of the corporation. For example, in Ontario today, a good percentage of prosecutions for pollution offences are against individuals, usually managers and supervisors, in addition to the prosecutions against the corporation itself for the same offence. In all likelihood, prosecutions will increase in number and will increasingly be directed at individuals. A corporate president has already served a jail term for contempt of court related to his corporation's breach of a court order related to sewer by-law offences. Although the case is on appeal, another president has become the first officer in Canada to be sentenced to jail for violation of an environmental protection statute. Other corporate officers and directors have recently been charged with breach of their duty under Ontario's Environmental Protection Act."

Jan 1, 1991

By Rob Barber

This paper shares the experience of the Alberta Energy and Utilities Board (EUB) Field Surveillance Branch over the past few years in building relationships with Aboriginal communities. Our goal is to provide and encourage best practices that may benefit you and your organization and result in strong, mutually beneficial relationships with a focus on Aboriginal communities. Historical information provides insight that aids in establishing effective working relationships with Aboriginal communities. An important component is appreciation of the perspective of these communities, which is achieved through awareness training. The use of local Aboriginal resource people as part of the training is recommended. A plan that is supported by management and staff is essential and lays the foundation for successful relationships. However, the plan must be flexible enough to change as circumstances warrant. The concept of having local people in communities address local issues is essential. This ?grass roots? approach, combined with the goal of exceeding a community?s expectations with respect to addressing issues, will go a long way to establish trust and credibility. Measuring the effectiveness of this work is the final building block to complete the picture.

May 1, 2004

By Dean Lindsay, Inna Dymov, Mariam Melashvili, Jim Smolik, Chris Fleming

"This paper presents results from the proposed cyanide detoxification circuit for Seabridge Gold’s KSM project. The proposed flowsheet uses a two-stage CCD (counter-current washing/decantation) circuit to transfer the flotation products CIL(carbon-in-leach) barren solution to a SART process (Sulphidization, Acidification, Recycling of precipitate, and Thickening of precipitate) to recover copper and free cyanide from the copper cyanide complex. The SART barren solution is then treated by an AVR process (Acidification, Volatilization of HCN gas, and Reneutralization) to concentrate the cyanide that was liberated in SART for recycling to leach. The washed CIL barren pulp (the CCD underflow) is treated with the SO2 /Air process to oxidize residual cyanide.The goal of this complex flowsheet is to recover and recycle as much cyanide as possible and produce a final effluent containing less than 0.5 mg/L copper and CNWAD at the lowest cost. The SO2/air process is capable of achieving low residual CNWAD (<1 mg/L) in the final product, but the persistence of aqueous copper above the target level has been detected in the treated solution in some instances. The expected high concentrations of copper and cyanide in the KSM CIL barren ( >200 mg/L each species) and the difficulties this might create for the SO2 /air process was a key factor in the decision to consider including the washing, SART and AVR steps in the project flowsheet.The target concentrations of CNWAD and Cu were readily achieved after aging the SO2 /air treated pulp, as would occur in a tailing or polishing pond. This suggests no additional treatment will be required to sustain low levels of these species in the final plant effluent."

Jan 1, 2015

By K. C. Viveros, R. R. Ambriz, C. García, F. De Villèle, A. Talha, D. Jaramillo

Cold hole expansion on base metal, weld metal and heat affected zone of 6061-T6 aluminum alloy welds was simulated by means of finite element method. Three dimensional compact test models with a previous fatigue crack length with a relation of ??= a/W = 0.3, were used to analyze the hole expansion process. Considering the local mechanical properties for each zone of the welded joint, the optimal expansion degree (1.64 to 2.46 %) was determined. The residual stress field, through thickness, after the expansion process in all welding zones, were correlated with the crack opening displacement obtained by finite element analysis. It was observed, that compressive residual stress fields for a post-expansion, in different crack lengths, provided a crack closure mechanism for base metal, weld metal and heat affected zone. Contrary, the crack remained open when residual stresses are positive. The results are given as tangential stresses versus distance from the edge of the cold expansion and crack opening displacement as a function of applied load.

Jan 1, 2014

By M. Arvola, A. Mäkinen, N. Isomäki

Arsenic is a compound that has no significant market value. However, it needs to be removed from ores, concentrates and other process streams because of environmental or technical processing concerns. A wide range of arsenic containing minerals exists in nature, and in many instances these minerals are also associated with the ones that have commercial value. For example, sulfide copper ores are normally closely associated with minerals like enargite, Cu3AsS4 and tennantite Cu12As4S13. After mineral processing these arsenic sources can report to the waste waters and these effluents need to be treated before discharge or recycling. Ferric arsenate precipitation is a well-established method for stabilizing arsenic in effluents. Electrochemical arsenic removal utilizes the same adsorption/precipitation ideology as ferric arsenate precipitation. Electrochemical arsenic removal, even though it is a simple process in terms of equipment, is a complex system involving chemical and physical mechanisms taking place simultaneously to remove dissolved and/or solid arsenic components from wastewaters. The whole process can be described by the following three steps: 1) electrolytic oxidation at a sacrificial anode (dissolving electrode metal, iron for example), 2) chemical reaction between dissolved iron and arsenic to form a solid precipitate and 3) aggregation of the particles to form flocs, which can be removed by known solid/liquid separation methods. Electrochemical arsenic removal is a very efficient way to remove arsenic from different waters to very low residual concentrations.

