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US 4,194,902 - Pig iron or other molten lion is effectlvely desulfurized by treatment with a mixture preferably about 60% by weight commercial grade calcium carbide, 30% dried limestone diamide, and the remainder bituminous coal. Equivalent desulfurization is obtained using a significantly lesser amount of desulfurizer than in previous mixture of calcium carbide and limestone diamide W Gmohling, assigned to SKW Trostberg AG. Mar 25, 1980. 3 pp. (75-55) Filed: 9-12-78 (941,659) Priority. West Germany, 9-15-77 (2,741,588). Same. British 2,008,153, dated May 31, 1979.

Jan 1, 1982

NORTH AMERICA ALASKA Anchorage.-Culver, H. W. Geehan, R. W. Strandberg, H. Chicagof.-Russell, J. C. Tracy, Q. S. College.-Dorsh, J. B. Fox, E. F. Joesting, H. R. Smith, M. C. Wilcox, H. G. Douglas.-Cahill. W. E. Fairbanks.-Adams, J. M. Barber, R. J. Beistline, E. H. Crawford, J. D. Doheny, L. C. Earling. R. B. Greves, J. H. Harris. Q. P., Jr. Henton. H. M. Herbert, C. F. Nester, W. B. Hopkins, J. E. CANADA ALBERTA Calgary.-Allen, R. E. deHart, J. B. Dunn, W. Gray, J. G. Johnson. R. V. Link, T. A. Slipper. S. E. Soul, N. Thorne, B. L. Thorne, H. L. Edmonton.-Ball, M. W. Lilge, E. O. Pitcher, N. C. Nordegg.-Shanks, J. Turner Valley.¬MacKenzie, W. D. C.

Jan 1, 1941

By F. M. Lewis, J. F. Meyers

This second progress report of grinding presents comments regarding ball consumption and data pertaining to the hydroscillator, which is closed circuited with the tricone mill. A study and postulate of how balls function is presented. The paper summarizes cost reduction obtained by the method of "grinding for the tail race" rather than for "mesh tons." AT the Regional meeting in Columbus, Ohio, in September 1949, the authors presented a progress report of the first year's operation with a Hardinge tricone mill in closed circuit with a Dorr hydroscillator. The present report covers our findings on this grinding circuit to January, 1950. In order to clarify our position, the authors wish to state that no invention or discovery is claimed. The Tennessee grinding circuit is simply an engineered arrangement of known equipment arranged to incorporate all of the recognized efficiency factors of comminution as they are known today. As we concluded our first report, it was not clear how effective the Tennessee mode of operation would be on harder ores. The only information we had at that time was that the Bond grindability test at 48-mesh gave 6.04 g of undersize per revolution. A later test on the same sample at 100-mesh reduced this to 2.04 g, which is definitely in the harder ore class, and which makes the reported 8.80 kw-hr per ton of —200-mesh produced a very creditable figure. Hydroscillator Operation The machine as now developed has proved dependable and easy to operate. It starts easily under full load and responds quickly to operating adjustments. The hydraulic holes in the oscillating plate do not plug when shut down under full load. Absolutely clean hydraulic water is essential. An Elliott water screen or similar device should be an essential part of the machine to keep all scale and trash of all kinds from the hydraulic compartment. The shift operators have expressed approval of the machine. In table I we show a typical screen analysis of the hydroscillator rake sand as compared to conventional classifier rake sand on our ore. We have previously reported that of the 28.7 pct reduction in power, the hydroscillator contributed 6 pct, on a —200-mesh basis. This is a conservative figure. Some of our test runs indicated that the saving was as high as 10 pct. Laboratory studies by the Dorr Co. engineers indicate that still greater efficiency is possible. Nevertheless, the 10-ft plate is overflowing 2100 tons per day at 3 to 4 pct + 65-mesh, which is a very creditable performance by

