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By Z. Zhang, X. -G. Chen, F. Breton, A. Arici

"The microstructure of Al-10Si-0.3Mg-0.5Mn alloy with 0.27% Zr and 0.19% V addition was quantitatively analysed and compared to the base material. The addition of Zr and V in the AlSi10Mg alloy exhibit a beneficial effect on the Si modification, resulting in the reduction of the size of eutectic Si particles on both as-cast and T6 conditions. The quantitative image analysis results show that the Zr and V addition and T6 treatment can reduce the size of the intermetallic phases. In addition, the presence of Zr and V is favour to the partial dissolution of the intermetallic phases during the T6 treatment. Different heat treatment procedures were tested to optimize treatment parameters. The mechanical properties of the alloys were evaluated using hardness measurements and tensile tests. The results show that the addition of Zr and V can remarkably improve the mechanical properties on as-cast and T6-treated conditions. The correlation between the microstructure and mechanical properties of the alloys is discussed.INTRODUCTION Al-Si-Mg foundry alloys have been widely used in automotive and aerospace industries due to their high strength-to-weight ratio, heat-treatable capability and excellent castability. The alloying elements such as Cu, Mn, Fe are traditionally added into Al-Si-Mg alloys to improve their mechanical properties (Mohamed, Samuel, Samuel & Doty, 2009). In recent years, the attention has been paid to the effect of the transition elements such as Zr, V, Ti, etc, as minor alloying additives, on the properties of aluminum alloys (Elhadari, Patel, Chen, & Kasprzak, 2011; Kasprzak, Amirkhiz & Niewczas, 2014; Shaha, Czerwinski, Kasprzak, Friedman & Chen, 2015; Shaha, Czerwinski, Kasprzak & Chen, 2014; Mahmudi, Sepehrband, Ghasemi & 2006; Meng, Cui, Zhao & Zuo, 2013). Kasprzak et al., (2014) and Shaha et al., (2015) reported that additions of Zr, V, and Ti in Al-Si-Cu-Mg cast alloys can improve the alloy mechanical properties at high temperature by forming stable intermetallics and precipitates on as-cast and heat treatment conditions. On the other hand, the mechanical properties of near-eutectic and eutectic Al–Si cast alloys depend not only on the chemical composition but also, even more importantly, on microstructural features such as the morphology and size of eutectic silicon and intermetallic particles, which are present on both as-cast and heat treatment conditions (Mohamed et al., 2009). However, there is rather limited information on the effect of Zr and V on the microstructure features and mechanical properties of near-eutectic Al-Si-Mg cast alloys."

Jan 1, 2018

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Ferrihydrite is ubiquitous in soils, groundwater and aquatic sediments and is usually classified as "2-line" or "6-line" according to the number of diffuse XRD peaks. It has high surface area and reactivity; therefore, it may serve as a sink for sequestering trace metals, metalloids and organic matters via adsorption and co-precipitation. Although considerable attention was paid to the transformation process of this thermodynamically metastable solid, there are still some controversies on the mechanisms of the formation of goethite or hematite from the ferrihydrite precursor. This work systematically investigated the transformation of 2-line ferrihydrite produced by using different neutralization regent (CaO vs. NaOH) into crystalline products at different pHs (4, 7 and 8), three temperatures (25, 40, 75 °C) and in different media (sulfate vs. nitrate). X-ray diffraction (XRD), Raman, Fourier transform infrared spectroscopy (FTIR) and chemical extraction were employed to characterize the transformed solids as well as the redistribution of Fe between the amorphous and more crystalline phases. The results showed that the transformation product in nitrate media was hematite (major) and goethite (minor), which was independent of pH, temperature or neutralization reagent. In sulfate media, goethite was the dominant solid under slightly acidic conditions (pH 4) with 6-line ferrihydrite as the intermediate product, whereas neutral to slightly alkaline conditions still favor the formation of hematite. Chemical extraction results indicated that there was only ~3 % of amorphous phase detectable after aging at 25 °C for 280 days at slight acidic pH. In contrast,~70 % of the iron remained as an amorphous phase under neutral to slightly alkaline conditions. The results suggested that the pH as well as the reaction media (sulfate ion) plays an important role in the 2-line ferrihydrite transformation process.

