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By Rauno Peippo

Horizontal Waste Heat Boiler (WHB), today's proven and dominating technology for copper smelter gas cooling, has been utilized by the industry for over half a century. During this time development has taken place in geometry, flow characteristics, cleaning technology and design details. This development has been driven by improved understanding of the specific process requirements, gained both by wide experience and by utilizing new emerging design tools, like computer flow modeling. It had to wait till mid 90's to unite effective and proven Spring Hammer cleaning technology and the process benefits gained by gas guiding vanes or baffle wall in the copper smelter WHB design. The new design has demonstrated improvement in gas cooling efficiency and the process conditions down stream in form of less dust sticking problems in the boiler and precipitators. Reduced weak acid production has also been reported as a result of the design. The theoretical aspects, computer flow modeling results and actual benefits measured in old smelting line modernization are discussed. Experience £tom modernization projects such as Phelps Dodge, Atlantic Copper, Mexicana de Cobre, and Nippon Mining, Saganoseki, are discussed. In mechanical design there has been development resulting improved gas tightness with less corrosion and better control of dust sulfation. An essential improvement is the integration of the boiler hopper and dust removing conveyor. Having no steel plate casings in the hopper and conveyor section but using of boiler tube membrane instead eliminates thermal expansion differences. The dust conveyor will be effectively cooled against hot dust lumps falling down while the acid dew point corrosion is prevented in the cooler sections of the hopper. Conceptual features are presented of a new generation Copper Flash Smelter WHB presently under construction at Boliden Mineral, Skelleftehamn, Sweden, where the latest development and innovations are adopted.

Jan 1, 1999

By R. M. S. Häggblad

The article deals with stabilisation and regeneration of Ce02 and Ce02/Zr02 based Pt water gas shift catalysts, subject to high initial deactivation. The reaction gas species effect on the catalyst deactivation was investigated by H2-TPR. Activity measurements enabled the effect of different promoters, some added to the Ce02 based catalysts and some to the Ce02/Zr02 based Pt catalysts, to be investigated. The catalysts were also characterised by BET and CO-TPR. Deactivated catalysts activity was restored by using various regeneration methods. Of the two selected carriers the Ce02/Zr02 based Pt catalyst showed the highest resilience to deactivation. For the two different carriers, Ce02 and Ce02/Zr02, Wand Re were the best promoters when the catalyst was subject to deactivation. Experiments with Hr TPR indicate a fast initial change in the platinum oxides concentration and composition. The CO-TPR was used to make conclusions about the various regeneration effects of water and oxygen on the catalyst. Finally it is suggested that not one deactivation mechanism is possible and which mechanism that dominates is dependant on the catalyst and the reaction gas composition.

Jan 1, 2005

By Hongling Wang, DI WU, Shuai Li, Hui Shu

Isothermal reduction experiments on carbon-bearing pellets of copper slag were investigated by the thermogravimetric method with biomass carbon as a reducing agent. The results indicated that the reduction process of copper slag‑biomass composite pellets was dominated by gas phase diffusion, and the apparent activation energy was 88.44 kJ/mol. In the temperature range from 1000 to 1200 °C, the metallization rate of pellets increased with increasing temperature, and the maximum metallization rate was 78.4%. The optimal reduction temperature of CSBCP (copper slag-biomass composite pellets) was 1200 °C.

Nov 23, 2022

By g. Caproni

The main constituent of the feed to the "Sulphide Section" (31 t/h), in the F. Sartori Plant (6000 tid) of the Miniere di Mon)eponi(Sardinia), is the ore of the Campo Pisano -Funtanaperda Mine (1 ? Difficulties have always been experienced in the treatment of this ore, owing to the extramely fine Pyrite-Sphalerite intergrowth and to the high Pyrite and soluble salts contents. The first mentioned difficulty was overcome with a rather complex flowsheet (see fig.1A and lB)(2); the others with a reagent combination that required a pH of 11 in a pulp loaded with soluble salts. This meant high consumption of alkalizer, and also of the other reagents; furthermore the alkalizer had to be mainly NaOH with only minor amounts of lime, because the latter tended to depress not only the pyrite but also the middlings, which were supposed to float. With dialchylditiophosphate alone as a collector, a lower pH could have been used, but a certain amount of amylxanthate was indispensable to promote flotation of the middlings. On the other hand, a bulk-flotation of sphalerite and pyrite at low pH could not be very advantageous on account of the high pyrite content in the feed(3).

