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By Takaaki Wajima

The slag was attempted to be converted into the adsorbent for phosphate removal from aqueous solution using the alkali fusion method. The slag was mixed with NaOH powder (NaOH / Slag = 1.6), and then the mixture was heated at 600 ? for 6 h to prepare the precursor. The precursor was stirred at room temperature in distilled water to synthesize the adsorbent, and the removal ability of the obtained adsorbent for phosphate from aqueous solution was investigated. The products, including hydrocalumite and calcite, were synthesized, and the removal efficiencies of the adsorbent for F- and PO43- showed higher than those of raw BF slag, especially removal of PO43- are excellent (99 %), while the removal of Cl- , SO42-, NO3- and Br- was minor. The adsorbent could remove PO43- selectively in the co-existing solution of Cl-, NO3-, F-, SO42- and Br-.The equilibrium adsorption capacity of the adsorbent for PO43- was extrapolated using Langmuir and Freundlich models, and experimental data are found to fit Langmuir than Freundlich. The calculated maximum adsorption capacity of the adsorbent for PO43- is higher than other adsorbent reported previously. The high affinity of the adsorbent for PO43- in aqueous solution was caused by the formation of hydroxyapatite [Ca5(PO4)3(OH)] and brushite [CaHPO4?2H2O]. The prepared adsorbent is expected to be anew inorganic adsorbent for the removal of phosphate ion from wastewater. Keywords: Blast furnace slag, Alkali fusion, Phosphate removal, High selectivity

Sep 1, 2012

Spent automobile catalyst is an important secondary resource of PGMs (platinum group metals) and the recovery is significant. Various methods of recovery technology have been reported and applied in practical production, including pyro- and hydrometallurgical processes. Since the grade of PGMs in the catalysts is so low, approximately 0.5 wt. %, the present recycling technologies require high energy-consumption, it is of great significance to enrich the PGMs with some energy saving physical separation methods as a pretreatment. Automobile catalyst is usually composed of cordierite phase as a substrate and alumina phase, with PGMs, which covers the cordierite phase. We adopted the quenching pretreatment, one method of thermal shock, to generate micro-cracks between the two phases and separate the alumina phase from cordierite. Quenching was carried out by heating the catalysts in an electric furnace of different temperatures followed by rapid soaking into cold water. It was found that the phase boundary between alumina and cordierite was broken in the quenching and selective separation (detachment) of alumina from the cordierite could be achieved in the following surface grinding. The effect of quenching was checked by microscopic observation, hardness measurement, and chemical analysis. This paper figures out the stress formula of the quenching process, which is largely connected with layer thickness and temperature gradient by using an FEM (Finite Element Method) simulation and clarifies the mechanism of crack generation in the quenching process. Keywords: automobile catalyst, PGM, quenching process, FEM

Sep 1, 2012

By H. J. Schulze

From a colloidal science point of view (Schulze 1984, Nguyen & Schulze, 2004) five micro-processes are responsible for successful particle-bubble formation: the approaching of the particle to the liquid-air interface, the thinning and rupture of the intervening liquid film, the expansion of the three phase contact perimeter, the generation of sufficient large capillary force to stabilise the aggregates and the transport process of particles into and within the froth layer. Flotation reagents influence mainly the thinning and rupture of the intervening liquid film between particles and air bubbles, the expansion of the three phase contact after the rupture of the liquid film and the stability of the aggregates against external destruction forces in the flow field. But it exist also a non-negligible influence on the approaching of particles to the bubble surface during the encounter process and on their passing over into the froth layer and the froth stability.

Jan 1, 2003

By R. Chowdhury

Axis House manufactures and supplies alkylhydroxamate reagent of various carbon chain lengths for application in flotation of oxide copper and other minerals. As part of reagent performance improvement the structural factors of hydroxamate are examined by various analytical tools in particular with X-ray diffraction of single crystals. In a recent publication, the structure of n-octylhydroxamic acid and its corresponding potassium salt are presented with findings of hydroxamic functional group geometric preference, H-bonding, keto-enol tautomerisation, acid-salt aggregation and alignment of carbon chain. In this paper an example of branched alkylhydroxamate 3, 5, 5-trimethylhexylhydroxamate will be presented and compared with the result of linear alkylhydroxamate.

