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By J. Casado

This paper presents the results of an analysis and summary of relevant literature on the mechanism of cementation of metals in acidic aqueous media, with the aim of reconsidering the conventional assumptions. The simplicity of the process as a mere galvanic metal displacement is discussed, and the real effects of pH and hydrogen pressure in different cases assessed. Finally, an alternative mechanism scheme with respect to the role of hydrogen species, in agreement with reported data, is proposed.

By L. J. Kane

Applications are described of various methods for determining the weight concentration and physical properties of solid and liquid impurities of gases in connection with problems encountered in synthesis-gas production. Of special interest among these methods may be listed: 1. A method developed for determining, the weight concentration of solid and liquid impurities in. hot, crude synthesis gas containing a high concentration of moisture. 2. A method developed for the same purpose but for highly purified synthesis gas or atmospheric air. 3. A method for obtaining a uniform dispersion of dry duet or, a microscope slide for particle-size determination or other purposes.

Jan 1, 1954

By Shawn P. Coughlin, Michael A. Schimmenti, Juan Leonardo Tello del Pino

"The Sistema de Potabilización Área Norte project (Northern Area Purification System) was a major expansion of the potable water system in Buenos Aires Province, Argentina. The aim of the project was to transport and purify raw water from the Paraná River to provide potable water for five communities in the northern part of the province, benefitting up to two million people. The project was constructed by a joint venture (JV) of four South American contractors and consisted of the following key components:• Treatment plant: A 16-ha (39-acre) area was cleared for the construction of a treatment plant to purify 900,000 m3/day (1.2 million cu ft/d) of raw water from the Paraná River and distribute it to the surrounding communities.• Bored tunnel: Nearly 15 km (9 miles) of 3.6 m (12 ft) inner diameter tunnel, ranging from 18 to 22 m (59 ft to 72 ft) below grade, was bored with two earth pressure balance (EPB) tunnel boring machines (TBM) to draw the raw water from the river. The TBMs started from a central launch shaft and proceeded in opposite directions. Cristina advanced northbound to the Paraná River Intake System, and Liliana advanced southbound to the new treatment plant.• Access and ventilation shafts: Five access shafts and eight ventilation shafts were installed along the length of the tunnel. The access shafts were designed to provide entry points for inspection and maintenance of the final tunnel. The five shafts consisted of one central launch shaft in the middle of the tunnel alignment, one retrieval shaft at each end of the tunnel (intake and treatment plant, respectively) and two intermediate shafts. The intermediate shafts were installed before the TBM passed, with a final liner to be installedafterward."

Sep 1, 2016

By Shiju Zhang, Yongnian Dai, Songli Liu, Wenhui Ma

The BaZrO3 and CaO-doped BaZrO3 ceramics were fabricated at 1750 °C for melting the Ti2Ni alloys, respectively. Employing XRD, OM and SEM, the influence of CaO on the composition of BaZrO3 and the interaction between the BaZrO3 ceramic and titanium alloy was investigated. The results showed that the CaO doped BaZrO3 was consisted of CaO and Ba 1−xCaxZrO3. The grain on the surface of BaZrO3 ceramic was loose after melting, and the thermodynamic analysis indicated that the dissolution-erosion was responsible for the interaction mechanism. An amount of BaZrO 3 refractory was attached to the Ti2Ni alloy bottom after the alloy was cooled. However, no refractory was found on the bottom of Ti2Ni alloy, which was cooled down on the CaO doped BaZrO3 ceramic. CaO additive can effectively reduce the interaction between the BaZrO3 refractory and the titanium melt, indicating that it was a very promising refractory for preparing the titanium alloy.

