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By Adrian Smith

14.1 INTRODUCTION From the time the last recoverable gold is extracted from ore on a heap leach, the ore - now spent ore - changes from being the resource, indeed the raison d'etre of the operator, to a potential liability. The spent ore contains process chemicals and constituents leached from the ore both in the interstitial pore water in the heap and on the surfaces of spent ore. If these chemical species were released to the environment, it could have a potential impact on the quality of both surface water and groundwater resources. Accordingly, the spent ore must be left in a condition where it does not present a potential environmental liability. This can be accomplished either on a decommissioned pad or, if the heap leach is operated as a load/unload scheme, in a waste facility. In general, the residual cyanide level in the spent ore is the perceived controlling factor when determining whether the leached material is suitable for abandonment. Regulatory authorities set permit conditions for heap leach abandonment in terms of residual cyanide levels, for example, Smith and Struhsacker (1987). This chapter discusses cyanide degradation and methods for detoxifying a heap leach in order to meet regulatory limits/permit conditions for abandonment. Cyanide degradation and detoxification by "natural" processes are described initially, based on the chemistry and geochemistry discussed in Chapter 13. This leads to a review of chemical treatment processes for detoxification of spent ore. The advantages and apparent disadvantages are then appraised. 14.2 NATURAL DEGRADATION AND DETOXIFICATION For the purposes of discussion, "natural" detoxification processes can be divided into two alternatives: • Passive abandonment (the so-called "do nothing" option); and • Water In the first alternative, the spent ore is merely left on the leach pad to age; the second alternative involves the flushing of the spent ore with water.

Jan 1, 1988

By K. Takahashi

The methyl stretching vibrations for a series of normal and iso xanthates were determined using an infrared spectrophotometer, and the results were compared with the published information on the corresponding alcohols. The frequency shifts of methyl stretching vibrations may be attributed to the inductive effect of polar groups. The hydrogens in the shorter chain alkyl groups are somewhat polar and can be expected to interact with water molecules by hydrogen bonding. Contact angle, surface tension lowering, and solubility appear to be related to the induced polarity of the alkyl groups.

Jan 1, 1968

By D. W. Fuerstenau

The success of industrial flotation separations has been the design of specific chemical schemes for regulating the bulk and the surface chemistry of the system. Highlights of fundamental research on the nature of flotation reagents and their mode of action in flotation, which has been carried on for about the past 65 years, is briefly reviewed.

Jan 1, 1995

By M. K. McCarter

INTRODUCTION Mining activity and basic geometry of open pit mines represent major obstacles in geotechnical mapping. Mining creates a constantly changing topographic base which may require corresponding updates of field sheets before mapping can proceed. The rapid pace of mining operations may also threaten removal of important geologic and engineering features before adequate base maps and surveyed control can be established. Maintaining such control during the mapping process is yet another complication. In addition, basic geometry yields nearly vertical outcrops. Access required for direct observation and measurement, essential to conventional plane table or Brunton techniques, may be impossible on such surfaces. Also, nearly vertical surfaces appear fore- shortened in plan view. This reduction in area provides little room for recording geotechnical detail. The difficulties encountered in open pit mapping can be substantially reduced by utilizing a modified form of plane table photogrammetry. This technique employs photographs taken from the ground as the base upon which details are recorded. The information is later transferred to plan maps using the plane table principal of location by intersection (Davis and Foote, 1953). Any change in topography can be accommodated by simply taking additional photographs. Proper spatial representation in plan view can be determined later when updated maps and surveyed control are available. In addition, horizontal photographs from the ground portray vertical surfaces as they are normally viewed thus providing maximum area for recording details. Any detail which can be identified on the photograph can be located correctly even though the actual feature is physically inaccessible. The technique presented in this paper was developed by the author for special applications at Kennecott's Bingham operation in 1970. The procedure was rapidly adopted for general use and has proven to be a practical tool for detailed investigation of potentially unstable areas (Zavodni and McCarter, 1976) and routine geological mapping (Richardson, 1975). Major advantages, other than those mentioned above, include: The speed and accuracy are greater than for conventional plane table or Brunton methods. The photo- graph represents a view from a station at some distance from the area being mapped. This vantage point allows evaluation of possible continuity of structures from one level to another which may not be evident at close range. The photographic base provides a permanent record of the topography at the time

