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By Gordon E. Ager

A technique for the synthesis of mineral processing flowsheets from laboratory batch test data is described and examples of the application of the procedure are given. The procedure requires the collection of kinetic data, the optimization of the flotation time in each separation stage, then simulation of the material balance for a continuous circuit.

Jan 1, 1989

By Waclaw Dziurzynski, Janusz Tracz, Danny Wooton, Andrzej M. Wala

The purpose of this paper is to present validation studies of the mine-fire simulator using data gathered from an actual mine fire which occurred in November 1991 at the Pattiki Mine. This study evaluates the suitability of the computer software package for modeling underground fires. The paper also discusses the importance of the on-line monitoring system for the validation process.

Jan 1, 1995

By Robert A. Jankowski, Jonathan Kelly, Edward F. Divers

Results for the first underground test of the ventilated drum in a U.S. coal mine are presented. Tests were conducted by the Bureau of Mines through a contract research program with Foster-Miller, Inc., to evaluate dust control effectiveness in a western mine and for gas control in a full scale laboratory facility. The ventilated drum is designed to reduce the amount of dust from cutting by drawing dust-laden air from the cutting zone through twelve water- powered "dust capture" tubes built into the shell of the shearer drum. High pressure water up to 1 12.48 kg per cm2 (1,600 psig), released from sprays, induces maximum airflow of 1.89 m3/sec (4,000 cfm) from the face side of the drum and provides cleaning for respirable dust and improved methane dispersion. At the gob side of the drum a deflector plate, attached to the cowl arm, turns the water spray and a proportion of the cleaned air back into the cutting zone. More than 50 ventilated drums have been installed to date in England, and their tests carried out on fixed height and single-ended ranging drum shearers have shown reductions in respirable dust of 60-80 pct, as compared with conventional wet cutting. The U.S. test on a double drum shearer showed slightly lower reduction.

Jan 1, 1987

By M. R. Stokes

Over the recent years there has been an increase in the application of retreat mining on longwall faces as mine operators strive for ever greater productivity. The purpose of this paper in then to review current practice as a starting point and then move forward to discuss the future geometry's that a longwall face may take. Single and double production zone three roadway faces are assessed. All possible configurations of three roadway faces are defined. Unsuitable configurations are rejected after analysis of broad ventilation issues. The remaining configurations are then assessed on an operational basis, this includes: limits on retreat synchronisation, structure of centre gate, floor bulging and equipment installation. The remaining viable configurations are then further assessed on ventilation issues, this includes: provision for gas control/gas fringe, face climate and balancing of face flows. Possible face climate is assessed using numerical simulation of the various configurations, the predicted dry/wet bulb temperature and predicted levels of heat stress indices are given and discussed in detail, along with face flow balancing. The necessary conditions required for the successful operation of a double production zone three roadway face system are formulated, together with conclusions as to the possible level of application.

Jan 1, 1997

By J. A. Herbst, J. E. Bohrer, Y. C. Lo

A systematic approach has been developed to analyze a phosphate grinding circuit with a view toward determining promising alternatives for increasing mill capacity. This analysis was carried out and capacity increases were predicted in the context of detailed population balance models developed for the plant ball mills and classifier systems. Model development and verification was performed using data obtained in a series of batch tests and two plant test campaigns. The effects of feed rate, percent solids, ball size, and mill material filling, etc., on grinding were investigated in the laboratory and plant. Residence time distribution tests were also performed to determine the transport behavior in the mill. The population balance models were found to provide accurate predictions of full-scale grinding circuit performance. Based on the findings of this study, additional capacity in excess of 25% was predicted for these ball milling circuits by a proper combination of ball size change, mill dilution, and adopting screen classification in place of hydro-cyclones. These predictions have been confirmed by plant tests in which the recommended operating changes have been implemented. Understanding the effects of operating variables on breakage kinetics and the interplay between kinetics, transport, and classification has contributed significantly to increasing the mill capacity.