Mar 1, 2018

By H. B. Humphrey, F. E. Cash

The Southern Appalachian coal field extends southward across Tennessee in a belt about 50 miles wide between the eastern and middle sections of the State. The earliest record of the production of coal in Tennessee is for 1840, and the first inspection laws were passed in 1881. In 1887, a second act of the legislature created the office of Chief Inspector, but little was done until 1891 when a new act was passed giving to the Department of Mines added duties and powers. Since that time, except for the years 1915 to 1918, com¬ prehensive annual reports have been published. Data for the tables given in this paper are taken from these annual reports, from those of the Southern Appalachian Coal Operators' Association, and from the publications of the United States Bureau of Mines, which has main¬ tained a station at Jellico, Tenn., since 1911. Complete figures for 1930 are not available yet and they are not included in the averages. The State Department of Mines, the operating companies, and the United States Bureau of Mines cooperate in accident-prevention work. It is the purpose of this report to present in uniform tables the available statistics in regard to fatal accidents in Tennessee and in the coal mines of the United States, in order that the progress in mine safety in Tennessee may be compared with that of the country as a whole, and the present period may be compared with various periods of the past, to indicate the main points of attack in the reduction of accidents.

Sep 1, 1931

By Jan Lückhoff

The introduction of the EAF Quantum furnace by Primetals Technologies represents an important milestone in the field of electric steelmaking during the last 15 years. In this process the latent and chemical heat of the off-gas generated during a melting process in an EAF is used to pre-heat scrap in an integrated shaft prior the melting of the scrap in the vessel. Combining proven own technologies, Primetals EAF Quantum enables nearly continuous process, cutting down idle times and enhancing availability for production. The essential benefits will be shown in this Paper.

Aug 16, 2017

By B. Hohenstein, B. McBain, B. de Jong

"The automated fire assay system (Fast In-line Fire Assay or FIFA) has not found acceptance in the Au mining industry as the lower measurable limit of 0.20 ppm did not allow Au tailings to be measured with confidence. The development of arrested cupellation has overcome this hurdle which was a limiting factor in the FIFA 1 process. In the new automated fire assay process, automated sample preparation, fluxing, fusion and separation of a Pb button are essentially similar to the FIFA 1 process, albeit with some improvements. However, the game-changer is the development and incorporation of arrested cupellation into the automated system, now called FIFA 2. The purpose of arrested cupellation is to reduce the 50 g Pb button to a 5 g Pb button by partial cupellation in a specially developed arrested cupellation system thereby concentrating the Au in the Pb by a factor of 10 and in so doing moving them into higher concentration ranges in the mini-button where they can be read on the spark spectrometer. Results show that concentrations down to 0.02 ppm Au in geological materials can now be determined using arrested cupellation in the FIFA 2 process, an order of magnitude improvement over FIFA 1.INTRODUCTION Traditional fire assay for Au has remained virtually unchanged for 3000 years. It has survived for so long because it is accurate, has relatively low detection limits and is relatively inexpensive. However, it is labour intensive, has a long turn-around time (typically at least 7 hours), is environmentally unfriendly and exposes assay operators to potentially unsafe conditions (toxic fumes, toxic dust and extreme heat from furnaces). The NiS collection method is not as effective for the assay of Au as it is for the PGEs. A rapid, accurate, cost-effective method for the determination of Au and the Platinum Group Elements (PGEs) in geological materials would be a tremendous benefit to mining companies. Many of these objectives have been met by the FIFA 1 (Fast In-line Fire Assay) developed some 15 years ago in which automated methods have replaced the manual procedures which are part and parcel of conventional fire assay. However, concentrations below 0.2 ppm have been very difficult to achieve with sufficient reliability."

