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By D Pienaar, B McFadzean, C T. O’Connor

Collector and frother molecules in sulfide mineral flotation are thought to have separate roles in the flotation process, where the collector selectively hydrophobizes the mineral surface and the frother adsorbs onto the bubble surface, inhibiting bubble coalescence. Molecular interactions have been observed between these molecules which allow them to co-adsorb at each of the respective interfaces, improving pulp phase recovery. This study investigated the molecular interactions between sodium diethyl dithiophosphate (SDEDTP) and hexanol, and the mechanism by which these interactions improve the recovery of galena. In this study each of the respective interfaces were investigated for the adsorption of SDEDTP. The adsorption of SDEDTP on galena was measured by UV-Vis spectrophotometry and isothermal titration calorimetry. At the air-water interface foam stability and pulp bubble coalescence was used to quantitatively discern if there are interactions between SDEDTP and hexanol. Microflotation and induction time experiments were performed to determine the effect of SDEDTP, hexanol and their mixtures on mineral recovery and bubble-particle attachment. The results of all these tests were collated to determine if SDEDTP-hexanol mixtures synergistically improve sulfide mineral recovery. It was found that SDEDTP reduced bubble coalescence in the pulp demonstrating activity at the airwater interface. Together SDEDTP and hexanol synergistically enhanced foam stability. This indicated that there are attractive molecular interactions between these reagents. Even though DTP did not adsorb onto galena, DTP-frother mixtures synergistically improved the recovery and attachment probability of this mineral. Adsorption studies with aeration showed that DTP in the presence of a frother transfers from the air-water interface to the galena mineral-water interface during bubble-particle collision. It was proposed that the transfer of hexanol through the thin film enhanced the kinetics of film thinning between the bubble and the particle by destabilising the thin film thus improving pulp phase mineral recovery.

Aug 24, 2022

By Ronald Smeink, Ton de Gouw

"Reagents are an important cost-factor in the flotation of minerals. The mechanism of collectors and frothers has been studied extensively, but on depressants – probably the biggest cost-factor in the reagent suite – very little is actually known. Theories are frequently faced with the bare facts, pointing in another direction. Fundamental research is complicated by the fact that the amount of possible interactions in the flotation cell is almost unlimited and makes “change-one-parameter-at-a-time” experiments questionable and at least difficult to interpret. Also, the adsorption of depressants on the ore is very strong and desorption merely impossible. Detection methods therefore tend to be indirect and – therefore - non-specific about the location of the depressant on the ore.Depressants are supposed to adsorb selectively on gangue minerals; not on the valuable minerals in the froth. In order to be able to develop better and ‘’smarter’’ depressants, an analytical method is therefore required that will enable to detect which (=qualitatively) depressant, in which concentration (=quantitatively) sits where exactly (= selectively) on the mineral surface. (Answering the question: ‘’ Which minerals is located direct under the depressant?’’)And also: does the depressant compete with other reagents for that location? (like collectors) This analytical method is under development. The actual status of the method is promising and the results will be shown."

Jan 1, 2003

By Xiangjun Zuo

This paper firstly reviewed the state of the art in the recycling of used Printed Wiring Boards (PWB), and then presented part of the authors study on the combustion of PWB powders with and without the addition of catalyst. During the combustion of PWB powders without catalyst addition, there were two obvious exothermic reactions, one at 300-380oC, the other at 450-500oC. With the addition of catalyst during PWB combustion, there were no obvious exothermic reactions, indicating that dehalogenation reactions are not exothermic: The results showed that NaHCO3 and CaCO3 were very efficient to control the emission of Br2 and C6H6, lowering 80% compared to the case without catalyst, Na2CO3 can slightly control the emission of Br2 gas but not for C6H6 gas mission, and NaOH has no any effect of the control of both gases.

