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By Pedro Jorge Walburga Keglevich de Buzin

The steel production in mini mills generates several process residues, among them there is the electric arc furnace dust (EAFD). This residue has as main elements Fe, O, and Zn, being classified as hazardous by the presence of Pb and Cd. Thermodynamic studies related to the formation of mineral species containing Fe, O and Zn elements were carried on due to the influence of these compounds in hydrometallurgical EAFD recycling processes. In recent years, a rise in the chlorine content of this residue was observed, mainly motivated by the increased use of scrap with polymeric impurities containing this element. In this work, based on computational thermodynamics tool FactSage, a general overview of gaseous and minerals species (found in EAFD) formed by Fe, Zn, O, Cl, H and C is shown – representing the organic origin of chlorine. For this study, the PVC polymer was used as the chlorine carrier substance which contaminates the EAF load.

Jul 30, 2018

By Rogério Felício dos Santos

Nitriding of metallic materials using electric discharges generated during electric discharge machining (EDM) is a recently developed technique. The aim of this paper was to correlate mechanical properties of a nitrided layer produced in AISI 4140 steel by EDM nitriding with the type and amount of nitrides. A conventional die-sinking EDM equipment and electrolytic copper electrodes were used to generate the electric discharges. The electrolyte was a solution of urea in deionized water. Knoop microhardness profiles assessed the variation of hardness along the nitrided layer, whereas the elastic modulus of this layer was measured using nanoindentation tests. Optical microscopy and X-ray diffraction (XRD) were used to characterize the nitrided surface. The results showed the formation of a nitrided layer containing iron nitrides with average thickness of around 25 µm. The amount of nitrides reduced from the surface towards the centre and these results correlated well with microhardness profiles obtained.

Jul 31, 2018

By Douglas Glenn Stalheim

Production of structural hot strip coils in yield strengths up to 700 MPa and higher is increasing worldwide. In addition to requiring higher strengths, structural designs require good formability, toughness and weldability. Toughness and formability come from optimization of ductility properties while weldability comes from lower carbon equivalent alloy designs. The key to the production of optimized cost effective hot strip produced structural coils is to create the correct balance of a proper alloy/processing design to create as fine and uniformly distributed cross sectional grain size as possible. In addition to the creation of the fine/uniformly distributed cross sectional grain size, the correct microstructure needs to be created. In the higher yield strength grades, not only does the grain size/distribution play a role but a proper understanding and control of microalloying precipitation kinetics is required. This paper will present various examples of hot strip alloy designs to produce cost effective hot strip structural coil in yield strengths up to 700 MPa with good ductility and weldability. In addition, steelmaking/casting parameters will be discussed to assure successful production. Optimized reheating, rolling and cooling parameters of these alloy designs will be introduced in an accompanying paper.

Aug 17, 2017

By André de Albuquerque Vicente

Os aços inoxidáveis duplex caracterizam-se por apresentarem microestrutura bifásica, ferrítica-austenítica. A fração volumétrica ideal das fases é 50% de ferrita e 50% de austenita, entretanto, essa condição é de difícil obtenção quando realiza-se a união por soldagem a arco desses materiais. Neste trabalho estudou-se as melhores práticas de soldagem do aço inoxidável duplex UNS S31803 garantindo a obtenção de frações volumétricas ideais de ferrita e austenita. Foi soldado um corpo de prova pelos processos TIG e MIG-MAG. Para esse corpo de prova foi realizada a soldagem de um passe de raiz e um passe de reforço através do processo TIG e o preenchimento da junta através do processo MIG-MAG. Foram realizados os seguintes ensaios no corpo de prova: micrografia (metal base, ZAC face, ZAC raiz, face da Zona Fundida e raiz da Zona Fundida), medição da fração volumétrica de ferrita, microdureza Vickers (HV500), ensaio de tração da junta soldada, dobramento guiado, Charpy e ensaio de corrosão por pitting.

