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This paper records the observations of faulting in the Black Star mine workings. By classifying the faults into two groups, i.e., strike faults and transverse faults, and by pointing out the differences between the groups and their effects on the silver-lead-zinc orebodies, a time relationship between the two groups of faults and the sulphide mineralisation is suggested.GENERAL GEOLOGY AND MINERALISATIONFolding and faulting are closely related to the mineralisation in the shales by silver-lead-zinc and iron sulphides.Commonly the various sulphides are fine-grained and closely associated with one another. However, exceptions do occur locally, where massive coarse galena, sphalerite, pyrite, and to a lesser extent chalcopyrite, have been observed singly or closely associated one with the other.In the main, the sulphide mineralisation forming the orebodies occurs as replacement of, and infilling along, the sheared bedding planes of the finely bedded shale host rock.The shales in general strike north-south with an average dip to 60° to the west; strong shearing along the bedding planes is evidenced by much slickensiding and slaty cleavage.Sequences of finely bedded shales of varying stratigraphic thicknesses alternate with very. massive beds, and it is in the more highly sheared thinner beds that the greatest concentration of sulphides occurs. The unmineraIised massive beds of shale, 11 in. up to 12 in. in thickness, occur singly or in groups between, and to a lesser extent. within, the orebodies. The massive beds resisted sulphide replacement and impart to the orebodies a most prominent banded structure.

Jan 1, 1953

By L Reynolds

The portable infrared mineral analyser (PIMA) was trialled to determine the extent and intensity of any hydrothermal alteration halo associated with gold mineralisation in the Hyde-Macraes Shear Zone (HMSZ) of the Otago Schist.   Twelve diamond drillholes through the HMSZ were analysed with the PIMA at a sample spacing of 1 m. The drillholes were selected on two traverses along the line of strike and down-dip of the mineralisation in and around Panel 2 of the Frasers underground development.   The study showed that the Hangingwall shear of the HMSZ has a more distinctive infrared signature in intersections with high grades. The Hangingwall shear in these drill holes is defined by a shift in the wavelength of the Al-OH absorption feature from ~2220 nm to <2210 nm. This shift is attributed to a change in the mineralogy from phengite to muscovite. Overprinting this trend in some of the drillholes is the presence of the 2210 nm Al-OH absorption feature, ascribed to kaolinite. Kaolinite also tends to be present in numerous other regions of the schist above the Hangingwall shear associated with steeply dipping faults and foliation parallel joints. In drill holes with low grades the Hangingwall shear does not exhibit any obvious infrared signature.   At the scale of study, the PIMA does not provide evidence for an alteration halo associated with hydrothermal mineralisation above the Hangingwall shear. Possible tectonic movement may have displaced any alteration halo that once existed, away from the zone of mineralisation. For this reason, PIMA apparently cannot be used for predicting the location of the Hangingwall shear during exploration drilling. However, the study did show that the PIMA could define the Hangingwall shear when the rocks were sufficiently altered and mineralised.

Jan 1, 2007

By I Haine, J Penm, T Waring

During 1999 there was a considerable turnaround in world prices for most minerals and energy commodities, except for the bulk commodities (coal and iron ore). The main reasons for this turnaround were: improved prospects in demand for most minerals and energy commodities in the Asian region following a return to both economic and industrial production growth in key economies in that region; continued moderate growth in demand in Europe and North America; substantial production cutbacks in a range of minerals and energy industries; effective reductions in the supply of oil by OPEC nations; and an announcement by European central banks that they would cap the amount of gold they sell and loan in the next five years. Most of these influences are expected to be sustained into the first years of the new millennium. In 2000, with exception of coal, average world prices of minerals and metals are forecast to rise significantly. Gross domestic product and industrial production is expected to grow in some European countries and most Asian countries in 2000 and, with moderate growth expected to be sustained in the United States, demand for minerals and energy is expected to increase. AustraliaÆs main bulk commodities, iron ore and coal, saw prices set for 1999 - 2000 at substantially lower levels in negotiations in early-1999. Double digit price cuts were locked in. However, similar falls appear to have been avoided for coal in Japanese Fiscal Year 2001, while increases of between four and six per cent were achieved for iron ore. Forecast modest recovery in economic growth in Japan and increasing demand elsewhere in Asia are expected to lead to tighter market conditions in 2000. Beyond 2000, world minerals and energy markets will be influenced by the expected robust global supply responses of minerals and energy companies, against a background of sustained economic growth and industrial production growth in major consuming countries. Over the medium-term, a return to declining real prices which have been evident for most commodities in the recent past, is expected as exploration, mining and processing technological change and associated productivity growth continues to reduce industry costs. While lower rates of exploration and mining investment in Australia between 1998 and 2000 will modestly constrain the rate of future industry expansion, Australia remains an important contributor to expected growth in global minerals supply over the medium-term. Australian mine production is forecast to grow between 1999 - 2000 and 2004 - 05, boosted by production from recently commissioned mines and minerals processing facilities and comissioning of other projects at advanced stages of planning.

