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By L. Allan White

Instrumental analysis is an indispensable tool to many phases of research on rare-earth metals and their compounds; therefore, the development of new and improved instrumental techniques is essential. This report describes an emission spectrometric analytical method using direct-current carbon-arc excitation of various rare-earth-oxide mixtures. Lanthanum oxide serves the dual purpose of an internal standard and a constant major constituent. The versatility of the method was demonstrated by three different applications: (a) Analysis of complex rare-earth concentrates; (b) determination of impurities in high-purity rare-earth oxides; and (c) detection of rare-earth elements in other types of matrices, such as those resulting from beneficiation of rare-earth ores. The average error of analysis in the concentration range of 0.2 to 10.0 percent was 14.6 percent for a group of complex synthetic mixtures of rare-earth oxides. An average error of analysis in the concentration range of 0.05 to 0.50 percent was 21 percent for a group of high-purity rare-earth oxides.

Jan 1, 1959

By J. K. Richmond

Early research on coal dust explosions by the Federal Bureau of Mines and in other countries is reviewed to examine the effect of a single inhibitor, rock dust, on the explosion limits of coal dust. The parameters studied in this research included coal dust fineness, volatile content, and type of initiation. This research resulted in appropriate safety regulations in the respective countries. Also reported are the results of recent research in the Experimental Mine of the Bureau of Mines to investigate in detail the limits of coal dust explosions; the research used three types of coal with rock dust added as the independent variable. New experimental techniques and new criteria for defining propagation/nonpropagation were applied to the experiments. Also, a limit explosion propagation model is proposed based on the assumption of rapid devolatilization of the coal particles, with the subsequent combustion of the evolved volatile products contributing primarily to the propagation of the explosions. The model assumes also that the resultant char acts mainly as an inert diluent similar to the rock dust. The model also suggests that the function of stronger initiation is mostly to lift more dust from the mine surfaces.

Jan 1, 1975

By F. E. Block, T. T. Campbell, D. Z. Hobbs

Several methods were investigated for the preparation of high- purity elemental boron in an attempt to develop a feasible process for producing boron on a large scale . In the work described in this report , the metal was prepared by metering boron trichloride gas into a crucible containing molten metal reductants . It was necessary to remove reaction byproducts by acid and aqueous leaching . Magnesium and sodium were tested as reductants , but best results were achieved using lithium or zinc as reductants . Contaminants originating from the materials of construction were the chief impurities in boron made by this method . Impurities ranged from 0.5 to 5.0 percent . Impure boron ( 85 to 90 percent ) was also prepared by the magnesium reduction of boron trioxide in a thermite - type reaction . This product contained magnesium as the chief contaminant . Impure boron made in this way could be upgraded by fusing with potassium fluoborate or potassium acid fluoride . After acid leaching the fusion cake , a product containing 95 to 97 percent boron was obtained . Analytical techniques for accurate determination of impurities in elemental boron are a major problem , requiring solution before a valid comparison can be made of the quality of boron prepared by these various methods .

Jan 1, 1964

By R. R. Nothdurft

The internal friction of eight single crystals of magnesium with orienta-tion ranging from 10° to 84° was measured at 33.5 kc and 272° C, and the results were interpreted in terms of the pinned-dislocation model proposed by Granato and Lucke. Results show that the strain-amplitude-dependent decrement varies with orientation in a manner predictable by the G-L model. Different values of strain-amplitude-independent decrement were observed at different orientation angles, but correlation with the theory was not conclusive. Problems and steps for further study are discussed.