Oct 30, 2017

By Maurilio Pereira Gomes

The aim of this work was to heat treat and characterize sintered valve seat inserts (VSI). The powder metallurgy route was the only way found to substitute cobalt and lead, used in the VSI original alloy, due to their high cost and toxicological effect, respectively. The studied VSI was obtained with AISI M2 high-speed steel powder mixed with iron powder and other additives such as manganese sulphide, graphite, zinc stearate, carbides and copper, which was added by metallic infiltration. All the VSI were air quenched and double tempered, for one hour each, at seven different equidistantly temperatures, ranging from 100 °C up to 700 °C. The physical and mechanical properties were evaluated by means of the VSI apparent density, apparent hardness and crush radial strength. The chemical composition was determined through gas analysis, for the light elements such as carbon and sulfur, and energy dispersive X-ray fluorescence spectrometry for other elements. Microstructural characterization was performed with the support of scanning electron microscopy and energy dispersive spectroscopy. Regarding the VSI final application, the best results were achieved with the inserts air quenched and double tempered at 600 °C.

Oct 30, 2017

By Luiz Henrique Accorsi Gans

First, this works carries an experimental evaluation for austempered ductile iron (ADI) as a gear material. And second, in order to provide a better understanding of the microstructural effect on the stress state of subsurface regions, a finite element method approach was considered using the submodeling tool in ANSYS 11.0. For this, ADI gears were produced from continuous cast iron bars, heat and thermochemical treated and tested in FZG test rig. The results were compared to those of carburized steel AISI 8620 and induction hardened steel AISI 4140 gears. The wear experiments were performed at the temperature of 90ºC with two torque stages: 135 N.m (running-in) and 302 N.m (steady-state). The time for pitting and spalling on the gears surfaces were measured using image analysis. The results showed a very good potential of using ADI for manufacturing gears, replacing induction hardened steels. Also, the ADI gear with smaller nodules showed higher life for pitting. In contact fatigue tests with severe load, the carburized AISI 8620 steel proved more adequate than the austempered ductile iron, showing that the mechanical properties are critical in the resistance to damage in gear contact. The austempered ductile iron with smaller nodule size showed to be very competitive with wear resistance similar to AISI 4140 steel induction hardened. With ANSYS, it was verified that the nodule size affects the gears life independently of the mechanical properties of the matrix. The results showed that the nodules indicate the presence of a concentration stress, but their size doesn’t affect the contact fatigue life as much as the total amount of nodules, regardless of the ductile iron microstructure. The size and number of nodules affects both the nucleation and the propagation stage of cracks. ADIs with higher amount of nodules have a greater wear resistance. Also, compared to the Hertz contact theory (isotropic material), the presence of graphite nodules indicates a non-isotropic material and made the maximum shear stress point moves toward the surface.

Jul 31, 2018

By Aline Lima da Silva

The reduction in SOFC operating temperature due to recent development in materials and fabrication techniques enables the use of ferritic stainless steels as interconnects for SOFCs. Ferritic stainless steels offer many advantages over traditional ceramic interconnects, such as higher thermal and electronic conductivity, as well as relative ease of fabrication. However, the formation of chromium oxide on ferritic stainless steel results in an increase in ohmic resistance and can lead to the loss of cathode catalytic activity (due to Cr volatilization, with cathode poisoning). The oxide growth depends on several factors, such as steel composition, temperature, oxygen partial pressure. In this way, knowing the phase stability, the oxidation behavior of the material and the oxidation kinetics is of great interest. In this context, a thermodynamic study of the oxidation of ferritic stainless steel 430 under oxidizing atmosphere (cathode), at the temperature of 750ºC, is carried out. As one can see, the thermodynamic system can be very complex, involving several phases (chromium oxide, (Fe,Cr,Mn)3O4 Spinel, iron-chromium oxides, etc.). The effect of oxygen partial pressure and alloying elements on phase distribution is evaluated. Thermodynamic modeling is compared with experimental results from literature.

Aug 8, 2018

By Joaquim Luiz Monteiro de Barros, Fabiana Moreira Costa

Este trabalho tem como objetivo principal apresentar de forma didática e através de exemplo prático, os processos de limpeza de gases de exaustão durante a produção de ferro e aço para atendimento as normas ambientais e a possibilidade da recuperação de energia térmica desses gases captados para aumento da eficiência energética das plantas siderúrgicas.