Jan 1, 2017

By A. Mainza, H. Hill, L. S. Bbosa

"Impact breakage is the most elementary size reduction mechanism in comminution devices. In comminution research, characterization of breakage is primarily concerned with the energy expended to cause it. The main challenges of this approach have been quantifying the actual energy requirements of impact breakage and developing mechanistic models to accurately describe the process. For engineering load analysis, fracture is characterized in terms of strengths such as yield stress and ultimate tensile stress, which govern the maximum loads specific materials can be subjected to before irreversible inelastic deformation and subsequently complete fracture occur. With this approach, the main challenge has been to elucidate the underlying mechanism, in the means that the load causes weaknesses in the material microstructure to act as sites for stress concentrations, leading to crack initiation, propagation and eventual failure. Studies dedicated to investigating particle fracture under impact loading have led to the development of several devices for conducting breakage characterization tests. These devices include the drop weight tester, split Hopkinson pressure bar, rotary breakage tester and the short impact load cell. All these have different particle loading and breakage methods, and thus can yield distinct information which can be compiled together to study a material and the nature of breakage. This work analyses the single impact breakage data obtained across the listed devices. A homogenous ore commonly known as blue stone is used for all breakage tests. The work is conducted using standard procedures specific to each device as closely as possible. Drop weight and rotary breakage tests were used to obtain hardness parameters based on an existing t10 breakage model, while split Hopkinson pressure bar and short impact load cell measurements provided properties based on conventional engineering load analysis. The results were used to highlight the significance of the loading geometry, impact mechanism and impulse on the extent of breakage."

Jan 1, 2018

By D. Bienstock, R. C. Kurtzrock, E. R. Bauer, J. H. Field

To remove hydrocarbons and carbon monoxide in automotive exhaust by oxidation , a catalyst of 4.2 percent Uз Og , 1.7 percent Cr₂ 0 , and 1.7 percent CuO supported on 1 /8 - inch y- alumina spheres was tested in a reactor in place of the muffler of a 1 / 2 - ton truck . Tests were made with both nonleaded and leaded gasolines . With the engine at operating temperature , tests were made with the engine idling and with the vehicle cruising at 30 mph . Auxiliary air was added to maintain an oxygen concentration of 3 to 4 percent in the gas leaving the catalytic reactor . The vehicle was operated for 83 hours (about 60 percent of the time with the engine idling ) and 525 miles with nonleaded gasoline . Conversions of 98 percent of the hydrocarbons and 100 percent of the carbon monoxide were achieved with the engine idling and with 7,000 ppm carbon atoms and 4- percent carbon monoxide in the feed to the reactor . Hydrocarbon conversions of 75 percent were obtained at cruising speeds of 30 mph with a feed of 1,700 ppm carbon atoms ; the carbon monoxide concentration was less than 0.3 percent in the feed and was unchanged in passage through the reactor . Identical activity was obtained initially in switching to a gasoline containing 1.9 ml tetraethyl lead (TEL) per gallon . However, there was a gradual loss in activity thereafter . Conversions in tests with the engine idling about 50 percent of the time , had decreased by 23 percent for the hydrocarbons and by 25 percent for the carbon monoxide from their initial values after 122 hours and 1,300 miles of operation with leaded gasoline . The levels of radioactive materials in the exhaust of the reactor and the radiation in the vehicle were negligible .

Jan 1, 1963

By H. Sevim

In a recently developed long term open pit production planning model, the optimum plan is found by exhaustively searching through nested pits of maximum-metal contents. A more efficient, dynamic programming (DP) based search algorithm now replaces the exhaustive search algorithm which was requiring prohibitively long execution time in real life cases. The logic and the formulation of the newly developed search algorithm are illustrated through a small hypothetical case. A real life gold deposit is treated to demonstrate that the algorithm does indeed find the optimum production plan among all possible plans. A comparison, in terms of computational savings between the two algorithms is also given.