Jan 1, 2009

By John Ralston, Jonas Addai-Mensah, Patience Mpofu

The flocculation and dewatering behaviour of kaolinite (non swelling) and smectite (swelling) clay dispersions has been investigated using hydrolysable metal ions Mn(II) and Ca(II) and anionic polyacrylamide-acrylate copolymer (PAM) at pH 7.5 and 10.5. A pH-dependent, specific metal ion adsorption behaviour, accompanied by a marked reduction in particle zeta potential and slurry shear yield stress, was observed to have a profound influence on the colloid stability of both types of clays. Due to the differences in the cation exchange capacity, the smectite clay dispersion required a higher amount of metal ions than kaolinite dispersion to produce similar effects. The adsorption density of the anionic PAM at the negatively charged clay particle surfaces correlated well with metal ion hydrolysis and adsorption behaviour, all of which had a strong effect on slurry settling rate and extent of consolidation. At pH 7.5 where Mn(II) ions hydrolyse, metal ion and flocculant adsorption densities were both greater in the presence of Mn(II) than Ca(II) ions. At pH 10.5, however, where Ca(II) ions begins to hydrolyse, higher adsorption densities were observed for Ca(II) ions in comparison with Mn(II) ions, as the latter hydrolysed completely and precipitated. The metal ion mediated flocculant adsorption led to improved hydrogen bond driven particle bridging and facilitated charge neutralisation flocculation mechanisms which significantly enhanced the dewaterability of both clay dispersions.

Jan 1, 2003

By Jan J. Cilliers, Nicolas Barbian, Esther Ventura-Medina

"Mineral froth flotation is one of the most widely used processes to separate particles of valuable mineral from its associated gangue. It involves the selective separation of the hydrophobic particles from the slurry into the froth. The hydrophobic particles attach to the air bubbles and rise up to the froth phase on top of the slurry. The valuable mineral is collected when the froth overflows the cell wall. The separation performance of the process can be linked to the amount of solids and valuable material loaded on the bubble shells. In addition, it is well known that in most mineral systems, the presence of solids can enhance the stability of the froths. How the solids get to be distributed and what proportion is actually attached and stabilising the bubbles is not well known.This study aims to establish the relationship between operational variables, solids loading on bubbles and flotation performance. For this purpose, a series of industrial experiments to sample the solids in the bubble films under different operational conditions were carried out in two copper concentrators under steady state conditions. Samples of the lamellae were taken by touching the top surface of the bubbles with a glass slide. The amount of solids and liquid per unit area in the bubble lamellae can subsequently be estimated gravimetrically and by image analysis. The grade of the attached particles was also measured by adequate sampling. This gives an indication of the maximum grade that could be achieved from the process under the operating conditions."

Jan 1, 2003

By Yongfu Yu, Xiaotie Wang, Fuguang Zhang, Liping Che

"Rare Earth water dregs is the drained waste dregs, which contains over 0.2 percent thorium dioxide and about 6-10 percent di-Rare Earth trioxide, which is beyond the standard of draining off that China governments set, so that the Rare Earth water leach dregs must be sacked and laid down in storehouse, which costs lots of money. It is a pity that the RE and thorium compounds very useful elements in industry are discarded. A lot of work must be carried out so that this resource was fully developed.In this paper, four separation techniques of recovery Rare Earth minerals and enrichment thorium element and reduction thorium content of drained dreg for the different test samples of Rare Earth water leach dregs which is radioactive waste dregs got from diverse locus are studied, respectively, and the separation characteristic and the separation process are described, using several combination processes of classification and gravity and flotation separation which were prepared according to the characteristic of test samples and technology. The test results show that the combination processes are the more remarkable separation techniques and the flotation reagents used in test can be applied to utilizing synthetically radioactive waste dregs. Through the combined technique process, three parts of products were obtained, namely, Rare Earth concentrate collected, the thorium product enriched and a large amount of the waste dregs product that can be directly drained and the total quantity is 50%-60%. In order to determine optimum technical condition, the effect factors of separation process were investigated in the test."