Jan 1, 1971

By Chaz Weaver, James Sheahan, Michael Mo

"The Virginia Department of Transportation (VDOT) undertook a program to replace four bridges along approximately 4 mi (6.4 km) of US 340 in Northwest Virginia. Two of these bridges, which span Compton Creek and the Norfolk Southern Railroad respectively, are the subject of this article. HDR provided roadway and structural design as well as geotechnical engineering services for the Norfolk Southern Railroad Bridge while their subconsultant, Saeed Associates, provided structural engineering services in support of the HDR roadway and geotechnical team for the Compton Creek Bridge.The project is located in the Valley and Ridge Geologic Province of Virginia, on an alignment that is adjacent to the Shenandoah River. The project lies within the Beekmantown Group consisting of limestone and dolostone that are prevalent and prone to karstic activity in a band that passes through the project area and north into Central and Eastern Pennsylvania. This area has been impacted by karst limestone conditions where caves and sinkhole activity is common. Caves at Luray and Front Royal, located to the south and north of the project, respectively, are popular public attractions.Since the potential for variability of subsurface conditions can be, and often is, greater in karst terrain, the need to develop a design that provides as much flexibility as possible during construction, and then to be prepared to efficiently review and respond to construction questions is heightened. Coordination and communication among the design staff, VDOT’s design and construction staff, and the contractor was a key factor in completion of this project.Compton Creek BridgeThe alignment for the new Compton Creek Bridge is located about 125 ft (38 m) west of the existing bridge, placing it between that bridge and the existing Norfolk Southern Railroad Bridge. No information about the foundations was available for the existing bridges. Borings in the Compton Creek valley encountered extensive voids (some clay filled and some open) with numerous boulders, rock ledges and pinnacles, particularly on the north side of the creek. Geophysical and geotechnical investigations indicated that below a poor and variable upper zone of rock was a layer of more competent and consistent limestone, which appeared to contain little or no voids."

Jan 1, 2017

By Jalal Vakili

In designing very large excavated slopes which are becoming increasingly common in both mining and civil engineering projects, the most important decision of the engineer is the selection of a slope angle. The purpose of the geotechnical study of the slope is to ensure reasonable stability of the slope in the most economical way. Because the rock mass composing each slope is unique, there are no standard solutions for slope stability analysis. A practical solution is formulated from the basic geologic data, engineering properties of the rock, geometry of the slope, and ground water observations. Stability analysis consists of analyzing the forces causing and resisting slope failure. There are several methods of slope stability analysis. The limit equilibrium method evaluates the overall stability of the sliding mass just on the verge of slip, using some or all of the three equations of static equilibrium of a plane problem. The stress-strain relationships of the rock mass are not considered. Method of analysis include the assumption of the shape of the slip surface. Peterson (10) introduced the Swedish method of analysis in 1916, which is based on cylindrical sliding surfaces. Fellenius (4) in 1926 extended this method and introduced the method of slices. This method was refined by Bishop (I) in 1955 and later used by Morgenstern and Price (8) in 1965. In many cases layers of extremely soft strata or strata weakened by neutral stress cause failure to take place by translation along plane of weakness instead of by rotation on a circular surface. In this paper, a slope with a horizontal layer of weak meterial is selected for analysis. This is a usual case for open pit lignite mines where lignite seam may be non-cohesive and 'weaker than the overburden rock or a soft clay layer underlies the seam. It is also a common case of rock fill dams supported on a foundation stratum of clay where the strength of the clay layer is less than that of the rock fill. It is shown that utilizing this method, the location of potential failure surface and the value of the minimum factor of safety can be calculated directly and the trial computations of factors of safety for a number of assumed failure surfaces are not necessary.

