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By Kalliat T. Valsaraj, Louis J. Thibodeaux

A mathematical model is described for the transfer of hydrophobic compounds from aqueous to an immiscible organic phase using fine bubble aeration; the process otherwise known as "solvent sublation" an adsorptive bubble separation process. The limitations of the model are explored by simulating experimental results both for a batch scale process and a continuous process. The qualitative predictions of the model with respect to the influence of the organic layer (mineral oil) are tested by performing experiments using chloroform and 2,3,6-trichloroanisole as hydrophobic compounds in the aqueous phase. The continuous process is seen to be limited by the requirements of fine bubble generation and the ratio of influent feed rate to air flow rate.

Jan 1, 1989

By R. Larry Davis

Over the past decade there has been a continual decrease in domestic oil reserves accompanied by a sharp increase in the demand for energy. Even with increased imports of foreign oil, the energy demand has not been met. This has forced many users to turn to substitute fuels. Of the many substitute fuels available most users are turning to and creating an increased demand for low sulfur coal. Because of the increased demand for low sulfur coal as well as the inherent problems in producing eastern coal, many producers have turned their attention to the large deposits of low sulfur coal in the western United States. Western coal mining is, however, not without its problems such as high moisture content, high ash content, highly variable sulfur content, multiple seams, and/or pitching seams. It is to aid in the solution of these problems that this chapter is directed.

Jan 1, 1979

By M. S. Prasad, K. J. Reid, M. P. Katsoulis

The State of Minnesota is interested in stimulating the development of clay resources and recently supported a two-year project to collect data on geological, mineralogical, processing, economic and environmental aspects of such potential developments. This paper presents the various process options adopted on bulk samples collected from the Minnesota River Valley area, which is a primary deposit and contains a major silica fraction. A standard test flowsheet involving degritting, dispersion. HGMS and cycloning was developed and for some samples yielded an acceptable filler grade product. Secondary streams containing relatively high grade kaolin but of coarse size were also obtained. Improvement in particle size distribution and in physical properties related to paper product specifications (brightness, viscosity) were obtained by size-reduction processes. Market and economic considerations for kaolin consumption in the upper Midwest are analyzed. Current markets for paper grade kaolin in Minnesota are briefly discussed.

Jan 1, 1992

By Anthony D. Hammond, Charles A. Kliche

A slope stability study for the Annie Creek and Foley Ridge Mines was undertaken to provide Wharf Resources, Inc. with a technical assessment of the stability of the slope for an overall pit slope angle of 60°. A rock analysis of the most critical and persistent combination of discontinuities was carried out using probabilistic methods. A detailed discontinuity mapping and assessment of the rock mass provided the orientation data used in this study. The orientation data were reduced and analyzed to identify the discontinuity sets. A statistical analysis provided information about the distribution of the data. A deterministic wedge stability analysis identified the critical combination of discontinuities; those with a low factor of safety were further studied using probabilistic kinematic and kinetic stability analyses. The results from this approach were used to obtain the reliability or probability of failure of the slopes.

