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By Sönke Schmachtel

Several possible physico-chemical properties of composite electrodes for oxygen evolution are presented to describe experimental data for which a mathematical model had been developed. On this basis, local electrical and electrochemical properties of a composite electrode were investigated with conductive atomic force microscopy (CAFM) and scanning electrochemical microscopy (SECM). It could be shown by CAFM measurement that the boundary between matrix and catalyst particles seemed to have special advantageous electrical properties. The SECM measurements showed the presence of mass transport phenomena with increased surface concentrations, whilst the thickness of the Nernst diffusion layer was very small. An intermediate was detected and assigned to be hydrogen peroxide. From all species involved in the oxygen evolution reaction (H2O2, H+ and O2), it was concluded that local active spots exist on the electrode on which hydrogen peroxide reacts to oxygen and protons. A two?step two-material process was suggested to explain the whole oxygen evolution mechanism.

Jan 1, 2008

By A. D. Pienaar

The aqueous chemistry of niobium and tantalum compounds with hydrofluoric acid is a mature field of investigation. In contrast, very little attention has been paid to reactions of these compounds in non-aqueous environments. Similarly, reactions of elemental fluorine with niobium and tantalum compounds have received little more than cursory attention in literature. This work discusses the isothermal reaction kinetics derived from thermogravimetry, using a less redundant approach than is currently the standard. We also discuss the most likely kinetic models for this reaction.

Jan 1, 2012

By W. C. Joughin

A risk evaluation model has been developed that enables the quantification of expected injuries and economic losses resulting from rockfalls associated with a support system in a given geotechnical environment, which is described in Part I (Joughin et al., 2011b). Part II presents the validation of the risk evaluation model. Underground mapping of joints and rockfalls was carried out to provide data for field calibration of the model. This survey was limited to small rockfalls, due to the relatively short period of mapping. Therefore the model was also correlated with rockfall and rockfall injury data collected by mine personnel. The analyses showed that the model provides a reasonable estimate of the expected frequency and size of rockfalls and the frequency of rockfall injuries, but further work is required to enhance the model. Three case studies are presented, which show the benefits of improved support systems from both economic and safety perspectives. This work has demonstrated that the risk evaluation model and the software developed are immediately useful, but further work is required to develop and improve the tools.

Jan 1, 2012

By K. Bryan, O&apos

A 10-year program to integrate crushing and screening models into daily flowsheet design practice has proven successful. A Circuit Analysis Program (CAP) is used worldwide to design and evaluate new and existing crushing flowsheets. To gain user acceptance of CAP and maximize effectiveness, model development, simulation flexibility, ease of use, and developing international access are key issues. These issues have been resolved effectively resulting in flowsheet simulations to assist in justifying increased capital investment. CAP is presently utilized in Canada, United States, and South Africa with intentions to expand to Europe and Asia.

Jan 1, 1987

By S. M. Rupprecht

"Artisanal mining is basic mining characterized by manually intensive work methods utilizing primitive or simple equipment and conducted by individuals or small groups exploiting deposits. Artisanal mining in Rwanda and Burundi is further complicated in that the techniques applied are often inadequate, resulting in low productivity and poor recoveries, and workers are paid low wages with owners reluctant to reinvest in the mining operations. A consequence of this vicious circle is often poor working conditions, with miners operating under unsafe and/or unhealthy working conditions. An additional problem is that mining is conducted in a manner that is detrimental to the environment.Artisanal mining is commonly more dangerous than large-scale modern mining operations. Artisanal operations are generally subsistence activities with the miners focusing more on immediate concerns than the long-term consequences of their activities. When miners have no other source of income, they will usually find ways to evade controls and carry on working. Machinery tends to be expensive and often far beyond the reach of most artisanal miners, and therefore there is a general tendency for workers to focus on labour intensive and riskier mining methods.This paper proposes the introduction of small-scale mechanization with labour-intensive manual mining utilizing a bench mining approach in artisanal mines operating in Central Africa. From the 1950s to the 1980s bench mining was successfully conducted in Burundi utilizing manual labour. In order to achieve a balance between job creation and project economics, the combination of manual and mechanized mining is proposed. Manual mining offers the benefit of local job creation while ensuring good mining techniques, such as minimizing mining loses and dilution. Through the introduction of mechanized loading and hauling activities, areas of high stripping ratios can be viably mined, thus increasing the amount of resources that can be exploited. The use of a loader and tractor-trailer arrangement is proposed, thereby improving throughput, productivity, and worker safety and, reducing the impact on the environment."