Jan 1, 1982

By D. A. Bird

Geochemical models using published thermo-dynamic data and laboratory derived kinetic rate laws allow prediction of post-closure pit lake geochemistry at open pit mining sites. A combination of "forward" and "inverse" modeling techniques can predict the pit lake geochemical evolution from initial infilling to eventual steady state attained decades or centuries after closure. Computer codes have been developed to model chemical reactions such as pyrite dissolution, describe the ground-water flow regime, and provide rock-water ratios. The incorporation of site specific information, such as ultimate pit dimensions, geologic and hydrologic data, acid generating potential (AGP) vs. acid neutralizing potential (ANP), and laboratory derived kinetic rates, allows application of the model to open pit mines at any stage of development.

Jan 1, 1994

By Shun-ichi Satoh

The electric arc welding of cast iron has been studied by Braune Lamberton, Schimpke, Kenyon, Gale Manufacturing Co., Wedemeyer Candy, Neese, Miller, Carter, American Welding Society, Namack Lebrun, Achenbach, Jansson, Xochendorffer and others.' The write of this paper has been able to obtain a series of cast irons, from gray tc white, without using cast-iron electrodes but by coating on wrought-iron bars mixtures of carborundum (Sic) and graphite (C). In this work, he found the curious phenomenon of barium carbonate.

Jan 1, 1929

By Normand Champigny

The Forces of Change ? The current business environment ? What can we expect for the future on management of physical assets ? The impact of maintenance on production costs ? What is RCM is doing is improving business performance ? The beginnings of RCM The RCM II Process ? RCM II is a structured process that involves employees in determining the best failure management tactics for systems and equipment in their operating context ? The method is an effective approach to risk and cost reduction as well as failure management

May 1, 2002

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) measurements provide direct evidence for the involvement of Cr(V) in the reduction of Cr(VI)· by NAD(P)H. Addition of hydrogen peroxide (H2 O 2) to NAD(P)H-Cr(VI) reaction mixtures suppresses the Cr(V) signal and generates hydroxyl (·OH) radicals (as detected via spin trapping), suggesting that Cr(V) reacts with H2O 2 to generate the ·OH radicals. Reaction between H2O 2 and a Cr(V)·glutathione complex, and between H2O 2 and several Cr(V)-carboxylato complexes also produces ·OH radicals. These results suggest that Cr(V) complexes catalyze the generation of ·OH radicals from H2O 2, and that ·OH radicals might play a significant role in the mechanism of Cr(VI) cytotoxicity. KEY WORDS: ESR. spin trapping, Cr(VI) reduction, Cr(V), hydrogen peroxide, free radicals.INTRODUCTIONThis communication reports an ESR spin trapping detection of hydroxyl ( OH) radicals.in reactions between some Cr(V) complexes containing biologically important ligands and hydrogen peroxide (H2O 2 ). This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step in the mechanism of Cr(VI) toxicity, the reaction· mechanism is not yet clear. 1 Mutagencity has been well documented for Cr(VI) via various bacterial assays, while Cr(III) has been shown not to be mutagenic.2 • 3 Since it has been reported that compounds containing Cr(VI) do not react with isolated DNA,4 the reduction of Cr(VI) by other cellular constituents has been thought to be important in the mechanism of Cr(VI) induced DNA alteration.1·4 • 5 For cellular systems earlier studies include those on the reduction of C~(VI) by microsomes,6-8 rat liver DT-diaphorase,9 and aldehyde oxidase. 10 Regarding the reduction mechanism, Jennette used ESR spectroscopy to show that a long-lived Cr(V) complex is formed as an intermediate in the microsomal reduction of Cr(VI) in the presence of NADPH.8 She postulated that Cr(V) is the ""ultimate"" carcinogenic form of chromium compounds. This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions.11 - 19 More recently, however, it has been suggested that oxygen-derived radicals generated during the Cr(VI) reduction are the species responsible for the DNA alteration.20.2• To the best of our knowledge, however, no information is available on the generation of such radicals in the reduction of Cr(VI) under biologically relevant conditions, except some preliminary results on the glutathionyl (GS·) radical formation in the reduction of Cr(VI) by glutathione (GSH). 11 - 19 We, therefore, undertook a systematic investigation of the reaction of Cr(VI) with NAD(P)H, GSH, ix-hydroxycarboxylic acids, and H2O 2 • NADPH was chosen as a model reductant because of its ubiquitous existence inside the cells, its critical role in the enzymatic Cr(VI) reduction,1·6-9 its representation of important cellular Cr(VI) reductants, and its ability to reduce other metal ions.22 GSH was chosen as another model Cr(VI) reductant because GSH also exists inside cells, it represents another important category of cellular Cr(VI) reductants, the thiols, and it also plays an important role in the Cr(VI) toxicity .1• 1 ""- 19.i3.i4 For further clarification, we also studied the reaction of Cr(VI) with several '1'.-hydroxycarboxylic acids in the presence of H2O 2 since these acids are definitively known to reduce Cr(VJ) to form stable, isolable Cr(V).25 .2 6 The results obtained indicate that Cr(V) complexes, produced in the reduction of Cr(VJ) by cellular reductants, react with H2 O 2 to generate ·OH radicals, which might be the initiators of primary events in Cr(VI) carcinogenicity."