Aug 1, 2019

By Johann-Paul Stemplinger

For lubrication of open gear drives applied in rotary furnaces, often gear greases are used as well as for lubrication of gear boxes in difficult sealing conditions. The selection of the gear grease influences strongly the wear behavior. Investigations with flow greases NLGI 00 were made in a back-to-back test rig determining the weight loss due to wear acc. to the standardised procedure ISO 14635 part 3. Different influences like base oil viscosity, thickener type and additional solid lubricant type were analysed. Only the type and amount of solid lubricant shows a significant influence on the weight loss due to wear. Finally, a linear wear coefficient clT according to the calculation method of the wear amount according to Plewe is derived and can be used to transfer the test results to any gears in practice.

Jul 31, 2018

By Homero Delboni Junior, Thiago Nunan, Flávia Vargas

Ball mill liners perform two main functions in grinding process: protect the mill shell from the aggressive milling environment and delivery input power to the charge. When it comes to liners optimization the challenge are to prolong the service life and improve grinding performance. Some liners characteristics such as A / B ratio, lifters number, lifter height, and attack angle are extremely relevant to grinding process. By analyzing process data, and through DEM simulations application, these parameters were improved on W-mill liner, located at Vazante concentration plant. The new profile promoted a reduction of power variability between the final and the initial life cicle intervals and, therefore, better stability to circuit operation. In addition, the new liner service life reached 21,603 hours, 25% higher compared to the previous one in use. This optimized profile therefore proved to be able to improve its functions by achieving superior process performance combined with longer service life.

Oct 3, 2019

By Abraão Santos Silva

Juntas soldadas são regiões críticas quanto a fraturas. Neste estudo foi analisada a tenacidade à fratura de soldas de reparo de tubos de mastros de sonda de perfuração de petróleo. Foram escolhidos os tubos principais de sustentação dos mastros. Seções do mastro são corriqueiramente reparados por soldagem TIG de raiz e preenchimento por eletrodo revestido. Estes processos provocam modificações metalúrgicas na zona termicamente afetada da solda, o que pode ter reflexo na tenacidade à fratura dos tubos. Foram produzidos corpos de prova para medir a tenacidade à fratura do metal base e da zona afetada termicamente. Os resultados indicaram que não houve redução de tenacidade a fratura devido as alterações microestruturais da zona afetada e isto foi associado ao procedimento de soldagem multipasses utilizado.

Aug 16, 2017

By Delciane Porfiro, Tiago de Mattos Serodre, Antônio Eduardo Clark Peres, Valdirene Gonzaga de Resende

The evaluation of the effect of the addition of carbon nanotubes (NTCs) directly to a etheramine on the flotation recovery of the quartz at pH 10.5 was carried out by means of microflotation tests in Hallimond tube. The quartz flotation was evaluated using 0.1% (w/v) etheramine solution with different percentages of carboxylic functionalized NTCs. The increase in the percentage of functionalized NTCs increased the flotation recovery to a maximum and from this it was observed a reduction of the recovery of the mineral. Pure etheramine and etheramine with the NTCs were characterized by FTIR spectroscopy and thermal analysis. FTIR spectra of both pure etheramine and etheramine with NTCs clearly showed peaks with the same wavelengths and diagnostics of the cation etheramine and acetate anion. Thermogravimetry indicated that the etheramine + NTCs-COOH mixture lost approximately the same weight percentage over a larger temperature range. In addition, the interaction of the nanotubes with the etheramine caused them to decompose at a lower temperature.

Oct 3, 2019

By Marcelo de Oliveira Lima

O cenário energético brasileiro nas últimas décadas apresenta períodos de escassez na oferta de energia elétrica. Essa realidade impacta o setor industrial por representar um risco operacional e fortalece a necessidade de aumentar a eficiência energética dos processos. Adicionalmente, a eficiência contribui para a melhoria nos resultados financeiros e minimiza impactos ambientais. Nesse contexto, o uso de iluminação LED se destacou nos últimos anos como alternativa às tecnologias tradicionais. No entanto, inicialmente os preços das lâmpadas e luminárias LED eram proibitivos. Esse trabalho apresenta um histórico do custo dessas lâmpadas em diferentes aplicações típicas à uma empresa siderúrgica e demonstra que atualmente o LED pode ser considerado atrativo em algumas delas. São apresentados também casos de sucesso implantados na AcelorMittal Tubarão, garantindo inclusive melhoria nos índices de iluminamento. Por fim, é apresentado de forma sintetizada o Programa de Eficiência Energética da ANELL que disponibiliza recursos das concessionárias de energia para implantação de projetos, sendo ilustrados exemplos de projetos reais e suas economias de energia utilizando iluminação à LED.