Jan 1, 2017

Guide Io Ihe Preparailon Of Papers For Publication In The Journal Of The South African Institute Of Mining And Metallurgy The following notes have been compiled to assist authors in the preparation of papers for presentation to the Institute and for publication in the Journal. All papers must meet the standards set by the Council of the Institute, and for this purpose all papers are referred to at least two referees appointed by the Council.

Jan 1, 1975

By L. A. Cornish, R. Süss, M. Sephton, N. B. Maledi, J. H. Potgieter, L. Chown

The gas turbine industry is faced with a challenge to improve the performance of engines, while simultaneously adhering to stringent environmental legislation. One way of addressing the problem is by further increasing the recipient working temperatures. Unfortunately, the use of nickel based superalloys (NBSAs) in the gas turbine industry has reached its limitations. Although coatings can be used for small increases, and air cooling is also incorporated by design, attention is towards developing stronger metallurgical materials having higher melting points, with acceptable creep and corrosion resistance. A series of ternary and quaternary Platinum-based superalloys were developed. Platinum was selected because of its higher melting points compared to nickel, similar fcc structure and better corrosion properties. Mechanical characterisation studies of Platinum-based superalloys alloys, which included oxidation, creep and hardness, demonstrated reasonable results, outperforming an oxide dispersed strengthening (ODS) Fe-based superalloy (PM2000) and a nickel based superalloy (MAR-M200). During any materials development where high temperatures are concerned, high strength is the primary property of interest. However, during the development of gas turbines, component life and reliability, which are influenced by temperature, need to be taken into consideration, and therefore creep as well as corrosion (both temperature dependant properties), are important. These properties become significant with increasing temperatures. With increasing demand for higher temperatures, it is becoming increasingly important to include hot corrosion properties of the alloy during the material selection process. A short description on hot corrosion and its degradation mechanisms are given in this paper. Coatings are currently dominating as the best practical solution to address temperature increases. This paper looks at benefits and shortcomings of coatings over Pt-based superalloys as candidates for applications under extreme conditions. Key words: Hot corrosion, Pt-based superalloys, Ni-based superalloys, Coatings

Jan 1, 2006

By M. Khodadazadeh, K. G. van den Boogaart, T. Leißner, L. Tusa, J. Gutzmer, R. Gloaguen, M. Kern

Ore sorting is a technology that is increasingly used to process primary raw materials. Timeconsuming and expensive empirical state-of-the-art test work is carried out to assess whether the use of ore sorting for the enrichment of a particular ore makes technical and economic sense. With the innovative simulation-based approach presented here, it is possible to direct the selection of a suitable sensor based on quantitative mineralogical and textural data, thus avoiding much of the empirical studies. Required data can be collected quickly and cost-effectively using available methods of automated mineralogy. The obtained parameters such as mineral grain size distribution, modal mineralogy, mineral area and mineral density distribution have been utilised in this study to simulate the prospects of success of ore sorting, applying different types of sensors. Empirical tests with commercially available sensor systems have been conducted to experimentally validate the predictions of the simulations. The estimation of the target mineral grade can be further optimised by the use of machine learning algorithms for the integration of automated mineralogy data and sensor data. The approach can easily be adapted to other types of raw materials and thus has great potential to become a key technology for the optimisation of processing experiments. Keywords: Automated mineralogy, hyperspectral imaging, machine learning, ore sorting

Jan 1, 2020

By L. Woollacott, R. P. King

This paper presents data collected from full-scale plants in order to verify the predictions of a new simulator of CIP or CL operations. Good agreement was found between the experimental data and the simulator predictions. The simulator is able to predict the effects of many of the complex operating phenomena in GIP and CL plants that previous simulation techniques could not describe. This is illustrated by predictions of how factors, such as the manner of carbon transfer, concurrent leaching, and gold loading on eluted carbon, can affect the performance of an adsorption plant.