Jan 1, 2000

By Barns K. E, Munro P. D, Brindley S. K

Ernest Henry Mining Pty Ltd started production in August 1997. The Ernest Henry orebody consists of two distinct parts, a complex supergene ore zone overlying a primary ore zone. The economic copper minerals in the supergene ore are chalcocite

Jan 1, 1998

This paper examines the broader implications of recent and ongoing changes in mineral resource managementå and reporting practices and the impact that these might have on mining companies. It is likely that an International Reporting Code will be developed in the near future, based on a number of National codes produced in recent years. However, this is only part of the reporting story, as an International Code brings with it a range of further issues to resolve. For the Code to be effective, there needs to be international recognition and perhaps licensing of Competent Persons and an expanded base of sponsoring professional bodies. Also, in an increasingly global business, shareholders, regulators and other interested parties need to know and understand the general processes involved in resource and reserve estimation and reporting in order to recognise companies that maintain the highest standards. There is a current trend towards greater scrutiny of company performance in a range of areas under the banner of corporate governance, and many changes are happening that will place greater disclosure burdens on all companies in the future. Good corporate governance means management of company assets for the benefit of the stakeholders. For a mining company, there is no greater asset than its mineral resources and reserves and directors are just as responsible for effective management of their mineral resources as they are for financial good practice. The paper looks at the relevance of corporate governance principles to mineral resource management and the changes that this could bring to the way that companies deal with regulators, shareholders, financiers and others. Finally, increased scrutiny and further regulation inevitably means greater effort by the industry and higher costs. Despite this the author believes that there are substantial offsetting benefits to be gained by companies prepared to take the initiative in improving resource management practices and communicating these improvements to shareholders. In order to achieve the benefits however, the industry needs to fully engage in the changes that are taking place û setting its own standards and working with the regulators rather than sitting back and being legislated against. Mineral resource reporting provides a good model of how this process can work and there will be other opportunities in the coming years as the industry seeks to develop best practice in mineral resource management. The author is an employee of Rio Tinto but wishes to point out that the views expressed in this paper are his own and not necessarily those of Rio Tinto.

Jan 1, 2002

By Burnett C. C H

GEMNet, (Grade Estimation using Mapping Networks), is a grade/reserve estimation software system that uses the artificial intelligence technique known as neural networks to perform reserve estimates from both two- and three-dimensional data samples from a mineral deposit. The system is the result of research carried out over the past three years into the feasibility of using neural networks for reserve estimation at the AIMS Research Unit in the Department of Mineral Resources Engineering at the University of Nottingham. This paper describes the architecture of the GEMNet system including details of the neural network components of the system. The performance of the GEMNet system is then compared to several other widely used reserve estimation techniques on two reserve estimation examples. The results produced by the GEMNet system compare favourably with more conventional estimation techniques, but require fewer assumptions to be made about the form of the data used, and do not require the use of complex mathematical modelling.

Jan 1, 1995

By Sloan GJ, Lysnar RD

Since the of Bergstrand's Geo-dimeter in 1946, and Wadley's Tellurometer in 1956, there have been numerous Electromagnetic Distance Measurement (EDM) instruments produced throughout the world by a variety of companies.This form of measurement has not merely replaced other methods of measurement, but has caused considerable change of emphasis in survey techniques. Major control surveys are now being accomplished using trilateration instead of triangulation. The surveying of open cuts or engineering work may be done in a fraction of the time and, in the majority of cases, to a greater degree of accuracy than with older methods.It is surprising that with this new tech-nology and development of EDM equipment which is compact, easy to use and no longer so expen-sive, no advance has been made in underground surveying. If we look at equipment being used by the majority of mining companies, we see that there have been very few changes since the Second World War. Very little research has been carried out to enable the surveyor to do his work more easily in conditions which, at the very least. are hazardous.