Jan 1, 1951

By George A. Laird

I. INTRODUCTION. THIS old and once famous district played, through its enormous production of silver and gold, an important part in the history of the State of San Luis Potosi. According to a pamphlet prepared under the direction of the Governor of the State, Sr. Don Blas Escontria, and presented to the visiting members of the Institute during the Mexican meeting of 1901, this district is situated 20 km. east of the city of San Luis Potosi, in a range of mountains of moderate height, extending 135 km. N. and S., and 16 km. E. and W.; and the mineralized area hitherto developed is about 600,000 sq. m. The history of the district,. as given by the record dated 1778, and formerly kept in the San Francisco convent, says that it was discovered in 1575 by Sr. Don Pedro Irarte, and adds that the city of San Luis Rey de Francisco del Potosi received its name (in allusion to the famous Potosi mines in Bolivia) by reason of the remarkable productiveness of its gold- and silver-mines in the first period of their exploration, during which they paid to the Crown, as " quintos " (the fifth part of the product), $97,000,000, as appears from the accounts of the royal treasury. The amount of the quientos paid during the " bonanza period " of 80 years was $72,000,000. The larger sum first mentioned probably represents a longer series of years. But either will suffice to indicate the great wealth of the mines. In 1663, the decadence of the industry began with the caving¬ in of several mines, concerning which the record of 1778, al¬ready cited, says, in substance, that on Good Friday one of the owners in the enterprise, in view of the unfavorable prospect of a lawsuit in which he was engaged, set fire to the timbers supporting the underground galleries and workings of the San

Jan 1, 1905

THE strike and dip of bedded formations is readily determined by trigonometry if some marker horizon is intercepted by three holes. If no marker can be identified and if orientation of the cores is unknown, as is the usual case in diamond drilling, the determination still can be made readily by the use of a stereonet if the bearing, inclination, and angle the bedding makes with the core axis is known for each of the three holes. Such determination, valid only if the bedding orientation is fairly uniform within the area drilled, is considered simpler, faster, and more effective than any solution previously published. Method: The steps of this procedure are as follows: 1) Mark north and south poles on tracing paper placed over stereonet.* 2) Plot the three diamond drillholes by drawing a line from the center of the net in the direction of the bearings of the holes. Then rotate the paper until each line, in turn, lies along the equatorial diameter of the net; the end of each line is determined by the inclination of the hole measured in degrees from the periphery toward the center of the net along the equatorial diameter. Fig. 1 illustrates a vertical hole and a hole inclined at —23" due east. 3) With the projection of one diamond drillhole along the equatorial diameter, measure from the end of the hole, to the east and then to the west, a dis- tance in degrees equal to the core axis-bedding plane angle. Find two more points by measuring the same number of degrees north then south along the great circle from the end of the drillhole. Draw a circle, the center somewhere along the direction of the projection of the drillhole, to connect these four points. Draw circles for the other two diamond drillholes in the same manner. See Fig. 1 for two circles representing core axis-bedding plane angles of 35" and 23" and Fig. 2 for these plus a third circle representing a core axis-bedding angle of 42" in a hole bearing S 50 W inclined at —52". 4) Rotate the tracing paper until one great circle on the stereonet is found which is tangent to all three of the circles or parts of circles derived in the previous step. Trace this great circle on the paper and join its ends with a straight line passing through the center of the net. The bearing of this line is the strike of the bedding. In Fig. 2 the bedding strikes N 77 E. 5) Rotate the paper until the strike is along the polar diameter of the net. The dip of the bedding is determined by measuring along the equatorial diameter the distance in degrees from the periphery of the net to the great circle derived in step 4. The dip of plane illustrated in Fig. 2 is 55" to the N 13 W. Fig. 3 indicates the solution for three holes whose bearings and inclinations are N 20 W and —43o, due E and —30°, S 30 W and 23" with core axis-bedding angles of 30°, 50°, and 43" respectively. The bedding (stippled area) strikes N 44 W and dips 70" to the southwest.