Sep 1, 2012

By Hong Nguen Vu, Pavla Ovcarí, Peter Fecko, Barbara Tora

The aim of this paper is to evaluate the suitability of a coal sample from the mine Jaworzno (Poland)- locality for bacterial leaching. Laboratory research used a pure bacterial culture of Thiobacillus ferrooxidans. The results showed that bacterial leaching was effective, with a one month leaching time, when 65% of total sulphur and 85% of pyritic sulphur was leached. The paper describes changes to the pyrite during and after bacterial leaching.

Jan 1, 2003

By P. Thareja, V. Prasad, S. P. Mehrotra

In recent times, the transportation of minerals and their tailings has become a major concern across the world. There exists a huge demand of efficient and cost effective transportation system which poses minimum environmental damage. One of the economically and environmentally viable techniques which potentially offer a solution to the above problem includes transportation of minerals and their tailings in the slurry form through pipelines. Slurry transportation through pipelines is reported to be more beneficial in terms of cost, environmental impact, maintenance and safety when compared with other conventional modes of bulk transportation such as train, truck, barge and conveyors. The main challange associated with hydraulic transportation of slurries is to obtain a non-settled slurry and to design a pipeline system which results in the optimum energy requirement for transporting a large throughput to longer distances at a lower cost. The feasibility of hydraulic transportation of slurries through pipes mainly depends upon slurry properties and flow conditions in the pipe. Results from rheological studies exhibit the presence of shear thinning flow behaviour of minerals and their tailings in water. The flow behaviour index (n) and consistency coefficient (k) obtained from the rheological analysis are further used for the specific energy consumption and energy losses during transportation. The cost of transportation in USD per ton per 100 km and transport capacity in tons per day are calculated from the specific energy consumption to transport these slurries. The results demonstrate that the slurries can be transported to long distances (say, 100 km or more) corresponding to optimum energy consumption and dissipation rate at a substantially cheaper cost than the existing rail and road transport in India. Although we have carried out transportation studies with coal fly ash (CFA), lignite & bauxite slurries, for paucity of space, the results reported here are essentially for CFA slurries. Details of our investigations with lignite coal & bauxite will be reported seperately.

Jan 1, 2018

By E. A. Bekchurina, Yu. P. Morozov

"This paper presents the results of a study of the concentration of flotation froths in tapered chutes. The tests were conducted on lab and full-scale plants, and the results obtained were mathematically processed. The kinetics of monophase recovery from a stationary flotation froth, hydrodynamics of froth flows traveling in a tapered chute were investigated. The effect was studied of the mass fraction of the valuable component in the chute feed, yield of the chute’s overflow, and chute design on the concentration performance. Processing of the collected data revealed the general laws of the process and allowed to develop a technique for modeling concentration of the flotation froths of sulphide copper ore in a tapered chute to predict the performance without testing. It was found that concentration in tapered chutes allows to obtain products that are comparable in quality with froths after one or several cleaner flotation stages.INTRODUCTIONThe present production expansion rates require continuous improvement in the grade of flotation concentrates, while the grade of the mineral feed is constantly deteriorating. This leads to a significant complication of flotation flowcharts. Flowcharts become multi-staged with multiple cleaner flotations, negatively affecting the production costs.In recent years, researchers are paying close attention to the processes occurring in the froth layer in the flotation cells. Improving the concentrate grade is facilitated by secondary concentration of minerals in the froth layer, which consists in fixing the hydrophobic particles released as a result of the coalescence of the bubbles of the upper layer when moving downward at the liquid-gas interface of the froth layer. In this case, the released hydrophilic particles, trapped in the froth layer as a result of mechanical removal, migrate from the froth together with the liquid phase."