Jan 1, 1984

By Zhang S

A probabilistic approach is proposed for updating open pit slope sta- bility based on successful performance. The suggested approach is developed within the framework of Bayesian probability theory. In seeking solutions to geomechanics problems consideration must be given to inher- ent variability of shear strength parameters and to the errors in the esti- mation of these parameters. The latter can be significant and may lead to consistent overestimation or underestimation of the values derived from site investigation and testing. Conventional deterministic methods of slope stability analysis do not allow systematic modelling of uncertainties in applied loads or in shear strength parameters. Within a probabilistic framework indicators of stability may be calculated, e.g., the reliability index and the probability of failure. Based on observation of slope per- formance at any given stage of a project, the mean or the standard devi- ation (or both) of a shear strength parameter may be updated. Consequently the indicators of stability can also be updated. The appli- cation of such an approach is demonstrated by an illustrative example.

Jan 1, 1989

Fundamentally, the development of a minerals processing project is a very risky enterprise. Most mining companies do not have sufficient financial resources to undertake significant projects and hence have to undertake external financing. Indeed, most resource companies understand the high risks associated in developing their projects and therefore, wish others to share in the risks. Most merchant banks, on the other hand, are searching to find suitable resource development projects in which they can share their risk and also share a large proportion of the ærewardÆ. To resolve this issue a Feasibility Study is completed by the project developer and assessed by the merchant bank often with the assistance of an æIndependent EngineerÆ (IE) who assesses the validity of the development proposal. Generally speaking, unless the Feasibility Study has been prepared improperly, the technical aspects of most mineral projects are reasonable. Some of the more recent so-called æhigh techÆ projects are exceptions but these still do not present major technical mistakes or misconceptions. p> In most cases, the major criticism the IE presents after discussing the validity of the ore reserves focuses on production plans, capital costs and operating costs. Of these three parameters the production plan is one in which owners tend to be far too optimistic and financiers, until recent years, have not taken a position. The most critical part of the development plan is the ability of the project, as designed, to attain the required design performance and, even more critically, the ability of the owner to reach and sustain this level of production. In short, how long should the æramp-upÆ be planned to take? Financiers have become more circumspect and are now taking a more conservative view of new project performance by factoring into their project financial analysis longer periods of ramp-up, higher capital costs and higher operating costs. However, these financiers can also be part of the æproblemÆ if they become overly conservative. This paper attempts, by way of case studies available from the public arena, to identify the pitfalls the project owners can meet and possible means of avoiding the disastrous financial conundrum whereby the second or third æownerÆ is the company that reaps the rewards initially extrapolated. The paper briefly discusses this problem by referring to projects known to the author and including previous studies that looked at this very problem. It is emphasised that many of the opinions stated within the paper are strictly those of the author and could be subject of much debate.

Jan 1, 2003

By Abraham B. K, Jensen B, Gillies A. D S

The aim of the research was to investigate the feasibility of using an impedance cell and ratio-transformer bridge to measure solids content in coal slurry pipelines. It appeared that this technique could be developed to measure variations in conductance which correlate with solids content. Successful implementation of the measurement technique would have a variety of applications in existing coal wash plants and the potential for automatic process control. A small pilot plant was designed for a feasibility study. This was a closed loop system in which the coal was uniformly dispersed in a tank with a variable speed agitator and then circulated through an external pipe returning to the top of the tank. The impedance cell was located near the end of the external pipe. Slurry concentrations were varied from clean tap water to 50 per cent solids by weight with the addition of weighed quantities of dry coal dust. Ratio-transformer bridge measurements showed that variations in individual observations were equivalent to measurement errors of about two per cent. These probably reflect variations in concentration of the mixture in the pipe. Data for increments in concentration of one per cent indicate that this is about the limit of resolution of the current system. The paper discusses the principles of operation of the impedance cell and measurement system. Results from the pilot study and proposed improvements in the impedance cell design are examined.