Jan 1, 1990

By Aidan Giblett, Karen McCaffery, Robert Dunne

"A worldwide decline in competency levels of practicing metallurgists over recent decades has become clearly evident and is a common topic of discussion among senior practitioners and professional associations. The associated impacts on the industry are material and include operational inefficiencies, missed optimisation opportunities and suboptimal new plant designs. There are many contributing factors to this condition. Decrease in competency is particularly evident both in regions where imbalance between supply and demand has led to a general reduction in experience levels for comparable roles over time and in emerging regions where a rapid rise in demand for practitioners has occurred in conjunction with rapid economic development and industrialization. The context, depth and breadth of education curricula and levels vary with location such that solutions to the technical competency dilemma may need to be developed specifically for each region with these influences in mind. Delivering, demonstrating and maintaining competencies are a critical requirement of undergraduate training and ongoing professional development. Other factors such as generational and cultural characteristics and expectations, political influences, role requirements and employment reward and recognition systems all play a critical role in determining if core competencies can be effectively developed, applied and subsequently maintained. This paper reviews factors impacting and some common approaches to competency development. The authors’ experiences in the management of professional development efforts within the global industry are reviewed and a blueprint proposed to address industry requirements in this area."

Jan 1, 2014

By Z. Zhiqun, V. A. Marple, B. Y. H. Liu

"IntroductionIt is commonly understood that aerosol particles may be injurious to human health if they are of a size that enables them to enter the respiratory tract. Coal Workers' Pneumoconiosis (CWP) is one disease known to be caused by coal mining related particles.The location in the respiratory tract where the particles are deposited is primarily a function of the equivalent aerodynamic diameter (EAD) of the particle. The equivalent aerodynamic diameter is the diameter of a spherical particle with a density of 1.0 gm/cm3 with the same falling speed as the particle in question. For a spherical particle the calculation is rather simple in that the equivalent aerodynamic diameter is simply the diameter of the particle in question multiplied by the square root of the density of the particle. For irregularly shaped particles, such as coal particles, there is no simple way to make the EAD calculation. For example, Figure 1 is only one of an infinite variety of particle shapes that can be found in practice and the aerodynamic size of this particle and, therefore, its deposition location in the respiratory tract would be nearly impos-sible to estimate accurately.The normal method for determining the aerodynamic diameter of particles has been to experimentally measure the size of the particles in a settling chamber or with an inertial classifier such as an impactor, cyclone or a centrifuge, since inertial classifiers have the property of classifying the particles according to their aerodynamic diameters."") However, these devices can only give limited information on the EAD of a single particle with a specific shape. Impactors and cyclones, for example, collect particles in size ranges and not at a specific size, so the determination of the EAD of a specific particle is not possible. A centrifuge, on the other hand, can measure the EAD of a specific particle but the equipment is costly and procedure laborious, and it may not be possible to disperse a particle of a specific shape into the centrifuge. The centrifuge can be used to determine the EAD of clusters of spheres in various arrays, but introducing particles of a specific irregular shape may not be feasible. Furthermore, the EAD is a function of the orientation of an irregularly shaped particle and the orientation of a particle in an inertial classifier is unknown. The orientation may also vary as the particle passes through the classifier.Because of the difficulty in determining the EAD of an irregularly shaped particle, we have undertaken a program to apply theoretical numerical methods to calculate the EAD of any shape particle. In our laboratory we have, for some time, been using numerical methods to determine the flow field of air within instruments such as impactors, (2) inlets, (3) and virtual impactors (4) Recently, this technique has been expanded into the three-dimensional regime, and the flow fields and particle motion characteristics within cyclones (5) and glove boxes have been studied. We have now begun to use these numerical three-dimensional flow programs to study the flow field around irregularly shaped particles to determine their drag coefficients, falling speed, and thus, their EAD."