Jan 1, 1988

By W. W. Koczkodaj, J. Partyka

Beat exchange in an open air-water system is considered. The system incorporates a vertical cooling tower, and a horizontal multi-stage spray chamber with unlimited number of stages. Mixing of two streams of both water and air is permitted. A spread-sheet implementation estimates temperatures of outgoing water and air for given mass flow of water and air, factor of merit for heat exchangers, barometric pressure, wet- and dry-bulb temperatures, and the temperature of incoming water.

Jan 1, 1987

By Robert B. Fulton

The objective of this chapter is to discuss the interrelationship between industrial minerals and chemical manufacturing. It is intended to supplement rather than duplicate the commodity chapters. Particular emphasis is given to the pertinent chemical element and to market factors. Condensing this broad subject into a few pages of this handbook permits treating only the most important elements derived from industrial minerals. Hydrocarbons, which quantitatively dominate as raw materials for the chemical industry, are omitted, as are the metallic elements and the minerals covered in other "use" chapters such as phosphorous, potassium, and nitrogen for fertilizers, and titanium dioxide for pigments. The remaining six elements of major importance are: boron, bromine, chlorine, fluorine, sodium, and sulfur. These elements are treated individually under separate headings. [Table 1] affords an overview of the main industrial minerals, the chemical products derived from them, and end uses of the products. Salt brines have particular importance as raw material sources for the chemical industry. Table 2 is a chart of the chemical compounds derived from four types of brines: (1) Owens Lake-type brines, which are sources of boron and sodium compounds; (2) Midland-type brines, from which bromine, iodine, and chlorides of calcium, magnesium, potassium, and sodium are derived; (3) Searles Lake-type brines, yielding boron, bromine, lithium, magnesium, potassium, and sodium compounds; and (4) Silver Peak- type brines, produced mainly for lithium. MARKET ATTRIBUTES Some of the important market traits common to industrial minerals used by the chemical industry are: 1. They are international commodities, such as fluorspar and sulfur, which largely move to foreign consumers. 2. Grade, and freedom from deleterious elements are important factors affecting their usability in chemical processes. An example is salt (NaCl) used in electrolysis where ultrapure evaporated salt is required to meet rigid specifications. 3. Purified products take on the characteristics of specialty items and command a distinctly higher price than the basic commodity from which they are derived. 4. In practically all cases, chemical users require some sort of cleaning or beneficiation of the naturally-occurring mineral to bring it to specification, and individual specifications may vary from user to user for essentially the same use. 5. In some instances it is necessary to strike a balance between what the vendor can supply and what the buyer requires, with the result that specifications have to be eased to afford the needed materials in marginal cases. 6. Because they tend to be bulk commodities, low cost for handling and transportation are important and such costs may limit the area from which a chemical user can draw his supply. 7. Shipments are usually in bulk and frequently in multiple-car, full-trainload or full-shipload lots to reduce transport costs, which in turn may require large terminal investment facilities. 8. Purchases are generally by contract of one year or longer term, with spot buying playing only a minor role. 9. Contract prices are usually fixed in short term commitments, but may vary according to assay, with premiums and penalties for content above or below the norm; however, general practice is for specifications to be fixed in the contract with minimums being set for the desired material and maximums for undesired elements. In longer term contracts, prices are often escalated on labor, fuel, and other vendor processing costs. 10. Suppliers of individual commodities to the chemical industry tend to be limited in number and are generally medium- to large-size producers that supply a few major consumers. 11. The bulk of the mineral volume is for basic chemical uses, sulfur suppliers to sulfuric acid producers and fluorspar for hydrofluoric acid producers being typical examples. These basic chemical products then are used for the production of other products. 12. Shortage of a supply of adequate quality leads consumers to seek substitutes. In the case of fluorspar, much work is being done on recovery of fluorine from phosphate rock. Success in the form of fluorosilicic acid and/or hydrofluoric acid production could, in time, affect the hydrofluoric acid chemical industry. 13. Markets tend to be characterized by cycles of shortage followed by oversupply, with attendant wide price fluctuations. 14. Baniers to trade can have an adverse effect on the necessary movement of industrial minerals used by the chemical industry in international trade. Antidumping laws, quotas, and tariffs can disrupt or dislocate normal markets. 15. Chemical industry consumers may back-integrate for security of supply or for favorable economics, sometimes by joint ownership and often with experienced mining partners.