Jan 1, 1995

New Zealand is an exposed part of a sub- continent that was detached from Australia when the Tasman Sea opened in the Late Cretaceous. The pre-separation rocks occur in three main belts. A western belt or terrane was part of Antarctica, was continuous with southern Australian rocks, and was moved eastwards in the Mid Devonian. A central belt of Hokonui and Caples rocks can be correlated broadly with the Gympie Terrane of eastern Queensland. It was an island arc, fore-arc basin and accretionary wedge system, and it was accreted to eastern Australasia in the Mid Triassic. The third belt consists of Torlesse rocks and was possibly emplaced over the Caples rocks by at least three pulses of strike-slip, in the Triassic, the Jurassic and the Cretaceous. The three episodes of strike-slip can be correlated with regional events in eastern Australia. Pre-Cainozoic New Zealand was an amalgam of terranes that had moved eastwards from south of Australia and southwards from east of Australia.

Jan 1, 1987

Hindustan Zinc Limited (HZL) is one of the leading base metal producers in India. It operates a two-smelter Complex at Visakhapatnam, Andhra Pradesh. At this zinc-lead smelter zinc is manufactured by the conventional hydrometallurgical route and lead is produced by Blast furnace technology generating residues or wastes which contain substantial quantities of metal values. Disposal of such wastes is a problem in any non-ferrous industry. Both the stringent environmental regulations and the changing industrial scenario emphasise the need for industrial research to find economically viable and environmentally friendly technologies to recover the metal values from these waste materials. The in-house R&D Centre at Vizag Zinc Smelter (VZS) thinking globally re-engineered its activities and major thrust was given for converting waste to valuable metals and metal compounds. Basic analytical chemistry with the hydrometallurgical concepts has been adopted in developing these innovative technologies. In this paper attempts are made to provide a clear history of the different waste raw material, the process developed for each raw material and their superiority of over other parallel work. Most of the processes described here are pilot plant tested and under patenting. The process flowsheet, results obtained and advantages of each process are presented. This paper provides a consolidated approach through which the varied smelter waste materials can be processed with cost effective and eco-friendly innovative technologies. In-house R&D efforts at VZS with its contribution and achievement in converting æwastes into wealthÆ technologies are presented in this paper on the following the major thrust areas:recovery of zinc from liquid effluent; recovery of zinc from effluent treatment plant (ETP) gypsum sludge; production of highly pure electrolytic zinc metal powder from zinc bearing gypsum residue/sludge generated at the effluent treatment plant; hydrometallurgical recovery of copper as copper sulphate solution which can be used for CuSO4.5H2O, copper cathode/copper metal powder from copper-cadmium cement; recovery of manganese, lead and silver from anode mud generated at Zinc Cell House and 4-metal extraction/recovery of manganese, cobalt, copper and nickel from Indian ocean bed manganese nodules; recovery of zinc, lead, silver and sulphur values from silver concentrate residue generated at the froth flotation process; recovery of silver and lead as lead-silver sponge/lead-silver sulphide concentrate from lead bearing residues; recovery of lead, silver and copper from copper matte; recovery of antimony as antimony metal or lead-antimony master alloy from antimony bearing dross; and recovery of nickel and dimethylglyoxime from Ni-DMG complex.

Jan 1, 2000

By S A. Ravishankar

An overview of flotation reagents used in sulfide and non-sulfide separations, from an industrial perspective, is given in this presentation to highlight the current applications knowledge. The historical and theoretical aspects, which are well documented in numerous books and reviews, will only be highlighted, when necessary, to support the theme of this paper, viz critical analysis of reagent research, design, selection and optimisation with an emphasis on relevance to plant needs and practice. The three types of flotation reagents; viz collectors, frothers and modifiers, used currently in the industry are briefly reviewed; pitfalls and gaps, arising from somewhat arbitrary and reductionistic practice in reagent applications, are identified; and the impact of environmental regulations on current and future reagent development is discussed. The importance of frothers and modifiers, which have received less overall attention than collectors, is highlighted. The need for a rational, holistic (or ætotal systemÆ, ætop-downÆ) approach for reagent design, selection and optimisation is discussed with a view to provide remedies for pitfalls and a platform for filling gaps in reagent chemistry and applications, and to develop reagent technology that can deliver robust solutions to plant needs. Flotation Matrix 100TM, a comprehensive package designed at Cytec to incorporate all the elements of the holistic approach û viz definition of mineralogy and plant needs, rule-based expert system rational reagent selection, and laboratory and plant best practices û will also be described.No paper available for this abstract

