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By [F. P. ] Stambaugh

Results of research on the hydrothermal precipitation of zirconium oxide from the Bureau of Mines' zirconyl chloride-sulfate strip liquors indicate that nuclear grade material can be prepared by this process. Greater than 99% of the zirconium value can be precipitated at 250-260°C in short (5-10 minutes) reaction time without consumption of acid value of the liquor. Thus, precipitation of zirconium dioxide on a continuous basis, i.e., the zirconium dioxide is precipitated in a continuous mode of operation by pumping the strip liquor through a heated pressurized reactor and recycle of the acidic (spent) liquor to the process stage are favored. The results of accompanying studies of liquod/solid separation, product washing and dewatering, product purity, and chlorination of the product are presented and discussed.

Jan 1, 1980

By Vijaya Bhushan Rao, Jason Redgers

The typical Vibrocompaction projects undertaken in the UAE are on reclaimed Sands. These Sands which are predominantly the crushable, calcareous, carbonate sands found locally as opposed to the more common quartz or silica sands that are featured in most design literature. The famous reclamations such as the iconic Palm Jumeirah in Dubai, often have specification for mitigation of liquefaction induced settlements, bearing capacity increases and total and differential settlement requirements. Often these performance targets are achieved by the means of achieving a particular relative density that are generally measured by a defined Cone Penetration Test, CPT targeting values of cone resistance (Qc), MPa at respective depth zones. In this paper some case studies are presented, where soil suitability for deep compaction by vibratory methods was firstly assessed for suitability using the Massarsch, 1991 compactability chart prior to the application of vibrocompaction and its subsequent evaluation. One such project named the Island Development required 17 to 23m depth of penetration only to treat the lower 5 to 6m of sand above rockhead as eventually the top 15m of sand will be further excavated to allow for the construction of basement. The paper will present pre and post CPT results, the results of initial site calibration trials and evaluation of the completed works.

Oct 1, 2022

The sixth Annual RMCMI Mine Rescue Evaluation was held during the 1997 Institute convention at Sheraton Steamboat Resort, Colorado. The Mine Rescue committee, co-chaired by Becki Boam and Gary Cook, is one of 18 committees of the Institute. In 1997 the largest number of teams participated in the program. There were nine: BHP Minerals - La Plata Mine, BHP Minerals - Navajo Coal Co., BHP Minerals - San Juan Coal Co., Bridger Coal Co., The Coteau Properties Co., General Chemical Co., The Sabine Mining Co., Solvay Minerals and Western Energy Co. Professional evaluators who provided challenging scenarios for the 80 participants were Jack Knight of Milton, Florida; Wilson Begay, Chris Saxon, and Gaylon Yazzie all of Western States Security; Mary Bailey, Bailey Associates; Tom Bass, California Department of Corrections; and Art Saenz, BDC. Seven members made up each team plus one or more trainers and represented the states of Montana, New Mexico, North Dakota, Texas and Wyoming. Ten different scenarios were presented during the two day evaluation. Each team was given the pertinent information to solve the problem as they assembled at the site. Mine Rescue families and friends participated as victims providing realistic scenarios to simulate the stress of an actual rescue incident. Each team was unaware of the circumstances until arriving at the various scenes in and around the Sheraton resort. [ ] These teams are providers of prompt rescue and medical care for accident victims at their respective properties. The members act with immediate and professional knowledge to save lives and prevent further injuries. Sponsors who contributed financially to the 1997 program are: Argo Industrial, Antelope Construction, Fisher Safety Supply, Flanders Electric Motor Service, Inc; Intermountain Electronics, Inc.; King Energy Services, Inc.; Rocky Mountain Electric Motors, LS.; TerraMatrix and Triune Inc. On Saturday evening, June 28, a reception was held for all mine rescue participants and spouses who had advance registered for this social event. The RMCMI Board of Directors was invited to attend and meet with the teams. As convention attendees, all mine rescue participants and registered families attended the Monday night country western reception and Bar-B-Q. This was followed by an adult western melodrama. [ ] Glass awards with the RMCMI logo and a Mine Rescue figure were presented at the Tuesday Mine Rescue buffet breakfast to all nine teams, each of which had achieved proficiency at level 3. Captains of the teams pictured below are (from left standing): Ron Neff, BHP-San Juan; Ted Laughline, Bridger, Terry Davis, Coteau; Jim Knutson, General Chemical (from left kneeling): Dan Allerdings, Rosebud; Ron Miller, BHP-Navajo; Jonathan Sorrell, BHP-La Plata and Ray Blaisdell, Solvay. Gary Cook is to be commended for his solo last minute supervision of the Mine Rescue program, due to Becki Beam's unavoidable absence. The teams look forward to the 1998 convention at Snowmass Village Resort, Colorado Thursday and Friday, June 25 and 26.

