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By J H. Kyle

Cyanide is a significant cost in gold processing, as well as an environmentally sensitive issue. It has been suggested that precipitation of cyanide from leach liquors as copper-iron-cyanide compounds such as Cu2Fe(CN)6 may account for part of the total cyanide consumption. This may be especially true for ores that are rich in both copper and iron minerals. Ammonia addition has been shown to decrease the cyanide consumption by copper. Cu2Fe(CN)6.xNH3 precipitates have also been postulated to form during conventional cyanide detoxification processes, using oxidants such as SO2/air, with ammonia arising as a breakdown product from the oxidation of free cyanide. The present work has examined the conditions under which such precipitates may form, particularly in gold plant process and detoxification liquors. Ammonia and pH were found to have a large effect on the extent of precipitation. The compounds that were formed were found to comprise mainly Cu2Fe(CN)6.7H2O, as well as a range of NH3-bearing variants. The stabilities of the various precipitates are important from an environmental perspective. The long-term stability of copper ferrocyanide precipitates in tailings dams may be a problem under alkaline conditions and when some free cyanide is present, elevating the measured total cyanide in solution significantly. Case studies including data from actual plants are also considered, and the importance of these effects is reaffirmed from these results.

Jan 1, 2000

By Kinsella B

Titrimetric studies have been carried out on the activated carbons Kintal 1105, Norit 2520 and Kuraray 2GA. Titration curves of the carbons before and after acid and water washing and gold loading indicate that the acid-base properties of the carbons are affected by both the method of treatment and also by the loading of gold. It is considered that the pKa values of the functional groups on the carbon surface are in the regions of 11, 7 and 3 respectively.

Jan 1, 1984

By Woodcock JT

This paper deals with some innovations and current proposals for the treatment of gold ores and considers the possibilities of incorporating new developments in new or revised ore treatment flowsheets. The main topics considered are I. typical practice in relation to the size of gold particles, 2. concentration of coarse gold, 3. leaching reagents, 4. in situ leaching, 5. heap leaching, 6. carbon-in-pulp adsorption, and 7. treatment of complex ores (gold in pyrite, gold tellurides, and carbon-containing ores).

Jan 1, 1982

By Till M, McGee WA

The Hermit Islands are situated at 145¦ E 1 30'S in the Bismarck Sea approximately 200km WNW of Manus Island. They are dominated by basalt flows, one of which yielded a K/Ar isotopic date of 3.4 + 0.05Ma. All basalts examined were olivine-bearing, but one sample also contained hornblende. Although many outcrops were weathered, no evidence of pervasive hydrothermal alteration was observed on any islands and non-weathered rocks are petrographically fresh and many retain glass.

Jan 1, 1990

About 11,000 tons of contaminated zinc flotation concentrate were available in the form of earth walls from dams used for atmospheric drying of the concentrate.Following successful laboratory tests this material was treated in a plant by crushing, grinding, and then flotation in a circuit consisting of roughing, scavenging, and two stages of cleaning. Reagents used were copper sulphate and a little butyl xanthate and frother. About 5,720 tons of zinc concentrate assaying 52· 3 per cent zinc were produced.

Jan 1, 1968

By Polthier K

A short discussion of the salient aspects of a dispersed flow model in relation to the gas flow in blast furnaces is given. The use of the theory in assessing vessel performance is mentioned. Tracer results of a blast furnace (688 m3) from three furnace levels and different radial positions are analysed and results presented as D/ud values. The significance of the shapes of experimental tracer curves are included and comparison is made with results obtained on other furnaces.

Jan 1, 1975

One of the often overlooked factors affecting the capital investment decision in new or existing plants is the value of stock holdings necessary to maintain the plant. This paper puts forward a simple decision matrix on whether a part should be stocked depending on 1. the criticality of the item of equipment in terms of the effect on cash flow of its failure, 2. the lead time of the part, and 3. the stock holding value if it were Stocked.