Jan 1, 1994

By G Sartor, A Rich, D Grimsey, R Forzatti, M White

An in-depth process model was developed for the pyrometallurgical, off-gas systems and water balance of the Kalgoorlie Nickel Smelter. This model was used to assess plant capacity with changing concentrate grades, increased throughput and tighter environmental emissions under a range of potential future operating conditions. Comparison of modelled results allowed for flow sheet optimisation across a range of metrics including sustainability, processing capacity and costs. Process modelling software, METSIM® (ver 2020.06 by METSIM International), was used to simulate the flash furnace, integrated electric slag cleaning furnace, Pierce-Smith converters, matte granulation, waste heat boiler, hot gas handling equipment, wet gas cleaning plant and acid plant. The METSIM® model was divided into three separate, yet interconnected models: metals, off-gas and water balancing. This allowed for improved modelling efficiency and traceability while minimising manual error. The METSIM® model was supported by inputs from other specialised software. Chemical thermodynamics software, FactSage™ (ver 8.2 by GTT Technologies), was used to establish relationships for the flash furnace fluxing strategy and determine the operating temperature. Arena® (ver 16.0 by Rockwell Automation), a discrete event modelling software, was used to simulate material movements within the aisle as well as Pierce-Smith converter operation, allowing for integration with upstream and downstream systems. A dynamic data exchange (DDE) was used to connect the results of each software package, interfacing through Excel® (version 4203 by Microsoft). The integration between models provided a streamlined approach to test capacity, bottlenecks, water consumption and emissions under a range of operating conditions, enabling a more robust process. Further downstream modelling techniques were used to assess mechanical equipment. METSIM® outputs provided key parameters for combustion assessments using computational fluid dynamics and finite element analysis for the furnace mechanical design.

Aug 21, 2024

By J. A. Holmes

Due to varying and complex mineralogy, the flotation tailings from the Chingola Concentrator have, for some years, contained upwards of 0.4% acid soluble copper. In 1968, an investigation was initiated, to determine a method for recovering this acid soluble copper. This initial investigation concluded with a recommendation to install a leach-solvent extraction-electrowinning plant at Chingola, to treat up to 900 000 tonnes of material per month, for an additional copper production of some 4 500 tonnes per month. The process consists basically of six stages :- Materials reclamation handling and preparation, acid leaching in air agitated pachucas, solid-liquid separation by countercurrent washing in thickeners, solution concentration and purification by solvent extraction, copper recovery by electrowinning, and residue neutralisation and disposal. This paper describes the development of the main parameters for design of each of the six sections, and gives details of the final plant design. Problems encountered in commissioning and initial operations are commented on, particularly insofar as they indicated any errors or misjudgements in the design. The choice of materials of construction is commented on in some detail.

Jan 1, 1976

By Arash Saeidi Rashk Olia, Dunja Perić

The increasing demand for renewable energy has attracted attention to energy geostructures as means of extracting clean geothermal energy from the ground. To further advance the understanding of soilstructure interaction in energy piles analytical solutions considering the self-weight of the pile were derived. These solutions were then incorporated in recently-derived thermomechanical weightless solutions to provide comprehensive analytical solutions for axial displacement, strain and stress in single energy piles. This was accomplished by comparing responses of energy pile under different loading scenarios that reflect presence and absence of the self-weight. Results of mechanics-based analysis revealed that the self-weight of energy piles embedded in stiff soils has no significant contribution to displacement, strain and stress that develop under thermo-mechanical loads. Overall, the significance of the self-weight contribution depends on the magnitude of thermal load as well as the soil-pile interface stiffness. The stiffness of end restraints imposed to the pile head and tip were also found to play an important role in contribution of self-weight in induced thermomechanical stresses in energy piles.

Oct 1, 2022

By Paul A. Rittenhouse

First of all, I want to thank John Dunlap for asking me to this AIME meeting in Denver. I was first introduced to Denver and The Rocky Mountains more than ten years ago and immediately decided it was one of the most attractive spots in the world. I've come back many times since and still welcome any opportunity to return, even if it means I have to prepare and give a paper on potash. When John Dunlap gave me this assignment, he told me that the program would include papers on the geology of potash, papers on new discovered potash deposits and new mines and asked me to discuss potash from the commercial point of view. He also asked me to include a supply/demand outlook for potash. However, one thing he did not mention was "how far into the future he wanted me to look" and it seems to me the time element is a crucial factor to you who are both geologists and miners as well as to me. In your case, you have to look far enough into the future to give you time to explore, find, evaluate, develop, and bring into production a commercial deposit. My mining associates and friends don't agree on how long that takes but it's probably somewhere in the range of eight to fifteen years. But, they all agree on one thing and that is that the time required is continually getting longer. Now my time problem is just the opposite. It is "relatively" easy, and I stress relatively, to identify and evaluate the importance of the various factors that impact on both the supply of and demand for a commodity such as potash if the time period is today. It gets a little tough if one has to project into tomorrow or next week or next month. And when we start talking in terms of a year, five years or ten or fifteen years, things really get sticky and the old crystal ball becomes mighty cloudy. But we economists and forecasters are not known for our temerity so let me get on with the job at hand and take a look at the world potash supply/demand outlook.