Jan 1, 2016

By G. R. Haiden, E. Henderson

"An LHD teleoperation and guidance system, developed at the Ontario Division of Inco Limited, has been demonstrated in operation at Copper Cliff North Mine (CCNM) since late September, 1993. The tests performed to date have evaluated the feasibility and production viability of multiple LHD operation, from surface by one operator.The systems technology required to accomplish this consists of an electronic monitoring and control package mounted on the LHD; a high bandwidth mining computer network capable of providing radio frequency coverage; and an operator control console which provides an operator workstation for multiple LHD operation.This paper discusses the systems required to accomplish the task of LHD teleoperation and guidance, the benefits of multiple machine operation and future research and development directions. IntroductionSince underground mining began, persolU1el have entered the mine workings to mine ore. Today, however, the rapid advancement of modem telecommunications, computer hardware and software technology has opened the door to remote mining technology that was considered unfeasible a few years ago. This paper discusses the ingredients of remote mining technology that have been developed at Inco Limited.Figure I represents an historical view of the application of electronics to LHD operation at Inco Limited. In 1980, the first radio remote controls for the operation of LI-IDs in large open stopes were tested. The successful application of this technology at Inco went hand-in-hand with the development and application of the Vertical Crater Retreat mining method. The combination of these two advances had a very positive effect on the productivity in the mid-eighties at Inco. In 1991, the Mines Research Department of the Ontario Division advanced remote control technology by developing a high capacity underground mining telecommunications system. This system is capable of moving voice, data and video information throughout the mine workings. The system is based on broadband communication technology found in most automated factories, with the added benefit of providing the information to and from mobile equipment through radio interfaces. The first test of the system consisted of an operator teleoperating a single LHD (on the 3000 ft level) from the surface. The next test on September 13, 1993, demonstrated the first production application of multiple LHDs being run from surface with a single operator."

Jan 1, 1994

By Norm Clegg

The Plant Engineering and Maintenance Association of Canada PEMAC is a national, not-for-profit industry association for plant and facility maintenance, engineering and physical asset management in all industry sectors in Canada. Our mission is to provide professional development for our members and the profession in Canada

Feb 1, 2008

By M. Coleman, M. E. Reed

The control of feed delivery quality to the flash furnace remains an unsolved problem. Many operations around the world still have limited control of feed quality to their flash furnace. Schenck Process and WorleyParsons continue to work towards the ‘holy grail’ of simple quality feed delivering both radial feed distribution and pulseless feed delivery. Ten years ago they joined forces to offer a system based on then Clyde Process RotoFeed system which could deliver ground level installation, online mixing of materials, pulseless feeding direct to the burner, with good radial distribution. Unfortunately, this proved to be too large a step for the Flash Smelting community and met with resistance from the process owners. Since then the community has developed a range of options some of which have been implemented over this period. Despite these improvements there are still areas of concern including safety issues associated with concentrate leaks and spills, uncontrolled variations in feed rate including massive flooding events, intermittent distribution improvement and set up of the burner continues to be trial and error and hard to repeat the success in each burner campaign. These continue to impact flash furnace performance globally on a daily basis. Following the community reticence to pursue the complete solution a number of interim steps are now available to pave the way to the ultimate feed system. The mixing of material has been installed and is delivering line blended materials on a daily basis. This paper will investigate the developments over the last 10 years and discuss the pros and cons of this incremental step process for overall furnace control. INTRODUCTION Schenck Process and WorleyParsons have continued to interact and observe changes in the flash smelting industry and to consider application of the Clyde RotoFeed now incorporated in the Schenck Process ProStreamTM range for delivery of feed directly to the concentrate or matte burner. Schenck Process pneumatic injection from the Clyde Process range, ProStreamTM, utilises two types of volumetric feeders to accurately control the feed of material into an injection pipeline. These are referred to as the RotoFeed and RotoScrew technologies and the choice of feeder type is dependent on the characteristics of the material to be handled. The RotoFeed is generally used for finer, granular and powdered materials which cannot be accurately handled with a screw such as pulverised coal and copper concentrate, whilst the RotoScrew is particularly suited to coarser lump materials, particularly abrasive of cohesive materials like zinc powder, electronic scrap and metal ashes. Both units can operate at high pressures and many systems work at 3 to 10 bar with the occasional system working at 20 or 30bar for carbon to gasifiers. For the Flash furnace the ProStreamTM units can be used to deliver each of the furnace feed materials into a single line, mixing the materials homogeneously and live to the burner.

