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By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By Kanhaiya Mishra, Phanil. K. Mandal, S. K. Behera, P. S. Paul, Prashant Singh, C. N. Ghosh

The techno-economic and social benefits of cemented paste backfill (CPB) resulted in its wide acceptance by the mining industry. The Ordinary Portland Cement (OPC) remains the key binder but to diminish its economical constraints, suitability of alternate binders has been examined worldwide. The present study aimed to investigate the effect of partial replacement of OPC with fly ash on the CPB’s strength and to determine the most optimal mix to achieve the required strength (1 MPa at 28 days of curing) at the most cost-effective way using the Bayesian network (BN). The CPB mixes were prepared at 72 wt.% solid concentration with mill tailings (87–91%), OPC (6–13%), and fly ash (0–4%), and instantly after mixing, fresh (slump, bleeding, density) CPB properties were measured. The strength was tested at 7, 14, 28, and 56 days of curing and initially analysed through traditional model. The traditional models follow the aleatory principle and are considered not appropriate for geotechnical engineering. Hence, the BN model was developed and tested. The reliability of two classifiers in learning model structure was compared which gives Naïve Bayes as the highest reliable tool. The CPB’s strength is most sensitive to the OPC content. The most consistent mix(s) is mill tailings: 87–88%, OPC: 9–11%, fly ash: 1–4%. Adding fly ash at 89–91wt% mill tailings possesses high failure probability of the CPB. The collinearity test indicates that the fines percentage and chemical composition of CPB’s ingredients are highly correlated with its slump, bleeding, and strength development.

Jul 14, 2022

Jan 1, 1967

By Luke Clarkson, David Williams

The intent of this paper is to provide overview context to allow broader understanding of conventional tailings dam failure mechanisms. The research leverages global knowledge, experience, and data collection and interpretation for the safe and controlled management of the geotechnical stability of a tailings storage facility. The motivation for this review is to facilitate transparent access to tailings dam background and understanding. This paper addresses the core understanding of geotechnical failure mechanisms, and how these eventuate to instability and failure of tailings dam structures. This research focuses on foundation failure, internal erosion and piping, overtopping, seepage, seismicity, and slope instability and provides insight into what factors contribute to failure, how failure progresses due to such failure, anticipating and monitoring for the aforementioned failure modes, and designing to mitigate their risk.

Feb 15, 2021

By F. G. Hyde

Passage of the Public Utilities Regulatory Policy Act ("PURPA") in I 978 created an entirely new industry that is referred to today as the Independent Power Producers ("IPP"). Requirements of project owners, environmental compliance, project design, the financial community and most of all, the need to be a low-cost producer presented a unique situation for the sourcing and the utilization of fuels. Depending on the specific type of project being developed, (e.g. coal-fired, wood/biomass, natural gas, petroleum coke or a blend of several fuel types) and the type of boiler design, it is important to acquire fuels that will optimize both the project's operating efficiency and flexibility. This paper will focus on the acquisition of fuel for coal-fired projects, but will describe the necessary steps in the sourcing, contracting for, and the utilization of fuels and transportation resources in the IPP industry today.

Jan 1, 1996

By Oliver W. Marsden, John O. Marsden

This paper presents the results of a hypothetical case study that evaluates the potential transition of a large copper mining and extraction operation to 90% renewable energy. The case study considers three phases to accomplish such a transition; phase I considers installation of renewable power generation at the site to meet a portion of the current electric power needs, phase II considers conversion of diesel combustion mining equipment to electric equipment, and phase III considers implementation of renewable energy generation coupled with energy storage systems to provide approximately 90% of the total mine site energy requirements. The paper evaluates the results in the context of a range of purchased electric power unit costs ($0.065, $0.100, and $0.135/kWh) as well as various carbon tax scenarios ($0, $5.00, and $37.30/t CO2). While the case study is hypothetical and considers a range of assumptions, it clearly identifies a pathway to potentially economically viable transitions to a renewable energy platform for mining companies. This represents an approach that mining companies can use to help to meet emissions targets, as well as social responsibility and reporting requirements.

Jun 4, 2021

By L. B. Pankratz

Thermodynamic data on the elements, oxides, sulfides, halides, and selected hydrides, carbides, nitrides, carbonates, sulfates, silicates, and miscellaneous compounds were reviewed, evaluated, and compiled at the Bureau of Mines. Values for CP°, S°, H° -H°298, ?Hf°, and ?Gf° are given in tabular form. A brief thermodynamic background and a number of examples and applications are presented.