Jan 1, 1956

By W. F. Durfee

In the year 1862 the author of this paper was called upon to design and superintend the erection and working of the machinery of an experimental works for the production of steel by a process

Jan 1, 1884

By AIME AIME

COMMITTEES. LOCAL COMMITTEE.-R. C. Crawford, Chairman; Harrison W. Craver, Secretary; Julian Kennedy, Taylor Allderdice, E. W. Pargny, Charles L. Miller, W. H. Rea, S. A. Taylor, M. E. Wadsworth, W. A1. Henderon, A. C. Dinkey, W. L, Jones, E. L. Messier, George Mesta, J. H. Jones, G. H. Riley, S. L. Goodale, D. W. McNaugher. LADIES' COMMITTEE.-Mrs. Taylor Allderdice, Chairman; Mrs. Julian Kennedy, Mr. R. C. Crawford, Mrs. E. M. Herr, Airs. J. W. Marsh, Mrs. T. A. Mellon, Mrs. G. P. Bassett, Jr., Airs. D. M. Clemson, Mr. Charles L. Miller, Mrs. V. L. P. Shriver, Mrs. W. A. Bostwick, Mrs. A. C.. Dinkey, Mrs. A. P. Childs, Jr., Mrs. F. R. Dravo, Mrs. Hermon Griffin, Mrs. W. H. Nimmick, Mrs. F. H. Lloyd, Mrs. S. G. Cooper, Mrs. S. H. Church, Mrs. E. N. Ohl. The Institute Headquarters was established at the Hotel Schenley, where a bureau of information was maintained for the benefit of the visiting members and guests of the party during the time of the meeting. TECHNICAL SESSIONS. The first session, held Tuesday evening, Mar. 1, 1910, in the large lecture hall of the Carnegie Institute, was called to order by Harrison W. Craver, Secretary of the Local Committee. Mr. Craver introduced Dr. John A. Brashear, who extended to the members and guests a hearty welcome to the city of Pittsburg, to which David W. Brunton, President of the Institute, responded. The following papers were presented in oral abstract by the authors: Biographical Notice of Dr. Charles B. Dudley, by Dr. R. W. Raymond, New York, N. Y. Biographical Notice of William Metcalf, by Col. II. P. Bope, Pittsburg, Pa. Development of Hindered Settling Apparatus, by Robert H. Richards, Boston, Mass. (Illustrated by lantern-slides.) A Few Mining Districts in the Argentine Republic, South America, by Z. S. Beyl. (Illustrated by lantern. slides.)

Apr 1, 1910

(This list. includes only those who have entered military service within the past month, or whose entry has only recently become known to us; it also includes a few names of those whose titles or assignments have been changed within the month. A complete list will he found in the Year Book mailed with this Bulletin. Another Honor Roll is maintained in the reception room of the Institute.) ALDEN, HERBERT W., Lieutenant-Colonel, Ordnance Dept. ALDER, ALFRED; Engineers' Reserve Corps. ALFORD, NEWELL G., Sergeant, Bureau of War Risk Insurance, Headquarters 84th Division. AMBLER, HARRY A., Lieutenant, 30th Infantry. ANDERSON, GEORGE K., JR., Sec. C, 1st Co.; 3d Officers' Training Camp. AYER, -FRANK A., 1st Lieutenant, 43d Squadron, 3d Prov. Regiment, Aviation Camp.