Jan 1, 1997

By S Steffen, S Talu, J Poulsen, G Watt, A van As, J S. Ooi

The economic success of cave mining projects is significantly influenced by the secondary fragmentation size distribution of the caved orebody and making the fragmented ore available for extraction. If the cave does not propagate as predicted, it may lead to stalled cave growth and/or localised preferential caving. This can cause significant ore loss and the inclusion of excessive waste in draw columns, both of which damage the economic value of the project. Uncontrolled caving can have severe consequences for the safety and economics of mines. Such safety risks include air blasts due to the formation of excessive air gaps and damage to infrastructure due to surface subsidence. Monitoring the cave-back delivers critical feedback that is required to exert control over its propagation and reduce the likelihood of adverse consequences. Current methods for monitoring cave propagation include access through open holes, microseismic monitoring systems, time domain reflectometers and extensometers. All of these monitoring systems rely on stable holes for installation and ongoing data collection. However, cables in holes often get sheared due to ground movement in the seismogenic zone well ahead of the cave front, rendering the systems useless. To resolve this issue, Elexon Mining, with the support of Rio Tinto, developed the Networked Smart Marker system, which is based on Elexon’s Smart Marker technology. This system provides a more robust and versatile alternative to other cave monitoring systems as the data is transmitted wirelessly through rock, and thus is not vulnerable to hole shearing/dislocation experienced with current cave monitoring systems. Installations at the Argyle block cave have proven that the Networked Smart Maker system can continue to provide information on the cave-back’s location long after all conventional monitoring systems have failed. This paper summarises the findings from these installations and highlights the benefits for all geotechnical monitoring systems reliant on the stability of drill holes to remain functional.CITATION:Steffen, S, Poulsen, J, Van As, A, Talu, S, Watt, G and Ooi, J S, 2016. Wireless system for monitoring cave-back propagation, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 251–256 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By E. Burdukova

Rheological measurements have found a wide array of applications in mineral processing research. Rheological properties of mineral suspensions are highly dependent on the mineral surface properties as described by DLVO theory, and the relationship between these properties and inter-particle interactions is well established. In this paper, rheological properties of mineral suspensions are used to study the differences in behaviour of isotropic talc and anisotropic zirconia minerals as a function of varying properties of the suspension medium, such as pH and polymer dosage, specifically carboxymethyl cellulose (CMC). It was found that the rheological tests when carried out in parallel with electrophoretic or point of zero charge measurements, clearly reveal differences between behaviour of the suspensions of isotropic and anisotropic minerals. These differences are further accentuated with the addition of carboxymethyl cellulose (CMC).

Jan 1, 2006

By Ralf Winterberg, Axel G. Nitschke

"Macro synthetic fiber reinforced concrete or shotcrete is seen by many design engineers as offering a viable alternative to steel reinforcement in tunnel linings. The technology is now commonplace for primary and permanent ground support in both mining and civil tunnel applications. It has for instance become the standard form of reinforcement in the Australian mining industry, and has been used for a majority of permanent tunnel linings in recent tunnel construction in Norway. Similarly, macro synthetic fibers are becoming a standard solution for the initial lining in the USA.The use of macro synthetic fiber offers innovative solutions, yielding robust and sustainable tunnel lining designs. Citing recent research and actual projects, this paper presents state-of-the-art design considerations for fiber reinforced tunnel linings relating to structural and long-term performance. Topics include seismic resistance, crack width control, corrosion and durability, as well as sustainment of performance with age.INTRODUCTIONMacro synthetic fiber reinforced concrete (MSFRC) and shotcrete (MSFRS) has reached maturity as an engineered material and is widely used in all forms of tunnel linings, for temporary as well as permanent ground support in both, mining and civil tunnel applications. In the Australian underground mining industry, it became the standard form of reinforcement, where 2014 literally marked the end of steel fiber use in shotcrete [1], and has been used for over 80 percent of permanent tunnel linings in recent tunnel construction in Norway. Similarly, macro synthetic fibers are becoming a standard solution for tunnel initial linings in the USA. Recent examples in civil tunneling are the Devil’s Slide Tunnel and Caldecott Fourth Bore Tunnel in California or the Anacostia River Tunnel Intershaft Connector Tunnel in Washington D.C. In addition, an increasing number of tunnels are adopting shotcrete permanent linings using macro synthetic fibers. Examples include the A3 Hindhead tunnel near Guildford in the UK and the North Strathfield Rail Underpass in Sydney, Australia [2, 3]."