Jan 1, 1977

By L. Yuan, J. Soles, D. Bahrami, W. Tang, R. Thomas

Mine equipment fires remain as one of the most concerning safety issues in the mining industry, and most equipment fires were caused by hot surface ignitions. Detailed experimental investigations were conducted at the NIOSH Pittsburgh Mining Research Division on hot surface ignition of liquid fuels under ventilation in a mining environment. Three types of metal surface materials (stainless steel, cast iron, carbon steel), three types of liquids (diesel fuel, hydraulic fluid, engine oil), four air ventilation speeds (0, 0.5, 1.5, 3 m/s) were used to study the hot surface ignition probability under these conditions. Visual observation and thermocouples attached on the metal surface were used to indicate the hot surface ignition from the measured temperatures. Results show that the type of metal has a noticeable effect on the hot surface ignition, while ventilation speed has a mixed influence on ignition. Different types of liquid fuels also show different ranges of ignition temperature. Results from this work can be used to help understand equipment mine fires and develop mitigation strategies.

Mar 2, 2022

By R. A. Burns

Kaolin clay has a broad range of applications with the paper market representing the largest end-use. Calcined kaolin finds application in paper, paint and plastics primarily for its high brightness and light scattering ability. It is well known as an extender for TiO2. Meta-kaolin possesses a unique set of physical and chemical characteristics finding use in both traditional kaolin/calcined kaolin markets as well as other unique applications. This paper discusses the intricacies of manufacture and the key physical and chemical properties of meta-kaolin. Specific applications and the relationship of the physical/chemical properties to end-use performance are discussed.

Jan 1, 2002

By T. K. Kim

Iron, cobalt, and nickel in waste ferric chloride solutions were separated from each other by solvent extraction. The iron was extracted from the cobalt and nickel by the use of methyl isobutyl ketone, and then the cobalt was separated from the nickel by the use of a high-molecular-weight quaternary amine dissolved in a solvent of high aromatic content.

Jan 1, 1980

By William G. Fischer

Equations developed by an early researcher in subsidence, F. Martos of Budapest, Hungary, have been slightly modified to produce effective equations for predicting the time-dependent nature of Green River trona mine subsidence. Following the initial study, a survey was run to check the results twenty years after mining of the area had been completed. The final results were within a few centimeters of the value that had been projected. Mining conditions in the Green River area are ideal for this sort of study with trough type subsidence being the surface manifestation of high extraction underground room and pillar caving operations.

Jan 1, 1986

By Joseph R. Hatch

During the past ten years detailed elemental analyses of approximately 8,000 well-documented samples of coils in the United States (including Alaska) have been produced by the U.S. Geological Survey and the various State geological surveys. Examples of data listings include Swanson and others (1976) Gluskoter and others (1977) Hatch, Affolter, and Davis (1979), and Wedge and Hatch (1980). These analyses serve as a basis for evaluating elemental abundances in coals from the various coal province, regions, and fields. When combined with additional geological and geochemical data, some of these analyses give insight into when certain elements were introduced into coals, and which physical and geochemical parameters are most important in determining coal elemental composition.

Jan 1, 1982

By Bernard E. Weichman

The oil shales in the Piceance Creek Basin of northwest Colorado occur in the Parachute Creek member of the Green River formation. The oil shales were deposited in a unique environment of deposition which caused the mineral nahcolite (NaHC03) to be precipitated within the oil shales. Post-depositional tectonics resulted in extensive fracturing of the Middle Zone of the Parachute Creek member, and to a lesser degree portions of the Lower Zone, which allowed percolating ground waters to dissolve the nahcolite in the fractured portion of the oil shale beds which is characterized by broken porous oil shale, certain beds of which have collapsed into rubble and debris. The extent and porosity of the Leach Zone aquifer is dependent upon the percentage of kerogen and nahcolite originally deposited in the oil shale. Any oil shale development program in the Piceance Creek Basin of northwest Colorado will need to be preceeded by an extensive study of the Leach Zone in order to determine the effects on a mining program.