Jan 1, 2003

By Patrick A. Turner, Timothy J. Olson, Abraham J. Schutte, Roman van Ommen

"The use of classifying devices in grinding circuits dates back to the early 1900’s when classifiers were installed to close ball mills. The search for ways to further improve grinding circuits led to the use of hydrocyclones in place of mechanical classifiers in South Africa in the early 1950’s. Today Hydrocyclones are considered as the best classifying devices to close grinding circuits. After 50 years of development the hydrocyclone has changed significantly when compared to the designs of the early days, but the focus to circuit optimization must be expanded to an understanding of the integral system consisting of mill, cyclone feed pump and cyclone.The key to good cyclone circuit design and operation in primary grinding circuits will be discussed including individual cyclone design features such as cone angle or materials of construction, as well as orientation and manifold configuration.Cyclone performance issues as well as maintenance considerations will be detailed in an effort to achieve consistent cyclone operation with minimal coarse solids in the overflow. “The importance of constant cyclone feed conditions is unquestioned today. The challenge of Cyclone sizing is a large number of not fully known variables prior to startup. The most significant unknown variable is slurry viscosity. Because of this, engineers often specify a conservative cyclone system that produces a finer than required separation. However, this approach often leads to higher circulating loads and a higher overflow density in order to produce the required separation. The higher cyclone overflow density results in a less efficient cyclone separation. The average concentrator can pick up 2-4% finer overall grind by having a more aggressive cyclone operation.”"

Jan 1, 2003

By Hamid-Reza Manouchehri

"The triboelectric charge attributes of some silicate minerals (i.e., feldspar, quartz and wollastonite) after contacting different triboecharging medium made of different materials were studied. The charge acquisitions by different size fractions of minerals were monitored and accordingly the energetic work function values, i.e., the main parameter determining the entity of triboelectric charges acquired by mineral grains, of the examined minerals were estimated. Moreover the separation behavior of different size fractions of these minerals through the electric field of a laboratory free-falling separator when the mineral grains are charged by different tribochargers were observed and considered as the electrical separation potential of the examined minerals.Furthermore, the role of adsorption of different chemical species on triboelectric charge characteristics and charge acquisition of mineral samples were described from theoretical point of view and the effects of some chemical reagents on triboelectric charge acquisition of the examined minerals were studied. In addition the separation behavior of chemically conditioned quartz, feldspar and wollastonite minerals, using different anionic and cationic reagents, through the electric field of a free-fall electrostatic separator before and after chemical conditioning were monitored.Finally an attempt was made to translate the findings from single mineral systems to a complex silicate ore, containing mainly of feldspars, quartz, and wollastonite. Different separation tests under various conditions were conducted to this complex silicate ore. Before passing through the separation device, the ore sample was conditioned by different cationic and anionic reagents and then was triboelectricaly charged by different tribocharging medium in order to find the effective reagent and tribocharging medium for separating silicates. Besides the role of temperature and humidity of the surrounding ambient in separation behavior were considered."

Jan 1, 2003

By P. N. Mohan Das, K. Harikrishna Bhat

"The major ilmenite reserves are located in India at Chavara (CH), Manavalakurichi ( MK) and Chatrapur, Orissa (OR). India stands first in terms of ilmenite reserves, which are estimated to be 278 million tonnes out of which, 142 million tonnes are processable. Mineralo-chemical analysis showed that Chavara ilmenite is the most weathered one with about 60% TiO2 while Chatrapur is the least weathered with about 50% TiO2. XRD and SEM studies of different magnetic fractions of these three mineral deposits established the co-existence of ilmenite with pseudorutile, rutile and haematite phases in substantially varying amounts. It is observed that the tropical weathering rather than the source rock difference has apparently played an important role in imparting major compositional and structural dissimilarities among the ilmenites in different places. Further, the chemical analysis, XRD and SEM characterisation of differently weathered samples of MK ilmenite separated by the magnetic fractionation showed that the degree of alteration was invariably associated with the decrease in magnetism, increase in the rutile phase and the change in Fe2+/Fe3+ ratio of ilmenite grains. Magnetically separated fractions when subjected to metallisation with carbonaceous reductant such as coke showed that the degree of reduction increases with the degree of alteration and with the decrease in the Fe2+/Fe3+ ratio.In the processing of ilmenite through the Becher process, aeration rusting of pre - reduced ilmenite is found to be the rate-limiting step thus, affecting the productivity and economy of the process. Investigations have proved that the addition of some organic compounds such as glyoxal, sucrose etc., to the system accelerates the reaction to such an extent that the rusting time has been reduced to less than half. The formation of acids by the these organic compounds during the rusting reaction was proved responsible for maintaining the pH of the solution in the range 3-4 at which iron hydroxide do not precipitate and block the pores in the reacting surface of the grain."

