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By G. L. Oldright, John D. Sullivan

"The present article is the second of a series of papers dealing with the dissolution of copper minerals in various reagents. Work done on the problem has been carried out at the Southwest Experiment Station of the United States Bureau of Mines, in cooperation with the Department of Mining and Metallurgy, University of Arizona. The first paper4 dealt with the dissolution of azurite, malachite, chrysocolla, and tenorite. Preceding articles5 have also dealt with other factors involved in the leaching of copper ores.Cuprite (Cu20) is usually considered as a mineral which is not adaptable to sulphuric acid leaching. Hofman,6 in describing leaching by sulphuric acid, states: ""Cuprite is decomposed into CuO and Cu; and ore carrying cuprite has to be oxidized (weathering, roasting) before treatment."" Greenawalt7 says: ""When acted upon by dilute sulphuric acid, it is partly reduced to metallic copper and partly oxidized into copper sulphate. When heated with strong acid it is entirely oxidized to sulphate."" Work to be described in this article was undertaken to ascertain the conditions whereby all the copper in cuprite could be converted into the soluble sulphate."

Dec 1, 1929

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of three samples collected from the Kidney seam, in the Northern Field of the anthracite region. Removal of the sink 1.70 specific gravity material from the samples collected would result in greatly reduced ash contents at yields in excess of 90 percent. The Kidney seam, in the locations sampled, proved to be a low-ash anthracite containing an unusually high percentage of float 1.45 specific gravity material.

Jan 1, 1970

By Oleg Terichow

Electrophoretic mobility measurements were made by the Bureau of Mines on samples of a Florida phosphate slime to determine the optimum conditions of coagulation and settling in an aluminum sulfate solution. Addition of anthracite to promote mutual coagulation demonstrated the practicability of heterocoagulation by reduction of the repulsive effect of double layers. By proper selection of the electrolyte and its concentration, the reduction of the double layers to a net zero point of charge causes the predominance of Van der Waals' forces of attraction leading to the coagulation and rapid settling of both particle systems, as is predicted by the Derjaguin-Landau-Verwey-Overbeek theory of colloidal stability. Confirmation was found in the microfiltration tests where a modified Carman equation was applied to evaluate the specific filter bed resistance.

Jan 1, 1975

By E. G. Valdez

The Federal Bureau of Mines, in cooperation with Ford Motor Co., investigated the recovery of polyurethane foam and other assorted plastics from the nonmagnetic reject of automobile shredders. Preliminary studies were con-ducted on a 1957 hulk augmented with additional foam and assorted plastics. The proposed flowsheet developed by the Bureau from the preliminary studies consists of a combination of screening, water classification, and gravity separation. The process was then tested on reject from two shredded 1972 cars. All of the foam and between 52 and 70 pct of the assorted plastics were recovered. The composition of the reclaimed foam concentrates ranged from 46 to 66 pct foam; the concentrates were hydrolyzed in laboratory tests by Ford Motor Co. to produce a reusable liquid mixture of polyether glycol monomers and toluene diamine.

Jan 1, 1975

By Stephen Krickovic

A methane emission rate study was conducted in 1969 on a longwall section of a Lower Kittanning coalbed mine in central Pennsylvania. The longwall face was mined with a drum shearer between developed headings on the head end and headings on the tail end that were driven with a ripper-type continuous miner as needed. The study was conducted over 22 consecutive shifts (7-1/3 days). The average methane emission rate from the Lower Kittanning coalbed during mining at the face and developing the headings at the tail end of the face was 34 Am. Caving of the gassy overlying strata as the result of mining at the face increased the methane emission to rates ranging from 702 to 1,049 cfm.