Jan 1, 1990

By R. E. Phillips, L. A. Cramer, R. T. Jones

Atomaer (Pty) Ltd is a technology-driven company with interests in Western Australian nickel. Atomaer (RSA) Pty Ltd is a process technology company operating in Southern Africa. It is a subsidiary of Atomaer Holdings Pty Limited (Atomaer), which has operating companies in Australia, Africa, South America, and Europe. In addition, Atomaer has substantial shareholdings in Braemore Resources Plc, a nickel company with interests in sulphide nickel projects in Western Australia and Southern Africa listed on the Alternative Investment Market of London Stock Exchange (AIM); Mintails Limited, a gold company with interests in gold operations in South Africa listed on the Australia Stock Exchange; and Brinkley Mining Plc, a uranium company with interests in Southern Africa listed on the AIM. Independence Platinum Limited (IPt) has been formed by Atomaer to undertake the commercial development and exploitation of Mintek's ConRoast technology with the strategic objective of providing independent smelting and refining facilities with lower capital and operating costs for the treatment and processing of platinum concentrates, including those with high chrome and/or nickel and/or low platinum group metal values, for the development of platinum projects by junior resource companies in South Africa. The platinum mines of South Africa have traditionally exploited the Merensky Reef of the Bushveld Complex for platinum production. However, the mining of this reef is reaching depths that require significant vertical shaft systems and costly refrigeration for access to the ore bodies at deeper levels. In the past decade, all of the platinum producers have begun to mine the UG2 reef because of its cheaper mining costs. UG2 ore usually has lower platinum group metal contents and higher chrome values. The new junior resource companies have gained access primarily to UG2 reefs. Consequently, platinum mining is becoming more UG2-based and the resulting concentrates contain high levels of chromitite. UG2 concentrates are difficult to smelt in the current six-in-line submerged arc furnaces, and this leads to increased capital and operating costs for those smelting operations. The platinum mines of South Africa produce the majority of the world's platinum metal used in automotive catalysts and jewellery. As the platinum market is forecast to grow at a healthy rate into the future, the SA producers Anglo Platinum, Impala, Lonmin, and Northam are planning to expand mining operations in the next decade. Furthermore, a number of smaller new producers who are accessing other mineral resources are entering the buoyant market and will produce platinum concentrates for purchase or toll treatment. Hence, a shortage in both smelting and refining capacities is anticipated. Further smelting and refining facilities independent of the major platinum producers will be required in South Africa by 2010. Mintek's ConRoast technology is best suited to fill the need to treat a high proportion of UG2 concentrates in a cost-effective and technically efficient manner. Atomaer base metals technology has been developed for rapid leaching of nickel and other base metals from alloy. Significant reductions in capital and operating costs are expected from the combination of the two advances in process technology compared with that installed at the existing smelters and refineries that were established over 20 years ago. Independence Platinum will be listed on AIM and the Johannesburg Stock Exchange (JSE) in 2007, and developed as an independent, vertically-integrated platinum company using its independent smelting and base metals refining facilities as a strategic platform to promote the development and mining of platinum projects by junior resource companies in South Africa through technical co-operation, strategic alliances, joint ventures, off-take, toll-refining, and marketing agreements.

Jan 1, 2006

By G. R. Marchant, B. K. Loveday

"A mathematical model has been developed for flotation circuit simulation. This model was designed to investigate the effect of varying the circulating loads and to determine whether an improvement in overall efficiency could be gained by a size separation prior to flotation.Model parameters were obtained by regression to plant data. Highly correlated parameters in the model were combined to reduce the number of parameters so that the need for excessive data gathering was eliminated. Mass balance smoothing was used to obtain a consistent data set for regression.The results of the simulation indicate that for the same grade of concentrate, an increase in copper recovery of 0.6 per cent may be Possible by increasing the circulating loads. The results of the simulation also indicated that recleaning of the plus 200-mesh material may be beneficiaL."

Jan 1, 2014

By P. S. Pashkovsky

Theoretical and experimental investigations of the process of self-heating the coal accumulation with use of geological and mining conditions of development of the seams, as well of mass recoil parameters, factors of oxygen diffusion in coals, critical temperatures of self-ignition, incubation times received under laboratory conditions allowed working out the method of the local prognosis of the hazard of coal self-ignition in the course of carrying out the mining operations. New relationships of calculation of critical dimensions of the coal accumulation and of the incubation time are proposed.

