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By T. A. A. Quarm

The concept of a continuous zinc smelting process which employs submerged combustion of coal char for both heating and reduction is described. An estimate of the results of smelting a marmatitic zinc concentrate indicates that both the operating and construction costs would be lower than those incurred in processes now in commercial operation. The results of smelting a complex zinc-copper concentrate are also estimated, but no simple commercial process exists with which they can be compared

Dec 1, 1971

By J. Gough M. D.

There are many points still obscure regarding the nature of coal-workers'- pneumokoniosis, but the interpretation of the disease has been greatly clarified in recent years. It is now known that exposure to fumes or gases or other conditions peculiar to coal-mining are not necessary factors in the production of pneumokoniosis. The same disease occurs in coal-trimmers working in the docks, and it is thus established that the inhaled dust is the primary factor. On the other hand, there is no completely satisfactory explanation of the distribution of the disease. Geological and petrological studies have not given an unequivocal explanation of the difference in incidence in different parts of the coalfield. It is an open question whether the quantity of dust inhaled is more important than its chemical composition. However, there is ample evidence from the medical side that elimination of dust and of tuberculosis from the environment of coal workers will be required to prevent pneumokoniosis. Much is being done with regard to elimination of dust, and a similar energetic action is required in regard to tuberculosis.

Jan 1, 1947

By G. J. Lyman

Mayer curves are used for process calculation in coal preparation. They can also be used to smooth washability data by fitting a hyperbola of particular properties to ash and yield, but to introduce the density variable an independent relationship with ash content must be adopted. When this ash-density relationship has a realistic form at low density, the implied form of the mass distribution function is unrealistic, suggesting that Mayer curves represented by a hyperbolic functional form are unsuited to coal washery calculations for low-density separations. Their use at higher densities is also uncertain. A similar conclusion can be anticipated when Mayer curves are used for other mineral systems.

Jan 8, 1992

By P A. Collier

The general view of the author is that all the good intentions of manufacturers can fail completely if the variations in circumstances in underground mining are not considered at all times. With a belief that it is the customer that has the experience and know ledge of problems which occur on long installations. Reilloc talk with customers in coal mines around the world, and have done so from their inception. With considerable experience in their home market, their technical approach was received with enthusiasm by coal companies in both Australia and South Africa, and whilst experience was obtained in other countries, it is the particularly close working relationship in these two areas that is covered in this paper. The refinement of manufacturing techniques and the fine tuning of the specification to which the chain is made was developed in conjunction with factual underground experience obtained by customers as they sought to improve their productivity and a reduction in working costs. With a reliable product the mines are able to concentrate on improved operational techniques to extend the useful working life and plan for multi-panel usage of the chain.

Jan 5, 1996

By D. J. Allan, W. R. Wilson

For conventional aerospace aluminium alloys of the 2000 (copper) and 7000 (zinc, magnesium) series the recycling of process scrap from both metal suppliers and aircraft manufacturers is a well-established, worldwide industry. The recent introduction of a new family of alloys that incorporates lithium has posed a new challenge to the recycling industry owing to the high cost of lithium, its high reactivity to the atmosphere and to refractories and its absence from the specifications of all other registered alloys. Various process options for recycling have been identified, but vacuum distillation has been selected as the most cost-effective and technically feasible solution. Experimental work established that the separation of Li from AI-Li scrap is feasible and an industrial process has been designed. The economics of Li recovery are very sensitive to the AI-Li content of the feed material. Owing to the design of aerospace vehicle manufacturing plants it is expected that the swarf will be mixed with other alloys. A method of enriching this feed has been developed that is based on the control of swarf morphology by thermal and mechanical treatments as a precursor to eddy-current separation. After eddy-current separation and vacuum distillation small proportions of Li are retained in the AI residue. The effects of this on the properties of conventional AI-Si shape-casting alloys were investigated and safe threshold levels have been established.