Jan 1, 1973

By Mario Eduardo Rossi

The Universal Kriging (UK) and the Ordinary Kriging (OK) systems of equations are variations of the well-known system of Normal Equations. They differ only by the number of constraints present in the system. The dual version of these sytems enables one to interpret kriging as the fitting, of an interpolation surface, whose components are a series of variogram functions plus a polynomial trend model. This trend model should account for any systematic decrease or increase of the variable over the study area. It is shown that modeling the trend is useful only when the locations being estimated are beyond the range of influence of neighboring data (extrapolation cases). A case study based on a public-domain coal data set is presented. The variable described (seam thickness) shows an actual trend of increasing data values towards the NW corner of the region considered. UK and OK are used to estimate coal thickness at locations within sample data range (interpolation cases). The UK algorithm that includes a model for the trend does not improve the estimation when compared to the simpler OK algorithm with no trend model. Thus, in interpolation situations, the simpler OK algorithm is recommended.

Jan 1, 1989

By Hemendra N. Kalia

The target to double the coal production by 1995 presents a formidable challenge to the coal mining industry. The mines of future, probably will be located in relatively difficult geological environment because of the exhaustion of the well defined bedded and easily minable deposits. To compound the problems of mining industry will be the reliance of power plants need for coal. The coal must reach the power plants on schedule to avoid expensive blackouts and brown¬outs. It will be imperative that the mines operate without interruptions and at designed capacities. The parameters which have been traditionally responsible for the interrup¬tions of production are: breakdown of production machinery, labor management relations and geological anomalies. Of these three problems, solutions for the first two can be arrived at by developing procedures to correct the situation. A planned maintenance and preventive maintenance program will go a long way in minimizing the equipment breakdowns. Labor relations will eventually improve as the miners begin to enjoy long-term employment. However, with the geological problems, the situation will probably continue to deteriorate and would require careful planning to minimize the impact of geological problems on production and safety. Some of the geological aspects which interfere with production are: faults, washouts, slips and slickensides, water bearing overlying strata, impuri¬ties in the coal seam, and presence of expansive clays in the coal floor. The design of large capacity mines will have to incorporate the geological distur¬bances and mine through them it may become very uneconomical to abandon producing sections because of the presence of the geological anomalies. This paper discus¬ses the geological aspects of coal mining which should receive consideration from the inception of the mining ventures. Pertinent geological aspects are discussed to develop the data base which will aid in evolving safe and efficient mine layouts.

Jan 1, 1976

By Kot F. v. Unrug

In spite of extensive research and accumulated experience from mining operations, appropriate coal strength values for pillar design remain debatable. Coal strengths determined in the laboratory on standardized samples vary widely among various coal seams with poor repeatability. Penetrometric in situ strength testing obtains multiple measurements at multiple horizons within the coal seam to provide a strength profile. Alliance Coal has used that method in many of its mines for pillar design. Pillars in these mines perform well. This paper presents a series of case studies and discussion of issues related to coal pillar design. The analysis demonstrates that the proposed default in situ strength of 900 psi is appropriate when no other data exist. However, in the case of appropriate strength measurements combined with analysis of pillar structural composition, differing values can be used successfully. In areas where the penetrometric derived in situ strength is greater than the standard 900 psi in situ strength, reserve recovery has been optimized as required by law without compromising safety.