Jan 1, 1984

By R. W. Hiteshue, C. O. Hawk, H. H. Ginsberg, M. D. Schlesinger

The Bureau of Mines studied single - step catalytic vapor - phase hydrogenation of oils derived from coal and oil shale . Treatment of middle oil , from hydrogenation of bituminous coal , gave good yields of gasoline with a German - made molybdenum- zinc - chromium catalyst . The Bureau also achieved good results with duplicates of this catalyst made from domestic raw materials . In one set of experiments with the German catalyst , 38 to 52 wt pct of feed was converted to gasoline . The total liquid product was 91 to 98 wt pct of the feed . Not all this gasoline can be claimed as production , however , because about 20 pct of the feed was in the gasoline range , and part of it undoubtedly survived the hydrocracking treatment . Hydrogenation of crude shale oil in the presence of cobalt molybdate catalyst produced a total liquid product of 89 wt pct of feed . The hydrogenation converted 27 wt pct of feed to gasoline and 44 wt pct of feed to diesel fuel . The remaining liquid product , 18 wt pct of feed , was residue boiling above diesel fuel . The gasoline was of poor quality , with an octane number of 39.1 . The overall product seemed a suitable feed stock for a conventional refining operation . Coker distillate hydrogenation , using a cobalt molybdate catalyst , gave a total liquid product of 97 vol pct of feed ; of this product 60 vol pct was jet fuel and 40 vol pct was diesel fuel . High nitrogen and sulfur in all three of these raw materials severely poison the usual refining catalysts . Thus , the common objective in these

Jan 1, 1964

By Nozomu Kotake, Rakshya Shrestha, Ralph Griffin, Stefanos Papadopulos, Jeff Fippin, Sushil Kafle

Direct Power Compaction (DPC) is a deep Vibro-compaction method used for liquefaction mitigation. In DPC, H-beams are used as vibrating rods penetrating deep into the ground, and a vibrating force is applied directly to the tip of these H-beams to densify the loose ground. A characteristic feature of DPC is the use of a flapping plate installed at the base of the H-beam to enhance the compaction efficiency during penetration. In addition, 2-rod and 4-rod type equipment have been developed to improve productivity and enable rapid construction. DPC was selected as the most suitable and cost-effective technique to mitigate liquefaction hazards in two projects in the San Francisco Bay Area, one on Alameda Island and another on Treasure Island. Both sites were capped with hydraulically placed sand fills. Liquefaction analyses indicated excessive liquefaction-induced settlements and large lateral spread without ground improvement. Densification using DPC was performed up to depths of 42 ft to reduce the liquefaction potential of the sand fill to acceptable levels and to allow planned improvements. Cone penetration tests were conducted before and after DPC to evaluate its performance. This paper describes the equipment and process involved in DPC and discusses its application in terms of subsurface conditions and geotechnical design considerations.

Sep 8, 2021

By A. León

El objetivo del presente trabajo es describir el sistema de relleno hidraúlico en los tajeos de vetas angostas de la mina de Morococha a través del método "Arch Back". Actualmente el sistema de relleno convencional es lento, costoso y ofrece desventajas respecto del *R/H. Los objetivos del R/H son aumentar la eficacia de minado, controlar las leyes del mineral, minar los tajeos de baja ley, mejorar el sostenimiento de las cajas y la baja de costo. En este sentido, se describen las operaciones unitarias de los tajeos con R/H y se comparan con los métodos convencionales, encontrando eficiencias en los tajeos aplicados con el método Arch Back y los tajeos de vetas angostas, así como se mejora la producción y los costos de la misma.

Nov 20, 1972

By Xavier B. Starnes

"SUMMARYThe J. D. Price property is in Crittenden County, Ky., about 5-1/2 miles west of Marion. The Levias-Crittenden Springs fault system traverses the property. Mines on 3 miles of the same fault system immediately northeast have produced about 250,000 tons of fluorspar ore. The Keystone property, adjacent on the northeast, has produced about 150,000 tons of ore. 3/About 1934, lessees, sank a shaft upon the Price property to a depth of 111.5 feet and crosscut from the bottom of the shaft to the principal fault. No ore was found. Later, in 1942-43, they explored the same fault by core-drilling, but this project also was unsuccessful in finding ore.The author visited the property in September 1944, and subsequently the Bureau further explored the property by core-drilling three holes. No ore was found.ACKNOWLEGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. This ex¬ploratory project was under the general supervision of E. D. Gardner, regional engineer of the Central Region, and 0. M. Bishop, district engineer, Bureau of Mines. The mining branch is under the direction of L. B. Moon. The work on the project was under the direct supervision of Xavier B. Starnes, mining engineer."

