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By Z. M. Dai

Microorganisms in AMD (Acid Mine Drainage) were enriched in 9K culture medium. The enrichment was applied to leach copper pyrite after the microbial community structure and metabolism was stable. Before and after bioleaching, the microbial DNA was extracted and applied to RFLP (restricted fragment length polymorphism) analysis to demonstrate the relationship between the leaching efficiency and the change of microbial community. Atomic absorption spectrometry results showed that when concentration of the pulp was 10% and pH were 1.5, 2.0 and 2.5, the leaching rate were 56%, 57% and 34% on the 18th day respectively. These results indicated that the rise of pH resulted in the decrease of leaching rate. In lower pH condition, the growth of microbe was faster: when pH was 1.5, the microbial cell number reached to 1.4×107cells/mL on the 9th day; while pH was 2.5, the microbial cell number decreased to 4×106cells/mL. The analysis of microbial community structure showed that Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans were dominant species before bioleaching (account for 43% and 32% respectively). And after bioleaching, these two species were still dominant when the initial bioleaching pH were1.5 and 2.0. While the initial bioleaching pH was 2.5, the proportion of these two species decreased. These results demonstrated that the initial bioleaching pH would affect the microbial community structure in bioleaching system at room temperature, and this affect could lead to different copper pyrites bioleaching efficiency.

Jan 1, 2014

As a leading global company in the mining sector, we are committed to sustainable development. To this end, we invest in the responsible, integrated management of economic, environmental and social issues. Vale?s objective is for our businesses to produce local, regional and global prosperity, enabling the construction of a positive legacy throughout the lifecycle of our activities. This covers everything from talking with stakeholders and preventing failures to complying with legislation, paying constant attention to environmental issues and respecting ethics in business. Keywords: sustainable development

Sep 1, 2012

By Gustav Hawlitschek, Henrique Kahn, Carina Ulsen, Renato Contessotto

"The problems related to waste dumping increased with the growth and development of large cities. In the U.K., more than 50% of landfill waste comes from construction use and the U.S. alone produces around 200 to 300 million tons of CDW annually. The exhaustion of natural sand deposits close to large urban centres stimulates the recycling of construction and demolition waste for the production of recycled aggregates as a construction material. This paper presents a flowchart for the production of recycled sand with low porosity and regular shape by the selective removal of the cement paste attached to recycled aggregates. The products characterization was carried out by the determination of the particle size and shape distribution, chemical and mineralogical composition, heavy liquid mineral separation and quantification of all present phases using a scanning electron microscopy with automated image analysis (SEM-MLA). The comminution of CDW by vertical shaft impact crusher made possible the production of a lower porosity recycled sand. The heavy liquid mineral separation showed that the proportion of low porous phases (d>2.5 g/cm3) is very high, exceeding 70% of the weight, encouraging further mineral processing separation to obtain a fine recycled aggregate with less cement paste content. The mineralogical characterization by XRD and SEM indicates that the main phases are tectosilicates, phyllosilicates and calcite which one can be attributed to both calcareous aggregate and cement paste. The precise quantification of cement paste and calcite/dolomite alone is just possible by automated image analysis. The characterization results demonstrated that proportion of phases with no cement paste attached increases progressively in denser products. The results of heavy liquid separations and image analysis are comparable and automated image analysis can be used for the characterization of phase content and their main associations."

Jan 1, 2014

By A. Muhammad, A. Abdelaal, M. EL Salmawy

"Energy is vital for economic growth and sustainable development. Greater efforts are being devoted to developing unconventional energy resources such as oil shale as an alternative promising source of oil or solid fuel supplement. The main object of this contribution is to determine the upgrade potential of El-Nakheil oil shale using froth flotation. Samples were prepared by comminution followed by sieving into different size fractions. The flotation behavior of the material and extent of cleaning was studied with respect to nonionic and ionic collectors of anionic and cationic types. It was found that the organic rich portions could not be rendered sufficiently hydrophobic by the used collectors and selectivity towards surfactant was very low."