Mar 1, 1989

By Alireza Javadi Nooshabadi, Kota Hanumantha Rao

Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by sulphide minerals during grinding was examined. It was found that pyrite (FeS2), chalcopyrite (CuFeS2), sphalerite ((Zn, Fe) S), and galena (PbS) generated H2O2 in pulp liquid during wet grinding and also when the freshly ground solids are placed in water immediately after dry grinding. Pyrite produced more H2O2 than other minerals and the order of H2O2 production by the minerals was found to be pyrite > chalcopyrite > sphalerite > galena. The pH of the water influenced the extent of hydrogen peroxide formation with greater amounts of H2O2 produced at highly acidic pH. Furthermore, the effect of mixed sulphide minerals, i.e., pyrite-chalcopyrite, pyrite-galena, chalcopyrite-galena and sphalerite-pyrite, sphalerite-chalcopyrite and sphalerite-galena on the formation of H2O2 showed increasing H2O2 formation with increasing pyrite fraction. There is clear correlation of the amount of H2O2 production with the rest potential of the sulphide minerals; the greater the rest potential of a mineral the greater the formation of H2O2. This study highlights the necessity of revisiting the electrochemical and/or galvanic interactions between sulphide minerals, and interaction mechanisms between pyrite and other sulphide minerals in terms of their flotation behavior in the context of inevitable H2O2 existence in the pulp liquid.

Jan 1, 2014

By M. Kunst

The creep behavior of three AJ62 alloys was investigated in a wide range of stresses and temperatures. Multi-level tensile creep tests revealed a distinct primary creep stage and a high stress exponent up to a value of 10. The threshold stress concept which is commonly used in combination with high stress exponents was utilized in the analysis of creep behaviour. This resulted in an effective stress exponent for the AJ alloys indi¬cating dislocation climb as the dominating creep mechanism. In addition, microstructural observations of the lamellar eutectic and of the a-Mg-matrix were carried out using opti¬cal microscopy, SEM and TEM. The creep properties of the alloys are discussed in the context of microstructural parameters such as phase volume-fraction, stability and solute supersaturation.