Jan 1, 2016

Based on experimental and computer simulation results from our group, we report a systematic, atomic level analysis of carbon dissolution from carbonaceous materials in molten iron. Experimental results on graphite / Fe-C-S system were obtained using carbon dissolution studies, XRD and FESEM investigations and were supplemented with Monte Carlo simulations. Three basic mechanisms, namely carbon atom dissociation rate, interfacial phenomena and mass transfer in the melt were found to be responsible for the overall dissolution process. While mass transfer in the melt is governed by the concentration gradients, melt composition and temperature; impurities present in ash play a significant role in the interfacial phenomena. For less ordered forms of carbonaceous materials, carbon atom dissociation rate depends strongly on the degree of long-range order and is an important rate controlling mechanism in the overall dissolution process. A systematic comparison of dissolution rates for a variety of coal-chars, natural and synthetic graphites has been carried out in an attempt to identify rate-controlling mechanisms. The structure of the carbonaceous material appears to be an important underlying factor in the carbon dissolution process.

Jan 1, 2003

By Gabe McClain, Thomas Pallua, Joe Schrank, William C. Gates

Because of restrictions on blasting in urban areas and, more importantly, the proximity of this construction to national historic landmarks, blasting operations were extensively monitored to measure and correlate ground vibrations as peak particle velocity (PPV), frequency, and strain—these being the major factors that would impact the surrounding buildings. As a result, copious amounts of data were gathered and interpreted within a short time to estimate blasting parameters and optimize the subsequent blast rounds

Feb 1, 2020

By E. C. Lane

During the past 15 years the Bureau of Mines has made and published several hundred analyses of typical petroleums and has developed a system of interpreting the analyses and of classifying crude oils. In describing crude petroleum frequent reference is made to the "base" of the oil, a usage the petroleum industry has found convenient. As part of its general study of the characteristics of crude oils, therefore, the Bureau of Mines has developed a system of classifying them according to "base." This system as first published in 19274 was limited to four classes and in its original form is no longer considered adequate. Since the system was first published the Bureau has analyzed a large number of crude oil-, including representative samples from nearly every important producing field in the world, and has found that the system of classification could be revised and amplified to advantage. The revised system is presented herein. Bulletin 2916 states that many oil producers and refiners use the word "base" much as it is used in pharmaceutical work. For example, the "base" or "basis" of an ointment or salve is the fatty material (lard, petroleum, or lanolin) used as a vehicle or carrier for the active medicinal principles. Apparently many of the pioneers in the petroleum industry considered crude oil similar in nature to these medicinal products in that it consists of a semisolid, nonvolatile base and 1 volatile portion can be distilled off to make gasoline, kerosene, and other products. Many crude oils when chilled slowly deposit a waxy material (paraffin); this fact may have been one reason for the use of the term "paraffin base" in referring to such oils. Almost all of the petroleum first discovered in the United States was of this nature; not until the oil industry was extended to California and along the Gulf coast was petroleum found that contained no wax but apparently did contain asphaltic material Accordingly, these oils were known as "asphalt-base" oils. The use of this term, however, seems unfortunate, as better-grade oils of this type contain little if any asphalt; the descriptive term "naphthene base" now seems to be a more desirable term than "asphalt base." The term "intermediate base" is also used commonly in referring to oils intermediate in oharacteristios between those of paraffin and naphthene base.