Jan 1, 1988

By S. K. Kawatra, S. Valluri

With increased CO2 emissions from steel and coal industry, there is great opportunity to capture CO2 and utilize the captured CO2 for economic advantage. The primary goal is to develop energy-efficient processes that reductively couple CO2, an abundant and renewable carbon source, for the production of value-added chemicals such as methanol, ethanol, and oxalic acid. These chemicals can be used elsewhere in the refining process or sold as valuable by-products. Geological sequestration, in comparison, has no economic return. Current CO2 utilization research at Michigan Technological University focuses on electrochemical reduction of CO2. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. This paper will present different ideas and their viability to utilize CO2 as a feedstock to produce several value-added compounds. INTRODUCTION Carbon dioxide (CO2) emissions into the atmosphere will need to be drastically reduced to curb the various undesirable effects of climate change. The large contribution in total CO2 emission originates from coal or natural gas power plants, and a considerable amount from steel plants. Average CO2 emissions in the US from steel industry is 2.9t CO2/t steel (Global CCS Institute 2013). Capturing the available CO2 from the steel and coal industries for economic advantage is a win-win situation for the industry. This technology is not only important scientifically but is also vital for a sustainable future. The various ongoing investigations can be categorized as biochemical, thermochemical, photochemical, and electrochemical approaches. Among these, the electrochemical method shows the most promise as an efficient form of CO2 conversion technology, because of its many advantages like high reactivity under ambient conditions and good extensibility from small- to large-scale processes1 BACKGROUND Extensive research has been done on the chemistry of transforming carbon dioxide into more useful products. Methods are known to convert carbon dioxide into a wide variety of substances, including methanol, isobutanol, carbohydrates, methane, carbonates, urea, formic acid, oxalic acid, carbon monoxide, epoxides, formaldehyde, and so on. Several of these (carbohydrates, formaldehyde, isobutanol etc.) are primarily results from biological processes. The rest are results of strong reduction reactions or electrolytic reduction. In short, electrolytic reduction can be used to form methane, methanol, formic acid, oxalic acid, carbon monoxide from carbon dioxide2. CO2 reduces at the cathode in an electrolysis cell. These processes have the general form of generating the carbon dioxide anion radical (2⋅−) and allowing it to react with itself or the electrolyte3. Catalysts can be added to influence the formation of the anion radical or to suppress side reactions3. The electrolyte, catalyst, voltage, electrode material and CO2 content are all known to effect the reaction pathway. Table 1 shows the overall reactions and energy requirements for electrochemical conversion of CO2 to chemicals

Jan 1, 2019

By J. G. Groppo, T. L. Robl, C. J. McCormick, W. M. Lewis

The combination of froth flotation and hydraulic classification can facilitate the production of a high-quality pozzolan that meets or exceeds ASTM specifications. This combination has been rigorously evaluated and results of pilot-scale testing are presented. Pilot-scale testing was conducted on fly ash from two active electric utility storage ponds. The tests demonstrated that a high-quality and consistent pozzolan could be produced using Advanced Pozzolan Technologies' Fast Float™ Process. Along with the pozzolan, the additional production of aggregate for masonry mortar and the production of a low sulfur, medium-Btu fuel were also demonstrated. The Fast Float™ Process incorporates several simple unit processes to ensure pozzolan consistency. Classification controls the particle size distribution, which is critical for achieving early strength;flotation controls the grade with respect to L.O.I.; and dewatering controls the moisture content.

Jan 1, 2000

By R. A. Jankowski

Although the number of operating longwall mining systems has remained relatively constant, longwall production levels during the last five years have increased significantly. In the United States, longwall mining now accounts for approximately 50% of all underground coal production. While longwalls are highly productive and offer other advantages, operations employing this method of mining continue to experience dust-compliance problems. This increased longwall productivity has meant that far more dust is being produced. An improved understanding of the longwall face-ventilation system and the advancement of face-ventilation technologies are necessary to ensure all face personnel are allowed to work in an environment that is free of excessive levels of airborne respirable coal mine dust. The Dust and Toxic Substances Control Branch, National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, examined several basic principles of the long wall face-ventilation system and has evaluated the effectiveness of numerous improved face-ventilation techniques for longwall mining systems. These include identifying improved techniques for measuring face-ventilation parameters on longwall mining sections and investigating the fundamental relationship between face airflow and the entrainment and dilution of respirable coal mine dust. Studies have been completed to determine the impact on face dust levels of using belt entry air to ventilate the longwall. Novel methods have been identified to increase the face air¬flow and to manage face airflow to effectively minimize dust exposure to face workers. Unique systems of auxiliary face ventilation have been developed and evaluated at full-scale, simulated longwall test facilities. The theoretical and applied aspects of each of these principles and technologies are discussed. Application of these results throughout the longwall mining industry, as documented from surveys conducted in the early 1980s and 1990s, have reduced the health hazard associated with excessive exposure to respirable coal mine dust.