Jan 1, 2003

By CHARLES W. BENTON

THE following paragraphs comprise such information as the Secretary has been able to obtain concerning the members and associates whose deaths have been reported. Further particulars or corrections of errors, and biographical data concerning deceased members or associates not already noticed in this way, are solicited. Charles IV. Benton was born at Kezar Falls, Maine, Nov. 12, 1843. We have no accurate knowledge concerning the early part of his career. In 1871 he engaged with the N. Y. Honduras Rosario Mining Co., at San Juancinto, Honduras, C. A., and later was employed at the Monserrat mine at Yuscaran, and at Santa Lucia, Honduras, with the Tenero Mining Milling Co. of Pennsylvania. In 1897 he became a member of the Institute. At the time he was stricken with his last sickness he was employed at the Paymaster mine at Tucson, Ariz. He died at Fairmount, Denver, Colo., Sept. 9, 1907. William R. Boggs, Jr.-The notice in the Bulletin for January was incorrect in saying that the murder of Mr. Boggs occurred while he was employed as metallurgical. manager by Mr. W. B. A. Dingwall, at La Maroma, San Luis Potosi, Mex. Mr. Dingwall writes that in March, 1907, Mr. Boggs left him, to return to his home at Winston, N. C., whence he. subsequently went to Durango, Mex., to take, with the Topia Mining Co., a position which he occupied at the tine of his death, Nov. 17, 1907. Mr. Dingwall says that, while in his service, Mr. Boggs never had any trouble with the workmen, but was esteemed and liked by them, as by all who knew him ; and adds, injustice to the State of San Luis Potosi, that the population, even in the mining-camps of that State, is orderly and law-abiding, and that the authorities are vigilant and just. Our

Mar 1, 1908

By D. M. MacHunter, T. Lawson, D. K. Henderson

The development and commercialization of new generation high tension electrostatic separators has provided a basis for simplifying mineral separation plant circuitry. The inclusion of new design features including insulated plate electrodes that have resulted insignificantly improved separation efficiencies in electrostatic separators are described. The increase in separation efficiency has resulted in a reduction in the number of treatment stages required to produce final high grade mineral products. Comparative performance data on different feed types are presented. A comparison between mineral separation plant flowsheets using both conventional and new generation high tension electrostatic separation technology is presented. A 55% reduction in the number of installed electrostatic separators and a 36% reduction in plant area was achieved through the use of this new electrostatic separation technology.

Jan 1, 2003

By John Feddock

A recent increase in energy demand has resulted in the rapid growth of coal consumption in the People?s Republic of China (PRC), which is the largest coal producer and consumer in the world. Reportedly, the safety issues in Chinese coal mines have been improving, but the number of fatalities and serious injuries continues to be alarmingly high. The number of fatalities from catastrophic accidents have prompted researchers to review the Chinese mine safety situation and to look for potential solutions. Marshall Miller & Associates, Inc. (MM&A), along with various collaborators, has investigated these issues as part of its work on various projects in the PRC and has discussed the concerns with relevant Chinese officials. Preliminary investigations by MM&A of coal mine accidents during 2001?2006 in the PRC indicate that 65%-78% of the total fatalities were the result of gas explosions and roof falls in underground mines. Even though the drainage of methane has been practiced for decades, current practices do not always produce satisfactory results due to technical constraints and equipment limitations. Based on prior experience of in-seam degasification at the Daning Coal Mine located in Shanxi province, MM&A believes that in-seam directional drilling technology can be a viable solution to degas the low-permeability Chinese coal deposits. This paper 1) reviews current Chinese coal mine safety conditions, 2) analyzes the advantages/disadvantages of current degasification practices in China, and 3) presents the pre-mining degasification practices for the longwall panel at the Daning Coal Mine.