Jan 1, 1965

By Arnold O. Tanner

The domestic mining industry continued to be strengthened and revitalized in 1989. The healthy conditions and the industry comeback that began in 1987 continued to spread and became more established for many commodities. Relatively comfortable and stable commodity prices, still found predominantly in the metals sector, reinforced other operational factors in bringing vitality to the mining and mineral processing industries. New streamlined business practices, mine and plant modernizations, and the progressive use of new technologies successfully helped lower operating costs and increase efficiency during the past 5 to 7 years. An element common to these three factors of industry renewal and growth was the ever-increasing infusion of and growing dependence on constantly advancing computer technology applications. This trend of increasing computerization was occurring throughout the mining and mineral processing business while it similarly was in most facets of modern business and culture. Some commodities and companies still struggled to outlive sluggish prices and other unstable market conditions or to modernize their businesses, but increases in productivity and profits were more common. A trend toward increased mechanical excavation in nonsoil materials was beginning to surface as a substitute for standard cyclic mine development techniques, such as drill-and-blast and surface shovel-and-truck routines. More continuous mechanical excavation offered the potential for increased production, fewer people at the working face, better ground control, and generally improved safety. The main limitation was rock hardness. The construction industry had already recognized the benefits of tunnel-boring machines for long underground drives and mechanical planers for pavement removal. The Colorado School of Mines held a short course during the year entitled, "Mechanical Excavation Techniques in Mine Development and Production,'" which was at-tended by nearly 100 engineers from 12 countries. The consensus of attendees was that for the most efficient use of these machines and techniques, new mining plans needed to be developed beyond the simple adaptation of those excavators to existing mine plans.1

Jan 1, 1991

By Rov G. Stott

In recent years there has been no loss of life from fires in the underground mines of the Lake Superior district, but numerous minor fires and several serious ones involving loss of property and production have occurred. The iron-ore-producing companies recognize that well-equipped mine rescue stations are a valuable asset against the ever-present ranger of mine fires or the possibility of hazardous atmospheric conditions underground. Prompt action by trained and properly equipped rescue teams is recognized as the prime essential in saving lives, property, and production when fires occur. To achieve this purpose, the mining companies have provided themselves with mine rescue equipment and maintain trained mine rescue crews. This circular describes how one progressive company has provided, maintained, and improved upon such protection for its underground iron-ore mines on the Marquette and Menominee iron ranges of Michigan's upper peninsula. SUMMARY The central mine rescue station of The Cleveland-Cliffs Iron Co. at Negaunee, Mich., has provided the company's mines with competent and well-equipped mine rescue teams. The new central mine rescue station at the Mather mine "B" shaft has the distinction of having underground training facilities provided as a part of the station. The company maintains the largest trained force in mine rescue in the Lake Superior district, and mine rescue training is employed as a part of the accident-and fire-prevention program. One of the most important results has been the promotion of closer cooperation and understanding between the management and the workmen. In addition to the service rendered to company mines, the station and its personnel have given assistance to others. The station and its equipment have also been used for training several nearby community volunteer fire departments. This mine rescue station and its personnel have been a dependable and valuable asset to the community in which it is located.

Jan 1, 1954

By C. Gary Reiness

A safety glass eyepiece which had been repeatedly exposed to mine environment over a number of years was studied to determine some of its optical properties. In the regions from 385 to 400 mµ and from 625 to 760 mµ, the transmittance was less than the 89 percent required by the American Standard Safety Code for Head, Eye, and Respiratory Protection. From 200 to 320 mµ the relative transmittance of two parts of the eyepiece was found to vary widely, having a maximum of 38 percent difference at 315 mµ. Irradiation of the glass by ultraviolet light caused enhanced absorption in the range from 200 to 1,200 mµ. There was a time-dependent increase of 1016 color centers per cubic centimeter throughout this range after 36.5 hours of irradiation. The rate-of-growth curve for the optical density, at 243.5 mµ and 23° C, was resolved into linear and saturable components, indicating zero order and first order

Jan 1, 1968

By Edward D. Thimons

The Bureau of Mines has developed a damage-resistant brattice, intended for use as a stopping in locations where blast damage to stoppings is a problem, the roof is relatively flat, and the differential pressure across the stopping is not high. Damage-resistant brattices consist of a series of vertically hung brattice panels joined to each other by Velcro connections that improve the airtightness of the brattice. When the brattice is subjected to strong blast forces, the Velcro connections peel apart, allowing the panels to open without incurring damage. The Velcro connections can then be resealed in a matter of minutes. A preliminary test in the Bureau's Safety Research Mine and subsequent long-term testing at the White Pine copper mine in Michigan and the Retsof salt mine in New York show that damage-resistant brattices withstand blasting better than conventional stoppings, while still performing as efficient air barriers when the Velcro connections are sealed.