Jan 1, 2014

By S. Jeon, N. Hiroyoshi, N. Kitajima, S. Tanaka, M. Ito, R. Pongsumrankul, C. B. Tabelin

"Gold (Au) extraction is inefficient when crushed waste mobile phones (WMPs) are directly leached by ammonium thiosulfate likely because of the cementation/precipitation of dissolved Au in the presence of base metals like copper (Cu), iron (Fe) and/or aluminum (Al). This study applied physical separation techniques to remove base metals as well as plastics and concentrate the Au containing fractions from WMPs prior to leaching. Coarse fraction of crushed WMP (+2-5.6 mm) was pretreated by jig and magnetic separation to remove plastics and base metals like Fe, Cu, and Al, while the fine fraction (-2 mm) was pretreated by flotation, and float and sink separation. The leaching results showed that Au extraction increased in both of the size fractions. In the coarse fraction, Au extraction increased by as much as 2-fold after pretreated (from 4 to 7%). Improvement of Au extraction in the fine fractions after pretreatments were even more dramatic. Au extraction increased from 4 to 61%. These results indicate that physical pretreatment to remove co-existing common metals and plastics is effective to improve Au extraction from WMPs. INTRODUCTION Global sales of mobile phones are expected to increase steadily in the foreseeable future because a lot of people buy newer phones with upgraded and more advanced functions almost every two years, which leads to the higher generation of waste mobile phones (WMPs). WMPs contain a wide variety of materials including plastics, glasses, base metals and precious metals such as gold (Au). Among all the valuable materials in WMPs, Au accounts for over 80% of its total metal price (Park et al., 2017), so recovery of Au from WMPs is needed."

Jan 1, 2018

By Hamid-Reza Manouchehri

"Sustainability calls for maintenance, rational use and enhancement of natural resources as well as balance consideration of ecology, economy, and social justice. The challenges in mining industry call for a sustained global effort using the leverage of available technologies and emerging new technologies. The industry uses significant amount of energy with the highest portion in comminution. To conserve energy, attempts have been made to improve the efficiency of the conventional crushing and grinding equipment. Nevertheless, the new and energy efficient comminution technologies are favorable through a longer term strategy. Since crushers are more energy efficient than mills, it is logic to conduct part of milling, in the crushing stage. After years of research and development, Sandvik introduces a new crushing technology, VibroconeTM, to change traditional crushing concepts. The new crushing device is able to crush and grind particles with a higher reduction ratio, more than two fold, than that of conventional crushers. By implementation of the new technology, a suitable feed size for milling can be provided to conserve energy as well as media and liner consumption, to reduce milling circulating load or increase mill capacity. There are other benefits associated with this machine, one of them being providing a higher surface area. This paper discusses the performance of the machine and its applications for comminuting different ores."

Jan 1, 2014

Incomplete liberation of mineral particles is one of the key factors limiting the performance of industrial flotation circuits. This work aims to quantify the relationship between different breakage modes and how these affect mineral liberation properties. A copper porphyry (bornite) ore sample was subjected to breakage using a piston-die compression unit and an impact mill. The particles produced as a result of each mode of breakage were then characterised using Mineral Liberation Analysis (MLA) to quantify the mineralogical and liberation properties of the progeny particles. The impact mill was found to produce bornite that was finer grained relative to the host particles. In con-trast, bornite discharged from the piston-die unit closely followed the size distribution of the host particles and was retained to a greater extent in the larger/intermediate size fractions. The results provide insight into what breakage methods are optimal for the purposes of downstream separation.

Jan 1, 2014

By Tohru Kamo, Shigeyuki Katano, Hideki Nakagome, Maiko Adachi, Shingo Nakamura, Kaneshi Taniguchi, Zar Zar Hlaing, Takaaki Wajima

Tantalum capacitor is a small-sized and has large capacity, and is indispensable for electric equipment. The demand increases year by year, and a quite large number of used tantalum capacitors is generated. Recovery of tantalum from tantalum condenser is recently important since production of tantalum have not been stable for the price and the quality. However, recovery of tantalum from tantalum-condenser is difficult since tantalum parts strongly cover with the flame retardant resin made of halogenated compound (mold resin). This research investigated recovery of tantalum parts from tantalum condenser using steam gasification with mixed molten carbonate. Mixed molten carbonate (Na2CO3:K2CO3:Li2CO3 = 1:1:1) (3 g) put into the reactor, and heated with electric furnace while flowing nitrogen (160 mL/min) and steam (1 mL/min) warmed by heater. After heating to setting temperature (450 - 650 oC), tantalum condenser (3 g) was put into the reactor, heated for 5-10 min, and then cooled to room temperature to recover the reacted capacitor by filtration after treating with distilled water. At relatively low temperature (550 oC) heating for 10 min, mold resin can be decomposed by using steam gasification with mixed molten carbonate, in comparison with using pyrolysis and steam gasification without carbonate, and decomposition reaction occurred over 500 oC by using steam gasification with mixed carbonate. Recovery of tantalum parts from capacitor is successful using steam gasification with mixed molten carbonate at 530 oC for 5 min, due to the effective decomposition and removal of mold resin from capacitor. Furthermore, most halogen gas generated from decomposition of mold resin can be trapped in molten carbonate not to exhaust halogen gas. These results suggested that recovery process of tantalum parts from used condenser using steam gasification with mixed molten carbonate is expected as a feasible way to recycle the rare metal in electric equipment.