Jan 1, 2003

By A. Smith

The practice of leaving barrier pillars between adjacent longwall panels at The Durban Navigation Collieries (Pty) Ltd (Dumacol) has resulted in a considerable loss of coal reserves. Dumacol has now modified the layout of its longwall panels to allow the concurrent mining of barri9f pillars and the extraction of the longwalls. The Implementation of the new panel layout has increased the percentage extraction of reserves and will result in an extension in the life of the mine. The method of extracting barrier pillars between adjacent longwall panels is described in this paper.

Jan 1, 1985

By F. H. Touwen, N. C. Joughin

"Simulation is a technique for studying the operation of systems by synthetic experimentation. With digital computers it is possible to simulate even the complex production processes in gold mining. This has great potential in that it enables the investigation, analysis and comparison of mining systems to be done accurately, rapidly and at low cost. Two programs have been developed to simulate the principal underground production processes in gold mining.These are the simulation of any stope contract and the simulation of underground transport operations. The programs synthesize these mining activities from a large number of small unit operations. The stope contract program simulates rockbreaking by drilling and blasting and the cleaning of the panels by face and gully scraping. The transport program simulates the functions and movements of all vehicles running on rails on one underground level. The simulation programs provide an effective means for experimenting with mining activities."

Jan 1, 2014

By A. G. Royle

The reasons for constructing a model of an orebody for which both the parent population and the sampling distribution are known are discussed and details of the model are given. A brief summary of Matheron's theory of regionalized variables is included, with particular reference to his kriging estimators and their variances. Using the model, a comparison is then made between these kriging estimators and other commonly-used estimators. These are compared to find the one with the minimum variance, and an analysis is included to investigate whether any of the estimators is biased. Also included is a comparison between theoretical and experimental variances for some of the estimators.

Jan 1, 2014

By S. Banisi, A. Ghasemi, E. Nematollahi

Discrete element method (DEM) has been used as a popular simulation method to verify designs by visualising how material will flow through complex equipment geometries. Although DEM simulation is a powerful design tool, finding a DEM model which includes real material properties (e.g., shape, cohesion and friction coefficients) is not computationally feasible. In order to obtain more realistic results, particle energy loss due to rolling friction has been highlighted by many researchers. To implement a reverse torque to account for rolling friction, various models have been proposed. On account of the complexity of the problem, there is no unique model for all applications (i.e. dynamic and pseudo-static regimes). In this paper, an in-house developed DEM software (KMPCDEM ©) was used to assess the robustness of three commonly used models by comparing the repose angle of iron ore pellets obtained through the draw down test in a laboratory setup and then the elastic–plastic spring dashpot model was modified based on considering the individual parameters instead of relative parameters of two contact entities. Results showed that the modified model could produce higher repose angle. The modified model was used to calibrate DEM simulation of repose angle of iron ore pellets in a laboratory setup of the draw down test. Comparison of the calibrated DEM simulation and laboratory results showed 2° differences between the predicted and measured angle of repose. This difference was attributed to considering the particle shape effects by assuming a spherical shape for particles. Keywords: DEM, rolling friction,particle shape, repose angle

Jan 1, 2020

By S. Krishnannair

Singular Spectrum Analysis (SSA) is an effective data-adaptive multimodal tool for monitoring chemical processes. However, monitoring multiscale signals using principal component analysis obtained from the multilevel decomposition of process signals using basic SSA assume the upper control limits of monitoring charts (" ) to have a Gaussian distribution. This assumption deteriorates the performance of basic SSA when applied to the monitoring of nonlinear processes. To address the issue in this paper, the kernel density estimation (KDE) was used to estimate upper control limits of monitoring charts for basic SSA based nonlinear process monitoring techniques. The monitoring performance of the resulting basic SSA-KDE approach was then compared with a basic SSA approach of which upper control limits of the monitoring charts were determined based on a Gaussian distribution. Application on nonlinear dynamic simulated process and base metal flotation plant chemical processes showed that the SSA-KDE approach provided better overall performance than the SSA approach with Gaussian assumption-based upper control limits for its monitoring charts. Keywords: Fault detection, singular value decomposition, singular spectrum analysis, kernel density estimation