Jan 1, 2000

By Marie-Antoinette Dziurla, Barrie Johnson, Åsa Kolmert

Acidophilic bacteria are well known for their role in accelerating the oxidative dissolution of sulfide minds, such as pyrite. Other acidophiles, however, are able to catalyze dissimilatory reductive reactions. Bacteria that reduce ferric iron to ferrous, and sulfate to sulfide, were isolated from ARD-impacted environments and immobilised onto porous beads made of recycled glass. Column bioreactors containing colonized beads were constructed and peacolated with synthetic and actual ARD, and evaluated for their capacities to promote iron or sulfate reduction, and pH amelioration. Iron reduction did not require strictly anoxic conditions in bioreactors, and rates of up to 800 mg Fe3+ reduced/(l*day) were achieved, with a conversion efficiency of up to 98%. Using mixed populations of acidophilic fungi and iron-reducing bacteria, the bioreactors were capable of promoting iron reduction using paper pulp as sole carbon and energy source. Reduction of sulfate in pack bed bioreactors was observed with acidic wastewaters of pH 3 and above, though average rates of 300 mg sulfate reduced/(l*/day) were less than those recorded for circum-neutral pH systems. Bioremediation of ferric iron-rich ARD was assessed using coupled iron-reducing and sulfate reducing bioreactors.

Jan 1, 2000

By J. F. Able, F. Djahanguiri

The US Bureau of Mines conducted research on underground stope leaching of metalliferous ores. Leaching underground would minimize the environmental impact of ore processing on the surface and would maximize minable reserves. An important aspect of this process is the minimization of pregnant solution losses and groundwater contamination by leach solutions. Bulkhead design and construction are important issues for solution control and stope-leaching economics. A reinforced-concrete bulkhead was designed, constructed and tested for solution control in an underground mine near Idaho Springs, CO. This paper presents the bulkhead-design methodology and construction procedure.

Jan 1, 1998

By Kalyan K. Bhattacharyya

A systematic slope design for open-pit mines has become a reality only in recent years. Advances in the science of rock mechanics, coupled with extensive use of computers, have enabled the numerical solution of slope design problems which were not previously amenable to analytical or numerical solution. This slope stability study was performed for the UJV-SB open-pit uranium mine of the Getty Oil Co., located in the Shirley Basin area, Wyoming. The purpose of the study was to determine the appropriate slope angles for a starter pit. The data generated during the mining of the starter pit would test the initial design and suggest appropriate modification in the design for future mining in the project area. There had been a history of slope failures in the open-pit uranium mines in the area due to the low competency of the overburden materials and adverse hydrological conditions.

Jan 1, 1979

By J. A. Organiscak

This paper examines methods for limiting occupational silica exposures for roof bolting personnel in underground coal mining. A canopy air curtain and an air tube were evaluated as means to provide filtered air over the breathing zone of these personnel. Laboratory testing showed that dust reductions beneath the air curtain and air tube approached 60 percent and 40 percent, respectively, with low interference air velocities. The data also showed that dust reductions were highest for positions closest to the device and that these levels decreased with distance. This paper also evaluates a metal rake, a flexible insert, and a rigid insert for cleaning the roof bolter dust collector box. Less dust was produced when using the rigid insert. Surprisingly, the flexible insert was sometimes no better than scraping or raking the dust onto the mine floor. However, little dust got on the coveralls when using either of the inserts.

Jan 1, 2002

By F. Djahanguiri

The US Bureau of Mines con¬ducted research on underground stope leaching of metalliferous ores. Leaching underground would minimize the environmental impact of ore processing on the surface and would maximize minable reserves. An important aspect of this process is the minimization of pregnant solution losses and groundwater contamination by leach solutions. Bulkhead design and construction are important issues for solution control and stope-leaching economics. A reinforced-concrete bulkhead was designed, constructed and tested for solution control in an underground mine near Idaho Springs, CO. This paper presents the bulkhead-design methodology and construction procedure.

Jan 1, 1997

By J. A. Herbst, S. L. Blust

Optimization of blasting, crushing, and grinding operations is filled with challenges. One of the more difficult tasks is accurately sampling and determining the size distributions of blasted and crushed materials at a reasonable cost. The task is difficult because of the large size of fragments and the tonnage involved. However, the size distribution measurements are necessary for models that predict the performance of mine-through-mill operations. This paper is concerned with the use of video sampling for this task at National Steel Pellet Company's operation in Keewatin, Minnesota Data gathering, data analysis, model building, and mine-to-mill simulation are all described.