Jan 1, 1971

Develop methods of enhancing and measuring the high-temperature softening and melting properties of iron oxide pellets reduced under simulated blast furnace smelting conditions. Approach Add dolomite and Limestone flux and a low-cost organic binder, such as starch, carboxyl methylcellose (CMC), or waste papermill sludge, to the iron oxide concentrate to produce hematite (ferric oxide) pellets with superior high-temperature metallurgical properties. Simultaneous increases in softening temperature, gas permeability, and enhanced metallization rates are sought to improve blast furnace productivity and energy efficiency. Background In the past, bentonite, an inorganic binder, was the only additive (binder) used in the production of pellets made from iron ore concentrate. Research has shown that the reducibility of conventional (acid) pellets can be increased by the addition of flux or an organic binder. The increase in pellet reducibility results in less wustite in the center of the pellet at high temperatures, such as those obtained in the cohesive zone of the blast furnace.

Jan 1, 1990

By M. K. Larson, J. K. Whyatt, R. B. Langston, J. C. Johnson, H. Kirsten, T. M. Brady

An experiment is described in which hollow inclusion cells (HICells) were used to measure stress in a jointed rock mass during drift development at the Stillwater Mine, Nye, MT, USA. Two HICells were installed in the footwall approximately two drift widths ahead of the face. One HICell was over cored and then immediately tested in a biaxial chamber. The other HICell was left in place and monitored as the drift was excavated in three advances, each one-half the width of the drift. Strains were recorded hourly by a datalogger. Results show that there was little stress change during the first and second drift advances, but that a large stress change occurred after the third advance. The measurements also showed that the in situ principal stress directions lined up with regional geologic structures. Stress changes during face advance were likely caused by deformation along localized joint sets and inelastic deformation near the face.

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

5. General Escapeway Requirements 5.1 Escape Routes Present escapeway regulations state "Every mine shall have two separate properly maintained escapeways to the surface which are so positioned that damage to one shall not lessen the effectiveness of the other, or a method of refuge shall be provided when only one opening to the surface is possible." "Escape routes shall be a. Inspected at regular intervals and maintained in safe, travellable condition, b. Marked with conspicuous and easily read direction signs that clearly indicate the ways of escape." "Application. "Regular" intervals means at intervals no greater than monthly where conditions are stable and oftener where conditions may change." "Designated escapeways inclined more than 30* from the horizontal shall be equipped with stairways, ladders, cleated walkways, or emergency hoisting facilities." As can be noted in present and proposed regulations there must be two separate properly maintained escapeways. In most operations, the escapeways will consist of one route that is the normal travelway used in day to day operations. The second route is usually a return airway through old work areas. Based on this generally accepted practice, we will designate the two types as primary and secondary.

Jan 1, 1976

By Daniel Edelstein

The supply of arsenic trioxide in 1982 was adequate to meet domestic demand. Allocation of supply by major domestic and foreign producers that began in 1977 ended during the first quarter of 1982. Major demand was about evenly divided between industrial chemicals and agricultural chemicals. Domestic Data Coverage.-Commercial- grade arsenic trioxide and arsenic metal were produced by only one U.S. company. In order to prevent disclosure of proprietary data, arsenic production data have been withheld.

Jan 1, 1983

By Harold F. Unger

The Bureau of Mines conducted drilling experiments in the laboratory with a commercially available percussive drill that has an independent rotational system. Eight rock types with a wide range of physical properties were drilled under several combinations of rotational speed, drilling thrust, and operating pressure. Penetration rates and energy per unit volume correlated well with the coefficient of rock strength as shown graphically. Size-distribution analyses of some of the drill cuttings show how particle size varies with rotation speed and rock hardness. In general, changing the rotational speed has a greater influence on the penetration rate in softer rocks, with penetration rate increasing with increasing rotational speed.

Jan 1, 1972

By Fred N. Kissell

Methane flows and pressures were measured in mines in the Pittsburgh, Hartshorne, and Pocahontas No. 3 coalbeds. From the data, the permeability of each of these coalbeds was computed. It was found to depend strongly on the type of coal and on the amount of water in the coalbed, and it was found to increase with time. All of the coalbeds had a high-permeability zone adjacent to the face or rib, and the Pittsburgh bed exhibited directional anisotropy. Surprisingly, little or no overburden effect was observed.