Jan 1, 2006

By Liyuan Chai, Qin Liu, Bing Peng, Jia Wang, Qiang Zhang

"Electrolytic Manganese Residue (EMR) was used as the main material to prepare cementing material activator for the utilization of the residue from electrolytic manganese dioxide (EMD) or electrolytic metallic manganese (EMM) production. The effects of chemical activation, thermal activation and mechanical activation on retarding activity and excitation activity of EMR were investigated according to the setting time and activity index of EMR-slag cementing material. The results showed that the EMR exhibited good activating performance after being ball-milled for 18 min and then treated for 1-2 hours at temperature range of 350-450 ?. The optimal properties of cementing material activator were achieved at the weight percent ratio 30 : 3 : 5 of EMR/Ca(OH)2/cement clinker.IntroductionMany hazardous industrial solid wastes such as blast furnace slag, fly ash, steelmaking slag, chromic slag and electrolytic manganese residue [1] are generated n China and their amounts increases every year. The accumulation of the solid wastes during past years is very huge and they could be hardly recycled effectively as a sustainable resource. 2.35 billion tons of industrial solid wastes have been produced up to now [2]. It is estimated that they would exceed 3.3 billion tons by the end of 2015 [3]. On the other hand, the quick development of Chinese infrastructural construction needs more cementing materials. The production of traditional building materials consumes lots of natural resource such as clay and limestone and discharges at least 1 ton CO2 and other pollutants per ton clinker [4]. Therefore, it is necessary to develop new types of cementing materials instead of clinker [5,6]."

Jan 1, 2012

By Charles Dowding, Cathrine Aimone-Martin

This article summarizes an investigation of the structural response of a brick façade home in New Mexico. The subject Ricter residence was located some 1100 to 1400 ft away from an aggregate quarry, and was subjected to a maximum peak particle velocity and air blast over pressure of 0.29 ips and 122 dB, respectively. Superstructure (corner) and mid-wall responses to blasting and human induced activities were measured. An existing exterior crack in the brick work was instrumented to measure crack width response to blasting, human induced activities, and environmentally induced changes in temperature and humidity. Crack and structure response data were correlated with ground velocity and airblast excitations. Amplification of ground motions at the upper structure were calculated and compared with values for typical wood frame structures. The natural frequency and damping characteristics of the structure were determined to compare with measured amplification values. Wall strains produced by bending and inplane tension strains were computed from upper corner structure response and compared to failure strains for drywall and brick veneer. Calculated strains were found to be far lower than those required to crack brick and environmentally induced crack response was found to be far greater than that caused by blast induced ground motion or airblast overpressures

Jan 1, 2005

By M P. Murphy, C M. D Barton

When developing a new underground mine, the geological interpretation that guides the mineral resource is crucial to the preparation of a reliable ore reserve. In preparing a robust geological model to underpin a resource estimate, practitioners must weigh the comparative risk of accepting a relatively wide-spaced drill hole pattern, versus a more close-spaced pattern that ensures a high local geological confidence for mine planning but may have an exponentially increased time and monetary cost. This paper details the authors’ investigations into the geological uncertainty of IGO’s Odysseus Deposit, which is approximately 645 km north-east of Perth, Western Australia. At Odysseus, the komatiitic nickel sulfide mineralisation is irregularly cross-cut by nickel-barren pegmatites that have intruded and offset its thick ultramafic orebodies. These pegmatites generate significant uncertainty in the precision of Odysseus’ resource volume and tonnage estimates, as well as the subsequent quantification of pegmatite mining dilution in its ore reserve. To quantify the geological uncertainty in the pegmatite interpretations, IGO’s mineral resource practitioners prepared several geological risk studies over the Odysseus North lode, which is the lode most affected by the pegmatites. These studies included categorical conditional simulation of the pegmatites, preparing implicit geological models with alternative algorithms, trialling a machine learning application to prepare a maximum likelihood geological model, and finally assessing the early results of the pre-production close-spaced drilling to these different models. To assess the precision of the different single-outcome models, the authors’ compared the estimated pegmatite content of each model to the range of possibilities modelled by categorical conditional simulation within the planned stopes at Odysseus North. An estimation confidence score for each modelling method was then prepared for each alternative single-outcome modelling method. From these studies IGO concluded that a close-spaced drill pattern is essential at Odysseus, supporting the view of the Competent Person in 2017 who proposed a 25 m drill spacing in areas affected by pegmatite which had been partially classified as Inferred.