Jan 1, 2009

By David Sainsbury, Bevan Thompson, Yuejun Cai

The practice of placing loose rockfill as passive support in open stoping voids, of narrow vein mineral deposits, lends itself to the sterilisation of substantial mining reserves in the requirement for regional crown/sill pillars. Significant benefits are to be gained by the Australian mining industry via the development of improved guidelines for the extraction of such sterilised mine pillars. The application of selectively injecting specifically developed ettringite (calcium sulphoaluminate hydrate) type cement grout into loose rockfill, enables an artificial pillar to stabilise the surrounding rockmass and prevent the caving of loose rockfill from the previously backfilled void during extraction of remnant crowdsill pillars. This paper presents the results of laboratory testing used to reduce the technical risks associated with the design of cemented rockfill pillars. A laboratory testing program was devised to investigate the critical parameters influencing the performance of a stabilised rockfill matrix, along with the critical parameters influencing the interpretation of laboratory test samples. The factors investigated include; sample size and shape, particle size distribution, curing time, water quality, cement : water ratio and the confinement effect.

Jan 1, 2001

By John A. Ames

Limestone for portland cement must be beneficiated to produce uniform raw material for the kiln. Careful quarrying and selective recovery are factors in this process, but the chief aspects of beneficiation are "in plant" processes, such as crushing and screening, washing, grinding, flotation, and heavy-media separation. Numerous technical and economic problems exist. Detailed studies of the limestone deposit and the stone itself are required for intelligent beneficiation. As used in this paper, beneficiation is defined as the improving of limestone composition so as to produce an economically usable raw material A limestone deposit is defined as a mass of limestone which can be recovered, by quarrying or mining, for sale or for use in a commercially profitable operation. The stone may require elaborate processing, or it may qualify with little or none. Obviously, the "commercially profitable" qualification may change as the economy changes. Potentially commercial deposits may be of much better quality than actually developed deposits, and yet may be denied development for various economic reasons.

Jan 1, 1966

By M. Robb, S. J. Bate, M. Boisvert

The never-ending quest for gold-bearing ore deposits is a primary industry in Canada, employing people of widely differing expertise. The exploration models for gold deposits are generally geologically complex and the targets have relatively small cross-sectional areas. These problems are compounded in Canada by the minimal outcrop exposure in most mineral provinces and the high percentage of water-covered areas. Naturally the chances of successfully delineating an economic gold deposit are very much greater if all parties involved can act as a team of explorationists constantly confemng amongst themselves particularly as the applicable disciplines generally overlap and complement each other. Three case histories (see Figure 1) are presented to illustrate this philosophy with emphasis placed on the role of the geophysicist in translating the exploration model as defined by the geologist into physically measurable parameters and identifying target areas with similar characteristics. The Conwest-Miminiska property in Ontario is a grassroots exploration play. Additional ore reserves needed to be delineated on the Salmita property in the Northwest Territories. At Laura Lake, near Chapais, Quebec geophysical methods were employed to trace thin high-grade mineral intersections under deep overburden and severe cultural interference.

Jan 1, 1989

By B. K. McMahon

Block caving is an efficient mass-production method for the underground mining of large orebodies. However, the block-caving method requires a substantial investment in developmental works, based on the assumption that the rock will cave. Efficient block caving is prevented if the rock forms stable arches or breaks into fragments that are too large to pass easily through the finger raises. Under these conditions, the cost of the additional labor, drilling, and blasting required to assist caving may be sufficient to make marginal orebodies uneconomic or alternative mining methods more attractive. Reliable methods for the prediction of the block-caving behavior of an orebody are clearly needed at the initial planning stage. These methods should be capable of considering both geological and engineering aspects of a block cave, as experience has shown that the manner in which a block cave is initiated and developed may be almost as important as the geological conditions such as the nature of the rock material, degree of alteration, characteristics of the joints and faults, etc. The initial state of stress in the rock mass should also be considered.