Jan 1, 2005

Prior to the merger of BHP and Billiton, both companies had a keenfocus on improving their performance in health, safety, environment and community (HSEC) matters. This shared intent, albeit executed insomewhat different ways, provided an excellent foundation for the newCompany. During the integration planning phase, a team was formed toconsider the organisational design for consistently achieving world class HSEC performance. The design included the policy platform, resources, structures, standards and procedures to be implemented in the merged entity. A key aspect of the design was the fully integrated HSECManagement Standards. These Standards create the framework for theconsistent application of BHP BillitonÆs HSEC Policy at all of ourmanaged operations across the world. The Standards have their origin in similar frameworks adopted by BHP during the 1990s, as well as thewell-known quality related standards (eg ISO 14001). However, they areunique in that they combine all aspects of HSEC management into asingle integrated set of auditable standards. By combining these areas and integrating our HSEC Management Standards with other aspects of the æBHP Billiton WayÆ, we are establishing a holistic, line management driven improvement approach. Over time, the BHP Billiton Way will embed a systematic improvement philosophy that we expect will become a key source of competitive advantage. The HSEC Management Standards are consistent with ISO 14001,OHSAS 18001, the Australian Minerals Industry Code for EnvironmentalManagement and generally aligned with SA8000. While compliance withthese external standards ensures that a systematic approach andimprovement plans are in place, BHP BillitonÆs HSEC Standards gofurther to include minimum performance requirements that reflect theintent of our HSEC Policy. Therefore, implementation at site levelensures that robust systems are in place to implement our Policy and that accreditation can be achieved to external standards if required.To assess implementation of the HSEC Management Standards anaudit system has been designed which incorporates both self-assessmentand peer review. Each site is required to undertake an annualself-assessment of compliance with the Standards using a commonassessment protocol. Every three years a peer review is conducted at each site to confirm the results of self-assessment and to provide a means of sharing knowledge throughout the Company. The review teams are composed of line managers and HSEC professionals from around theCompany, representatives of our joint venture partners and independentspecialists as required. The Company has committed to public reportingof the audit results through our annual HSEC report and this is reflected in our published targets. From a wider perspective, as we in the resources industry strive tocollectively raise our HSEC performance and reputation, there may be arole for industry based HSEC Management Standards complemented bya level of independent review.

Jan 1, 2002

By F A. Roddick, C Swaminathan

As remaining gold deposits tend to become more refractory, some form of oxidative pre-treatment involving hydro or pyrometallurgy is necessary to maintain high metal recoveries. These pre-treatments include pressure oxidation, bio-leaching or roasting. In the past, the primary criterion for selection of oxidative pre-treatment relied mainly on the extent of gold recovery and relative economics. In this study, a different approach has been adopted, ie the quantitative determination of environmental performance of the oxidative pre-treatment processes bio-leaching, roasting and pressure oxidation to assess which had the least impact on the environment. By establishing the environmental performance of processes, waste minimisation can be addressed early in process selection. Using mass balances, the environmental theme method was applied to determine the performance, on the basis of gold treated, of the oxidative pre-treatment processes of selected plants. No clear trend was observed in the overall impacts of each of seven plants, with all but one of the environmental evaluation indices being of the same order of magnitude; this was probably due to masking effects arising from the large variations in feed composition, tonnage, and gold levels. Within each type of pre-oxidation plant however, certain trends were detectable. For instance, irrespective of plant size, ore composition or mineralogy, for the bio-leaching and pressure oxidation units, the general order of environmental impact from greatest to least was sequentially toxicity, acidification potential, depletion of resources, solid waste generation and greenhouse enhancement. For the roasters the acidification potential was the most significant. Determination of the environmental performance of the oxidative pre-treatment of a hypothetical ore in a plant of fixed tonnage was undertaken to remove the possible masking effects of variables associated with feeds of different mineralogy, gold tenor and tonnage. The bio-leaching process gave a marginally better performance than pressure oxidation, the roasting process the worst, although there was not a great difference between them. The decreasing order of contribution to the environmental index was acidification potential, toxicity, resource depletion, solid waste generation and greenhouse enhancement for bio-leaching and pressure oxidation; whereas it was acidification potential, solid waste generation, toxicity, resource depletion and greenhouse enhancement for roasting. Since the major contributor to the environmental index was the acidification potential, the environmental performance of treatment processes for the acidic effluents was calculated. After neutralisation of the net acid resulting from bio-oxidation and pressure oxidation, and the application of various scrubbing and product formation processes for the sulphur dioxide from the roasting process, it was shown that pressure oxidation gave a marginally better performance than bio-leaching, ahead of roasting. This study demonstrated the potential for the development of a predictive tool which could be used in determining the environmental performance, and thus the selection, optimisation, and improvement of pre-oxidation processes for least impact on the environment. These would allow operation of these processes within defined environmental performance limits and decisions regarding the desirability of processing various parts of a heterogeneous orebody to be made on environmental grounds.

