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By J. C. Franklin

The U.S. Department of the Interior, Bureau of Mines, has developed a data acquisition system to continuously monitor radon, working level, absolute pressure, temperature, relative humidity, and air velocity. Data have been taken in intake and exhaust drifts, working stopes, and sealed-off areas of positive and negative ventilated uranium mines. Radon emanation rates, ranging from 1.7- to 12.2 x 2 10-l4 Ci/cm /sec were determined in four mines. The ratios of short duration, primary fan shutdown time to radon normalization time were 1 to 2 and 1 to 4, respectively, for-negatively and positively ventilated mines. Blasting and slushing caused radon increases of 160 and 67 percent, respectively.

Jan 1, 1980

By J. Paraszczak

With regards to the cost and profitability of a mining operation, the performance of the equipment employed is one of the key issues. Cost and profitability depend on, among other factors, the reliability and availability of the equipment. In an attempt to reduce equipment downtime, it is indispensable to collect and analyze reliable data and information on failures and maintenance actions. This paper reviews common problems encountered in this respect, with particular emphasis on the lack of uniform terminology and methodology. Recommendations concerning the standardiztion of reliability and maintainability concepts and measures are given. Regarding the benefits that the latter may bring, the paper concludes with a proposal for an industry-wide initiative in this respect.

Jan 1, 2002

By Abdellah Chlk, Driss Msatef

Sedimentary phosphate ores are known for their relatively high specific surface area and porosity, which have a positive influence on their reactivity when used as fertilizer in acidic soils or in the manufacture of wet phosphoric acid and phosphatic fertilizers. However, these physical properties could have a negative effect on the behavior of these ores if dried. This effect has been studied on several phosphate ores samples by: the determination of mineralogical and textural properties of these samples, the determination of vapor water sorption isotherms, at different temperatures, from which the sorption heat has been calculated, carrying out several drying tests using a laboratory fluidized bed reactor under constant conditions, which showed important differences in drying rates and residual moistures.

Jan 1, 1999

By Jiro Yamatomi, Susumu Takemura, Osam Sakai, Hiroshi Shimotori, Yoshio Otsuka

The Toyoha Mine is operated under extremely high rock temperature. The geothermal heat is 10 to 20 times more active than the average of the Japanese Islands. The highest temperature ever observed in exploration drill holes is 242°C that must be equivalent to those of the geothermal fluids utilized for power generation in Japan. In order to improve the underground climate, the mine has a plan to introduce paste backfilling and to effectively reduce the heat flows from the mined out stopes. The surface flow test was carried and the second test is being arranged in underground.

Jan 1, 2001

By Malcolm J. McPherson

This paper describes the algorithm used in a BASIC program for an IBMXT microcomputer, to simulate the underground mine climate. The program called CLIMSIM has been developed and refined over several years as a result of considerable use at operating mines. The program has been designed to be easy to use and be understood by the practicing mine ventilation engineer. It provides predictions of the work place climate, so that the optimum ventilation/cooling system can be designed to obtain a certain air cooling power or effective temperature at the work place. An example is given of the application of the program to a mechanized cut and fill stope at the Homestake gold mine in South Dakota.

Jan 1, 1986

By J. M. Kruger, P. Berendsen, A. Martinez

High-resolution ground-penetrating radar (GPR) was used to image the near-surface extent of two exposed Late Cretaceous kimberlites intruded into lower Permian limestone and dolomite host rocks in northeast Kansas. Six parallel GPR profiles identify the margin of the Randolph 1 kimberlite by the up-bending and termination of limestone reflectors. Five radially intersecting GPR profiles identify the elliptical margin of the Randolph 2 kimberlite by the termination of dolomite reflectors near or below the kimberlite's mushroom shaped cap. These results suggest GPR may augment magnetic methods for the delineation of kimberlites or other forceful intrusions in a layered host rock where thick, conductive soil or shale is not present at the surface.

Jan 1, 1998

By J. A. Brierley, Arpad E. Torma, Victor C. Storhok, C. L. Brierley, Batric Pesic

Chemical and electrochemical studies were performed during bioleaching of cobaltite concentrate with Thiobacillus ferrooxidans. The two principal minerals present in the concentrate were pyrite and cobaltite (CoAsS). During chemical studies, the effect of pH on dissolution rates was examined under uncontrolled and pH-controlled conditions. It was found that in the pH range 1.5-3.0 there was no pH effect if the initial pH was not controlled (maintained). When the initial pH was controlled, the leaching of Co, As, and Fe depended strongly on pH. Electrochemical studies were performed by using cyclic voltammetry and constant potential techniques. A sequential reaction mechanism was proposed for dissolution of cobaltite.