Jan 1, 2016

By Diankun Lu, Ganfeng Tu, Edouard Asselin, Feng Xie

A novel separation process for detoxifying cadmium-containing residues arising from zinc hydrometallurgical processes has been developed. An initial investigation indicated that a high concentration of zinc in the sulfate solution can be effectively separated from cadmium by solvent extraction with P204 (di(2-ethylhexly)phosphoric acid, D2EHPA). The mixture of sulfuric acid and ammonium citrate ((NH4)3C6H5O7) is thus used to extract metals from the residue at room temperature. Copper in the leachate is recovered by solvent extraction (SX) with LIX 973. Cobalt in the raffinate from the copper SX process is recovered by precipitation with a-nitroso-ß-naphthol. The results show that more than 50% of the copper and virtually all the zinc, cadmium and cobalt in the residue can be leached under the experimental conditions used here. Virtually all dissolved copper and cobalt can be recovered in the subsequent solvent extraction and precipitation processes. The presence of (NH4)3C6H5O7 could significantly facilitate the extraction of zinc by D2EHPA in the subsequent separation of zinc and cadmium. More than 97% of the dissolved zinc can be recovered through a two-stage counter current solvent extraction process. After separating copper, cobalt and zinc, cadmium can easily be recovered from the solution either by cementation with zinc powder or by electrowinning, while the purified solution can be recycled back to the leaching process.

Jan 1, 2014

By L. R. Plitt, A. A. Turak, B. C. Flintoff

"Since the publication of empirical cyclone models by Lynch and Rao in 1975 and by Plitt in 1976, the technical literature on this subject has consisted primarily of reports of applications, with only a few articles discussing basic modifications or enhancements in model form. In fact, most of the modelling eff ort in this period has been concerned with theoretical models based on the hydrodynamics of multiphase flow. (Preliminary resutls have been encouraging, however, it will be some time before this approach reaches the practical application stage.) This paper presents a review of empirical cyclone modelling technology, with an emphasis on developments since the mid 1970s. The topics addressed include homogeneous and heterogeneous ores, parameter estimation techniques, parameter confidence intervals, and the introduction of a new conceptual model of cyclone operation.IntroductionSince their first reported application in the mineral industry by Driessen (1939), cyclones have become a common unit operation in all of the process industries. The widespread use of the cyclone stems from its relative low cost and its versatility. It can be employed to carry out liquid-liquid, solid-liquid and solid-solid separations. It is the area of solid-solid separation which is of greatest interest to a mineral processing engineer. Historically, this area was divided into two application categories: (I) Separation according to density, the cyclone washer, and, (2) Classification according to particle size, the cyclone ciassifier. (When water is the carrier fluid, the cyclone is more often called the hydrocyclone. For the purposes of this paper the two names are used interchangeably). Classification is the principal application in mineral processing circuit s. Within this category, the cyclone is most commonly employed to provide some positive control over the size distribution of product from a grinding circuit. Other uses include sand-slime separation prior to froth flotation and mill tailings treatment, either for dam construction or in backfill preparation."

Jan 1, 1987

By D. J. McLaws

"Recent innovations in metal smelting technology utilize continuous oxygen-enriched smelting and converting processes which are capable of producing off-gases containing up to 60% SO2 or more. Other SO2 recovery processes, involving solvent absorption and steam or vacuum regeneration, can produce off-gases with SO2 concentrations nearing 100%.Processing of these high-concentration SO2 off-gases in conventional sulfuric acid plants can cause excessively high catalyst bed temperatures and poor SO2 conversion. In order to avoid these problems, a conventional acid plant design must dilute these high SO2 process gasses with dilution air in order to provide the required oxygen to effectively convert the SO2 and provide a heat sink (via the inert N2) such that the exothermic reaction, SO2 + ½ O2 ???SO3, does not exceed the temperature limit of the catalyst or the converter vessel.MECS, Inc. (MECS) has proven that a high SO2 feed gas design can be a viable option which can increase energy recovery, reduce energy consumption and potentially reduce capital costs."

Jan 1, 2014

By Michael Godard, Peter Cleyle

"Suncor Energy’s Project Millennium increased oilsands production capacity by an additional 95,000 barrels per day to its present level of 225,000 barrels per day. This massive venture included an expanded Mine, new Extraction and Upgrading facilities, as well as, steam and utilities infrastructuresIn the Primary Extraction process, removal of the bitumen from the oil sand begins with slurry preparation and is followed by primary , secondary and tertiary separation processes. The final cleaning step of the bitumen froth is the Secondary Extraction process, that removes residual water, mineral and solids to produce a clean diluted bitumen suitable for Upgrader feedstock.This paper will review the flowsheet of the Millennium Primary Extraction facility, from its recent commissioning through the ramp up to design production rates. In addition, new technologies in the Primary Extraction flowsheet will be reviewed.INTRODUCTIONAs conventional supplies of oil and gas are depleted in Canada, the Athabasca oil sands industry of Alberta becomes an increasingly important source of energy. Today, high quality crude from Alberta’s oil sands accounts for roughly 30% of Canada’s daily petroleum production. According to government projections, over the next 7 years, oil sands production is expected to more then double, and by 2010 more than half of Canada’s crude oil is expected to come from the oil sands.Oil sands deposits consist of a layer of sand saturated with bitumen covered by a muskeg overburden and underlain by silt and clay. The oil sand is mined where the overburden is economical to remove, typically less than thirty meters thick. The Athabasca oil sand deposits around Fort McMurrray is ideal for mining. Bitumen can be described as a diverse collection of hydrocarbons, organosulfur, and nitrogen compounds."

Jan 1, 2004