Jan 1, 2018

By Lokesh K. Thakur, Peter Radziszewski

"For the cases tested (11 mills with 15 operating conditions), the Bond abrasion test steel media wear rate prediction gives an overall error of 73% and a standard deviation of 192.5%. However, total steel media wear in a given mill (ball or SAG) grinding process is a product of three recognised wear mechanisms -- impact, abrasion, and corrosion. A total media wear model can be defined on the assumption that the effect of each wear mechanism can be independently determined which allows for a total media wear model to be defined as the summation of the wear result of each mechanism (eqn. 1). It is assumed that impact and abrasive media wear is a function of the energy dissipated in impact and abrasion as estimated by a DEM charge motion simulation. Corrosive media wear is assumed to be a function of the media surface area present in a mill.The 3 initial tests developed (steel abrasion wheel, corrosion batch mill, impact chamber) coupled with the impact and abrasion energy spectra from a DEM charge motion simulation produced total steel wear rate results for the same cases as the Bond abrasion test giving an overall error of 0% and a standard deviation of 66.1%. However, if one were to consider the general observation that wear is proportional to energy and maintain the assumption that corrosion is proportional to media surface area then one would realize that the total media wear eqn. (1) can be reduced to eqn. (2). As this is a linear equation and one has, for the same mill, media wear and operating data for three different operating cases, one obtains three equations with three unknowns. This defines a simple matrix manipulation to determine the constants k1, k2 and k3. From the previous data set, we had 6 identical mills grinding the same ore but having different worn liner profiles and charge volume which provided the opportunity to average out the ki values over 20 combinations of 3 cases. With the determined ki values, it was possible to determine a second estimate of the contributions of impact, abrasion and corrosion to total media wear giving an overall error of 0% and a standard deviation of 56%."

Jan 1, 2003

By M. Ghiani, P. Massacci, A. Manni, R. Peretti, Center for Mining and Mineralurgical Studies, S. Serranti

"The research study has been devoted to point out the better way to process a colemanite concentrate characterised by a high content of two kind of As sulphides (realgar and orpiment) finely disseminated in the matrix of the boron mineral.Scanning Electron Microscopy analyses have been carried out to determine all the mineralogical constituents and to evaluate their distribution, frequency and mutual relationships.There is a not neglectable part of realgar highly disseminated into the colemanite crystals.The orpiment recurs in small acicular crystals of 20÷30 µm in length and 5 µm in width, very difficult to liberate from the colemanite mineral particles.The colemanite concentrate, in fact, has been addressed to a chemical plant which products were boric acid and gypsum, the contaminated by As. It was unacceptable for further applications and very dangerous if rejected in the environment.Grinding tests under dry and wet conditions have been carried out in order to evaluate the liberation modality of the As sulphide minerals from the colemanite.Some difficulties have been overtaken in order to obtain a selective liberation of the As sulphides from the colemanite even if a certain decreasing in As grade in the higher size classes has been registered.All the comminution products have been analysed by SEM monitoring the liberation degree of the mineralogical constituents.Flotation tests have been carried out after different comminution flow sheet adopting different modulating conditions in order to evaluate the influence of the following parameters:• collector concentration versus contaminants concentration (As minerals) in the froths;• kind and quantity of the frothing agent to maximise the mineral recovery in the froths;• kind and quantity of the modulating agents to maximise the selectivity of the process;• conditioning modalities in order to obtain a suitable dispersion of fines and to avoid segregation of Asbearingparticles together with colemanite ones;• solid/liquid ratio of the pulp to minimise the water flow into the plant."

Jan 1, 2003

By V. A. Chanturiya

The state-of-the-art of mineral mining and metallurgy industry in Russia is characterized by high demand of nonferrous, rare, rare earth metals, and highgrade coal, on the one hand, and by involvement of natural and technogenic minerals with low content of valuable components, fine (nearly emulsion) dissemination of valuable components and close physicochemical and process properties. This calls for high-productive and ecology-friendly technologies for more efficient mineral beneficiation based on intensification of operating and new methods to extract valuable components from rebellious ore and technogenic minerals, relying on the last achievements of basic sciences, combination of dressing and chemico-metallurgical processes and using advanced pyro- and hydrometallurgical technologies. The transition to a new strategy of processing is only possible based on the new technological–mineralogical appraisal of a mineral raw material. Actually, the process mineralogy has a stock of modern high-resolution physical methods for analyzing composition, structure and properties of geomaterials, inclusive of micro- and nano-levels: - Identification of micro- and nano-size noble metals, and natural and induced formations on mineral surface; - Experimental validation of structural phase and chemical transformation of minerals under different energy input; - Justification of choice and mechanism of interaction between flotation agents and noble metals with complex material constitution; - Analysis of structural, phase and chemical transformations of sulfides and rocks under leaching. Thus, process mineralogy is an informational background for a unified theoretical approach to scientific justification of flowsheets of efficient mineral processing. The article gives a brief review of practices that have found application and proved to be of high economic efficiency. Such practices are: X-ray radiometry and photometry separation (Uchalinsky and Gaisky Mining and Processing Integrated Works of ALROSA); selective disintegration (equipment engineered by Mekhanobr-Tekhnika and IPKON RAS); process selectivity enhancement (IPKON RAS, Central Research Institute for Geological Exploration of Nonferrous and Noble Metals, Chinakal Institute of Mining, Siberian Branch RAS, etc.); bacterial gold leaching (Olimpiada MPIW, technologies developed the Central Research Institute for Geological Exploration of Nonferrous and Noble Metals, Nezhdaninsky deposit projects, etc.); combination processing at a mining and metallurgy plant (Norilsk Mining and Metallurgical Company, Yaregsky deposit projects and others); processing of waste: overburden, mill tailings, slag, etc. (Kovdorsky MPIW, Svyatogor JSC, Ural Mining and Metallurgical Company, plants designed by the Central Research Institute for Geological Exploration of Nonferrous and Noble Metals, Mining Institute of Kola Science Center RAS, Research Institute for Chemical Technologies); water conditioning in mineral dressing circuits (ALROSA, equipment by IPKON, etc.); utilization of process water (ALROSA, Ural Mining and Metallurgical Company, Severalmaz JSC and others). Thus, Russia this time has the academic and engineering background for development of efficient energy-saving technologies for comprehensive advanced processing in accordance with the world’s standards, or even higher in terms of a number of the technologies, which has continually been highlighted by participants of recent international congresses on mineral processing.