Jan 1, 1969

By Uday Kumar

This paper presents details of an availability study for a fleet of diesel engine operated load-haul-dump (LHD) machines used in a Swedish mine. For the purpose of this study, the LHD machines have been considered as a system comprised of many subsystems like engine, brake, transmission, etc., in series. As availability is dependent on both the reliability and maintainability characteristics of the system, together with reliability, the concepts of maintainability are also discussed. The need for exploring the data for the presence of any structure, which is very common in repairable system data sets, is emphasized with suitable examples. Simple graphical techniques are used for verifying the independent and identically distributed (IID) assumption for the data set. The error introduced due to the use of the exponential distribution in place of more appropriate distributions in estimation of availability and reliability characteristics is analysed.

Jan 1, 1989

By P. K. Hopke, A. Hubbard, K. H. Leong, J. J. Stukel, K. Nourmohammadi

INTRODUCTION In order to understand the transport and deposition of radon daughters in mine atmospheres, it is necessary to know the variation in the attachment of the daughter atoms to particles as a function of particle size, composition, number density, relative humidity, temperature, and radon concentration, the free gaseous diffusion coefficients of the daughters, and the variation in the mass transfer of the activity, both free and attached to particles, to mine surfaces as a function of particle size distribution, surface roughness of the mine walls, and the flow conditions. If all of these parameters are known in a model system, it should be possible to understand the transport and fate of the airborne radioactivity in real mines under certain well-defined flow conditions. There have been a number of recent investigations of the attachment of radon decay products to particles 1-4, but there are still a number of unanswered questions regarding the process. However, it is clear that for most real mine atmospheres, the vast majority of the activity is attached to particles. The size distributions for the activity-bearing airborne particles have been studied 5,6, and it has been found that most of the activity resides on particles with diameters in the range of 0.05 µm to 0.3 µm with an average mass median diameter between 0.1 and 0.2 µm. The behavior of the unattached radon daughter species has also been recently studied[ 7], and many of the previous problems regarding the value of the diffusion coefficient for Po-218 have been resolved. A major problem in the understanding of the airborne transport of radioactivity in mines is the lack of detailed knowledge of mass tranfer to and fluid flow over rough walls under fully developed turbulent flow conditions. This paper will report the progress on a project that is designed to obtained that information. MATHEMATICAL MODEL DEVELOPMENT Deposition of particles on smooth surfaces in turbulent flow has been extensively studied. A comprehensive review of these results has been prepared by Sehmel 8. There has not been such a comprehensive study of particle deposition on rough walls under such flow conditions. In recent years, only a single model has been proposed to explain such deposition 9,10 and in both of these papers the flow structure in the rough walled pipe was not taken fully into account. As part of the work being conducted on this project, a more complete model was outlined in a previous report [11]. The basic theory will be reviewed to provide a context for the flow measurements to be reported. The flux of particle deposited on the walls of a pipe in a turbulent flow is derived from the one dimensional form of Fick's law as given by [N = Dpdpp/dr (1) where N is the flux of particles deposited per unit area per unit time, D is the total eddy diffusivity of the particles, p is the airborne concentration of particles, and pr is the distance measured from the center of the pipe. The rate of deposition is best expressed by a deposition velocity Vp = NIP pb (2) where P b is the mean particle concentration in the sulk flow. The shear radius, V/ut and the shear velocity, u , are used to calculate a nondimensional distance, and velocity, respectively, where v is the kinematic viscosity of the fluid. The nondimensional form of equation 1 is given by Vd = DP dpp(3) V dr+ where Pp = Pp/ Ppb(4) By integrating equation 3 from the rough wall stopping distance, S , to the center of the pipe, the deposition velocity can be obtained. In order to make this calculation, it is necessary to have accurate descriptions for the particle eddy diffusivity, stopping distance, and shear velocity in order to insure that the influence of the flow structure has been properly accounted for. The shear velocity can be determined experimentally from the shear stress evaluated at the wall, Tw, and the fluid density, ut =VT w/p = ub V f/2 (5) where ub is the mean bulk axial velocity. The wall shear stress for a given pressure drop, dP/dL, and hydraulic diameter, Dh, is]