Jan 3, 1918

By A. L. Blomfield

THE Golden Cycle Mining and Reduction Co. operates its custom mill at Colorado Springs on Cripple Creek ores exclusively. These ores are straight sulpho-tellurides, with practically no base metals such as Pb, Cu, Zn, As, or Sb. Upon entering the mill, the ore all passes through the sampler to storage bins, where beds of 5000 tons each are made to insure uniformity in roasting. CLASSIFICATION OF ORES For efficiency, it has been found advisable to separate the ores into two classes according to their line content. Other constituents have their effect, such as alumina and magnesia, but, speaking generally, these are roughly proportional to the line, which, as CaO, is used as the indicator. Class A contains not more than 2 per cent. CaO and comprises about 66 per cent. of the ore treated. Class B contains over 2 per cent. CaO, and comprises 34 per cent. of the ore treated. Typical analyses of both classes are as follows: Class A Class B Insol 56.70 75.90 Al203 2.30 3.40 Fe 3.26 3.48 CaO 1.57 5.12 S 1.79 1.80 Mg0 0.21 1.08 Ignition loss 3.20 6.50 99.03 97.28 The beds of each class of ore are made as large as possible with the available ore as it comes in, to avoid changing from one bed to the other any oftener than necessary. Each roaster will handle 50 percent. more of class A ore than of class B, with practically the same results. This necessitates changing the rate of feed for each new bed and tends toward a poor roast and loss of tonnage at each change.

Jan 8, 1918

By John Stewart

The market at present supplied by shipments from the phosphate districts of Quebec, Ontario, and New York State requires high-grade ore, carrying from 75 per cent. to 90 per cent. of phosphate of lime. In sorting out such material by hand, much valuable phosphate is necessarily left in the "culls" or refuse, besides which, much phosphate-rock of low-grade is not now mined at all, because it cannot be made available by the crude method of cobbing and hand-sorting. The utilization of such material, which would, of course, greatly benefit this industry, requires either a mechanical separation or a chemical process which would concentrate the phosphate in a form suitable for agriculture. Considering the rich phosphate now shipped as the first class, we may arrange the lower grades in three classes, as follows: Second Class.—Cull-ore from the first class, and the mass of deposits having, as gangue, pyroxene or hornblende. The following table gives the hardness and specific gravity of the minerals concerned: Hardness Spec. gravity. Apatite,....... . 5 3.1 to 3.25 Crystalline limestone (pink calcite),. 3 to 4 2.5 to 2.9 Pyroxene,..5 to 6 3.23 to 3.5 Hornblende,.5 to 6 2.9 to 3.4 Feldspar (orthoclase),. .. . 6 to 6.5 2.5 to 2.6 It is evident that when pyroxene and hornblende are present in large proportions, this ore cannot be successfully concentrated by crushing and jigging. It may be reduced to fine powder by successive treatment in a rock-breaker and a Sturtevant or Frisbee-Lucop mill, or other suitable apparatus, and in this condition it could be largely used by applying it freely upon exhausted clay soils, such as occur in Quebec and Ontario. The occupants of these once fertile river-lands are, however, hard to move in the direction of such improvements. When water-power is at hand, the cost of crushing

Jan 1, 1893

By B. G. Klugh

(New York Meeting, February, 1912). IN a paper before the Institute at Wilkes-Barre, Pa., June 1911,1 Mr. James Gayley discussed the application of this process to iron-bearing materials. The same author2 described the results of operations at the plant at Birdsboro, Pa. The purpose of the present paper is to present further discussion of some technical details involved in the operation of this plant, and of the theoretical and practical relations of this product to blast-furnace practice. Since Oct. 1, 1911, the Birdsboro plant has been in operation at the blast-furnace of the E. & G. Brooke Iron Co. The results have been highly satisfactory, although the material treated, being chiefly the flue-dust currently made by the furnace or taken from the accumulated stock-pile, was excessively high, and yet not uniform, in carbon, so that the desirable control or regularity of the amount of fuel in the mixture treated could not be maintained. Nothing could more forcibly demonstrate the flexibility of the process than the fact that, under these conditions, the sinter produced was, in all cases, of excellent quality. The Dwight & Lloyd process, as such, and its present highly-developed mechanical appliances were described by Mr. Gayley in the paper above mentioned. While the repetition of some particulars will be unavoidable in this paper, it will be confined to features bearing upon the metallurgical principles involved. According to the principle of the process, the finely-divided iron-bearing material to be sintered is intimately mixed with

May 1, 1912

NORTH AMERICA ALASKA Anchorage.-Strandberg, H. Tuck, R. Coal Creek.-Moore, E. G. Spencer, W. W. College.-Hance, J. H. Henricksen, R. Henton, H. M. Comet.-Albertson, F. E. Cordova.-O'Neill, W. A. Douglas.-Cahill, W. E. Fairbanks.-Crawford, J. D. Earling, R., B. Fowler. D. A.