Jan 1, 1994

By F. C. Schwerer, C. R. McKee, J. C. Seccombe

Production of methane from coal seams requires hydrofracturing, and the length of a hydraulic fracture determines we11 spacing. Since the volume of fluid injected is known, the fracture length is the volume divided by average width and height. If the fracture is contained in the known height of the seam, then fracture width becomes the major factor con- trolling length. Width is proportional to coal compressibility; bulk compressibility is known to be larger than intrinsic compressibility. A method is given here to measure in-situ compressibility (a) from transient pressure testing. Theory linking flow in porous media with rock mechanical properties is reviewed. A consistent derivation of the porous flow equation is given incorporating 3-D deformation and the effective stress parameter "st' linking changes in effective stress and pore pressure. The relations for "st' in terms of a and intrinsic compressibility (ai) are substituted into the field measured porosity-compressibility product (net) and solved for a, the constrained matrix compressibility. In a field example, using 4 wells with an anisotropic analysis, the ratio of major to minor permeability was 17 for the Pratt A seam. a was found to be 6x10-5/psi as opposed to the laboratory value of 1.4x10-6/psi.

Jan 1, 1986

By P. R. A. Andrews

Areas of bubble contact were delineated for topaz and tourmaline in the presence of chloride, fluoride, sulfate, phosphate, oxalate, and citrate ions using dodecylamine hydrochloride collector. The limits of pH and the minimum collector concentration were established using the bubble pick-up technique. Bubble contact did not occur below the p.z.c. (point of zero charge), estimated to be 5.6 for topaz and 6.6 for tourmaline, in the presence of chloride ion. Flotation below the p.z.c. was, however, extended by citrate, oxalate, phosphate, sulfate, and fluoride ions. Oxalate, citrate, and fluoride ions displayed the greatest pH range of activation, followed by phosphate and sulfate ions. Chloride ion acted as an indifferent electrolyte. Topaz was selectively activated with respect to tourmaline by fluoride and phosphate ions. Topaz was activated by fluoride ion between pH 2.4 and 5.6. Tourmaline flotation in this pH range was virtually insignificant. Topaz was activated by phosphate ion between pH 4.9 and 7.4. Tourmaline flotation in this pH range was only partial. Activation appeared to be strongest when anionic protonated species were in maximum concentration. Strong activation also corresponded to very stable metal ion species thought to be formed on the surface of each mineral.

Jan 1, 1991

By Rajiv Hadkar, M. D. McKinley, J. B. Hiskey, B. J. Scheiner, G. W. Warren

Flyash from municipal solid waste incinerators containing roughly 13 to 15% Zn, 2% Pb and 0.2% Cd is an attractive material for simultaneous metal recovery and detoxification. Results have shown that Pb in flyash is present as PbSO4 and PbC12 and that about 70% of the Zn is present in the form of soluble amorphous compounds. Leaching results in a number of acid and basic lixiviants show that acid leaching is clearly more effective than basic leaching which is limited by low solubility of Cd and Zn. Cementation in acid solution with pH < 1 promotes redissolution of the precipitated metal. Successful zinc electrowinning from chloride leaching solutions has also been demonstrated, although Pb2+ and Na+ can be potentially detrimental. The presence of Pb2+ can prevent deposition of metallic Zn, forming zinc oxychloride, ZnC12.4Zn(OH)2, instead. High concentrations of Na+ can also result in precipitation of NaCl. This investigation has shown that hydrometallurgical treatment of MSW flyash through leaching, cementation and electrowinning is a potentially feasible method for simultaneous detoxification and recovery of metal values. Several issues have also been identified which would require further investigation for final process development.