Jan 1, 1986

By J Lane, D J. Barker, B Pei

Queensland Alumina Limited (QAL) is the worldÆs largest producer of smelter grade alumina, located in Gladstone, Queensland, Australia. The plant employs evaporative cooling towers for waste heat rejection. Process water requirements include red mud residue disposal, steam venting to the atmosphere and Calcination feed moisture. Raw (untreated) water consumption in 2001 was 37 700 m3/d or 3.8 m3 per tonne of production. The Gladstone region experienced a water shortage in the period 2001 to 2003, resulting in progressive water restrictions. Industry operated under a ten per cent restriction from April 2002 and in November 2002 a 25 per cent restriction came in force. The maximum restriction level of 50 per cent was anticipated for the middle of 2003. Water restrictions of these magnitudes have the potential to result in significant production limitations, which would have major economic consequences for QALÆs owners, customers, suppliers and employees. Therefore it was imperative that measures be found to mitigate the impact of these restrictions. Furthermore, as one of the largest water users in the Gladstone region, QAL had an obligation to the community to minimise water usage as much as possible. A thorough analysis of water usage on site was conducted, focussing on all water streams leaving the plant. The philosophy used was that by minimising water outputs, the inputs would follow suit. Where possible, preference was given to solutions that provided lasting water savings. This occurs when the value of the water saving justifies the project cost, irrespective of water restrictions. By June 2002 an average water saving of 19 per cent was achieved, almost double the required saving. By end November 2002 further projects had increased the total water saving to 29 per cent, mainly through the re-use of GladstoneÆs municipal treated effluent as wash water. Further measures to reach the target of 50 per cent reduction were investigated. The evaporative cooling system was to be replaced with seawater cooling, using cooling towers to minimise the seawater pumping cost. Another benefit of this concept was the ability to dispose of the cooling tower bleed stream with the existing system for neutralised red mud disposal. This would avoid the need for an additional environmental outfall from the plant. In February 2003 the Gladstone region received over 500 mm of rain, which boosted water reserves to five years supply at forecast usage rates. This led to the lifting of all water restriction. As most of the implemented water savings measures are economically viable in the absence of water restrictions, raw water usage at QAL is still less than 75 per cent of pre-2002 levels.

Jan 1, 2003

By Bhaskara Sarma P V R

Solvent extraction of cobalt from an ammoniacal ammonium sulphate medium was carried out using Di(2-Ethyl Hexyl) phosphoric acid in kerosene as diluent. The effect of ammonium chloride and ammonium sulphate on the extraction efficiency was studied. The extracted species in the ammonium chloride and sulphate systems were CoAz2HA.NH4CI and CoA3.HA.2(NH4)2SO4, respectively. Ammonia scrubbing and cobalt stripping studies were carried out from loaded and ammonia free organic Respectively.

Jan 1, 1992

Operation of a pilot heavy medium separation plant allows flexibility of operation not normally possible in an operating plant. Much useful data can be obtained, although some limitations apply. Projects carried out at AMDEL have included HMC separations at 1.5 to 3.6 specific gravity, comparative operation of HMC and DWP separators and the use of fine feed and product screens. Investigations of this type have provided a considerable amount of information on HMS plant performance and characteristics under a wide range of operating conditions.

Jan 1, 1987

Historical exploration of the Ballarat East goldfield defined two primary quartz vein lode types. Tracking the intersection of these lodes with vertical lines of enrichment (or so-called æindicatorsÆ) was the basic practice for historical mining. This strategy proved highly successful in terms of identifying quartz veins associated with mineralisation. However, it provides little understanding of the timing or processes involved in the formation of these veins, or the associated emplacement of gold. Current underground mapping shows the Ballarat East gold deposit can be subdivided into four stages of vein formation. The earliest veins (V1 and V2) strike north-south and formed during bedding flexural slip and limb thrust fault propagation in parasitic chevron folds. V3 veins are subhorizontal and relate to further fold tightening involving a transition from east-west compression to north-south extension that initiated re-shear of bedded slip surfaces and additional strike-slip faults. Sporadic V4 veins overprint the shallow-dipping sections of V2 and V3 veins and are associated with weak north-south compression. The V4 veins mineralogy is distinguished by a high carbonate content and sphalerite-galena sulfide assemblage. Vein sampling indicates a significant increase in gold mineralisation where overprinting by the later deformation/veining has occurred. As a result of these observations, a new model is emerging that identifies the chronology, structural control and spatial distribution of respective quartz vein types. This is a major advance in terms of exploration targeting, resource modelling and mine planning.