Jan 1, 1937

By A. C. Stevenson

IN OUTLINING the various steps taken and the exigences met during the time of unwatering and rebuilding the burnt top equipment at the Hecla mine, the major portion of the detail is omitted and a general description of the experience only is given. All the electrical power lines were out of commission, as were the mine feeder cables. The first effort, there- fore, was to restore electrical connections. The Washington Water Power Co. immediately put a crew to work restoring the power line, it being necessary to rebuild about 4000 ft. of 66,000 volt transmission and about 2000 ft. of 2200 volt feeder. This work was rushed and power was again available at the mine sub- station about 26 hours after the fire. During the same time temporary lighting lines were strung and transformer equipment obtained, so that when electrical connection was resumed the lights were turned on and the dump well lighted that night.

Jan 1, 1924

LIST OF MEMBERS AND ASSOCIATES ARRANGED ACCORDING TO STATES AND TOWNS ALABAMA Aldrich, Aldrich, W F Anniston, Noble, A E, Smith, N B Aibacoche, Bradley, D II Bessemer, Fergusson, V Birmingham, Aldrich, T H, Aldrich, T H, Jr, Bowron, J, Bowron, C E, Davis, F H, Dimmick, F D, Hillman, McCarthy, M E , McCormack, McCrery, Ramsay, E, Shook, A M Bridge¬port, Wheeler, S K Ensley, McDonald, S, Shook, J W Fanbanks, Hamil¬ton, A L Helena, Squire, J Huntsville, Moss Lehigh, Toulmin Oxmoor, Green¬amyer, A G Plasma, Gage Rock Run, Garvin Sheffileld, Miller, D I Tuscaloesa, Lodge, J University, McCalley Woodward, Bukofzer, Woodward, A H ALASKA Dawson, Buck Douglas Island, Corbus, J P , Macdonald, J Hames, Le Wald, E A Jualin, Hoggatt, W B Juneau, Denby, Gaifield, Garside, Hamp¬ton, W H Rodman Bay, Phillpots Snettisham, Tisdale Sumdum, Thane Tel¬ler, Hirshberg, M R Treadwell City, Batcheller, J H , Kinzie Valdez, Esterly, G M Yukon, Dawson, Elmer, J M ARIZONA Bisbee, Clark, G C, Coombs, H L , Douglas, W, Hoatson, Parnall, S A, Pelton, R T, Ricketts, L D, Sherman, G F G, Smith, F W, Smith, H A Black Diamond, Bagge Blanchard, Cummins, Murray, J J Casa Grande, Rich¬mond, A B Clifton, Colquhoun, Grabill, Murray, H T , Plater, Smith, J D A, Veitch, Watson, W S Congress, Goodloe Crown King, Alexander, G E Douglas, Cornell, Kraemer, E L, Lee, G B, Rutherford, F Globe, Berray, Hoar, Snell Harrisburg, Smith, F C Jerome, Clark, W A, Thomas, C A Kingman, Treadwell, Wallace, J P Kirkland, Bretherton, G K Kofa, Lamp¬shire, J O , Pomeroy, H G Mayer, Haggott, E A Metca j, Blumenkranz, M , Forbes, D L H Morenca, Clark, C D, Fleming, J B, Honey man, Mills, C E, Wallace, L R Morristown, Stevens, H W Nogales, Glove, H G, Sandoval, A , Sandoval, P Octave, Rose, G W Phoenix, Armstrong, T , Butler, C E, Defty, Lindsay, L Prescott, Blauvelt, H , Bunker, C E, Claypool, W M , Drescher, F M , Fairbank, Nissen Tombstone, Gage, Poindexter, C L , Staunton, Walker, E W Troy, Cutting Tucson, Blake, W P, Burgess, De Lashmutt, I, McCleary, Mann, Prout, J W , Jr ARKANSAS Fayetteville, Purdue Fort Smith, Bache, F , Denman, H Little Rock, Fordyce, Scholz CALIFORNIA Alameda, Arents, King, L Arnador City, Downs, Tregloan Angeles Camp, Dig¬gles, R N , Kenney, C E Antioch, Belshaw Auburn, Coe, I J Ballarat, Thorns Berkeley, Abadie,, Christy, Dozier, Hall, F F , Hersam, Landfield, Lind¬say, L , Mansfield, N T, Morley, W S , Sharwood, W J Bag Oak Flat, Dron Bodae, Hamilton, W R, Hoover, T, Hoover, T J, Jackson, B L , Nutter , E, H Bullion, Power, H T Callahan, Scott, E H Campo Seco, Baird Cartero,