Jan 4, 1993

By R. J. Gochin, P. Bevilacqua, G. D. Schena

This class of flowsheet-dependent simulators does not replace modular simulators, such as Modsim and Microsim, which are necessary for the assessment of different flowsheets before selection of the most desirable technical option and for investigation of the fine details of unit processes. The system presented here is regarded as complementary, serving in the early stages of feasibility studies as an aid to assessing the convenience and economics of preconcentration; the example used is of dense-medium preconcentration of a barytes-fluorite ore

Jun 13, 1905

By R. R. Liebenberg, M. I. Brittan

The kinetics of the copper segregation process has been investigated. The experimental strategy used to isolate the rate-controlling reaction step is described. This step was found to be the chloridisation of the oxide copper minerals in the ore. The link between the rate of chloridisation and the overall rate of segregation is demonstrated experimentally. The influence on the kinetics of the various parameters in a TORCO system is examined and the implications are discussed

Dec 1, 1971

By S. G. Tsimas, A. K. Moutsatsou, S. G. Tsivilis, G. K. Parissakis

(NH4)2SO4 can be used with success as a leachant to remove gypsum contained in celestite ores. The process, which is applied before flotation, provides an upgraded feed and problems related to the simultaneous flotation of CaCO3 and SrSO4 are reduced. The process is independent of the gypsum content of the feed so that each leaching stage decreases the gypsum content by almost 50%. The use of (NH4)2SO4 has an insignificant effect on the co-leaching of SrSO4 (0.45 wt.%) at each stage

Jun 13, 1905

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

Thermodynamical data of importance in connection with copper smelting have been reviewed and a collection of the most reliable information is presented in Tables XXV-XXVIII and Figs. 67 and 6 8 (folding plate). The data given in these figures and tables consists of (i) graphs and equations showing the variations in the temperature range 0-2000°C. of the standard free energies of formation of most of the oxides and sulphides met with in copper smelting (Table XXV and Fig. 67); (ii) equations showing the temperature variation of the free energy of formation of iron silicates (Table XXVI); (iii) graphs showing the variation with temperature in the range 1000°-1600°C. of the standard free energies of the principal reactions occurring in the smelter (Fig. 6 8 ); (iv) the standard heats of formation at 1200°C. of the main iron and copper compounds and gases reacting in the smelter (Table XXVII); (v) the standard heats of reaction at 1200°C. of a few of the reactions for which the free energy relationships were given in Fig. 6 8 (Table XXVIII). The data presented are discussed in more detail.

Jan 1, 1953

By R. Winand, P. Harlet

he cathodes produced are of electrorefined grade; metallographic structure and surface roughness are controlled to a depth of 1.3 cm (single-side deposits); silver levels in the cathode are regulated by the presence in solution of Cl- and Br- ions; organics must be used at very low concentrations (around 0.1 mg/l with a consumption of about 0.01 mg/l/hr). The required concentrations of additives were established according to a well-defined strategy based on the consumption of organics at the cathode by a mass transfer limited-process.

Jan 4, 1992

By M. Dobias, N. Mayor, J. Lillo, A. Gonzalez, R. Lunar, R. Oyarzun

The central domain of the Spanish Central System contains a series of Ba-(F)-(base metal sulphide) hydrothermal vein deposits that are hosted by adamellitic granitoids. Fluid inclusion and sulphur isotope data suggest that the mineralisation was formed by low-salinity hydrothermal solutions that incorporated fluids, metals and sulphur from a magmatic source. Mineralisation occurred in two main stages; a first stage of open-space filling with quartz-Ba-(F)-(base metals) ; and a second stage of brecciation and deposition of quartz-barite. The two mineralising events can be clearly related to two tectonic episodes of late Variscan age that involved extension along east-west trends followed by ductile transcurrent movements along northeast-southwest trends.