Jan 1, 2014

By Arkady Senchenko, Yuri G. Seredkin, Alexander Aksenov

"This paper describes the development of efficient technology for the treatment of complex ores containing gold and copper as major valuable components, where silver is present as well. Copper is mostly represented by oxidized minerals in these ores; however, copper sulfides are also present. Gold is present in its free form and in associations with oxidized and sulfide minerals; silver usually accompanies gold. Complex composition of the ore requires complex solutions for their treatment. The results of searching for the techniques to recover valuable components are described in this paper. Gravity methods allow for free gold recovery, flotation methods allow one to recover major part of copper and precious metals in associations; and in the result of leaching process additional amount of copper, gold and silver is reported to solution. Combining all these methods help achieving high levels of valuable components recovery. When implementing a combined technological flowsheet about 80 % of copper goes to concentrates from gravity and flotation of sulfide and oxidized copper minerals; and sulfuric acid leaching allows increasing total copper recovery up to 90 % and higher. Major part of precious metals (up to 90 % of gold and 80 % of silver) is recovered to these concentrates, and after hydrometallurgical treatment it is possible to increase gold recovery up to 96 %, silver recovery - up to 90 %. The suggested technology helps solving the problem of precious metals recovery from complex gold-copper ores, and allows treatment of the ore with different proportion of sulfide and oxidized minerals, and at different valuable components grade."

Jan 1, 2014

By Ray Everson, Henry Kasaini

"Adsorption of Pd (II) anions on the surface of activated carbon (Norit 0.8) occurred at high proton concentration (0.01 – 2.5M, HCl) in the feed and averaged 27 mg/g. The adsorption process was interpreted in terms of surface ionisation and adsorption model. Enthalpy of adsorption averaged 0.4 kJ/mole indicative of an instantaneous physical adsorption process. We found that the Toth isotherm fit the adsorption data fairly accurately. A combination of the Langmuir and Freundlich equations yields an effective three-parameter Toth equation (1) which is frequently used to describe adsorption on heterogeneous surfaces.Figure 1 shows the comparison between experimental results and the model isotherms. We found that Langmuir isotherms underestimated the adsorption capacity on the porous surface while the Freundlich isotherm overestimated adsorption. Furthermore, the surface coverage at equilibrium was well described by both the Langmuir and Toth isotherms. But, Freundlich isotherm predicted a surface fraction coverage that was higher than unit. Based on better prediction of surface coverage and a reasonable fit to adsorption data, we concluded that the Toth isotherm best described the adsorption data of palladium. The adsorption process was limited by mass transfer resistance through the external film. We estimated the rate constant from equation (2), where e, ?b, and rp are porosity, fluid density and particle radius, respectively"

Jan 1, 2003

By Ricardo Duque-Soto, Gonzalo Montes-Atenas

The depletion of water resources has posed an enormous challenge to the continuity of many mine sites, particularly those located in arid zones worldwide. In Chile, the use of seawater has been foreseen as one possibility to solve this problem. Nevertheless, the direct use of high ionic strength solutions such as those present in the sea has been found to have some drawbacks. Specifically, rhe extraction of copper from complex ores using high ionic strength solutions such as that of seawater has become one of the most relevant topics in the field of copper hydrometallurgy. This study aims to determine the effect of the degree of salinity on copper extraction kinetics in mixed oxide-sulfide ores. A leach protocol was implemented to study the extraction kinetics, varying the degree of salinity of the medium and the temperature. A thermodynamic model was developed to explain differences in the metal extraction. It was found that the ionic strength impacted positively the copper extraction, probably due to the reduction of the effective concentration in solution due to ionic interactions enhancing the diffusive mass transport of copper ions. This effect is observed to be enhanced when up to an overall salinity values close to 20gpl.