Jan 1, 1910

By H. G. Schneider

The Smackover oil and gas field lies in Ouachita and Union Counties, Ark., in the south-central part of the state, in T.15 and 16S., R.15, 16, and 17W. It is 10 miles north of El Dorado, the principal business and railroad center in the south-central part of the state, and extends from the town of Smackover in all directions. Productive territory having an aggregate area of nearly 55 sq. mi. has been developed. It extends 6 miles from north to south and 12 miles from east to west. The field may be divided into two parts: the east district, which includes the area east of the town of Smackover, and the west district, which includes the area west of the town of Smackover. In relation to the neighboring productive fields of Arkansas, the Smackover field is 9 miles north of the El Dorado oil and gas field, 8 miles slightly west of north of the East El Dorado oil and gas field, and 16 miles east of the Stephens oil field. Smackover was discovered in May, 1922, when the Oil Operators Tnist drilled well No. 1 on the J. T. Murphy farm, in the southeast quarter of sec. 8, T.16S., R.15W. This well is located almost on the top of the Norphlet dome and was drilled to the Nacatoch sand. It had an initial open flow volume of 30,000,000 cu. ft. of dry gas per day, and a rock pressure of 950 lb. per sq. in. In July, 1922, the V. K. F. Co. completed the first oil well in sec. 29, T.l5S., R.l5W., on the north side of the Norphlet dome, and 3 miles north of the first gas well. This well started the active development of the north and northwest sides of the dome.] The field was extended westwards, when oil was discovered in the Nacatoch sand, during October, 1922, in sec. 4, T.l6S., R.l6W., 51/2 miles west of the original gas well. This opened up the so-called "light oil district," which is located on a structural terrace, for which the name

Jan 1, 1924

Lead-zinc production in Canada accounted for 19% of the total value of metals and minerals produced in 1976, says Keith C. Hendrick, president of Noranda Sides Corp. Mine production of recoverable zinc w as 1. 158 million toils of 27.4% of free world production in 1976. Slab zinc pro¬duction was placed at 472,000 tons that year. Canadian mine production of recoverable lead was 247,000 tons or 10.6% of the free world production. Refined lead that year was at 177,000 tons.