Jan 1, 1972

By Dhaval Patel, Kim Witte, Charles Vaught, Michael T. Stephenson, Steve Booth-Butterfield, Cynthia Zuckerman, Brian L. Quick

This longitudinal field study was designed to encourage Appalachian coal miners in West Virginia and Pennsylvania to engage in hearing-protection behaviors. Method: Participants were mailed postcards that featured either a positive, negative, or neutral message on the outside of the postcard and a message encouraging hearing protection behaviors on the inside. The first posttest measurement of the effectiveness of the persuasive messages was conducted about a week after the postcards were mailed. The delayed posttest measurement was conducted six weeks later. Results: Responses from 307 coal miners revealed that the positive or neutral messages generated significantly more self-reported hearing protection behaviors than the negative message. Identical results were obtained in a delayed posttest assessment of miners' self-reported hearing protection behaviors. The positive message was also more effective than either the neutral or negative message in preventing defensive mechanisms from emerging over time. Impact on Industry: Positive and neutral messages were convincingly more than negative messages in facilitating self-reported hearing protection behaviors among coal miners. Similarly, the positive messages kept defensive processes at bay. Keywords: Hearing protection; Hearing loss; Coal miners; Campaign; Messages

To quickly and more reliably measure the alignment and deflection of mine guides used to run skips and cages into a mine shaft. The Problem Conventional mine guide alignment measuring systems require the use of a plumb bob and tape measure. This method is not only laborious, but it is time consuming as well. Approach Aware of the drawbacks of the current measuring method, the Bureau of Mines designed a self-contained instrument system that can accurately perform vertical guide alignment and deflection measurements by remote control. How It Works The Bureau-developed instrumentation system, called the Guide Alignment Measuring System (GAMS), is based on conventional mechanical electronics using inclinometers and displacement transducers. The instrumentation system is attached to an operating skip or cage where it functions as a completely self-contained measurement system, operating in conjunction with nor-mal travel of the skip or cage. An on-board tape recorder or a mini-computer with memory can be used to record all telemetry.

Jan 1, 1987

By J. H. Maysilles

The Bureau of Mines is examining a variety of low-grade uranium ores because projections indicate that an appreciable percentage of future U.S. uranium production will be derived from resources containing 0.01 to 0.1 percent U308. One possible source is represented by a granitic material from Wyoming; the available samples contained 0.06 and 0.12 percent U308. Tests were conducted to explore the general leaching characteristics of this potential resource. The material responded to both acidic and alkaline leaching techniques. Conventional acid leaching extracted 93 percent of the uranium in 18 hours; the required acid addition was 50 to 100 pounds of H2S04 per ton of ore, and the oxidant addition was 3 pounds of NaCl03 per ton of ore. The acid consumption continues after maximum uranium recovery has been reached; this effect may complicate heap or in situ leaching with acidic solutions. Some variation in reagent requirements was noted between the two ore samples. Conventional carbonate leaching with strong solutions at 85° C extracted 94 percent of the uranium in 24 hours. These granitic materials also showed some response to dilute carbonate solutions, and the results suggest that the material may be chemically amenable to heap or in situ leaching with dilute carbonate solutions.

Jan 1, 1977

By Ann G. Kim

Methane in coal constitutes a serious hazard during mining. Draining the methane from large blocks of coal in advance of mining is an effective method of improving the safety and efficiency of coal mining. Because of the similarity of the two gases, drained methane can be recovered and added to pipeline supplies of natural gas. To effectively apply advance drainage techniques and recover drained gas, a gross estimate of the methane content of coal is necessary. Using data from previous investigations, the virgin reserves of the Pittsburgh coal in the central and southwestern parts of Washington County, Pa., are estimated at over 1.5 billion tons, with a methane content of 50 to 100 fts/ton. The Pittsburgh bed in this area of approximately 265 mi2 contains over 130 billion ft3 of methane.