Jan 4, 1992

By J. Cech

Discussion is presented of a decision-making support method for the spacing of ore passes along a long vein orebody and the division of the orebody into convenient stopes for future mining operations. The method was tested on a Slovak siderite deposit and also on some hypothetical cases with the objective of obtaining more general results

Jun 18, 1905

Discussion following the presentation at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, included the author's introduction, written contributions by Bedson P.P., Gregory T.W.D. and Morgan J.D., oral contributions by Louis H., Greener T.Y. and Severs W., and the author's reply

Dec 1, 1916

By D. J. Reddish, B. N. Whittaker, G. X. Sun

An image analysis technique has been used in the assessment of subsurface fracture levels in the context of water inflow into longwall mine workings. The technique was used to analyse results from physical modelling which are represented by black and white photographs taken directly from the model tests. Binary images of fracture patterns are obtained by scanning the photographs with an image analyser coupled to a video camera. The images are manipulated by a C program which allows them to be processed in vertical and horizontal directions and filtered to differentiate quantitatively between vertical and horizontal fracture intensities. The fracture density distributions provide a valuable database for further numerical and statistical analysis. This allows assessment in terms of water inflow into the excavation. A comprehensive image analysis was undertaken on several extraction models. Results indicate that extraction thickness has a significant effect on the fracture pattern and the fracture density distributions. The results can be used to adapt model findings to situations with a range of extraction thicknesses. The technique has allowed improvement in image enhancement and in the interpretation of model results. In particular, a qualitative comparison between different models is possible.

Jan 12, 1992

By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984

By B. Sonmez, B. Aksanl, S. Ersaym, I. F. Erkal, S. L. Ergun

The comminution circuit at the plant has experienced severe problems arising from a feed containing much larger amounts of clay and having a higher moisture content than expected. Three solutions were proposed: replacement of the crushing circuit by tooth roll-type crushers; using washing drums; and introducing primary autogenous/semi-autogenous millling instead of crushing. Computer simulations studied the effects of the first two solutions on the circuit capacity. Laboratory and industrial scale ball mill batch grinding tests were carried out. The parameters of a kinetic model were determined. The ball mill circuit was sampled and operating model parameters were calculated. The ability of batch grinding parameters to represent the operating conditions was studied. Tests failed to find acceptable model parameters, but parameters from an industrial size batch mill were found to be suitable for simulation studies. The simulations indicated that a continuous feed of -12 mm provided by tooth roll crushers would maintain the desired capacity. Increasing the feed size to -25 mm would reduce the capacity by 8-15%. The use of washing drums could also solve the capacity problem, but small fluctuations in water flow rates might result in problems of excess water in the grinding circuit.

Jan 4, 1993

By R. Patel, J. Ephraim

The production of titanium dioxide (TiO2) from its minerals such as ilmenite is challenging, and subsequent isolation of titanium from TiO2 is even more difficult because of the metal-oxygen bond strength. Currently, titanium sponge is mainly produced via the Kroll process, which is energy intensive and generates large quantities of waste. A number of international research groups have come up with technologies for the production of titanium metal. However, none of them have been commercialised, because of engineering or economic issues. The team at Bradford have confirmed that ultra-pure titanium powders can be separated from TiO2 powder through metallothermic reduction and are working to scale up the process.

May 1, 2015

By Z. Sawlowicz

Finely dispersed, primary sulphide mineralisation in the Cu-Fe sulphide zones of copper-bearing shale of the Polish part of the Permian Kupferschiefer is mainly present in the form of framboids and spherules. This type of mineralisation is especially well preserved in organic-rich shale, where it often dominates over a later diagenetic mineralisation that consists of large grains and veins. In microscopic observations special attention was paid to composite grains of copper and iron sulphides. The results suggest that the Cu-Fe and Cu sulphides precipitated in the Kupferschiefer sediment before pyritisation of the framboids had ceased and that they replaced metastable precursors of pyrite. The precipitation of copper sulphides could have been delayed owing to the formation of Cu-organic complexes.

Jan 4, 1992