Oct 30, 2017

By João Victor Gomes Guimarães Ananias, Itavahn Alves da Silva, Thiago Araújo Santos de Oliveira, Salvatore Giuliano Peixoto Tropia de Abreu, Guilherme Santiago Queiroz, Carlos Antônio da Silva

Oct 1, 2019

By Edson José Costa Santos

Uma fonte promissora de pós-descarga é a obtida por cátodo oco, isso devido a sua operação, baixo custo, elevada densidade de espécies ativas e design. Neste trabalho empregou-se a espectroscopia de emissão para diagnosticar as espécies ativas produzidas descarga em catodo oco. Variou-se a corrente elétrica na descarga de Ar entre 150 e 600 mA para verificar a influência da corrente na descarga. Posteriormente, fixou-se a corrente elétrica e variou-se o fluxo de N2 na pós-descarga de 1 a 6 cm3/min. Observou-se que a corrente elétrica influenciou na intensidade de emissão das espécies produzidas pelo sistema de descarga cátodo oco. Além disso, não foi observada a emissão ótica da espécie de ? 2 N na pós-descarga Ar-N2.

Aug 7, 2018

By André Oliveira Galon, Caio Vaccari Silva, Victor Bridi Telles, Raphael Mariano de Souza, Felipe Fardin Grillo, José Roberto de Oliveira

Neste trabalho foi estudada a influência da granulometria de CaO adicionada ao processo de desfosforação, temperatura e teor de FeO da mistura desfosforante na aglomeração de partículas sólidas na escória. Para isto, foram realizados testes laboratoriais em sete condições experimentais distintas, bem como a análise de imagens via software Quantikov, para medir a aglomeração, além de análise termodinâmica computacional. A granulometria, temperatura e porcentagem de FeO se mostraram parâmetros relevantes na aglomeração da escória de desfosforação e a análise de imagens mostrou-se uma ferramenta útil para a obtenção destes resultados.

Oct 1, 2019

By Willian dos Reis Lima, Breno Totti Maia, Guilherme Silva Machado, Adeilson Roberto Ribeiro, Carlos Alberto de Souza, Douglas Augusto Pena, Fabrício da Silveira Garajau, Marcelo de Souza Lima Guerra

Oct 1, 2019

By Luiz Eduardo Machado De Cnop

O trabalho apresenta estudo de casos onde a falta de uma análise mais profunda do problema leva a decisões técnicas de compras de equipamentos que praticamente não acrescentam benefícios ao projeto e, ao contrário, se mostram verdadeiros “sorvedouros” de energia, justamente na contramão dos programas de “eficiência energética”.

Sep 25, 2017

By Pollyana de Aragão Trigueiro

A distribuição de soluto durante a solidificação rápida de uma liga Ag-15%massaCu, foi obtida numericamente. No presente trabalho, utilizamos um modelo de difusão de entalpia e concentração médias, proposto anteriormente, para a solidificação de uma gota de liga binária (atomização). Nossos resultados mostram que a refusão da estrutura pode gerar um perfil de microssegregação em ligas solidificadas rapidamente bastante diferente dos que resultam da solidificação perto do equilíbrio.

Aug 7, 2018

By Shaney Gonçalves Mileipe

No contexto atual, os estudos de engenharia de confiabilidade se tornaram cada vez mais essenciais para o acréscimo de disponibilidade das plantas e estabilidade operacional. Este trabalho tem por objetivo, através da metodologia de análise e solução de problemas (MASP) focada em modos de falhas prioritários, reduzir o tempo de manutenção não planejada do processo de Sinterização da Arcelor Mittal Tubarão. Os resultados obtidos concretizaram um aumento de 2% na disponibilidade da planta após a elaboração de um plano para corrigir os modos de falhas críticos, revelando a importância e o potencial de ganho em se investir em estudos de confiabilidade e registro de falhas.

Oct 30, 2017