Jan 1, 1935

By L Bergin, D J. Williams, S Islam, T A. Vangsness

The flooding of open strip coal mines in the Bowen Basin and Hunter Valley Coalfields of Eastern Australia has the potential to soften the spoil and floor materials to produce “mud”. This mud can act as a slip plane or weak zone when spoil is dumped into it, resulting in geotechnical instabilities. Once mud has formed, typical handling techniques include its costly removal by mechanical means, or its isolation and capping.There are little data available on the moisture state and shear strength of the capped mud. To investigate the effectiveness of isolation and capping, research has been conducted using a large slurry consolidometer (150 mm in diameter by up to 410 mm in height) to simulate capping in situ. Once consolidated, the mud was subjected to shear strength testing in a direct shear box measuring 60 mm by 60 mm by about 20 mm high. The shear strength of the consolidated mud was compared to that of competent, fresh spoil, a mixture of spoil and mud, and to completely degraded spoil (mud alone).These results have been used as inputs in stability calculations using the commercial computer program Slide 7.0, which demonstrates the strong influence of consolidation of the mud on overall low wall slope stability. The results provide insight into the design and construction of capping to isolate in-pit mud.CITATION:Vangsness, T A, Williams, D J, Islam, S, Smith, A and Bergin, L, 2018. Consolidation and shear strength testing and stability analysis of coal mine spoil degraded to mud, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 97–109 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By R. W. Lawrence, O. Lopez

Many gold deposits in the world have not been developed clue to the presence of copper and other base metals which can cause metallurgical and environmental challenges clue to the formation of base metal cyanide complexes. SART technology (sulphidization-acidification-recycle-thickening) can resolve these issues by recovering copper as a high grade sulphide concentrate, recycling the associated cyanide back to the gold leach, and eliminating the downstream environmental liabilities. Project economics can be improved substantially, leading to a positive re-evaluation of new and existing gold-copper projects. Some aspects of the design and operation of two recently commissioned SART plants will be discussed.

Jan 1, 2011

By Evangelia Ieronymaki

Civil engineering education relies on traditional methods of teaching, comprising mostly of deductive instruction by presenting the theory, followed by applications. This paper presents an alternative way for teaching foundation design to senior students, introducing a more inductive approach. The students are presented with a project/game adapted to a real-world problem at the beginning of the course. They are asked to identify the correct steps and methods throughout the lectures, for reaching an appropriate solution that they document and present at the end of the course. To make the project more enjoyable, the project has the format of a game where the students compete with each other on completing the task faster and more efficiently. The goal of this teaching approach is to enhance the ability of the students for problem solving and the engineering way of thinking, while playing a game. In the end, the students were requested to respond to a survey regarding the efficiency of this project/game on their learning. The results showed that students prefer more inductive methods for a design course, feeling that this project made them think more like engineers, while the ‘game’ twist of it made the whole course more fun. INTRODUCTION Most civil engineering courses are taught in 2019 the same way they used to be taught 40 years ago in the 80s. Classic methods are mostly deductive, where the instructor presents the theory first and then applications of that theory follow. Little or no attention is given initially to why the theory was developed or what are the problems it solves. The applications of the theory, and thus the purpose it serves, come only in the end and after methodologies have been presented, leading the students to show low interest in the material. As Albanese and Mitchell (1993) have reported, people are mostly motivated to learn things when they clearly see the need to know them. This explains the students’ little motivation that, if any, comes mainly from the fact that the material may be useful either in other courses or in their future careers. On the other hand, there are alternative inductive methods of teaching, where the role of the students is more active. A lot of researchers have highlighted the benefits of inductive methods in teaching engineering courses. Based on Prince and Fedler (2006), inductive methods include; a) inquiry-learning, b) discovery learning, c) problem and project-based learning (PBL), d) case-based teaching, and e) just-in-time learning. Inquiry-learning is maybe the most traditional method of inductive teaching/learning methods, where the instructor asks questions or poses problems and the students need to apply the theory they have learnt in order to find the solution (Bateman 1990; Prince 2004; Lee 2012). Similar to inquire-learning is the discovery learning, where students have to find the solution to a problem or answer to a question, while the instructor simply provides feedback to the students without guiding their efforts (Leonard 1988; Westbrook and Rogers 1994).