Jan 1, 1993

By D. Ince

Flotation of dolomite from apatite was investigated, using dodecylamine hydrochloride or sodium oleate as the collector, with and without inorganic modifiers such as sodium chloride. Separation of dolomite from apatite was anticipated from the single mineral experiments under various pH and collector concentration conditions. Flotation selectivity in the mixtures, however, was found to be limited. Attempts to control the flotation response of these minerals by addition of salts such as NaCl and KCI indicated that selectivity is possible. The presence of sodium chloride was determined to depress apatite flotation using sodium oleate, leaving dolomite flotation unaffected (Moudgil and Ince, 1989). In this paper, conditions for optimum separation and the effect of major parameters on the desired selectivity are discussed.

Jan 1, 1992

By K. A. Natarajan

This paper deals with the various electro- and biochemical mechanisms involved in the bioleaching of multisulfide minerals such as those containing copper-lead-zinc and copper-nickel-iron. Galvanic series for sulfide minerals consisting of pyrite, chalcopyrite, galena, sphalerite, pentlundite, and pyrrhotite in an acid bacterial leaching system is illustrated, and the role of relative electrochemical activity on selective dissolution is discussed. Typical leaching results are shown to illustrate the practical applicability of galvanic effects in bioleaching of multisulfides. Attachment of Thiobacillus fewooxidans onto chalcopyrite and sphalerite mineral substrates is illustrated through scanning electron micrographs. The role of high-metal-tolerant, specially adapted strains in the leaching of multimetal concentrates is also outlined.

Jan 1, 1987

By L. G. Austin, R. C. Klimpel

Batch breakage kinetic tests were performed in a mill of 0.3 m diameter for a range of mill conditions. Accurate simulation required the measurement and use of factors which accelerated the specific rates of breakage of the top sizes as finer material accumulated in the slurry. These factors depended on the size distribution expressed relative to the top size, not the absolute size, suggesting that they are due to a packing effect not a rheological effect. The data simulated correctly a series of steady-state continuous tests in a mill of the same diameter providing values were corrected to the hold-up, ball load, slurry density, and size distribution measured in the continuous mill tests.

Jan 1, 1990

By Hassan El-Shall, M. N. Ahmad, Ponisseril Somasundaran, C. R. Holland, G. M. Walker, N. Iles, R. D. Chandler, Regis Stana, B. Duddy, Patrick Zhang

Phosphoric acid is a major raw material for the production of ammonium phosphate (AP) that is used as an intermediate in fertilizer production. Impurities within commercial grade wet process phosphoric acid are important in producing a fertilizer granule with good handling properties. The impurities identified as being important are; iron (III), aluminium and fluorine-containing compounds. Results show that the viscosity of the AP slurry produced increases by increasing the amount of impurity in the acid. Bench scale tests have been successfully replicated on a plant scale leading to a better understanding of the composition of impurity levels within phosphoric acid required to produce a high quality, free flowing, hard, spherical and non-caking granular fertilizer.

Jan 1, 2002

By G. A. Munoz, J. D. Miller

Gold leaching of an auriferous pyrite ore from the Portovelo deposit in Ecuador indicates that noncyanide leaching systems, such as thiocyanate and thiourea, are not as effective as the traditional cyanide system. For example, whereas approximately 95% of the gold can be leached from the ore with cyanide, only about 50% gold dissolution can be achieved with a thiocyanate leaching system. Electrochemical measurements indicate that gold is not cathodically protected by pyrite in these systems. Based on the results of preliminary diagnostic experiments, it appears that gold dissolution in thiocyanate and thiourea systems is limited by passivation due to the formation of either elemental sulfur or sulfur compounds on the gold surface.

Jan 1, 2000

By M. M. Botz

Cyanidation tailings disposed of in a surface impoundment experience a loss of cyanide due to natural attenuation, which frequently reduces the cyanide concentration to very low levels. Quantifying cyanide losses in terms of impoundment geometry, local weather conditions and feed-solution chemistry has been largely empirical in spite of the fact that, in many cases, mining operations rely on surface impoundments to reduce cyanide to below an internally regulated concentration or below an effluent limitation. To permit a quantitative evaluation of cyanide losses in an impoundment, a computer simulation was developed to estimate the losses of free, weak acid dissociable (WAD) and total cyanide due to dissociation, photolysis and volatilization. Results of the model are compared with data collected for a North American tailings impoundment in 1998.

Jan 1, 2000

By D. T. Maiers, P. L. Wichlacz, P. A. Pryfogle, J. H. Wolfram

The effects of metal solution concentration, biomass density, length of exposure time, and pH were determined for biosorption of molybdenum (Mo) and chromium (Cr) by three organisms. Results indicate that it is possible to sorb Mo and Cr from dilute solutions. Differences were observed in the abilities of an organism to sorb Mo and Cr as well as among respective abilities of the three microorganisms. This suggests an inherent selectivity of the organism which may afford the means to control a sorption-based process. Results also indicate that the metal sorption abilities of these microorganisms depend on duration of exposure, biomass density, solution pH, and the metal concentration of the solution. Each of these parameters suggests an additional means of controlling the sorption process.