Jan 1, 2014

By P. Somasundaran

While sustainability itself needs to be redefined in a selfless way, methods of measuring and optimizing it also need to be reformulated. Gone are the days when we had the luxury of abundant resources and the freedom to extract values in self-centered ways. In the past, focus has been mostly on reagent performance, processing operations, and upgrading of tools to maximize rather than optimize value extraction from the earth's crust. Today we as extractors face a new set of challenges that include value separation from low quality resources including wastes, but within the energy, environment, and societal constraints. Development of such technology depends on understanding the role of entities and concepts such as bio-molecular interactions at surfaces, forces involved in inter-granular versus intra-granular fracture in new fragmentation methods, robotic in-situ or extraterrestrial mining, exploiting new membrane and nano technology, use of new sensors and actuators for detection and separation and computation capabilities for faster and economical processing. Equally importantly, we need to communicate with everyone what we foresee and anticipate when we extrapolate the type-performance-cost relationship of ores to the era ahead of us and establish viable schemes for ecological survival. Keywords: sustainable mineral extraction

Sep 1, 2012

By Rodrigo Ladrón, Gonzalo Rund, Gonzalo Montes-Atenas

Modelling ore comminution processes have been a highly fruitful scientific topic. The models have been proved to be largely dependent on the selected comminution technology. Among them, semiautogenous (SAG) mill technology has been widespread implemented in plants but no complete understanding of the mechanisms involved in the process is available. Tracing back in history, SAG models considered only some granulometric cut sizes such as the t10 and attempted to relate these parameters with the energy involved in the impact between particles. Other models evolved towards incorporating physical properties of the material being ground and the mill operating conditions. These material properties have assisted to obtain a more comprehensive description of the breakage mechanisms; nevertheless, the gathering of all known parameters still have not delivered a model able to describe the process. This may be a result of emergent properties or phenomena originated from interactions inside the process which are hard to predict turning the size reduction operation into a complex system. Cellular automata provide one answer to describe complex systems by following simple rules. The aim of this research work is to establish the preliminary rules of thumbs enabling the implementation of cellular automata able to predict the particle size distribution at the exit of a SAG mill. The methodology involved developing a simple 2D model of a ROM sample. Plant data from two mine sites were correctly described by a set of three rules: two rules describing the particle reduction and one rule associated with material transport across the mill. Further analysis related with expanding this model to 3D and its impact on the liberation of valuable material is also discussed.

Jan 1, 2014

By P. Radziszewski

In comminution research, ore breakage and wear are usually studied independently of one another. Much of this is due to the fact that wear is usually a slow process compared to ore kage. However, the abrasion wheel test used to determine the abrasive wear contribution to total steel media wear provides the opportunity to study not only abrasive wear and friction but also ore breakage. In this paper, we will explore the use of the abrasion wheel wear test device to study abrasive wear, friction and ore breakage using standard Ottawa foundry sand. We will look into the feasibility of applying the work index as well as t10methodologies to this test set-up. We will also look at how the work index results evolve with abrasive wear and friction. We will then discuss the merits of pursuing the use of this abrasion wheel test for not only wear characterization but also breakage characterization.

Jan 1, 2014

By Gökçe Törenli, Okay Tutar

"Predicting the performance of plant-scale comminution circuits is essential to monitor the energy use and product size distribution, allowing us to control and optimize the whole process. In the light of this issue, with the assist of recent technologies, simulation techniques utilize the chance of putting the theory into practice in the most accurate way. For this purpose, this study aims to evaluate and optimize the efficiency of a plant-scale ball mill circuit by using perfect-mixing ball mill model on a simulation environment. The comminution circuit is selected from a specific copper-ore processing plant in Turkey. The essential parameters which are required for this study such as fresh feed Bond work index, size distribution etc. are determined by laboratory experiments. The forecasted data which are calculated by third-party software will be compared by the industrial operating data, in order to determine the performance of comminution circuit. In addition to that, this methodology provides a greater ability to analyse, optimize and understand the comminution circuit of ore treatment plant. The authors believe this work will provide supplementary data for further studies on simulation and subsequent optimization of comminution circuits.INTRODUCTION By the assist of mathematical models of the grinding mills and classifiers, simulation of the grinding circuits become more common in comminution because it is relatively economical and able to consider many variables simultaneously. It’s proceeds depends on the accuracy of the models and capability of reflect real operations. Computer-based simulation studies would provide the quantified information about the effects of the proposed changes on the comminution circuit performance in terms of size distribution, mass flow rates, equipment efficiency etc. Then the mentioned data used in order to check the suitability of the current equipment to the modified conditions, and for equipment selection. The outputs of circuit could also be used to estimate downstream flotation circuit performance because the general aim in this study is to The aim of the study is to investigate optimum operating variables and achieve p(80) size of 57 µm and 64 % of -36 µm particle in hydrocyclone overflow stream, which is optimum for that porphyritic copper ore for best concentrate recovery after flotation process in specific copper ore comminution circuit by using modelling and simulation techniques. Sampling survey was carried on the fine ore bin in order to perform Bond work index test and determine work index value (Wi). Thereafter mass balancing, using the size distribution data and tonnages, models for ball mills and hydrocyclone were developed. Finally, the circuit performance were investigated by computer simulations via JKSimMet software."