Jan 1, 2019

By Paul D. Merica, R. G. Waltenberg

Although nickel was discovered and isolated as early as 1750 and its valuable properties recognized, many years passed before it was used commercially for wire, sheet, rods, etc., in the pure form. This was due partly to its high cost at that time and partly to the fact that it was not possible to refine and cast nickel into ingots sufficiently malleable to be amenable to the usual forging, rolling, or drawing processes. So remarkable was this fact, and so different from the experience at that time with metals such as copper and iron, that it has left its impress on the nomenclature within the nickel industry. To this day, furnace-cast nickel produced in such a manner as to be suitable for rolling and forging is called malleable nickel to distinguish it from the ordinary pig and shot nickel of commerce. In 1878, the firm of Jos. Wharton, of Philadelphia (which later became The American Nickel Works, a constituent of The International Nickel Co.) exhibited at the Paris Exhibition specimens of rolled pure nickel strip and of drawn nickel wire. About this time, there was considerable activity in the study of the refining of nickel and several methods were described, some of which were patented, for the production of furnace-cast malleable nickel including the use of manganese (Boed-dicker,1 Selve and Lotter2), the use of potassium permanganate (Berns-dorfer Metallwarenfabrik3) and the use of phosphorus (Garnier4). By far the most efficient method was discovered by Th. Fleitmann in 1879;5 it consisted in adding to the molten nickel, just before pouring the castings, from 0.05 to 0.125 per cent. of metallic magnesium. This soon became the recognized final malleableizing treatment for furnace-cast nickel.

Jan 1, 1925

By Gaston Gendreau, Marcel Allard

"Sidbec-Normines Inc. est une société formée de trios partenaires soient: Sidbec, British Steel Corporation et la Compagnie Minière Quebec Cartier. L'objectif de l'opération minière est d'exploiter à ciel ouvert le gisement d'hématite spéculaire de Fire Lake et de produire au concentrateur de Lac-Jeannine, près de la ville de Gagnon, 6 million de tonnes de concentré pour alimenter l'usine de bouletage de Port Cartier.Le présent exposé a pour but de fa ire ressortier les caractéristiques d'une opération dont la mine est située à plus de 100 km du concentrateur, d'en faire ressortir les particularités touchant le transport du personnel et du minerai. En plus, on traitera de l'importance dans une telle situation d'une organisation efficace dans la gestion des services et de l'opération (atelier, concasseur, entrepôt, etc.).IntroductionSidbec-Normines Inc . a entrepris l'exploitation minière du gisement de Fire Lake, le 1er janvier 1977. Le but de l'entreprise est de produire annuellement six millions (6 000 000) de tonnes de concentré d'hématite (oxide de fer) titrant 66% Fe au concentrateur de Lac-Jeannine a partir d'un minerai d'une teneur moyenne de 33% Fe, extrait de la mine de Fire Lake. Ce concentré est ensuite achemine à Port-Cartier et alimente I'usine de bouletage.Les installations minières de Sidbec-Normines sont situées a trois endroits différents : la mine à Fire Lake, le concentrateur à Lac-Jeannine et l'usine de bouletage à Port-Cartier. La mine de Fire Lake se situe à 83 km de la ville de Gagnon et à 100 km du concentrateur de Lac-Jeannine. Une route provinciale relie la ville à la mine et au concentrateur. Le minerai est acheminé de la mine au concentrateur par chemin de fer et le concentré est transporté par train sur une distance de 309 km à l'usine de bouletage de Port-Cartier."

Jan 1, 1982

By S. Heukelman

Zincor uses O2 enrichment (up to 26% O2 in the fluidizing air) to increase the processing rate of zinc concentrates in the fluidized bed roasters. The aim of this study is to determine whether O2 enrichment can be reduced by introducing micro-pelletized concentrate into the feed blend, while maintaining current roaster feed rates and calcine quality. It was found that, with a load of 20% micro-pellets introduced into the feed blend, that O2 enrichment could be reduced by 60%. It was determined that entrained particles spend on average between 0.46 hour and 2.44 hour in the roaster, compared to particles remaining between 3.93 hour and 4.00 hour in the bed overflow. This compares well with a radioactive tracer test performed by Spira. The required reaction time for micro-pellets was found to be less than the residence time inside a Zincor roaster. The result achieved indicated that the average particle residence time inside the roaster was increased successfully in order to compensate for the longer reaction time required to roast micro-pellets at lower levels of O2 in the fluidizing air.