Jan 1, 1989

By A. Gene Collins

The demand for lithium may increase because of its potential use id lithium batteries and in the generation of electrical power by fusion. Therefore, lithium abundance in some United States oil-field brines was surveyed. Oil-field brines from numerous locations were found to contain more than 100 mg/l lithium and several exceeded 500 mg/l. An area of 25,000 km2, with a reservoir thickness of 60 m, an effective porosity of 5 percent, and a brine with a specific gravity of 1.2 containing 100 mg/l of lithium, contains about 0.75 x 106 tonnes (1 tonne = 1 metric ton = 1,000 kg) of lithium in 7.5 km3 of brine. It is postulated that the brines were enriched in lithium by lithium-rich spring water or lithium leached from volcanic rocks followed by evaporation sequences.

Jan 1, 1978

By Bob Gordon, Allen Furth, Dan Dobbels

A 4.8 m (16 ft) diameter hard rock tunnel was driven through granite bedrock to create the 1.7 kilometer (1.1 mile) long Hampton McCloy Retention Tunnel for the city of Richmond, Virginia. During the work the tunnel encountered narrow seams of partially decomposed granite that were not self supporting and could be dealt with using ribs and lagging. However, as the tunnel approached the receiving shaft, it encountered a large seam of highly decomposed rock, alluvial deposits and running sand which resulted in soil loss into the machine. As a result of this condition, a jet grouting program was quickly developed to allow the tunneling to continue. This paper will describe the manner in which jet grouting was used to solidify and stabilize the decomposed bedrock, alluvial soils, and running sand to allow the TBM to continue tunneling.

Jan 1, 2003

By I. Iwasaki, K. A. Smith, X. Cheng

A cathodic decomposition model was examined for both pyrrhotite and chalcopyrite in an attempt to analyze the formation of surface coatings in deoxygenated solutions at natural, near neutral pH. Combination potentials established between the mineral-grinding media pair were simulated by applying a potential of -0.455 V (vs. a standard hydrogen electrode) either to a pyrrhotite or to a chalcopyrite electrode. Chronoamperometry was used to study the polarization behaviors and alteration of mineral surfaces through cathodic processes. The kinetic parameters of cathodic decomposition of pyrrhotite and chalcopyrite were determined and compared. It was concluded that pyrrhotite decomposed faster than chalcopyrite in near-neutral pH solutions. Both minerals were then covered by a film consist¬ing mainly of iron hydroxides, which adversely affected their flotation.

Jan 1, 1999

By Noel N. Moebs, John L. Ellenberger

Geologic structures in mine roof rock contribute to many roof falls in Appalachian coal mines. These structures include paleochannels, scours, pinch-outs, slickensides, clay veins, and cravasse splays consisting of thinly interlaminated sandstone and shale. These structures often can be identified during, and sometimes before, development and mine projections can be revised to reduce the adverse effects of discontinuities in roof structure. Large areas of roof consisting of laminated sandstones or incompetent strata generally can be delineated from exploratory drill-hole data and the need for supplementary support can be anticipated. Because an accurate description of roof geology also provides some indication of optimum length and type of roof bolts that should be installed, this Bureau of Mines paper describes the hazardous roof structures most commonly encountered in the Appalachian coal region.

Jan 1, 1982

By Richard A. Brown, Robert D. Norris

By-product metals can be a significant source of revenue for a mining operation if their recovery can be accomplished without negatively impacting primary metal recovery. The main problem encountered in separating primary and secondary metals is to selectively control the solubility of the individually important metals with¬out affecting their ultimate recoverability As a class of hydrometallurgical chemicals, peroxygens have a versatility which permits the selective recovery of individual metal species. Peroxygens function as more than simple oxidants. They are effective solubility control agents and have proven utility in complexation, precipitation, dissolution, extraction, oxidation and reductive processes Peroxygens have been used commercially to recover by-products vanadium, uranium, molybdenum, and cobalt and have proven experimentally to recover rhenium, gold, silver, manganese and zinc

Jan 1, 1983

By D. III Earley, R. L. Blake

The Bureau of Mines is investigating the potential for in situ mining (ISM) of gold and silver mineralization. This preliminary study examined samples from several types of deposits. It used light optical microscopy and the electron microprobe to characterize the ore and gangue minerals and textural features of these samples. This included the spacial relations between the target minerals and likely natural fluid channel ways. Low-grade disseminated deposit types from the western US were found to contain fracture- hosted or matrix-hosted gold and silver minerals, some of which are encapsulated by quartz or pyrite. Successful ISM application to gold and silver deposits needs this data in order to understand potential problems of the lixiviant reaching the ore minerals.

Jan 1, 1991