Jan 1, 2018

By M. Özer, G. Önal, F. Arslan

"The use of ultrasonic in industrial processes has increased during the last few years. Ultrasonic vibrations are used in sieving, grinding, ore washing, cleaning, and flotation in mineral industry. There are also some attempts for the utilization of ultrasonic treatment in separation and removal of fine particles from gases and liquids. In Kalemaden A.S. (Turkey) four different types of clay mixtures (1. A mixture of clays from Balikesir-Düvertepe and Istanbul-Sile, 2. A mixture of clays from Ukrania and Balikesir-Düvertepe, 3. Sögüt-Kadikelimesi, 4. A mixture of clays from Sögüt and Istanbul-Sile) and kaolin from Balikesir-Düvertepe (Turkey) are concentrated before their use in ceramic production. Dewatering is the important step in those types of concentration plants. Sedimentation of concentrated clay has always been difficult and taken long times due to their nature and having small particle sizes. Flocculants can be used to enhance the sedimentation, but they are not preferred by the ceramic industry since they affect the quality of ceramic products. For this purpose, ultrasonic treatment is used in the sedimentation of clays mentioned above for solving the problems encountered related to the ceramic industry and promising results were obtained.Kaolin sample, subjected to this experimental study, from Balikesir-Düvertepe region of Turkey was brought from the plant as a pulp in containers and throughly mixed with a stirrer before sedimentation experiments. A two liter graduated cylinder and an ultrasonic bath (with 25 kHz frequency and 0.5 KW power) were utilized in the tests. Superfloc A-120 (1% concentration) was used as a flocculant. The settling distance was reported against the settling time during the experiments. Initial and final pulp densities were also determined. The effects of several parameters such as pulp density, flocculant addition, and ultrasonic treatment on the sedimentation of kaolin were investigated and the results are represented in terms of settling distance versus settling time."

Jan 1, 2003

By Gülay Bulut, Mustafa Özer, Yunus Emre Benkli, Olgaç Kangal, Istanbul Technical University, Mustafa Tarkan

"Zeolites are naturally occurring as hydrated aluminosilicate minerals. They belong to the class of minerals known as “tectosilicates” and are related to the common minerals feldspar and quartz. Seven natural zeolites that occur in large, commercially exploitable deposits, are: clinoptilolite, chabazite, mordenite, phillipsite, erionite, analcite, and ferrierite. Among them, clinoptilolite is the most abundant one and is not the best known, but is one of the more useful natural zeolite. Clinoptilolite [(Na3K3) (Al6Si30O72) 24 H2O] is very closely related to heulandite and is currently being considered for disuse it self as it may just be a variety of heulandite. It differs from heulandite significantly only in its enrichment in potassium and slightly more silica and it is argued that a separate mineral is not needed.There are large zeolite deposits in western part of Turkey. The sample used in this study was taken from the Gördes region of these deposits. Screen, chemical, XRD and mineralogical analyses were used to determine properties of the natural zeolite sample used in this work.According to the size distribution of the sample, it is found that the zeolite sample used in this study is below 1 mm in size and almost 80% of it is below 0.5 mm. X-Ray Diffraction (XRD) and mineralogical analyses show that the natural zeolite is found to be in the forms of clinoptilolite and heulandite. Clinoptilolite forms as a devitrification product of volcanic glass in tuffs. Quartz, clay minerals, orthoclase, plagioclase, biotite, seruzite-muskovite and epidote were observed as impurities. XRD analysis also shows that the sample contains approximately 58-60% clinoptilolite, 5% quartz, 5% feldspar, 10% smectite, 5- 10% illite and mica and remaining volcanic tuffs. Several types of mineral processing methods were performed in order to remove impurities from the natural zeolite sample to produce high purity zeolite. Gravity separation methods such as shaking table and superpanner were carried out for separating heavy minerals, while high intensity dry magnetic separation was used for discarding magnetic minerals."