Jan 1, 1978

By Zenjiro Asaki, Teruo Tanabe

"To clarify the formation of light rare earth (R =Ce, Pr, Nd or Sm) -Fe compounds in the reduction-diffusion (RD) process, two kinds of experiments were carried out: (a) RD experiment in which briquettes composed of R oxide powder, Fe (particles or wire) and CaH2 were reacted, and (b) immersion experiment, where an Fe plate was immersed into R-Fe melt having the composition of Fe-side liquidus line in Fe crucible. The compound formation was examined by using XRD, SEM and EPMA. The formation rates of RzFe17 measured by the RD experiment were compared with those obtained by the immersion experiment. The growth rates of compounds obtained in the RD experiment for Pr-Fe and Nd-Fe systems were much lower than those obtained in the immersion experiment. This result was explained by the difference of the reduction rates of R oxides by Ca. The parabolic rate constants for the formation of RzFe17 were separated in two groups of (a) Pr-Fe and Nd-Fe systems and (b) Ce-Fe and Sm-Fe systems. This was discussed in connection with the difference of their crystal structures and the driving force of diffusion. The parabolic rate constants for the formation of compounds in Ce-Fe and Sm-Fe systems decreased in the order of RFez, RFe3 and RzFe17.IntroductionTo understand reaction behaviors in the production of rare earth (R) -iron intermetallic compounds, which have excellent magnetic properties, is very important from engineering point of view. And the reduction-diffusion (RD) process<O has recently attracted attention as one of the promising processes to economically produce R-related materials. A few fundamental studies on the compounds formation in the RD process have previously been reported. Qi, Hino and Yazawa(2) observed the formation of R(Nd, Sm)-Fe and R-Co compounds in the process from various view points. Song and Ogawa(3) measured the growth rates of Nd-Fe and Sm-Fe compounds by using Nd or Sm vapor supplied from Nd-Ca or Sm-Ca melts. The authors have also carried out fundamental studies (4)-(8) to clarify the rate and mechanism in the production of R-Fe intermetallic compounds."

Jan 1, 1998

By R. Sellaro, E. Sarver

It has long been understood that extended occupational exposures to respirable mine dusts can lead to chronic lung disease. In underground coal mines, coal workers pneumoconiosis (CWP) and silicosis are major concerns. While many efforts have been made with the aim of understanding the mass-based concentrations and silica contents of respirable dusts under a variety of mining conditions, little research has been completed in characterizing dust at the individual particle level (by composition, size and shape). This study employed scanning electron microscopy with energy dispersive x-ray (SEM-EDX) to analyze dust samples collected from an underground coal mine in Central Appalachia. The results indicated that particle characteristics can vary widely between locations, though many trends might be explained based on knowledge of mining conditions. A continuous personal dust monitor (CPDM) was also used during the collection of some samples to determine respirable dust concentrations, which were compared against estimated concentrations based on the particle-level analysis.