Jan 1, 2000

By OÆBrien D, Priddle D

In order to avoid costly moisture penalties on coal shipments and to minimise rail freight costs, screen bowl centrifuges were selected and installed in the Mount Thorley Coal Preparation Plant for dewatering fine coal product. The Mount Thorley fine coal circuit consists of desliming the -0.5 mm (ww) fine coal in two stages of classifying cyclones prior to recovery by froth flotation. Provision has been made to bypass the flotation circuit with the classified flotation feed reporting directly to product and the centrifuge dewatering circuit has been designed to handle either flotation feed or flotation product. Major mechanical failures of the gearboxes and the ceramic tiling occurred early in the operation life of the machines which led to design changes being made to achieve satisfactory operation. This paper discusses the operating experience at Mount Thorley with respect to both mechanical and metallurgical performance of the screen bowl centrifuges since their installation in 1985.

Jan 1, 1989

By Espinosa-Gomez R, Johnson NW

The Copper Concentrator at Mount Isa Mines Limited treats on average 18 000 tonnes/day of chalcopyrite ore containing typically three per cent copper. The main gangue minerals are iron sulphides (-13 per cent) and non sulphide gangue (-78 per cent). In August, 1991, the comminution flowsheet was changed from a conventional circuit (crusher/rod mill/two stage ball milling) to a modem circuit (fully autogenous grinding/one stage ball milling). The 80 per cent passing size of the flotation feed with the conventional circuit was 125 microns. The Copper Concentrator has two parallel grinding lines, two roughing and scavenging flotation lines, and common cleaning, recleaning and retreatment sections. During the first six weeks of the installation phase, one of the two flotation lines was fed by the conventional grinding circuit and the other by the autogenous grinding circuit. Data from parallel surveys and historical data are used to analyse the rougher/scavenger flotation performance before and after the change. The solid and mineral distributions of the flotation feed, the pulp chemistry and the reagent requirements are compared. The mineral liberation before and after the installation of autogenous grinding is compared on a sized basis using data from the 14 consecutive months before, and the seven months after the change. Liberation was measured using the QEM*SEM(*) instrument. The overall effect of the new grinding circuit on the plant metallurgy is also assessed using the copper recovery values, the dilution of the final concentrate and the distribution of copper losses in the final tailings. (*) Quantitative Evaluation of Materials by Scanning Electron Microscopy

Jan 1, 1993

The explosion of a charge in a drillhole sets the surrounding rock mass into vibrating stress wave motion. Except in the immediate vicinity of the drillhole, the dynamic stresses associated with this motion do damage only to pre-existing joints, cracks, or other weak planes, not to the rock material in between these. The joints are weak in tension, therefore the damage occurs as a result of tensile stresses. The initial damage process in the rock mass that ultimately breaks loose in front of the hole is similar to that in the remaining rock behind the drillhole. Recorded or calculated values of the vibration velocity and frequency contain a wealth of information about the combination of stress and strain that causes the damage. This paper outlines a new technique by which the peak strain energy derived from measured or calculated vibration velocity records is used to determine the local fragment size distribution. It combines two previously known and well tested techniques, namely the Holmberg-Persson calculation of the peak vibration velocity generated by an extended charge and King's calculations of the fragment size distribution as a function of the strain energy in rock crushing. Both of these calculations are based on experimental data and have been tested and found to agree well with actual conditions in their respective fields. Holmberg-Persson's calculated peak vibration velocities have been used successfully to predict and control damage to the remaining rock in cautious blasting, while King's calculation successfully describes the comminution of rock in mechanical crushing. Preliminary predictions of fragmentation in two types of rock blasting, a large hole open pit mining blast and a tunnel round, indicate that the new technique for fragmentation prediction has the potential for predicting fragment size distributions within the rock removed by the Blast.