Jan 1, 2018

By Kaiwen Liu

Activated carbon is widely used in the removal of organic and/or inorganic contaminants from waste water due to its high surface area, porous structure, and specific surface reactivity. However, in practical applications, it is difficult to recover the activated carbon completely by screening or classification. In this project,we prepared a magnetic form of activated carbon (magnetic activated carbon or M-AC) by precipitation of iron oxides on the surface of activated carbon. The M-AC can be easily separated from effluents by applying an external magnetic field, thus it can be recycled and regenerated for reuse. M-AC was characterized by X-ray diffraction (XRD), specific surface area measurement, and scanning electron microscope (SEM).XRD results show that the major phase of coated iron oxides on activated carbon is magnetite (Fe3O4). The specific surface area of activated carbon was found to be reduced after the impregnation of magnetite particles on the surface. The SEM micrograph shows the aggregation of the iron oxides on the surface of activated carbon. M-ACwas found effective in removing DETA (diethylenetriamine) species and metal ions from solutions. Cu (II) with initial concentrations from 5 ppm to25 ppm in solution is removed by more than 99% with the addition of 0.1 wt.%ofM-AC. For the removal of 25 ppm DETA species from solution, an addition of 0.5 wt.% of M-AC is required due to the larger size of the DETA molecule. Moreover, M-AC showed a good loadingproperty for nickel and gold ions from solutions. M-ACshows a better adsorption capacityover activated carbon and its potential applications in carbon-in-pulp for gold leaching and waste water treatment. Keywords: magnetic activated carbon (M-AC),diethylenetriamine (DETA),metal ion,adsorption

Sep 1, 2012

By A. Mainza, H. Hill, L. Bbosa

"The main objective of ore breakage characterization is to quantify the relationship between the energy supplied for breakage and the size of the resultant progeny. In this study, the ore breakage characteristics of drill core particles and crushed particles were compared. Single impact breakage tests were conducted on a basalt ore sample using the JK rotary breakage tester. The size-dependent model by Shi and Kojovic was used to fit the breakage data because the effect of initial particle size is accounted for in the model. It was found that crushed particles consistently gave a higher degree of brokenness than drill core particles and the differences were attributed to the internal structure of the particle. Drill core particles contain a lower crack density (paths of weakness) than crushed particles which have been pre-weakened during the crushing process. An increase in crack density is directly related to a decrease in the minimum threshold energy. Upon application of a stressing force above the stress threshold, particles with a higher crack density will fracture more easily because of a higher rate of crack propagation due the numerous paths of weakness available. It was therefore concluded that under the same conditions, drill core particles are more competent than crushed particles. INTRODUCTION Comminution devices have commonly been reported as being the largest energy consumers in mineral processing circuits (Napier-Munn, 2015). Cleary (1998) reported that the inefficiency of comminution devices is a result of less than 5% of the supplied energy being utilized for breakage, with the majority being expended as heat and noise. With steadily declining fossil fuel supplies and a looming global energy crisis, the mineral processing industry has increased its focus on energy reduction measures. Ore breakage characterization plays a critical role in the design and optimization of comminution circuits (Tavares and King, 1998). The main objective of ore breakage characterization is to empirically quantify the relationship between the energy supplied for breakage (specific input energy) and the size of the resultant progeny through laboratory particle breakage tests (Napier-Munn, 1996). Commonly used laboratory breakage devices include the Drop Weight Tester (DWT), Split Hopkinson Pressure Bar (SHPB) and more recently, the JK Rotary Breakage Tester (JKRBT). Typically, a standard single impact breakage test procedure consists of a matrix of experiments on particles in four to five narrow size fractions each tested at low, medium and high energy levels. The resultant progeny of each test is sized to obtain a particle size distribution (PSD) from which the degree of breakage, usually in the form of a t10 value (percentage of the progeny material that passes 1/10 of the feed size) can be obtained for each size fraction and energy level (Napier-Munn, 1996)."