Jan 1, 2011

By J. G. Groppo, A. E. Bland, B. K. Parekh, W. F. Stotts

Many coal preparation plants discard fine coal (generally minus 100 mesh) because it is difficult to beneficiate economically. At the Kentucky Energy Cabinet Laboratory (KECL), the waste streams from several Kentucky preparation plants were evaluated for cleaning with counter-current column flotation. A series of performance evaluations were conducted using a 0.05 m (2 in.) internal diameter (I.D.) 7.9 m (26 ft.) high laboratory column. The objectives of these tests were to assess the performance in terms of recovery and percent ash in clean coal and to optimize the operating parameters relative to combustible recovery and grade. Refuse streams containing 30-50 percent ash were upgraded to 2-8 percent ash with Btu recoveries of nearly 90 percent. A pilot scale column flotation cell was installed at the Bell County Coal preparation plant. This pilot plant utilized a 5.79 m (19 ft.) high and 0.15 m (6 in.) I.D. column to verify the performance data of the 0.05 m (2 in.) I.D. column for two different waste streams. Performance evaluation and pilot plant testing results related to scale-up are discussed.

Jan 1, 1988

By W. Collingwood

As openpit mines continue to grow deeper and productivity continues to increase, the management of respirable dust and noxious gases can become a challenge. The natural wind flow in openpit mines is often recirculatory. This recirculation traps dust and gases in deep openpit mines. This problem is particularly acute in high-latitude openpit mines, due to a phenomenon known as atmospheric inversion. In the winter, arctic and subarctic regions experience short days and long nights. This deficit of solar radiation creates a situation in which cold, still air accumulates near the bottom of the pit. In openpit mines, this can result in unhealthy accumulations of gases and other contaminants. In this study, the natural wind flow patterns in and around openpit mines were investigated using a computational fluid dynamics (CfD) program. Two-dimensional models were created for a variety of pit geometries. The effect of depth, slope angle and wind speed on the recirculation pattern in the pit was examined.

Jan 1, 2012

By M. de Beer

The conversion of carbon-containing feedstock into liquid fuels can proceed via the Fischer-Tropsch synthesis, which is catalysed using supported cobalt catalysts. These catalysts contain noble metals to facilitate the reduction of oxidic cobalt species in the catalyst precursor to metallic cobalt, which is the catalytically active species for the Fischer-Tropsch synthesis. This is thought to occur via hydrogen spillover, i.e. the diffusion of atomic hydrogen over the support from the noble metal to the oxidic cobalt moieties. Noble metals may also affectthe dispersion of cobalt in the active Fischer-Tropsch catalyst. The economic aspect of the addition of noble metals to the Fischer-Tropsch catalyst is discussed.

Jan 1, 2014

By S. P. Narayan

The hot deformation behavior of Pure Mg and Mg-0.29Ce alloy were studied by isothermal hot compression tests in the temperature range of 250 - 500°C and strain rate range of 10-3 - 102 s-1 in a computer-controlled 50kN servo hydraulic universal testing machine (UTM). The results show that the flow stress of Mg pure and Mg-0.29Ce alloy increases with strain rate and decreases after a peak value, indicating dynamic recovery and recrystallization. Process efficiency was increased by nearly 10 to 12% by addition of Ce in Mg. Mg pure exhibits instability zones between 250-275°C at 10 ? 102 s-1 and 400¬500°C at 101 ? 102 s-1 temperatures and strain rates respectively, rest is the safe deformation zone. Wherein, Mg-0.29 Ce exhibits two low efficiency zones from 250 ? 300°C at 10-2? 10° s-1, 400 ? 500°C at 101 ? 102s-1 and high efficiency zone at 450 ? 500°C at 10-3? 10-1s-1. 4D process maps were generated for the above said alloys which illustrate contours of power dissipation and instability in the 3D space of strain rate, temperature and strain.

Jan 1, 2011

By W. K. Collins

Engineered Scavenger Compounds (ESCs), developed by the U.S. Bureau of Mines, are a novel class of compounds that can selectively recover a desired element from a solid or molten alloy. Lithium titanate (Li2Ti3O7 or L'20-3T'02) is being used as an ESC to recover lithium (Li) from Aluminum-Lithium (Al-Li) alloys. X-ray diffraction measurements have shown that lithium titanate undergoes a phase change from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of Li in the matrix of the material and the effect of temperature. Although both are metastable, the hexagonal phase that forms during the scavenging of Li from Al-Li alloys appears to be the more stable phase. Recovering Li from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. Both the orthorhombic and the hexagonal structures of Li2Ti3O7 have similar scavenging capacities for Li. This paper proposes a new mechanism for the phase transformation.

Jan 1, 1993