Jan 1, 2008

Sample preparation for gold samples, where the distribution and size of gold particles is often irregular, usually demands that a relatively large sample weight is taken to produce a representative sample for analysis. Traditional sample preparation of gold samples incorporated multiple stages of coarse particle size reduction followed by subdivision of the sample prior to final fine pulverising. This technique developed because of the limited equipment options available to laboratories. As a result significant errors are introduced and the final sample size being pulverised is a small fraction of the original sample weight. Three significant developments have occurred in the last 25 years to significantly improve sample preparation of gold samples: 1.  large capacity fine pulverising,2.  fine jaw crushing, and3.  whole sample coarse pulverising. In the mid-1980s an Australian manufacturer developed large capacity pulverising bowls which had the ability to reduce samples with a mass of 1.5 - 3.5 kg to a nominal 0.075 mm product in approximately three to five minutes. Laboratories were able to produce a large homogeneous pulverised sample which significantly reduced the error in sampling. However, exploration and mine samples are usually 7 to 10 kg and the sample requires a subdivision stage following crushing to produce the 3.5 kg for the pulverising step, thus introducing potential for significant error. The development of fine jaw crushing allowed particle size reduction to -2 mm which reduced the subdivision error of the bulk sample prior to fine pulverising. Subdivision of the crushed sample at -2 mm still results in potential sampling errors, where the gold particles are not sufficiently liberated to be representatively sampled. Clearly the best option would be to reduce the particle size small enough to ensure a representative sample prior to final pulverising. Continuous mills offer a partial solution but are relatively slow and subject the sample to differential pulverising prior to subdivision. Clearly this does not provide the best solution for routine laboratory applications where high volumes of samples are to be processed. The recent development of a large capacity coarse pulverising system allows samples of up to 10 kg to be reduced to -0.25 mm prior to subdivision, and fine pulverised to -0.075 mm. Laboratories now have the necessary equipment to perform reliable large capacity sample preparation of gold samples. The exact choice of a sample preparation scheme may still depend on particular ore types but the need for multiple crushing and subdivision stages is redundant.

Jan 1, 2008

By C V. Putnis, T Geisler, A Putnis

In nature, ilmenite (FeTiO3) undergoes weathering through oxidation and removal of Fe to form an apparently continuous series of compositions from ilmenite to pseudorutile (ideally Fe2Ti3O9), and with further weathering, to leucoxene. To determine the mechanism of acid-leaching of ilmenite to ultimately form rutile, we have carried out an experimental study of ilmenite alteration in autoclaves at 150¦C in HCl solutions. Resulting products were studied by X-ray diffraction, scanning electron microscopy, electron microprobe and Raman spectroscopy. In some experiments the solution was initially enriched in 18O and the distribution of the isotope in the alteration products mapped from the peak shift in the Raman spectra. The results indicate that the alteration may proceed in two stages, each with a sharp interface between the parent phase and the product. The alteration begins at the original ilmenite crystal surface and along cracks through which the fluid can migrate. The first alteration product is pseudorutile û no phases intermediate between ilmenite and pseudorutile were detected. The textural relationship between ilmenite and pseudorutile suggests a coupled dissolution-reprecipitation mechanism rather than a solid state continuous oxidation and Fe diffusion mechanism. The second stage involves a further dissolution-reprecipitation step to form rutile. Raman spectroscopy shows that the 18O is incorporated in the rutile during the recrystallisation. Throughout the alteration process the original morphology of the ilmenite is preserved although the product is highly porous. The rutile inherits crystallographic information from the parent ilmenite, resulting in a triply-twinned rutile microstructure.