Jan 1, 2018

By Seher Ata

This paper is concerned with the coalescence behaviour of two bubbles in dilute solutions of cetyltrimethylammonium bromide, methyl isobutyl carbonil and triton x-100. Two bubbles were produced at the tips of adjacent capillaries and the time elapsed between the first contact of the bubbles and film rupture was determined by means of a high speed camera. It was found that the amount of surfactant required to stabilise the bubbles increased in order of CTAB>TX-100>MIBC. The probability of coalescence decreased sharply with increasing surfactant concentration in CTAB and TX-100 solutions while with MIBC each bubble pairs resulted in coalescence, giving hundred per-cent coalescence probability.

Jan 1, 2014

By Yuriy V. Gulyaev, Galina V. Sedelnikova, Valeriy D. Lunin, Valentin A. Chanturiya, Igor J. Bunin

"Probable mechanisms of disintegration of mineral particles in gold-containing sulphides and benefication products exposed to high-power electromagnetic pulses are discussed. Experimental data are presented to confirm the formation of breakdown channels and selective disintegration of mineral complexes as a result of pulse irradiation, which makes for efficient access of lixiviant solutions to precious metal grains and enhanced precious metal recovery into lixivia during leaching. Experiments with different gold-containing products revealed a synergetic effect of high-power electromagnetic pulses with widely varying parameters and moisture in mineral pores on breaking-up and gold extraction processes for various resistant goldcontaining mineral products.Several series of tests performed in IPKON RAS, IRE RAS and TsNIGRI yielded an absolute gain in precious metal recovery, up to 30-80 % for gold and 20-47 % for silver, with resultant gold recovery as high as 90 %. An essentially new, environmentally safe and energy-saving breaking-up technology has been developed for resistant gold-containing products. This new method would shorten the way from raw minerals to final products and help significantly reduce the cost of these products as it obviates the necessity for using the expensive procedures of energy-intensive and environmentally hazardous oxidative roasting and autoclave breaking-up for ore concentrates."

Jan 1, 2003

By A. M. Raichur, S. P. Vijayalakshmi

Fine coal dewatering is a major problem in the coal industry because the fines hold significant amounts of water and account for two-thirds of the product surface moisture. Present methods include flocculation using polymeric flocculants followed by filtration. But the kinetics of filtration are not favorable with such flocculants. In this study, a novel method involving flocculation with microorganisms for improving the settling rates and dewatering kinetics has been investigated. Two Gram-positive microorganisms, Mycobacterium phlei and Bacillus subtilis were used as bioflocculants. The effect of time, pH and ionic strength of the electrolyte used on adhesion and flocculation were studied. Adhesion tests showed that maximum adsorption occurred in 20 minutes in the pH range of 2-7 and the total amount of bacteria adsorbed was almost the same with both the flocculants. Nearly 98% of the coal flocculated with both the microorganisms in about 5 minutes. The filtration rate of fine coal almost doubled with addition of bacteria and electrolyte and maximum filtration occurred near the point-of-zero-charge of the bacteria.