Jun 1, 1947

By Bao K. Le, Khang T. Truong, Masaki Kitazume, Toru Kobayshi, Long P. Le, Tanaka Hitoshi, Makoto Kamimura, Hoang-Hung Tran-Nguyen

"Earth levees constructed using dredged materials taken from a river along an earth levee have annually damaged in the Mekong Delta due to high void spacing in earth levees and floodwater. Sliding and internal erosion due to floodwater or piping are two key factors causing earth levees’ failures. This study proposed to apply Deep Mixing Method (DMM) to reinforce earth levees in the Mekong Delta, Vietnam. The DMM creates a soil cement wall or soilcrete wall having better engineering properties such as higher strength and low hydraulic conductivity than those of the in-situ soils. The DMM can be applied to reinforce earth levees with limit additional materials that provinces in the Mekong Delta are difficult to supply. The study investigates capacity of the DMM to reinforce earth levees in the Mekong Delta, Vietnam against annual floods. Seepage and slope stability analyses under various conditions were performed with various scenarios of earth levee’s body. The analysis results indicate that the DMM can create a wall that cuts off piping across earth levee significantly and can improve stability against deep sliding due to rapid drawdown of the floodwater.INTRODUCTIONThe Mekong Delta produces agriculture products of 50% of the whole country even though the Mekong Delta has an agriculture area of 30% of the country (Wikipedia 2014). Rice is the main product for the domestic demand and export. This is the main reason why the local people want to cultivate rice 3 times per year to increase the total rice product for export. To do that, the local provinces have constructed earth levees surrounding each area of 100-200-hectare against annual floods to protect rice fields, and farmers can grow rice in the whole year. There are thousands of kilometers long earth levees in the Mekong Delta, and the local governments have spent millions of US dollars to repair and to maintain their earth levees yearly (reports of Dong Thap province 2012; 2014).Earth levees in the Mekong Delta have often failed in flood seasons (e.g., from August to December), especially in Dong Thap and An Giang provinces – the two provinces confronting directly the annual floods from the Mekong River when the floods reach the Vietnam land. The main failure of earth levees is piping, and then causing collapse of some section of an earth levee. An earth levee was usually constructed by piling up dredged materials along a river with minimum compaction. Subsequently, floodwater flows through connected void spacing and washes out soil particles in the body of an earth levee slowly to create piping. Annual wet-dry cycles make the top clay layer swelling and shrinking to form cracks that can store rainwater to trigger sliding (whitlow 2001; Ton That Vinh 2003)."

Jan 1, 2015

By Lisa R. Papandrea, David Chen, Walter E. Kaeck

"Construction of the University at Buffalo’s new School of Medicine and Biomedical Sciences (UB-SMBS) required excavation in variable ground to a depth of more than 40 ft adjacent to the NFTA Metro subway and Allen Street Station. Complicating the building design and construction, the new medical facility incorporates the at grade Station entrance building, requiring a combination of temporary and permanent excavation support structures, a complex sequence of ground support installation, and a mix of shallow and deep foundations to accommodate the large floor spans and concentrated column loads introduced by building over and adjacent to the Station entrance. Excavation and foundation construction was challenged by a stratified soil profile with interlayered and sensitive sands, silts and clays and complicated groundwater regime with perched and regional water tables. Efficient construction required ongoing coordination between the design team and contractor, careful field observation, and construction monitoring in several facets of below grade construction. This paper describes the design and construction of excavation support structures and foundations to manage the variable ground, congested site conditions, and complications of building adjacent and above an active subway station. Use of site instrumentation and monitoring data to provide guidance in construction when unanticipated field conditions arise is illustrated. Lessons learned in installation and sequencing of excavation support, groundwater control and foundation construction are also discussed.INTRODUCTIONUniversity at Buffalo President Satish K. Tripathi heralded the new School of Medicine and Biomedical Sciences (UB-SMBS) as a future linchpin of UB’s downtown campus that will revitalize the area and enhance western New York’s emerging bio-sciences corridor. The $375 Million, 628,000 square foot, eight story building with two basements is expected to house 2,000 faculty, student and staff allowing UB to increase class size from 140 to 180 students. It will be constructed above the Niagara Frontier Transportation Authority’s (NFTA) Allen Street Station, creating a direct connection to Buffalo’s light rail system. The 200 ft x 400 ft site is bounded by Main Street, High Street, Washington Street and the Roosevelt Apartments and adjoining parking lot at the west, north, east and south respectively, as shown in Figure 2. Groundbreaking for the new building was in October 2013 with the facility scheduled to open in early 2017."