Jan 11, 1977

By W. G. Lidman, H. J. Hamjian

' I HE fabrication of many materials from powders involves a sintering process. A mass of powder will sinter because of the excess free energy over the same mass in the densified state caused by the higher total surface area of the powder. An understanding of the kinetics and mechanism of sintering should assist in improving the properties of such materials. The present investigation conducted at the NACA Lewis laboratory deals with the sintering of chromium carbide. Dry sintering (sintering at a temperature below the melting point) was divided into two stages by Shaler:' the first stage, during which the particles preserve much of their original shape and the voids are interconnected, and the second stage, during which densification occurs and the pores are isolated. The mechanism of forming interfaces between particles, or welding together of particles, has been investigated by Kuczynski2 and may be described by any one or a combination of the following mechanisms: viscous flow, evaporation and condensation, volume diffusion, or surface diffusion. The mechanism by which pores are closed or eliminated (densification) during sintering, is of interest. Grain growth observed during sintering may be attributed to the variation in the surface energies of individual grains, causing some grains to grow at the expense of others. Grain boundary migration occurs presumably by a diffusion process, therefore the rate of grain growth would be expected to increase exponentially with increasing time and temperature. Thus, for practical sintering times of less than 1 hr, a certain minimum temperature may exist at which major structural and property changes will occur. Densification and kinetics of grain growth during sintering under pressure of chromium carbide were investigated to provide additional information which will aid in describing more accurately the sintering process and the mechanisms involved. This material was selected for this study because of the current interest in high strength, oxidation resistant refractory materials, such as carbides, which are sintered to produce solid, dense materials from powders. Sintering under pressure is a process where the heat and pressure are applied to the compact simultaneously, specimens for this work were prepared by sintering under pressure at different temperatures and for various time periods. Experimental Procedure Preparation of Specimens: Chemical analysis of the commercial chromium carbide used in this investigation was as follows: Cr 86.19 pct, C 12.14 pct, and Fe 0.2 pct. X-ray diffraction powder patterns gave characteristic diffraction lines of Cr3C2 crystal structure. Powder particle size was determined microscopically and the average initial particle size was 6 microns with 85 pct between 2 and 10 microns. Specimens sintered under pressure were formed in graphite dies3 heated by induction. Sintering temperatures were measured with an optical pyrometer by sighting into a 3/8-in. hole drilled 1 in. deep at the midsection of the graphite die. A load of approximately 1 ton per sq in. was applied to the powder. The die assembly was heated in 20 min to the highest temperature (2500°F') at which no increase in grain size could be observed, and less than 2.5 min were required to heat from this temperature to the maximum temperature (3000°F). Sintering temperatures and times for the specimens of this investigation are indicated in Table I. Analysis of Specimens: Specimens polished with diamond abrasives were etched to reveal the grain boundaries with a 1:1 mixture of 20 pct potassium hydroxide and 20 pct potassium ferricyanide heated to 160°F. Representative areas of each sample were photographed at 1000 diameters. The largest diameters of all well-defined grains were measured, but only the measurements of 15 of the largest grains were averaged in order to determine an index of grain size on the assumption that they were among the first to begin growth. Densities were determined from differential weighing of the samples in air and water. The reported density values are considered correct within ±0.01 g per milliliter. Results and Discussion Metal compacts have exhibited grain growth when sintered at temperatures about two-thirds of the absolute temperature of their melting point.' Grain growth also occurs during the sintering of chromium carbide and is illustrated by the micrographs shown in Fig. 1. These micrographs were prepared from specimens sintered for 90 min at temperatures ranging from 1371°C (2500°F) to 1648°C (3000°F). Average grain size and density measurements of specimens investigated are presented in Table I. The relationship between grain size and sintering tem-