Jan 1, 1978

By M. W. Von Bernewitz, J. J. Forbes

"In the United States there are hundreds of underground and surface (inside and outside) inclines at coal mines on which trips of cars are continually being run with coal, rock, supplies, and men. The safety of the men and prevention of damage to the slopes depend, excluding the personal element of the hoist-man, on the strength and condition of the wire cable, draw bars, and the couplings, and on the links of chains and pins as well. Within a recent period of four weeks there have been two runaway trips, one on the surface and one underground; it seems desirable to call attention of mechanical engineers and others at coal mines to the need for closer and more frequent inspection of the cable, draw bars, coupling links and pins, derailing devices, wheels, brakes, and other parts of cars or trips on which men are hauled on inclines. This bureau has never published anything on this class of accident heretofore.How frequently runaway trips occur is not known. If no serious injury or fatalit has to be reported to the State authorities, a number of such happenings may occur and not be mentioned outside of the immediate vicinity of the mine.Runaway trips can and do result in considerable loss of life, in injuries, and damage, either at or near the place of the break, or throughout a mine by causing an explosion of gas or coal-dust or both, This report is restricted to a study of the mechanical and physical phases of car trip construction and of the metal of couplings and ropes; derailed trips are not included and may be the subject of another paper. There is no need to mention gas accumulations, coal-dust and rock-dusting, open lights, protected power lines, and permissible equipment, because these have all been well covered in Bureau of Mines publications which have been widely distributed and partly or wholly reprinted by others.Most of the items regarding the runaway trips tabulated have been abstracted from reports made respectively by Clarence Hall, W.O. Snelling, and J. W. Paul; D. Harrington and J. J. Forbes; H. C, Howarth and G. S. McCaa; K. L. Marshall and E. H. Denny; J. J. Forbes, G. W.- Grove, and R. D. Currie; S, P .Howell and K. L. Marshall; and .J. W. Paul, H. D. Mason, and G. E. McElroy, all of the mining and safety divisions; and C. H. Herty, jr., and G. R. Fitterer of the metallurgical section of the Bureau of Mines. W. J. Fene, K. L. Marshall, and S. P. Howell of the safety division, and J. F. Lessig, mechanical engineer, and G. St. J. Perrott, superintendent, Pittsburgh Experiment Station, read the text and offered sugges¬tions. W. J. McGregor, coroner for Allegheny County, and P. F. Nairn, State Mine Inspector of Pennsylvania, contributed valuable information."

Mar 1, 1931

By Jack R. Woodyard

Bonding angles, promotion energies, and relative atomic sizes can be estimated through the solution of a set of algebraic equations generated from simple atomic models, and quantum mechanical parameters such as bond strength can be estimated from simple, hydrogenic form-wave functions. The precepts of The Engel-Brewer Theory are melded with the "Crystal Approximation Model" to produce atomic-structure models making these predictions, The two-valence-electron case is presented in this report. For the candidate atoms Be, Mg, Ca, Sr, and Ba the calculated promotion energies agreed within a few percent of their experimental values. These atomic parameters determine the possible crystal structure of the candidate atoms when alloyed. This is part of the effort at the U.S. Bureau of Mines to develop methods for alloy design in response to requirements for new high-performance alloys that conserve critical or rare materials.