Jan 1, 2019

By A. A. Lavrinenko, N. I. Gluhova, L. M. Sarkisova, D. V. Makarov

"The investigated sulfide Cu-Ni ores are characterized by low PGE contents and emulgated impregnations of pentlandite and palladium minerals in the main ore-forming mineral pyrrhotite, which hinders their selective separation, requiring a collective flotation of sulfides to concentrate, and hydrometallurgical processing. As revealed by studies of floatability of Pt-Cu-Ni ore in a mixture of butyl xanthate and chelating phosphorus containing reagents, the most effective additive is Aerophine 3416 (a phosphinates mixture) manufactured by Cytec. Using collective flotation with a butyl xanthate – Aerophine 3416 composite in the ratio of 1:3 has afforded to enhance the Pt, Pd, and Ni recovery by 13.6 %, 9.2 %, and 9.4 %, respectively. The optimal ratios of Aerophine 3416 to butyl collector for the collective flotation are the following: 1:1 for Pt and Pd and 3:1 for Ni. The effect of these reagents on the electrode potential and surface hydrophobicity of pyrrhotite, pentlandite, and platinum black has been investigated. The extraction UV spectrophotometry experiments demonstrate that DIBDTPI exists on the pyrrhotite surface mainly in the form of disulfide in weak acid medium and in the form of compounds with Fe on the mineral surface in minute amounts. There appears some disulfide and few amount of (DIBDTPI)2Ni on the surface after interaction of DIBDTPI and pentlanditeINTRODUCTIONXanthates are widely used in flotation of copper-nickel ores containing platinum group metals (PGM) as sulfides collectors which can concentrate the most part of PGM connected with the sulfides. Though xanthates are hardly efficient for flotation of free PGM, the latter are floated more slowly compared to the sulfides of base metals. The reasons for poor floatation of free (mineral) forms of PGM are under-researched, however the key accepted reasons are: fine disseminations of free PGM, insufficient interaction with xanthate and negative influence of blue copperas and sulfur-containing ions which are sulfides oxidation products (Penberthy et al. 1999; Shackleton et al., 2007). That’s why an additional collector, normally dialkyldithiophosphates, is used during flotation of PGM-containing copper-nickel ores. A reagent DP-4 is used for recovery of PGM at Norilsk mining and metallurgical plant. The reagent represents a slightly-soluble organic calcium sulfonate which is given to flotation pulp in the form of water emulsion of 5% - solution in automotive diesel oil."

Jan 1, 2016

By Michel Ruel, Ali Soltanzadeh

This paper describes how to make advanced control choices when difficult processes need improvement. The decision-making process involves choosing between a rules-based approach and a model-based approach as well as weighing benefits and drawbacks, complexity and simplicity, investment and results. This paper will present briefly each solution: basic control, advanced regulatory control, model predictive control and expert systems such as fuzzy logic controllers and neural networks. Three examples are presented: ARC (Advanced Regulatory Control) on pH in a comminution circuit, MPC (Model Predictive Control) for combustible management and FLC (Fuzzy Logic Control) on a Semi Autogenous Mill. The article then proposes a decision tree for selecting the most appropriate approach. A table will compare usage, development, commissioning, maintenance and lifecycle costs for each approach. Finally, conclusions and suggestions will summarize the methodology.

Jan 1, 2014

By Edmond Chow

Shovel bucket blast fragmentation analysis is an alternate way to assess blast performance and its effects on downstream mining processes. A camera is installed on the boom of cable shovels, and the stick of hydraulic shovels. Images are captured automatically as the shovel digs, and are processed to acquire rock size information. The automatic data acquisition makes this method safe to use with minimal manual labour. It also allows for a large set of sample data to be captured from both the surface and the interior of a bench face. The system has been deployed in several mines to provide an objective assessment of blasting performance. Images are captured from their cable or hydraulic shovels. The images are grouped into sets based on the shovel location and time to match the fragmentation to specific blasts. Blast fragmentation reports are created for each blast after reviewing the results. Measuring blast fragmentation from the shovel bucket proves to be an effective alternative for blast performance assessment with unique advantages. The blast fragmentation information has been valuable to the mines, and the mines have begun adopting it into their operations.