Jan 1, 2007

By K. Wenrich

The uranium industry has made a dramatic turnaround in the past three years that even the most optimistic economist was not willing to predict during the uranium downswing of the 1990s. Uranium reached a 30-year low in February 2001 of $6.50/lb. By the end of February 2006 it had soared to $38.50/pound. This nearly 600% increase in the uranium spot price within 4 years dwarfed the increase in gold price that has barely mustered a 100% increase. The initial slow rise from $6.50 in February 2001 to $10.75 in April 2003 (fig. 1) was primarily driven by the decrease in the value of the dollar. Since then several factors have contributed to the soaring price: (1) The awakening of many to the simple fact that uranium supply has not met demand for several years and that the world’s stockpiles are being drawn down, (2) How sharply this fragile supply can be impacted by disasters at the world’s major uranium production facilities, such as a) the flooding of the McArthur River Mine in the spring of 2003, b) fires at Olympic Dam, c) the potential that Rossing, with an annual capacity of 4000 tonnes uranium might close by 2007, (3) the withdrawal of Tenex from the HEU (highly enriched uranium) feed agreement, and (4) the announcement by the Chinese of their intent to build 30 new nuclear reactors.

Jan 1, 2007

By Bill Stormes

This paper will discuss implementation of the Hilti OneStep rock anchor technology to improve face bolting operations during the May 2008 longwall move; increase rock anchor installation capacity; and improve safety by reducing employee exposure periods by utilizing the Hilti OneStep rock anchors.

Jan 1, 2008

Drilling in the south of the Rapahoe Sector at Greymouth Coalfield has demonstrated the existence of thick coal seams in the upper Rewanui Member. Seam correlation is handicapped by complex lithostratigraphy and laterally variable geophysical log profiles. An integrated investigation of coal measure stratigraphy, coal petrology, and proximate analyses, suggests a feasible model whereby most of the major seam intersections belong to a single horizon. Coal properties vary laterally in response to original swamp conditions, which are believed to have ranged from well-drained to ponded. A new model of peat accumulation is proposed for the northern Rapahoe Sector, whereby Upper Rewanui peat accumulation occurred on a flood plain between the levees of a major south southwest-flowing fluvial system in the east and the toe of a western alluvial fan.

Jan 1, 1985

By K. A. Natarajan

Interaction with microorganisms results in significant surface chemical changes on minerals. For example, chemolithotrophs such as Thiobacillus ferrooxidans and Thiobacillus thiooxidans significantly alter the surface chemistry of several sulfide minerals such as pyrite, chalcopyrite, sphalerite and galena. Heterotrophic bacteria such as Bacillus sp. could alter the electrokinetic properties of oxide minerals such as hematite, alumina, silica, kaolinite and calcite. Microbe-mineral interactions could thus be beneficially utilised in mineral beneficiation as different from bioleaching. Microbially induced mineral beneficiation unlike bioleaching deals with interfacial phenomena at mineral-solution-bacteria interfaces and surface chemical changes are brought about at very rapid rates amounting to a few minutes resulting in mineral separations in an aqueous medium.

Jan 1, 2003

By A. M. Tonnos

Underground mining has yet to see an industry wide solution for control of their ventilation systems due to the complexity and sensitivity of the underground environment. Complexity arises from multi-level, multi-zone operations and sensitivity is associated with the impact that changes in equipment status and output have on air flows and quality throughout the mine. Our approach to solving this challenge incorporates system modeling and industrial control systems in a unified architecture. Although this approach can be applied to other processes and industries, this paper will cover the theoretical and practical aspects of an integrated model-control system (MCS) as it applies to underground mining ventilation.