Jan 1, 2010

By J. W. Jensen

Alloys of manganese and copper containing from 65 to 80 percent manganese possess mechanical strength and vibration-damping capacity in an unusually high degree. The success of their use in reducing vibration in structures depends, to some extent, on their fatigue properties. This report describes the results of fatigue tests on alloys of four compositions. Three metallurgical conditions were investigated for each alloy. Or the basis of the data in this report, the general rule that vibration-damping manganese-copper alloys are comparable to mild steel in hardness and strength may be extended to include fatigue strength. Methods for casting and fabricating these alloys were described in a previous report,4 which contained data on the mechanical and damping properties of the solid-solution alloys, and on alloys aged for 2 hours at 450° C. The aging heat treatment of solution-treated alloys results in optimum mechanical and damping properties throughout the range of specified composition. However, in the present work, measurements also were made on alloys aged for 2 hours at 500° C., because it was theorized that the additional precipitation of a-manganese under these conditions might have a pronounced effect on the fatigue strength of the alloy.

Jan 1, 1961

By Raymond M. Stateham

Microseismic noise rates and slope movements were measured in an unstable area along the north wall of the Tripp-Veteran pit, Kennecott Copper Corp., Ruth, Nev. Low-noise, wide-band microseismic geophones were located at various points in the wall, and the change in distance across open fractures, resulting from instability, was determined by repeated measurements between fixed points set on each side of the fractures. The microseismic noise rate increased and decreased with corresponding increases and decreases in the rate at which the fractures opened. The microseismic noise rates and changes in width of the fractures show excellent agreement, and the two types of measurements complement each other in monitoring the progress of pit wall failure.

Jan 1, 1971

By A. C. Fielder

It is with some diffidence that I venture to address the Montreal Section of the Society of Chemical industry on the subject of motor fuel from coal at a time when crude petroleum is produced in greater quantities than at any time in history, and at a time when the known reserves exceed all expectations, even the optimistic estimates of the Committee of Eleven of the American Petroleum Institute. Not only are new fields being discovered in America a -an embarrassing frequency but sources outside of the North American Continent show, unmistakable signs of adding materially to the world's sources of oil. Were it not for the tremendous scientific and technical importance of the work done in the past few years in transforming coal into liquid motor fuels, I should prefer to let this subject rest until a more propitious time, such as prevailed some years ago, when the gasoline consumption curve was rising rapidly and the production curve was slowing in its upward rise. That was the period which stimulated the researches which resulted in tetra ethyl lead and anti-knock gasolines on this side of the Atlantic and in methanol, synthetic gasoline and hydrogenation of coal on the other side. Some of you will recall a symposium on Motor Fuels and Oil Conservation held at the Chemists' Club n New York in September; 1925. Dr. R. L. Brown and I presented a paper at this meeting on "Complete Utilization of Coal and Motor, Fuel, in which we pointed out that coal was the most likely raw material source of gasoline substitutes if and when needed. We grouped the present and future, processes' for obtaining motor fuel from coal in three classes, namely:

Jan 1, 1928

By N. E. Hanna

Experience with the current version of gallery test 4, in use since 1913 to evaluate the incendivity of permissible explosives in the presence of coal dust, has shown the procedure to have inadequate discrimination. Consequently the Bureau of Mines used the up-and-down method of statistical design to investigate the incendivity of permissible explosives in the presence of coal dust and gas. A suitable device was developed to measure coal dust concentrations in the air-gas mixtures and to disperse the dust in the gallery atmosphere. A proposed testing method which uses suspended shots in a predispersed coal dust-gas-air mixture was evaluated. The new method can discriminate between different explosives with respect to their incendivity. Maximum ignitibility of the coal dust cloud by permissible explosives occurred in the vicinity of 0.3 oz/cu ft. About 10% sodium chloride in permissible explosive formulations had a very significant effect in reducing the probability of igniting coal dust. Bundled charges were more incendive than column charges.

Jan 1, 1966

By K. K. Kershner

The purpose of this investigation was to develop methods on a laboratory scale for recovering tin from metallurgical slime, Tin chlorides were volatilized using mixtures of hydrogen chloride and reducing gases, such as hydrogen, carbon monoxide, hydrogen sulfide, ethane, propane, and butane. Optimum conditions were found to be n mixture of 3:1 of hydrogen and hydrogen chloride at 475° C. Over 95 percent of the tin was volatilized as chlorides. Low temperatures and relatively rapid rates of reaction are distinct advantages of the chloride volatilization process. Research is being continued with various slimes and will be extended to tin ores, where the method offers interesting economic possibilities in comparison with current tin-smelting practice.