Jan 1, 2008

By Nilmani M, Fountain CR

Injection of gases into slag-melt mixtures produces various zones as a result of bubble formation and disintegration within the melt. The extent of these zones depends on the type of reactor used. When compared with ferrous processes, non ferrous processes are character- ised by large bubbles formed adjacent to the tuyeres, low flowrates and shallow tuyere sub- mergence. These features can result in a greater proportion of reaction occurring above the bath, more refractory wear and tuyere blockage with more splashing. The large bubble zone adjacent to the tuyeres has been investigated using the tech- niques of physical modelling, mathematical modelling and plant trials. Large bubble form- ation in physical models was recorded using a high speed camera and a rapid response pressure transducer coupled to an oscilloscope and data recorder. It was found that the bubble volume (Vb) could be correlated at low flowrates using the single bubble model Vb = 1.378 Q6/5 g-3/5 Deviations from this correlation occurred with increasing gas jet momentum. Plant trials were carried out on a copper converter at Mount Isa Mines during five different charges. Pressure measurements were made through the tuyeres during the slag blow and commencement of the copper blow. The power spectrum density showed that the dominant pulse amplitude occurred at a frequency of approximately 3 pulses/sec. Plant data from this and other converters were correlated using the same relationship as for physical modelling. De- viations occurred due to the state of the re- fractory, bath composition or bath circulation effects.

Jan 1, 1984

Opening AddressThank you for inviting me here today to open what promises to be a significant conference on the technological aspects of extractive metallurgy. I would especially like. to welcome delegates who have travelled great distances in order to contribute to, and be participants in, this examination of the technical innovations which have always been a crucial part of our industry.

Jan 1, 1992

By M Heidari, M Ataei

Today, the selection of a mining method is a multi-criteria decisionmaking process, with many factors in this process connected to each other. These trends do not have a high degree of confidence. In this study the analytical hierarchy process was used to select the suitable mining method for anomaly No 3 of Gol-Gohar iron mine of Iran. The results of this study show that gathering all existing information from the exploration stages and using AHP technique, the open pit mining method is the mining method for this anomaly.

Jan 1, 2003

By Smitham J. B, Keast-Jones R

Six Australian coals were selected to determine their potential to produce, ultra low ash (less than 2 per cent) coal by progressive size reduction followed by density separation and/or froth flotation. Density separation in organic liquids is effective in the absence of contaminating liberated mineral matter which can be removed by froth flotation with several cleaning stages. The limit of cleaning of these coals was an ash value of 1 per cent while commercially attractive yields were obtained at 2 - 3 per cent ash depending on the coal.

Jan 1, 1987

By Brimblecombe P

Morwell Open Cut is a continuous mining operation employing 5 buck- etwheel excavators, I bucket chain excavator and 54 conveyors. The combined bunkering capacity at both client Power Stations represents less than 12 hours maximum coal demand. This creates an extremely dynamic operating environment, which is further complicated with significant variations in both excavating and transportation plant capabilities. To achieve set objectives, including- I adequate reserves, 2 coal supply reliability, 3 cyclic plant maintenance, 4 minimal cost of coal, scheduling of the operation requires constant monitoring and reappraisal.

Jan 1, 1989

By Scott IA, Jefferson C, Dipasquale S

This paper describes the use of modelling and simulation techniques in the analysis of the heavy medium plant at the Lead/Zinc Concentrator of Mount Isa Mines Limited. The objective of the study is to determine how to increase heavy medium plant recovery at a higher than current rejection rate in order to achieve the desired throughput through the grinding and flotation sections of the concentrator. Three options were considered: 1. Install smaller aperture preparation on screen to enable the cyclones to be fed finer materials. Install smaller diameter cyclones. 3. Maintain low viscosity medium.

Jan 1, 1987

By Groudeva VI

The biohydrometallurgy of gold is based on different processes which could be grouped into four main groups (Attia, Litchfield and Vaaler, 1985; Karavaiko et al, 1988; Groudev, 1990): 1. bacterial oxidation of gold-bearing sulphide minerals by chemolithotrophic bacteria to facilitate the subsequent chemical extraction of gold; 2. solubilisation of gold from oxide ores by means of heterotrophic bacteria; 3. recovery of gold from solutions by biosorption; and 4. microbial modifications of the surface of gold-bearing sulphide minerals to improve the subsequent gold concentration by physical dressing methods (eg flotation, oil agglomeration).

Jan 1, 1993