Jan 1, 1974

Assist in controlling or extinguishing fires that occur in abandoned mine lands (AML) by providing a compilation of information on past fire control projects, the estimated extent of the current problem, and factors affecting the occurrence, propagation, and extinguishment of AML tires. Conventional fire control methods and their probable effectiveness are evaluated. Background Fires that occur in abandoned coal mines, waste banks, and coal outcrops constitute a serious health, safety, and environmental hazard from toxic fumes, deterioration of air quality, and subsidence. Although fires on AML occur in every coal-producing State, the severity of the problem varies, with most underground fires occurring in Kentucky, Pennsylvania, and Wyoming. Surface fires are prevalent in Kentucky, Pennsylvania, and West Virginia. Methods to extinguish or control AML fires, including excavation, fire barriers, and scaling, are generally expensive and have a relatively low probability of success (see figures 1 and 2). Bureau of Mines Study The Bureau compiled information from a variety of sources and found that the problem of AML fires is a serious one. Such fires can involve a high degree of hazard and can be difficult and costly to control. AML fires usually involve smoldering combustion in outcrops, waste banks, or abandoned mines. Given the nature of these fires, it is unlikely that the extent of the problem or the cost of solutions will decrease in the near future.

Jan 1, 1992

Develop methods to detect and repair poorly functioning dust collectors on roof bolters. Approach In conjunction with a research project to reduce silica dust in coal mines, a variety of roof bolting machines operating under different conditions were examined to find out how much these machines were contributing to the silica dust problem. Results The investigation concluded that if the bolting machines' dust collector is properly maintained, very little dust can be measured in the air, even with minimal airflow over the bolter. Poor maintenance, however, frequently results in high dust levels. Three major problem areas were found. These were: (1) filter leaks, which allowed dust to escape, (2) accumulations of dust in the collection system, and (3) low airflow at the bit due to hose, fitting, and relief valve leaks.

Jan 1, 1984

Enable mine personnel to determine the effectiveness of and to optimize the mine fire stench warning system without resorting to costly trial and error fire drills. Approach The mine fire stench warning system is used by underground metal/nonmetal mines to warn mine workers of a fire or other emergency. Stench is released directly into the mine ventilation and/or compressed air lines, and its repulsive odor warns miners to evacuate the mine or to follow other established emergency procedures. Unfortunately, since most deep metal mines have complex ventilation systems, some areas of the mine may receive nauseatingly high concentrations of stench while other areas, in more remote locations, may receive no warning or greatly delayed warring at best. The Bureau of Mines, through research, endeavored to solve this problem with a computer modeling system designed to calculate the distribution of odorant by the stench warning system.

Jan 1, 1986

By Fred N. Kissell

Methane flows and pressures were measured in mines in the Pittsburgh, Hartshorne, and Pocahontas No. 3 coalbeds. From the data, the permeability of each of these coal beds was computed. It was found to depend strongly on the type of coal and on the amount of water in the coalbed, and it was found to increase with time. All of the coalbeds had a high-permeability zone adjacent to the face or rib, and the Pittsburgh bed exhibited directional anisotropy. Surprisingly, little or no overburden effect was observed.

Jan 1, 1972

Continuously separate mixture of non-magnetic materials (such as scrap, precious metals, or certain ores) at a reasonable cost. Approach Nonmagnetic materials of different densities are rapidly float/sink separated by an augmented lifting force produced In a magnetic fluid (liquid) by the effect of an external magnetic field. The magnetic fluid is a colloidal suspension of magnetite In kerosene, prepared by a low-cost process. How It Works Separation is accomplished in an open trough filled with magnetic fluid. A magnetic field is established in the fluid, by energizing an electromagnet having poles on each side of the trough. Due to the design of the magnet poles and air gaps, the magnetic field is strongest at the bottom, about 10,000 oersteds, and uniformly decreases in strength to about 2,000 oersteds at the top of the fluid. Therefore, the magnetic field gradient increases with depth. The magnetic force attracts the entire separation medium (magnetic fluid) creating a reaction force of equal magnitude and acting in the opposite direction. This reaction created within a magnetic fluid/magnetic field combination is called a magnetic levitation force. It increases with the field strength. In this case because the magnetic field is strongest at the bottom of the trough, the magnetic levitation force will quickly float lighter material while heavier material sinks.

Jan 1, 1980