Jan 1, 1957

By Martin J. Gavin

In an earlier paper (Karrick, Lewis, C. A convenient and reliable retort for assaying oil-shales for oil yield: Bureau of Mines, Reports of Investigations, Loral No. 2229, March, 1921. Reprinted in Eng. and Min. Jour, April 30, 1921, also in Mining & Met., May, 1921) which describes the apparatus and method used in the laboratories of the Bureau of times for assaying oil-shales, no mention is made of the quality of oil obtained when the apparatus is operated under conditions determined to be most suitable for producing highest yields of oils. So many inquiries regarding the nature of the oil have been received, that it seems advisable to present a short report on the subject. Experimental work indicates that it is possible to vary the quantity and quality of the oil obtainable with the assay retort from a given shale by varying the conditions of retorting. As an example, some figures that are averages for several closely agreeing tests are shown below.

Jan 1, 1921

By H. J. Heinen

The Bureau of Mines, investigated a cyanidation-carbon adsorption technique for extracting gold from arsenopyrite concentrates. Agitation leach experiments were conducted on 85-pct-minus-35-mesh gravity concentrates containing 21.8 oz gold and 6.4 oz silver per ton. Results obtained in leaching the concentrates showed that 96.9 pct gold and 90.7 pct silver extraction could be achieved in 96 hours of agitation. Gold and silver were recovered from the resulting pregnant solution by exposure to granular activated carbon in a countercurrent system. Carbon loadings of 2,556 oz of gold and 502 oz of silver per ton were achieved. These loadings are significantly higher than heretofore thought practical.

Jan 1, 1980

By Robert Howard

With the rapid depletion of the Peerless Coal Co.'s mine in Spring Canyon, it was necessary, if the company was to remain in the coal-producing business, to look to the development of a new property or to acquire a mine already developed. After careful investigation of several operating properties it was decided by the officials of the company to take over the lease on an undeveloped acreage held by a private party in Price Canyon, about 3 miles north of Castle Gate, Utah.

Jan 1, 1930

By R. S. Dean

A general survey of the metallurgical work of the U. S. Bureau of Mines has been given in an article in the Missouri School of Mines Alumnus, and a somewhat more detailed review of the bureau work on lead and zinc will be found in the Mining Congress Journal. C. C. Furnas has contributed one general mathematical article. Dean, R. S. U. S. Bureau of Mines. 4, 1930, pp. 7-8. Program of Metallurgical Investigations of the Missouri School of Mines Alumnus, vol. 4, No. Investigations of the U. S. Bureau of Mines on the Milling and Smelting of Lead and Zinc. Min. Cong. Jour., vol. 16, 1930, p. 799, 808. Furnas, C. c. Evaluation of the Modified Bessel Function of Am. Mathematical Monthly, vol. 37, the First Kind and Zeroth Order. No. 6, 1930, pp. 282-287.

Apr 1, 1931

By H. G. Iverson

As a part of the program of investigation of domestic sources of manganese ore, mining engineers of the Bureau of Mines examined and sampled three properties in the vicinity of Winnemucca, Nev. As the ores were too low grade for direct production of ferromanganese, they were tested for their amenability to concentration by ore-dressing methods. Two samples of ore were procured by examining engineers of the Bureau of Mines from several outcrops in the Pollard Canyon area, Pershing County, about 30 miles southeast of Winnemucca. The manganese occurs in relatively small lenticular bodies as secondary replacement deposits in chert and quartzite. The first sample represented average run -of -mine ore as exposed in the Pollard Canyon deposits. Sample 2 was composed of hand-sorted, high-grade ore.

Jan 1, 1954