Jan 1, 2003

By M. A. C. Goes

Over the last twenty years CETEM has been involved in the preparation and certification of reference material from ores, concentrates and related materials for use in analytical laboratories associated with mining, metallurgy and earth sciences. CETEM provides reference materials from mineral samples, not available from the existing sources, to meet the needs of the mining and mineral industry. CBPA-1 and CBPA-2 respectively are samples of copper sulphide ore and flotation concentrate, both originated from Sossego Mine, located in Pará State, Brazil. The batch characterization was carried out by a collaborative measurement program with participation of 20 industrial, commercial and government laboratories from South America, North America, Europe, Asia and Africa. The certificates and report were issued in December 2007 (http://www.cetem.gov.br/ mrc/ing). The objective of this paper was to describe the procedures for material preparation and the collaborative approach involving a collaborative interlaboratory measurement program to certify CBPA-1 and CBPA-2.

Jan 1, 2014

By Yuri L. Nikolaev

The treatment of placer gold with fine gold, associated with gold-bearing sulfide minerals, heavy minerals and oxidized minerals such as manganowolframite (gubnerite) is not an easy task. In this case, this complex material cannot be treated using physical separation methods such as deep concentration and finishing, magnetic separation and solvent extraction. This technology is usually employed in gold washings finishing plant. The easiest way to recover precious metals in the form of an easy-to-sample saleable product is metallurgical treatment. This paper describes the application of pyrometallurgical processes with oxidative roasting, re-cleaning of cinders (if required) and ore-thermal smelting for producing gold bullion. Hydrometallurgical treatment of slags as an additional operation is recommended in order to maximize recovery of valuable metals. After this treatment, a barren leaching cake rich in PGM can be sold in the market. PGM can be collected as gold-silver alloy during smelting which allows the phase formation of polymetallic matte due to specific composition of fluxes. The PGM are then in the form of saleable gold bullions in the refinery.

Sep 1, 2012

By A. Singh, M. Ntlhane, V. Ross, M. Dlame

"Fine valuable particles are often lost to flotation tailings streams due to inefficient collection by air bubbles as well as passivation of surfaces by oxidation and slimes. The application of high-shear hydrodynamic cavitation devices (HCDs) to overcome this problem has already proven to be a considerable success in the industry. This paper details the results of further investigations that were undertaken at Mintek to better understand the mechanisms involved when preconditioning feed slurries in an HCD. By promoting inter-particle attrition and conditions of high shear within the reactor, cleaning of particle surfaces is enhanced as well as the formation of superfine (nano) bubbles which are believed to aid their agglomeration and subsequent collection by normal sized bubbles. In order to broaden the envelope of understanding with regard to application of the technology, rather than tailings material as investigated earlier, a Platinum Group Mineral (PGM) UG2 ore from the Bushveld Complex in South Africa was used in this study. The results of a series of batch flotation tests in a 10L Denver cell are presented, being conducted after the feed has been subjected to different methods of preconditioning. It was demonstrated that the preconditioning significantly improved the flotation kinetics of the PGMs, the optimum being obtained after around 20 passes through the reactor. This was accompanied by a much enhanced recovery-mass pull relationship and a significant improvement in the grade-recovery response. Significantly, the selectivity between the PGM and the deleterious chromite (expressed as Cr2O3) gangue more than doubled under these conditions. Modelling of the PGM data by means of the modified Kelsall model indicated that both the fast and slow floating rate constants were improved.INTRODUCTIONIt is well known that the flotation recovery of fine and ultrafine particles, typically less than 10 micron in size, is a challenge (Yoon et al., 1989; Miettenin et al., 2010). Although these particles are typically well liberated, due to their very low mass and inertia, the collision efficiency with air bubbles is low as a result of the inability of particles to penetrate the liquid streamlines around bubbles. Hence the probability of contact is often regarded as the ratedetermining step in flotation of ultrafine particles. Introducing more power into conventional flotation machines is likely to solve only part of the problem, as conventional mechanisms are effective only to a point in terms of shear and micro-turbulence. Further challenges are posed by the treatment of low-grade or oxidised tailings dump material, where valuables are passivated due to prolonged exposure to the atmosphere or slimes. Over the years, various mitigating strategies have been investigated, including the use of dissolved air flotation (Martinez-Gomez et al., 2013; Calgaroto et al., 2015), shear flocculation (Subrahmanyam and Forssberg, 1990), seed or carrier flotation (Tabosa and Rubio, 2010), sonication to clean particle surfaces (Aldrich and Feng, 1999; Newell et al., 2006), high intensity conditioning (Bulatovic and Salter, 1989; Chen et al., 1999; Tabosa and Rubio, 2010), and various electrochemical approaches such as changing Eh in order to promote formation of dixanthogen, dissolution of oxidation products by lowering the pH, activation by sulphidisation (Newell et al., 2006; Becker et al., 2014), and the use of alternative collectors."