Jan 1, 1993

By Kenneth S. Johnson

High-purity gypsum of Permian age crops out in three major gypsum districts of western Oklahoma. The northwest and southwest districts have important reserves in the Blaine Formation, whereas reserves of the west-central district are in the Cloud Chief Formation. Gypsum beds of the Blaine Formation typically are 10 to 30 feet thick, 95 to 99 percent pure, and interbedded with shales that are 2 to 30 feet thick. The base of the Cloud Chief Formation consists of a massive bed of gypsum that typically is 20 to 100 feet thick and is 92 to 97 percent pure. Anhydrite is present in the sulfate beds, beneath 20 to 100 feet of overburden, at a number of places in all three districts. Total gypsum reserves in the three districts are estimated at 48 billion short tons. These reserves are well suited for open-pit mining or quarrying, because gypsum typically forms hills in the semiarid climate of western Oklahoma, and the gypsum layers are nearly flat lying, without folds or faults. Seven companies currently mine a total of 1.0 to 1.4 million tons of Oklahoma gypsum each year for wallboard, for plaster, as a retarder in portland cement, and as a soil conditioner.

Jan 1, 1978

By G. J. Olson, K. S. Noah

A combined physical/biochemical process for the precombustion removal of 13 inorganic hazardous air pollutant (HAP) precursors, i.e., Sb, As, Be, Cd, Cr, Cl, Co, F, Pb, Hg, Mn, Ni and Se, from coal was tested. Biochemical processes for removal of HAP precursors from coal potentially offer advantages of deeper cleaning, more specificity and less coal loss. The slurry column is a second-generation process for the beneficiation o f fine (60-mesh x µm coal by a combination of physical separation of mineral matter and biooxidation of pyrite. Sixty-seven percent removal of pyrite from a 60-mesh Pittsburgh #8 coal was achieved at a 35% (w/w) slurry concentration and a five-day reactor residence time. Ninety percent of the heating value of the feed coal was recovered. Among the HAP precursors of most concern, over half of the Se, As and Hg were removed from the feed coal. From 40% to 70% of most HAP precursors were removed from the feed coal. Hg in the feed coal was reduced from 0.12 to 0.054 ,µg/g in the product coal, while waste coal contained 0.24 µg/g.

Jan 1, 2000

By Jakub Nalaskowski, Robert Aranowski, Jan D. Miller, Jan Hupka

The polyolefins, mainly polyethylene and polypropylene particles, are used as an active filler material in polymer-polymer blends and are being used for the modification of asphalts to pro- vide for high-load, low-maintenance road construction. The stability of prepared blends depends on the interaction forces between polyolefinfiller and the matrix and/or between two polyolefin filler surfaces in the polymeric matrix. Various additives, especially surfactants, can be used to modify these interactions and improve the stability of polymer blends. In current research, direct force measurements between polyethylene (PE) surfaces in n-tetradecane, a nonaqueous solvent imitating the polymer matrix, were performed in the presence of lauric acid and dodecylamine using the AFM colloidal probe technique. Additionally, the zeta potential of polyethylene particles in the presence of surfactants in n-tetradecane was measured. The interac- tion forces between the polyethylene surfaces can be described as a combination of electrical double layer repulsion and steric repulsion between polymer chains extending into the n-tetradecane sol- vent. The addition of surfactant to the n-tetradecane was found to increase the repulsive force between the PE surfaces. The strongest repulsion was observed for dodecylamine. Additionally, the temperature efect on the interactions in n-tetradecane was studied. It was found that steric repulsion between the PE surfaces increases with an increase in temperature.

Jan 1, 2003

By C. McLean, S. G. Kolb, A. J. Erickson, S. C. Moore

The Grossschloppen vein-uranium deposit, Bavaria, West Germany, was examined with underground workings during 1980-82 by Esso Erz GmbH, an affiliate of Exxon Minerals Company (EMC). Geologic evaluation entailed dense drilling of a portion of the deposit from workings constructed specifically for the program. Discovered in 1977, the deposit was initially explored by surface diamond drillholes which allowed definition of a 30-60 m wide vein system discontinuously mineralized along a 1000 m strike length and to at least a 450 m depth. The underground program was conceived as a cost-effective procedure to answer questions on vein correlation, grade continuity and variability. A 1200 m decline allowed access for detailed sampling of approximately 10% of the known area of mineralization. Fanned drillholes, logged by gamma probe, were spaced to provide intersections of veins at 10 to 20 m intervals. Six cross-cuts also penetrate the pitchblende and uranophane mineralization which occurs in 0.1 to 2.5 m thick quartz veins. Detailed cross-sections and level plans were constructed for resource estimates of the intensively studied portion of the vein system. The program resulted in the discovery of local, high grade areas and an average grade in the evaluated area nearly double that expected from surface drilling.