Jan 1, 2020

By M. Rudolph, J. Sygusch

Froth flotation is well-established and efficient in the selective separation of valuable particles from unwanted material with sizes ranging from 10 μm to 200 μm. However, when it comes to the separation of ultrafine particles (< 10 μm) there are still some challenges, or rather opportunities. This research aims at developing a method for the separation of ultrafine particles based on multiple particle properties. Amongst such properties are wettability, morphology (shape or roughness) and size with applications not only in mineral processing but in general chemical engineering. In this study, three differently shaped fractions are used as valuables for testing: spherical particles, elongated particles and irregularly shaped particle fragments; together with ultrafine magnetite as the gangue material, in order to investigate the effect of particle morphology on ultrafine particle flotation, as well as wettability, which is varied by esterification using alcohols. Flotation tests are carried out using a novel flotation device that was designed especially for the flotation of ultrafine particles, combining advantages from machine-type froth flotation and column flotation. The results showed that, in contrast to previous studies, recoveries for ultrafine spheres were higher than for ultrafine fragments for all wettability conditions, and hydrophobisation generally increased particle recoveries for said morphologies. Tests using fibres showed different behaviour as hydrophobisation had negative effects on their recovery, despite increased selectivities and kinetics. These findings suggest that apart from influences of particle properties within the suspension zone, their effects on the froth characteristics should be studied in more depth. Keywords: Ultrafine particles, Flotation, Particle shape, Wettability, Esterification of glass, Hydrophobisation

Jan 1, 2020

By E. Moosavi, K. Tolouei

In mine production scheduling problems are well-known, where most are categorised into deterministic and non-deterministic NP-hard problems because of their complexity. Many researchers have attempted to solve the problem by applying various optimisation techniques. While using traditional methods they observed extreme difficulty in solving highly complex problems. In the 1990s, many researchers addressed long-term production scheduling (LTPS) by using simulated annealing, the genetic algorithm, the tabu search algorithm, and the ant colony algorithm. These algorithms are known as the meta-heuristic algorithms, and have proved to be the most efficient algorithms for solving LTPS thus far. The firefly algorithm is one of the best methods for visualising problems related to LTPS, and provides the best possible optimisation. It is one of the simplest methods, and easy to apply to any NP-hard problem. The experimental, and comparison with other recently published algorithms shows that the proposed algorithm is feasible, and is an effective approach for long-term production scheduling problems. The results indicated that a better solution is obtained by the proposed method, compared to other methods in terms of cumulative net present value, and average ore grade. Additionally, the CPU time via the proposed model is roughly 2.52% higher than the other method.

Sep 1, 2021

By C. Musingwini, C. Beaumont

"Kansanshi mine, located in northwestern Zambia, uses conventional openpit mining to produce primarily copper, with gold as a by-product. The ore is extracted from a deposit with highly complex mineralogical suites that are difficult to process, sometimes leading to poor recoveries. The mine was using an ore classification system called ‘Mat-Type’, which classified various ore types into 22 different quality categories, ranging from poor to good quality. Ore with poor recovery was classified as ’poor quality’ ore and directed to long-term stockpiles. Due to a lack of proper integration between the technical and functional areas forming the mine value chain, Mat-Type unintentionally misclassified ore. A geometallurgical analysis was therefore undertaken to review Mat-Type and a new geometallurgical ore classification system, called ‘OXMAT ’, was developed to replace Mat- Type.When implemented, OXMAT eliminated nine of the 22 ore categories and the remaining 13 ore categories could now be more accurately and consistently defined, leading to a significant change in the quantity of ore being mined. OXMAT demonstrated that within a defined test volume of the geological model, waste tonnes could be reduced by 19% while ore tonnes could be increased by 17%. This paper therefore demonstrates the value created through integrated geometallurgical modelling. IntroductionKansanshi mine is located in northwestern Zambia, approximately 10 km north of the provincial capital Solwezi and about 160 km west of Nchanga mine in the Central African Copperbelt (Broughton and Hitzman, 2002). The location of Kansanshi mine relative to other major copper deposits in the Copperbelt is indicated in Figure 1.Kansanshi mine uses conventional openpit mining methods to exploit copper- and gold-bearing veins hosted in a structurallycontrolled mineral deposit. Mining is carried out in two areas of the deposit, the Northwest and Main pits. A third area of the deposit, called Southeast Dome, is currently not being exploited (Figure 2)."

Mar 1, 2019