Jan 1, 2003

By D. Saramak

"High-pressure grinding technology is considered as one of the most efficient techniques of ore comminution, especially in terms of energy consumption. HPGR devices has been utilized in many mining-related industrial sectors, including iron and non-ferrous metal ores processing (copper, platinum, gold), as well as cement and limestone flour production. Even though the technology well known (introduced into mineral processing circuits in 80’s), there are still examples of ineffective operation of HPGR devices. This is a result of improper application of HPGR into individual crushing circuit. The purpose of the paper was to analyze selected effects achieved in HPGR on the course and effectiveness of beneficiation operations. Investigations were carried out for copper ore, and investigative programme was run for different values of HPGR pressing force, as well as changeable ore characteristics (content of fine size fractions, material moisture). All crushing products were then treated in flotation process, in order to determine useful mineral recovery. Results of investigations show that HPGR operating pressure influences the metal recovery in proportional way, however too extensive pressure values have relatively lower impact on increasing of the metal recovery. Particle size distribution of HPGR feed and its moisture have lower influence on recovery level than HPGR pressure, but too extensive moisture content influences the higher energy consumption of the roller press, together with less effective comminution. The second aspect raised in the paper was a possibility to control and optimize the HPGR-based circuit. There were presented the proposed approach to adjustment of HPGR operating parameters that enables the higher metal recovery.INTRODUCTION The high-pressure grinding technology, invented and developed by Professor Schoenert in 70’s (Schoenert, 1979), is currently regarded as one of the most efficient methods of hard ore comminution. Since then the technology was introduced into raw materials treatment circuits in many mining and mining-related industrial sectors, including iron and non-ferrous metal ores processing (copper, platinum, gold), as well as cement and limestone flour production. Considerable number of works concerning modeling and optimization of HPGR operation were also presented (Daniel & Morell, 2004, Tavares, 2005, Saramak, 2012, Saramak & Kleiv, 2013). Nowadays high-pressure grinding rolls devices are considered as well know technology with over 500 sold machines, according to various sources."

Jan 1, 2018

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

Results of flotation process combined with atmospheric leaching and high pressure leaching for recovery of copper from low-grade silicate-copper ore have been presented in this study. The low-grade copper ore contains a small amount of copper (0.42 mass %), iron (4.6 mass %), and silicon (38.3 mass%) and among many other metals (Al, Ca, K, Mg, Na, Ti and S). The main mineralogical constituents of the copper ore are calcium aluminosilicate (Ca(Al2Si2O8), amesite (Mg2Al2SiO5(OH)4) and gypsum (CaSO4×H2O), and quartz (SiO2) as resulted from the alteration of an igneous rock. This study has shown that about 92 % of copper can be recovered with a maximum copper grade of 4.2 mass% in a froth after 15 minutes of flotation at pH 8.5 when used potassium amyl xanthate as a collector, MIBC and Dow-froth 250 as frothers and calcium hydroxide as a pH adjuster. The images of bubbles in the cell during flotation process were recorded using a high-speed camera. The froth concentrate with average copper grade of 2.0 mass% was further processed by atmospheric leaching with a solution of sulphuric acid and hydrochloric acid, respectively and high pressure leaching with sulphuric acid solution. As a result, leaching rate of copper reached about 60 % in an atmospheric leaching with sulphuric and hydrochloric acid respectively, whereas the rate can reach more than 70 % by autoclave leaching at high pressure under the controlled condition. A process to recover of copper from its low-grade ore can be developed by optimization of flotation combined with acid leaching.

Jan 1, 2014

By M. E. Ramírez

In this research bioleaching or extraction of iron present in a kaolin from La Virgen mine, Anti-oquia/Colombia, was carried out. Organic acids produced in SF with Aspergillus niger were used in the process. The fermentation process was carried out in 3 L aerobic stirred bioreactors, at a temperature of 30 °C, a stirrerd speed of 700 rpm, an initial pH of 4 and a fermentation time variable between one to 8 days, obtaining broth fermentation samples daily per bioreactor. For iron extraction, fermented broth from second to sixth day of fermentation was evaluated and it was found that the fermentation broth of the third day showed a larger potential for iron removal, 786 ppm, by using kaolin with an initial iron content of 1401 ppm. A set of tests using commercial organics acids such as citric acid and oxalic were carried out because those were found in the fermentation broth and it was found that oxalic acid presented three times more iron removal than citric acid.

Jan 1, 2014