May 24, 2023

By E. W. Davis

IF the tonnage of merchantable iron ore remaining in the Lake Superior district is divided by the average of the annual shipments for the past 20 years, it will be found that this ore supply will be exhausted in approximately 35 years. This computed exhaustion period would be an indication of the future activities of the iron-mining industry if it were not for the fact that merchantable ore is being manufactured from low-grade ore, of which there is an almost inexhaustible supply in the Lake Superior district. It is true that at present only the simplest of these low-grade ores are being concentrated to any considerable extent, but progress is being made with the treatment of the more complex ores, and now, in addition to 20 washing plants on the Mesabi Range, three plants are equipped with jigs for the treatment of ore that cannot be concentrated simply by washing. The latest addition to the ore-treating plants of the Mesabi Range is a magnetic roasting and concentration plant at Cooley, Minn., in which ore that cannot be concentrated either by washing or by jigging is roasted to the magnetic state and concentrated on magnetic separators. This plant is beginning its third season of operation, and while it is too soon to make definite predictions, there are strong indica-tions that this new process may make commercially possible the manu-facture of high-grade, merchantable iron ore from large quantities of low-grade ore now considered worthless. After the iron oxide contained in an ore has been converted to mag-netite, almost any desired grade of concentrate can be produced, using magnetic-concentration equipment of the types now in general use for the concentration of the natural magnetites of New York, New Jersey and Pennsylvania. The conversion of hematite (Fe203) to magnetite (Fe304) is easily accomplished by heating the ore to a dull red tempera-ture in a reducing atmosphere. The reaction is slightly endothermic, and while it requires 200 B.t.u. to heat to 900° F. one pound of hematite ore containing 45 per cent Fe, it requires only 100 B.t.u. to convert the oxide into magnetite. In the laboratory, using small quantities of ore, this conversion is very simple, but large furnaces suitable for commercial

Jan 1, 1936

By Paul M. Tyler, Amy B. CLINTON

The four elements fluorine (F), chlorine (C1), bromine (Br), and iodine (I) form the most intimate family in the entire system of elements and are grouped under the name "halogens" or salt formers (by derivation from the Greek). The first member of this family, fluorine, is the most chemically active element known; and fluorspar, and to a less extent cryolite, the chief sources of fluorine, are important commercial minerals. Fluorine occurs in nature chiefly in combination with sodium as common salt, but it also appears in other natural compounds in sea water, salt-well brines, and bedded deposits. In addition to common salt, various compounds containing chlorine (chlorides) have long been consumed by industry on a large scale, and within the last two decades that element itself has come rapidly into prominence as one of the leading industrial chemicals. Bromine and iodine, the two retaining members of the family, are less abundant in nature and less readily isolated and in consequence of their relatively high price have found few industrial uses, being consumed chiefly in medicine and in photography. Bromine, however, is now entering the industrial field to a considerable extent, due to the rapidly growing use of ethylene dibromide in anti-knock compounds for gasoline. The present paper is devoted to bromine and iodine, but in order to compre- hend the physical and chemical characteristics of these two elements (and hence their potential economic significance) it is convenient to consider them as members of the family series to which they belong. The family relationship of the halogens is illustrated by the following:4 (1) The similarity in the chemical and physical properties of the elements and their corresponding compounds is such that the prop- erties of any one member of the family can be said to summarize or rather to typify the properties of all the other members, although fluorine diverges a little in some of its properties. (2) The gradual transition of chemical and physical properties is such that if the elementa are arranged in order F, Cl, Br, I the variation in any particular property in passing from fluorine to iodine nearly always proceeds in the same order, and that is the order of their atomic weight. Taxing almost any property and comparing its magnitude in passing from the element fluorine to iodine, or from the fluorides to the iodides, a similar graiation will be observed. Thus, take the melting point of the cadmium, calcium, barium, sodium, or potassium salts, in degrees.

Nov 1, 1930

By Robin Sheremeta

What is the goal of every organization when it comes to safety? Everyone Going Home Safe and Happy Every Day Good old days: Era of Death (accidents will happen) Era of Engineering: (Eg. hand rails, limitswitches, machine guards, etc.) Era of Legislation: procedures, laws and regulations (Eg. SWP?s, Mines Act) Era of Behaviour-Based Safety: (eg. STOP program)

May 1, 2010