Jan 1, 1992

By Eric Forssberg, Benny Andreasson

The paper describes experiments to stabilize mineral processing waste materials for use in construction. Fine mineral processing wastes from various mines have been mixed with binders and compacted. As binders blast furnace slag and other materials have been used. Experiments have been made in laboratory scale and in large scale. The results have been evaluated by means of determinations of compression strength and the modulus of elasticity. The paper also describes some experiments in laboratory and large scale to use stabilized mineral processing wastes for back filling in cut and fill mining.

Jan 1, 1992

By Deborah A. Kramer

Although beryllium was initially discovered in 1797, it was not until 1916 that the first significant quantity of beryllium metal ingot was produced in the United States. Before 1940, most of the small quantity of beryllium metal used in the United States was supplied by Germany. Beryllium was not used in its metallic form; it was used as an alloying addition to other metals, mainly copper and nickel. World consumption of beryllium at that time was estimated to be a few hundred kilograms annually. Because of increased tensions in Europe before World War II, imports of metal from Germany ceased in 1940, and domestic production was required to meet the needs of the military. As a result, by 1946, the United States became the principal supplier of beryllium products for the world, a condition that prevails today. Because of beryllium&apos;s high strength, light weight, and high thermal conductivity, it has been used in a large number of industrial and defense applications as a metal, alloy, and oxide. The United States is the only country other than China and the former USSR currently producing beryllium products from beryllium ores and concentrates. Bertrandite, mined in Utah, is the principal ore source of domestically produced products. Imported ore, mainly from Brazil, supplements domestic ore supplies. Production and consumption data for the United States is shown in [Figs. 1 and 2]. Production data for 1969-1979 is withheld to avoid disclosing company proprietary data.

Jan 1, 1994

By R. Larry Grayson

A menu-driven, linear-programming- based, user friendly computer program was developed to assist mine managers in determining optimal longwall panel dimensions for a given set of operating conditions. A sensitivity analysis must be performed by varying key mining and configurational parameters over an expected, practical range during the optimization process. Results from analysis of a base case mine indicated that no single combination of longwall panel length and face width is optimal for all operating situations. Each mine manager must therefore look closely at his operating situation and determine the proper dimensions to minimize total mining cost.

Jan 1, 1989

By Henry P. Cole, Andrzej M. Wala

Engineers and psychologists at the University of Kentucky have developed simulation exercises that teach and test proficiency of mining technical personnel for coping with planned and accidental connections between separate air courses in underground mines. The exercises are based upon investigations of actual mine disasters. The exercises are judged as valuable and interesting training materials by experienced mining personnel. Although these specialists generally perform well on the exercises, potentially fatal errors are not uncommon. The use of such realistic exercises may better prepare miners for preventing and coping with underground mine ventilation emergencies.

Jan 1, 1987

By Y. M. Jiang, R. L. Sanford, D. W. Park

Artificial intelligence has emerged over the past two decades as an important problem-solving tool. Techniques include expert systems, neural networks, free classification, fuzzy logic and genetic algorithm. These methods can be employed to solve rock mechanics and ground-control problems associated with the highly complex nature of rock masses and ground conditions. A current study focuses on the development of an artificial-intelligence system for real-time interpretation of data collected from longwall monitoring stations and on the development of an early warning system for the prediction of undesired conditions and the prevention of longwall-mine instability problems. The successful application of these artificial-intelligence techniques will contribute to a safer and healthier mining environment.

Jan 1, 1997

By C. Bemelmans, L. Chia, T. O’Keefe

Lead alloys function effectively as oxygen-evolving anodes in copper SX-EW operations, and they are highly resistant to corrosion. However, the presence of an organic (from solvent extraction circuits) in the electrolyte seems to enhance solution line attack. Laboratory tests showed that lead is soluble in D2EHPA, Acorga and LIX 984 to a limited, yet measurable, degree. Lead alloys and various lead phases formed on the anode were tested to evaluate their effect on the corrosion process in organic media. Possible causes for anode corrosion and mechanisms responsible for their initiation are discussed.

Jan 1, 1998