Jan 1, 2009

The ventilation conditions at the underground coal mines are influenced; first: by the disturbances of the natural nature (barometric pressure, methane liberation, etc.), and second: by the disturbances caused by the production process. The major goal of this study was to determine the changes of the ventilation parameters, such as the flow, pressure and methane concentration around the longwall panel, particularly, along the longwall face due to the shearer operation (motion). It is well known from the practice, that the movement of the shearer influences the ventilation parameters around the longwall panel, including the gob area. Until now, these data were gathered in a single or multiple locations at the different time. However, only the simultaneous measurements of all of these values allow seeing the time dependent interrelationships between measured parameters. To be able to show these interrelationships, special experiments, described in this paper, were carried out by the author. These experiments were prepared and executed at the BUDRYK Coal Mine in Poland. During each experiment a simultaneous measurements and monitoring of the barometric pressure, air velocity and methane concentration at the different locations along the longwall face, were performed. The investigation was possible by using a special setup of instruments with a short sampling time, i.e., within 2 seconds. The monitoring of the absolute pressure was conducted by using the digital barometer µBar, developed by EMAG, based on the SETRA pressure transducer, model 470. The velocity of air was measured using the electronic vane-anemometers, developed by IMG-PAN. The methane concentrations were measured using methanometers as the part of the EMAG automatic gas monitoring system. The investigation data confirmed that disturbances due to the operation (motion) of the shearer at the longwall face have a local character. It could be also seen that a large diameter shearer (compared to the total cross-section area available for the air flow) is acting as the piston compressing the air (the overpressure) ahead of the shearer. This fact affects the methane mixing process and flow patterns in the vicinity.

Jan 1, 2009

By W. R. Hardwick

This Information Circular describes the development of block-caving methods and practices by the Miami Copper Co. at the Miami mine in Gila County, Arizona. It is one of a series published by the Bureau of Mines on mining methods, practices, and costs in various mining districts of the United States. This report gives a history of the district and outlines early prospecting and exploration including methods of sampling and estimation of ore tonnage and value at the Miami mine. Early mining methods are described, particularly those that influenced developments in the caving method. Mine exploration, development, and operating methods for block caving are described with particular attention to those factors, physical, economic, engineering, and managerial that have improved efficiency in the mining operations over a long productive period. Extraction, ventilation, wage system, safety, water supply, power plant, and shop facilities are discussed. The last section gives a brief summary of such costs as are available for publication.

Jan 1, 1965

By Bruce Hebblewhite

This paper focuses on the recent achievements and practices developed through the Minerals Tertiary Education Council (MTEC) initiative of the Minerals Council of Australia (MCA), in conjunction with the three partner universities involved in mining engineering education – University of New South Wales (UNSW), West Australian School of Mines, Curtin University (WASM), and University of Queensland (UQ). The collaboration between these partner universities and industry has led to the development of shared course material, cross-institutional teaching arrangements, and development of a number of flexible, distance-based delivery programs. The paper will then move on to future initiatives. Importantly, the exciting challenge is the future initiative planned to cement this collaboration by the formation of a “virtual” national school of mining engineering – Mining Education Australia (MEA). This will provide a common 3rd and 4th year program to all three universities from 2007, involving innovative teaching and learning arrangements, greater student exchange potential and a more significant input by industry into the education process. Such an initiative is not without its challenges, and has a long way to go, before becoming a reality. However, it offers greater attractiveness and marketing potential to prospective students, as well as economic efficiencies, whilst delivering a better quality, and hopefully greater quantity of graduates to industry. It can also form a launching platform for a much greater level of international collaboration, through a proposed International Mining Education Network (IMEN) which is currently being floated amongst a number of international educators.

Jan 1, 2005