Jan 1, 2014

By W. E. Robinson

Samples of raw oil shale and kerogen concentrates were oxidized by alkaline potassium permanganate, air, nitric acid, oxygen, and ozone to obtain information about the chemical structure of organic kerogen in oil shale. In one test, oil shale and oil-shale products were oxidized exhaustively with alkaline potassium permanganate, and the distribution of the organic carbon in the final oxidation products was determined. Comparing results of this oxidation with those obtained from other carbonaceous materials and known compounds gave information about the structure of kerogen. Alkaline potassium permanganate oxidation also was used partly to degrade kerogen into soluble products for characterization purposes. Structures present in these degradation products were indicative of type structures originally present in the kerogen. Nitric acid, oxygen, and ozone were used also for partly degrading kerogen to soluble oxidation products. Carbon-balance oxidation tests using alkaline potassium permanganate showed that Colorado oil-shale kerogen differs from many other carbonaceous materials such as coal and kerogens from other areas. Composition of the degradation products indicated that Colorado oil-shale kerogen is predominantly cycloparaffinic and saturated heterocyclic structures with some long-chain paraffinic and aromatic structures present. The ring systems may be connected through short carbon chains or bridges containing oxygen, nitrogen, and sulfur.

Jan 1, 1963

By Donald Giroux

This report documents the design, fabrication, testing, and coal mine demonstration of a hopper-feeder-bolter during a four-phase program for the U.S. Bureau of Mines. The machine was designed to increase productivity and safety in under-ground room-and-pillar mining. It performed well as a hopper-feeder for continuous haulage during a coal mine demonstration. Testing in a simulated mine showed that the machine also has good roof bolting capability.

Jan 1, 1987

By Harry Verakis, Thomas Lobb

Blasting accident data over a 30-year period (1980-2010) are summarized and presented for all types of surface and underground mining operations in the USA. The historical record of injuries from blasting accidents in all types of mines continues to show a significant decline. The overall decline in mine blasting injuries in the U.S.A. has resulted from advancements in blasting technology, training and improvements in blasting products and blasting processes. Some of the technology advancements such as safer blasting agents and computerized bulk vehicle loading, electronic detonators and remote operated blasting systems, and computerized blast design have and continue to significantly contribute to improvements in the historical blasting safety record. Also, the progress of significantly improving the safety of mine blasting has resulted from the combined efforts of miners, mine companies and operators, miners, unions, explosive and blasting product manufacturers, associations such as the International Society of Explosives Engineers and the Institute of Makers of Explosives and various government agencies.

Jan 1, 2012

By Seth C. Schaefer

The Federal Bureau of Mines studied the Gibbs free energies of formation of chromous fluoride (CrF2), chromic fluoride (CrF3), and chromium (II,III) fluorides (CrF2.40 and CrF2.45) with high-temperature galvanic cells employing calcium fluoride doped with 1 mole-pct yttrium fluoride as the electrolyte. Free-energy changes were obtained from open-circuit potential measurements for the following cells: Cr, CrF2 // CaF2 // NiF2, Ni (a) NiO, NiF2 // CaF2 // CrF3 , Cr203 (b) CrF2 , CrF2.40 // CaF2 // NiF2, Ni (c) and CrF2 ?45 , CrF3 // CaF2 // NiF2, Ni (d) with the following overall reactions Cr(s) + NiF2 (s) = Ni(s) + CrF2 (s) (1) 3NiO(s) + 2CrF3 (s) = 3NiF2 (s) + Cr203 (s) (2) 5CrF2 (s) + NiF2 (s) = 5CrF2.4O (s) + Ni(s) (3) and 3.64CrF2.45 + NiF2 (s) = 3.64CrF3 (s) + Ni (s) . (4) These results were combined with the best available literature values of ?Gf° of NiF2, NiO, and Cr203 to deduce Gibbs free energies of formation for the chromium fluorides expressed as follows: ?Gf°(CrF2) = -179.31 + 24.33 X 10-3T ± 0.43 kcal-mole. (5) (858.1 - 964.9 K) ?Gf° (CrF3) _ -226.16 + 1.82 X 10-3T ± 0.79 kcal/mole (6) (880.8 - 957.8 K) ?Gf°(CrF2.40) _ -213.65 + 32.14 X 10-3T ± 0.44 kcal/mole (7) (0053.9 - 936.8 K) and ?Gf°(CrF2.45) _ -176.17 - 12.67 X 10-3T ± 0.80 kcal/mole (8) (875.1 - 937.6 K). Free energies and equilibrium fluorine pressures for three univariant and one bivariant equilibria are illustrated.

Jan 1, 1976