Jan 1, 1954

By R. E. Fryxell, E. C. Duderstadt, P. K. Conn

Permeation rates for nitrogen through are-cast tungsten were measured in the temperature range 1800° to 2600°C at nitrogen pressure differentials of 1.0 and 0.1 atm. Gas chromatography was used to measure the quantities of nitrogen which permeated through 0.26-and 0.53-mm-thick membranes. Permeation rates were proportional to the difference between the square roots of the nitrogen pressure on each side of the membrane and inversely proportional to membrane thickness, indicating that atomic nitrogen was the difjusing species and that diffusion was the rate-limiting step of the process. Permeation coefficients calculated from the rates may be represented by the equation: where P is expressed in the units cu cm (stP)-mm per 1/2 sq cm-min-atm"' and 70.0 * 0.8 is the activation energy in kcal per mole of permeating species. In a previous paper' permeation rates were reported for hydrogen and for oxygen through tungsten. The permeation cells used for the hydrogen measurements were suitable for measuring nitrogen permeation under similar conditions, so the study was extended to include nitrogen. Permeation rates of nitrogen through the polycrys-talline arc-cast tungsten membranes were measured in the temperature range 1800" to 2600°C using two membrane thicknesses and two nitrogen pressure differentials. Permeation coefficients were calculated and the activation energy of the process determined. THEORY For diatomic gases which dissociate prior to diffusion, the quantity of gas which permeates through a membrane or wall at an elevated temperature where bulk diffusion is the rate-limiting step of the process is given by the equation: where: q = total amount of gas permeating a membrane, P = temperature-dependent permeation coefficient, A = area of membrane, t = time, p1 = gas pressure of high-pressure side, p2 = gas pressure of low-pressure side, and d = thickness of membrane. When bulk diffusion is the rate-controlling step, and the solubility of the gas obeys Henry's law, a further relationship is that, for any given temperature and pressure, the permeation is the product of diffusivity and the amount in solution. The permeation coefficient, P, is temperature-dependent according to the equation: where: Po = permeation constant, Q = activation energy, R = gas constant, and T = absolute temperature. EXPERIMENTAL PROCEDURES Cell Design and Experimental Apparatus. Two of the permeation cells used for the previous measurements of hydrogen permeation are shown in Fig. 1. Each consisted of a cylindrical chamber divided into two parts by a permeation membrane fabricated from high-purity (>99.9 pct W) wrought tungsten sheet made from vacuum arc-cast tungsten. The membrane in one cell was 0.26 mm thick and the other was 0.53 mm. The fabrication of these cells was described previously.' The permeation cells were mounted vertically in a high-temperature tungsten resistance furnace and the membranes and the center portions heated to test temperatures. Temperatures were measured by sighting an optical pyrometer on the edge of the membrane through a small hole in a tungsten plate which was fastened to the side of the cell. This arrangement provided an approximate black-body condition and eliminated the need for emittance corrections. Appropriate corrections were made for the quartz window through which the temperatures were measured. Argon gas flowed through the 10-liter volume of the furnace at the rate of 4.7 liters per min. An impurity

Jan 1, 1969

By Walter E. Hopper

(Wilkes-Barre Meeting, June, 1911.) I. LOCATION AND EXTENT. THE Caddo oil-field, shown in Fig. 1, is located in Caddo parish, northwestern Louisiana. The known producing territory of oil is covered by townships 19 N, 20 N, 21 N, 22 N, and ranges 15 and 16 W., shown in Fig. 2. The center of the field may be taken as Oil City, 24 miles north of Shreveport, on the Kansas City Southern railway. Shreveport is the second largest city in the State, and is the connecting point of five rail-road-lines. Drilling at the present time, however, is going on all over northern Louisiana, especially in Caddo and the neighboring parishes. II. HISTORY AND DEVELOPMENT. Natural gas escaping at the surface is found at numerous places in northwestern Louisiana. At Shreveport, the plant of the Shreveport Ice & Refrigerating Co. has been lighted by natural gas for 20 years. The well was drilled for water, but was abandoned on account of the gas. A test well, put down in 1905 near the western limits of Shreveport, was driven to 1,650 ft., and encountered indications of gas and oil at various depths, but did not succeed in finding enough to be profitable. Attention was first attracted to the Caddo field in 1895 by indications in water-wells from 40 to 60 ft. deep, in which the pressure of natural gas was noticeable. This indication of gas in a shallow well led to the drilling of the first well in the Caddo field, the old Savage Brothers & Morricell, or the Caddo Lake Oil and Pipe Line No. 1. The rig for this well was erected in May, 1904, and drilling began in June, 1904. The well was bailed Mar. 23, 1905, with a small amount of oil. It was deepened July, 1905, and converted into a "gasser " Jan. 3, 1906. It was abandoned January, 1907. In consequence of the finding of oil in the Savage well, drilling-operations were pushed with energy; and in April, 1905, four wells were drilling. Great trouble was experienced with

Apr 1, 1911