Jan 1, 2018

By Matveyeva Tamara

The main deposits of gold-sulfide ores of Russia are characterized as refractory raw material with the non-uniform finely-interspersed sulfide mineralization, submicron gold, the low gold content (3-5 ppm) and non-uniform distribution of the gold associated with pyrite and arsenopyrite. These ores show low indicators of extraction of gold and silver at cyanidation. Flotation is one of the basic technological procedures of processing of gold sulfide ores however simultaneous presence of pyrite and arsenopyrite and lack of effective methods of their selection constrains application possibility of flotation schemes because of rigid requirements to flotation concentrates under the arsenic content and practically excludes smelting of pyrite concentrate. The main losses of precious metals at flotation technologically are concentrated in thin classes (up to 15 %) demonstrating an inefficiency of standard reagent modes. For an estimation of expediency and possibility of application of selective flotation of pyrite and arsenopyrite a scientific substantiation of the mechanism and criteria of selection of gold-bearing ferrous sulfides of various material structure is developed and for difficultly divided pairs of sulfides with close technological properties the new selective reagents providing effective extraction of gold from hard-to-beneficiate ores are designed. The original technique for modifying surface composition of natural sulfides by nano-sized Au is worked out and the mechanism of selective adsorption of new reagents ? oxypropyl ester of diethyl-dithiocarbamatic acid (OPDTC) and oak bark extract (OBE) on Au-bearing sulfide minerals is revealed. Formation of almost insoluble OPDTC-Au compounds is defined by methods of scanning electronic microscopy (SEM) and UV-spectroscopy. Application of developed reagent modes using new reagents have been tested in laboratory conditions at flotation gold-sulfide ores samples and collective concentrate probes providing high extraction of gold and improved quality of the concentrate (less than 2 % As). Keywords: pyrite, arsenopyrite, selective flotation, flotation reagents adsorption, complex-forming, gold recovery.

Sep 1, 2012

By I. Silin, H. Wotruba, J. Huben, A. Ognyanova

"With increasing shortage of raw materials, the beneficiation of ultra-fine ores will play a larger role in the near future. Many established process technologies do not yield satisfactory separation results for ultra-fine materials. Without selectivity, high-grade concentrates cannot be produced. The material at hand is a taconite which had to be ground to d(90) = 25 µm to guarantee liberation of the iron oxides. The comminution was done by High Pressure Grinding Roll (HPGR) and resulted in smooth surfaces and clear grain boundaries. This is an indication of selective grinding and mineral liberation. Further processing steps included selective desliming, magnetic separation as well as reverse flotation. INTRODUCTION During the last centuries, the processing of iron ores became increasingly important. The coarse-grained, so-called lump ores that are ready for direct usage in blast furnaces without further processing are becoming gradually less abundant. The processing of ultra-fine-grained ores, which in addition require a complex ore beneficiation due to the composition of the material, will progressively gain relevance with increasing resource shortages in the future (Arvidson, 2013). The term “ultra-fine” does not hold a precise definition in mineral processing. In this paper, “ultra-fine-grained” ores are defined by the required grind size for full liberation smaller than 20 µm. Many established mineral processing technologies do not yield satisfactory separation results for ultra-fine materials. Thus, they are limited in their application to produce high-grade concentrates suitable for sintering and pelletizing for direct reduction processes. The production of a high-grade iron concentrate (over 68% Fe) with low silica content (under 2.5% SiO2) is possible from both magnetite and hematite containing ore. In addition to the mineral processing technologies (magnetic and gravity separation, flotation), technologies for the liberation of fine-grained iron ores need to be developed and improved. In contrast to the conventional wet grinding circuit by means of tumbling mills, several future trends in dry and wet grinding and regrinding are already in use. These include technologies such as vibration mills (Palla®Mill), stirred media mills (Vertimill®), vertical roller mills (Loesche) and high-pressure grinding rolls (HPGR) (Jankovic, 2015). This study preliminary investigated the mineral processing of a low-grade, ultra-fine-grained, complex iron ore in a laboratory scale after dry grinding by HPGR to 90% < 25 µm without consideration of the grinding, milling, energy and classification cost."

Jan 1, 2018