Jan 1, 2016

By V. R. Degner

The trend in both the metallic and non-metallic mining industry is toward processing increasing y higher tonnages of lower grade ores, thereby resulting in a growing interest in progressively larger volume individual machines in the flotation circuit. Because of the relatively high cost of large flotation machine development and evaluation, it is important to establish a rational basis by which the existing smaller flotation machine experience can be extrapolated to establish the configuration of the next larger family of flotation machines with a minimum of development modification in the field. This paper reviews the R&D approach used in translating smaller flotation machine experience to establish the configuration of a 1000 cu ft (2B.3 cu m) induced air machine. Internal cell hydrodynamic principles, which governed this extrapolation, and cell (liquid) surface and froth management considerations will be reviewed, and prototype machine mill tests will be summarized.

Jan 1, 1978

A variety of cement raw materials occur within the Cenozoic sequence in Northland. These form the basis of Golden Bay Cement's cement manufacturing operation at Portland, Whangarei. High grade limestone is taken from the Whangarei Limestone formation, which has been shown to have been sub-aerially weathered and developed mature karst features prior to deposition of the overlying allochthon sediments. In this instance, remobilisation of allochthon sediments following uplift and erosion is inferred. At Portland Quarry, argillaceous limestone is extracted from deformed thrust sheets in the allochthon sequence. Quarry operations have been designed to handle the steep asymmetric folds, thrust faults and fracture zones that affect the resource.

Jan 1, 1999

By J Leem, S Mehrishal, J Kim, A Fereshtenejad, J Song

Rock mass discontinuity mapping plays a crucial role in developing a reliable Discrete Fracture Network (DFN), providing insights into the distribution of geometrical and mechanical properties of discontinuities. This enables an accurate assessment of geotechnical infrastructure and mining excavations. Data obtained through conventional mapping approaches are substantially limited by factors such as accessibility and subjectivity. Moreover, these conventional methods may pose inherent risks due to manual techniques, exposing practitioners to potential dangers. Recent digital developments in remote surveying techniques offer opportunities for safer and more reliable rock mass discontinuity surveys. These technologies allow extensive three-dimensional surveying and the production of high-resolution 3D surface models, applicable at any time. This paper presents a workflow for digital discontinuity mapping employing drone technology and photogrammetry. Additionally, the capabilities and challenges of applying artificial intelligence (AI) algorithms in the rock mass discontinuity characterisation process are discussed.

Sep 1, 2024

Reduce the respirable dust exposure of the roof-bolter operator when downwind of the continuous miner, particularly in mines where respirable dust standards are more stringent because of silica in the respirable dust. Dust Sources If roof-bolter dust levels are excessive, the bolter dust collector should first be checked to ensure that it is operating properly. (Technology News No. 219 provides information on how to spot and repair bolter dust collector problems). If the roof-bolter dust collector is operating properly and dust levels are still excessive, then the source is most likely a continuous mining machine operating upwind. In many sections, the roof-bolter operator must work on the return side of the continuous miner during part of the production cycle. In three-entry longwall developments with single split ventilation, this may happen as much as one-third of the time. Factors which pro-mote high quartz dust exposure are:

Jan 1, 1985

The Golden Cross Mine will be the first underground gold mine in New Zealand to operate since 1952. The development plans, along with the conditions and circumstances presently found in the now ongoing mine development, will be discussed as well as a brief review of planned stoping activity and stoping results to date.

Jan 1, 1991

Study on Selective Reduction and Magnetic Separation of Low-Grade Nickel Laterite Ore to Produce High Nickel Concentrate

Sep 13, 2010

By Victor Spironello

The Bureau of Mines is studying cupola ironmel technology with the objectives of conserving high-quality raw materials through substitution and productivity. In the research re-ported here, a ize was modified by a gas-fired melting and/or ing chamber into the stack above the level of the coke bed, for study as a prototype for a coal-fired melting chamber. The modified cupola, in which natural gas was used to partially replace foundry coke, was evaluated in several trial runs. Data were obtained on furnace performance, metal and slag chemistry, and scrubber waters as particulates. Results of the modified ion were compared to those of conventional cupola operation. Although this research was preliminary--since the ultimate goal is to use pulverized coal instead of yielded ample evidence that the melting rate of a cupola can be icantly increased with less than a increase in energy input. Other evidence suggests that melting of low-density scrap can be enhanced and that scrap containing undesirable and/or oxidizable elements can be appreciably upgraded. This work is continuing and will include the use of pulverized coal of low rank to assist in melting.

Jan 1, 1984