Jan 1, 1981

By H. Polat, Q. Hu, M. Polat, S. Chander

The electrostatic charge on spray droplets of ionic surfactant solutions and coal particles was measured and the results were correlated with the dust collection efficiency. When various surfactant were added, the magnitude of the droplet charge increased significantly and it was observed to be a function of surfactant type and concentration. The concentration of maximum droplet charge coincided with surfactant concentration where maximum collection efficiency was observed for these surfactants. Particles of coal also carried substantial amount of charge magnitude of which seemed to be a function of coal rank. Based on the results presented in this paper, it was concluded that ionic surfactant primarily act as a strong electrostatic charge inducer for droplets. Due to interactions between these highly charged droplets and naturally charged particles, the efficiency of droplet-particle collisions play a primary role when compared to the wetting and engulfment phenomenon which could only follow a successful collision. INTRODUCTION Water spray are widely used to suppress airborne dust in mine atmospheres (Walton and Woolcock, 1960; Kobrick, 1970; Hamilton, 1974; Jayaraman et al., 1986). Several investigators have considered the use of surfactants to enhance the effectiveness of water sprays especially for difficult to wet particles such as those of coal (Glanville and Wightman, 1979). The capture of dust particles by water droplets involves droplet-particle collisions, adhesion of particles to droplets, and engulfment of particles into droplets. Surfactants affect these sub processes through their influence on droplet charge, surface tension, and wetting. The last two mechanism have been thoroughly studied in recent years (Walker et al., 1952; Cohen and Rosen, 1981; Glenville and Haley, 1982; Chander et al., 1988; 1991). However, little attention has been paid to the role of electrical charge on particles and droplets on the collision and adhesion of spray droplets and dust particles. Airborne particles of dust have long been known to carry a significant amount of electrostatic charge (Hopper and Laby, 1941; Kunkel, 1948; Kunkel, 1950; Dodd, 1952; Liu et al., 1987; Kutsuwada and Nakamura, 1989). It is reasonable to assume that presence of charge on particles will effect their agglomeration and particle-droplet interactions. Polat et al., (1991) showed that virtually all freshly generated dust particles were agglomerated in air. They suggested that electrostatic charge and humidity were important factors responsible for agglomeration. Previous theoretical studies on the interactions between charged particles and collectors by Nielsen and Hill (1976) show that, the collision efficiency is a strong function of the particle charge. In addition to charge on particles, spray droplets might also carry substantial amount of charge (Chapman, 1937;1938; Blanchard, 1958; Iribarne and Mason, 1967; Jonas and Mason, 1968; Byrne, 1977; Bailey, 1988). In theoretical studies of interactions between a spherical collector and airborne particle, it was found that the collision efficiency was significantly altered depending on whether the collector and the particles were charged. If neither the collector nor the particles carried a charge, the collision occurred by inertial and gravitational forces. The collisions took place on the front part of the collector (the front capture). If either of the collector or the particles were charged, the collision was enhanced due to the induced image forces. If both the collector and the particles were charged, the collision efficiency was significantly affected by the sign of the charge as well as its magnitude. For oppositely charged collector-particle pairs a collision could take place on the rear of the collector even if the particle flied past the collector upon approach (the rear capture) (Nielsen and Hill, 1976; Wang et al., 1986; Chang et al., 1987). On the other hand, the columbic force became negligible as the particle size increased and the inertial force became dominant. The electrostatic attraction was predominant for particles of less than about 2.5 µm in diameter. For particles larger than about 8 µm the inertia of particles was sufficient to overcome the columbic force and inertial impaction became the dominant collision mechanism (Grover and Beard, 1975; Chang, 1987). Previous studies of dust suppression using charged spray droplets generated by applying high voltage to the spray nozzle showed significant improvements in collection efficiencies (USBM open file report, 1983; McCoy et al., 1985). However, it was considered that highly charged spray droplets obtained by direct charging might have

Jan 1, 1993