Jan 1, 2000

By B. Govindarajan, L. S. Rao, T. C. Rao, B. R. Rao

Laboratory leaching experiments were conducted to extract potassium from glauconitic sandstone, and the effects of important variables were studied. The reduced time plot (RTP) for all of the variables obtained from the experimental data has been quantified by this simple equation: R = 100 (1 - exp (-0.693 *(T/T50)0.605) The time required for 50% extraction (T50) has been correlated by a regression equation to variables such as acid strength, temperature, fluorite: glauconite ratio and % solids. Both of these equations were used to predict the extraction percentage at different process-variable levels. In addition, several other experiments were conducted at arbitrary levels of the variables to verify the equations developed.

Jan 1, 1994

By Roshan B. Bhappu, Sukhendu L. Barua

The economics of developing and operating small precious metal mines are unique and require much more scrutiny than larger mines since a limited tonnage must carry a heavy burden of capital investment as well as operating cost per unit ton to be mined and processed. Moreover, potential operators of small mines do not have the required expertise available to critically evaluate the technical and economic aspects of their projects. In this paper, the authors have attempted to provide technical and economic guidelines for developing and operating small precious metal mines. Capital and operating cost estimates as well as return on investment are provided for various scenarios utilizing different mining and processing techniques.

Jan 1, 1987

By Jeong-Heum Kim, Jan M. Mutmansky

A number of solution methods for solving the nonlinear equations derived from mine ventilation networks use meshes selected from the network as the basis of the solution techniques. Mathematicians working in network theory have outlined several methods for speeding up the computations through mesh selection and ordering procedures. In the mine ventilation area, a fair amount of attention has been paid by ventilation specialists to procedures for choosing the meshes so that the computational effort is eased. However, little attention has been paid to mesh ordering methods. This paper outlines research into random mesh ordering procedures plus two non-random mesh ordering procedures and compares some results using these procedures within four solution algorithms.

Jan 1, 1993

By Robert Dunne, Paul Gelfi, Vernon Martins

The New Celebration Gold Mine is located 32 km south of the regional mining centre of Kalgoorlie. The current mill throughput is 1.7 million tonnes per annum with a gold production of around 120,000 ounces per year. The main source of ore for the mill comes from the Hampton Boulder and Pernatty pits. Over the last two years the oxide reserves from these pits have been depleted and the harder primary sulphide ores are now being processed. This change has led to a decrease in cyanide extractable gold.

Jan 1, 1991

By Pierre Louis, Jacques Duparque

ACTIRED is a new process for gold and silver elution from activated carbon based on the addition of hydrazine, needing no extra investment and which generates a systematic increase in elutions kinetics. This process either operates at a lower temperature and maximizes financial gain or reduces elution time or operates at a compromise between these two options taking into account the needs of each plant. Industrial use of the process at SNC Lastours, France (Zadra elution column 3,5 bars -125°C) has proved at 95 ° C the following points:

Jan 1, 1995

By Jan M. Mutmansky

While production scheduling for both surface and underground mining operations is similar in nature, a rather large array of techniques is applied in solving such planning problems. The techniques consist of both rigid operations research (OR) methods and practical procedures which are not mathematically based. In the following sections, a short summary of some of the techniques that are applicable to production scheduling problems in mineral operations is presented. The techniques discussed are: linear programming, integer programming, dynamic programming, graph and network theory, simulation, and heuristic methods. For an in-depth comprehension of these techniques, the reader is referred to any of the available textbooks on these subjects. One or more references will be listed for each topic to provide a starting point.

Jan 1, 1979

By H. Lind

Mining in Estonian oil shale deposit mainly takes place in the Ordovician, Keila-Kukruse aquifer. The aquifer is affected by mining and is fully dried out around the working mine areas (Perens and Savitski, 2008). The groundwater level is decreased down to 30 m, to the mine floor elevation using about 30 pumping stations (Lind, 2005). The pumping rate is very high - depending on the season, ranging from 10 up to 40 m3 per ton of produced oil shale (Reinsalu et al., 2006). The Estonian oil Shale Company mined 15.5 million tons of oil shale in 2007 (Source: Estonian Oil Shale Company). In order to predict the effects, and avoid the social and environmental impacts, there is a need to continuously monitor the situation and run software simulations aiming at decreasing the pumping rate. This becomes even more important since the environmental taxes on usage of groundwater resources increase every year. Therefore, it is necessary to monitor groundwater level and quality, and develop a groundwater model for the overview of the situation during mine operations and also for a number of years after mine closure.

Jan 1, 2008