Jan 1, 1995

Ferromanganese metasediments in the immediate vicinity of the Mid-Proterozoic Broken Hill Pb-Zn-Ag lodes, have undergone high grade (upper amphibolite facies) metamorphism,to form Mn-pyroxenoid (rhodonite,pyroxmangite) and garnet-rich lithologies. Such lithologies bear compositional (bulk rock,rare earth element)and morphological similarities to recent and ancient ferromanganese hydrothermal sediments of the Pacific.The non-metasomatic,stratiform garnetites are predominantly composed of magnesia-rich, calcium-poor almandine spessartine and quartz, which possess a bulk chemistry comparable to alumina-rich ferrommanganese oxide deposits of the Pacific. Such sediments are attributed to a mixed protolith comprised of clay and ferro-manganese oxides (mainly amorphous goethite with lesser todorockite-birnessite). Manganiferous pyroxenoid rocks are probably derived from alumina-poor ferromanganese cherts,similar to Japanese tetsusekiei.Rare earth element compositions ofBroken Hill garnetites are very similar to those of recent ferromanganese seafloor accumulations, suggestive of some genetic link.

Jan 1, 1990

By Laajalehto K

The basic condition necessary for flotation is hydrophobicity of the surface of the mineral to be floated. For sulphides, this condition usually requires treatment with a collector solution. The conditions for this treatment have until recently usually been chosen by the trial and error principle which has indeed been working relatively well under favourable conditions; ie for simple homogeneous ores. However, the present tendency to increasing use of complex and often relatively lean ores sets increasing requirements for the control of the flotation process. This development is the reason for the present rapid development of process control methods in flotation. In addition to the already well-established practices of pH and reagent feed controls, the importance of measuring and controlling the electrochemical potential of the ore particles to be floated is recognised in the case of sufficiently conductive minerals. In fact, the electrochemical potential seems to be the basic quantity determining the flotation behaviour of such relatively well-conducting minerals as sulphides. Since the hydrophobicity of the mineral and, hence, its flotation properties are ultimately determined by the composition and structure of its surface, information on these under different process conditions is important for design and operation of efficient flotation processes. The basic requirement set for the methods used for obtaining this information is high surface sensitivity of the method. The recent rapid development of surface characterisation has produced several methods which fulfil this requirement. Their application to the problem of characterising surfaces of mineral samples in contact with collector solution is, however, often complicated. The main reason for this is the vacuum environment necessary for the measurement. In the case of flotation experiments this means that in most of these methods the measurement cannot be made in situ, but the sample must be extracted from the liquid and subsequently evacuated in the vacuum chamber of the instrument. It is essential to carry out these steps so as to avoid to the extent possible changes in the sample surface. For the purpose of establishing whether this has been accomplished it is important to compare the results of methods operating in vacuum with some available in situ method. An optimal choice of methods seems therefore to be a combination of the available powerful vacuum methods with in situ measurements. The most usual combination seems to be X-ray photoelectron spectroscopy (XPS or ESCA), Fourier transform infrared spectroscopy (FTIR) and electrochemical measurements. This choice combines the unique possibilities for direct elemental and chemical characterisation offered by XPS (Cecile, 1985) with the in situ capability of FTIR and electrochemistry. In the XPS measurements, it is essential to apply a special sample handling technique to avoid loss or damage of some sensitive species of the collector-based layer on the mineral surface. In the following will be given some examples of the application of the XPS technique in combination with electrochemical methods of sample treatment to studies of the layer formed on sulphide substrates in ethyl xanthate (EX)

Jan 1, 1993