May 1, 2011

By J. G. Peacey, G. Csicsovszki

The target of this study was to clarify the role of lead on the dissolution of gold in the (NH4)2S2O3-Cu leaching system via chronopotentiometry, linear sweep voltammetry and chronoamperometry. It was found that the dissolution of gold was significantly increased with lead concentration up to 10 mg/1 Pb in the system of 0.1 M (NH4)2S2O3 and 50 mg/1 Cu. \/oltammograms suggested that the anodic dissolution of gold was virtually independent of lead concentration in the range of 1-10 mg/1 in 0.1 M (NH4)2S2O3 solution while in solutions containing copper as well, addition of lead increased the anodic dissolution of gold.

Jan 1, 2011

By P. R. A. Andrews

"The sillimanite group minerals, kyanite, sillimanite and andalusite are identified as alumino-silicate minerals with the common chemical composition AIP3.Si02' so that each possesses similar physical properties. Kyanite is the most abundant mineral and mainly occurs in Quebec, Ontario and British Columbia; sillimanite occurs in Ontario and Manitoba; and andalusite in Nova Scotia. The main use for the sillimanite-group minerals is in refractory applications for the production of refractory bricks and shapes. In refractory applications, the main performance criterion is the relative percentage of mullite formed within the material during firing. This phase gives a greater degree of resistance to creep deformation and slag attack, and improves the ability of the refractory to withstand high temperatures under load. The beneficiation of refractory silicate minerals has been the subject of many investigations at CANMET, and the former Mines Branch. Eighteen kyanite, two sillimanite, and three andalusite evaluation studies were conducted between 1933 and 1987. A review of some of the more important studies is presented, which includes information concerning mineralogy, beneficiation methods and flotation data."

Jan 1, 1995

By A. Probst, J. A. Finch

"Solids concentration (% solids) profiles and the clear liquid/slurry interface level (mudline) were determined from conductivity measurements in thickeners at Falconbridge' s Strathcona mill (Ni concentrate and non-mag thickeners) and Kidd Creek Division (Cu, Zn concentrates and final tails in the concentrator and thickeners in the Zn plant).The conductivity measurement system consisted of a probe 1.5 m in length with 24 electrode cells, a 24-channel relay, a conductivity meter and a computer. A conductivity profile is collected which locates the mud-line by the sharp change in conductivity. The conductivity measurements are readily converted to solids concentration profiles without need for calibration.The results from the conductivity measurements were compared with those from pressure profiles and direct measurements on local samples obtained using a modified Noranda sampler.It is concluded that the conductivity technique is applicable to locate the mud-line and to estimate the solids concentration profiles in thickeners. This on-line information could improve the operational efficiency of industrial thickeners.INTRODUCTIONAn automated, on-line technique for detecting the clear liquid/slurry interface (or mudline) and the variation in solids concentration with depth would enhance thickener operation and control. In some processes such enhanced control offers significant benefits. For example, in hydrometallurgical operations solid/liquid separation is often the process limiting step. Water treatment plants are increasingly expected to operate remotely and reliable sensing is vital.Current attempts to detect the mud-line include reflection of some signal (e.g. sonar), floats (Dahlstrom, 1985) and measurement of pressure (Rosenblum, 1991), and in one case, natural radioactivity of the solids (Johnston and Simic, 1991). A recent commercial development uses reflection from a vertical array of optical transmitters/sensors, which also gives local solids concentration (BTG Inc., 1991)."

Jan 1, 1993

By M. B. McClenaghan

"The Ontario Geological Survey completed a regional till sampling project between 1984 and 1988 in the Black River Matheson (BRiM) area of northeastern Ontario. The project was designed to aid mineral exploration in the area by documenting the Quaternary stratigraphy and by providing a database of till geochemistry. This paper summarizes the results from the sonic overburden drilling component of the BRiM project carried out in areas of thick drift (> 5 m). Results from till sampling in areas of thinner drift (<5 m) have been presented in a separate paper. Approximately 1100 till samples were collected from 225 sonic drill holes. For each sample, the non-magnetic heavy mineral (>3.3 S.G.) and fine (-250 mesh) till fractions were analyzed geochemically and visible gold grains were recovered by panning.Gold and other multielement geochemical data were plotted using proportional symbols to highlight anomalous areas and to demonstrate how to evaluate and interpret a very large geochemical dataset. Thresholds for identifying anomalous concentrations of Au in till samples, defined using the 95th percentile, are 1500 ppb and 12 ppb for the heavy mineral and fine fractions, respectively. The heavy mineral fraction of older ti1ls and to a lesser extent, Matheson Till, display a number of significant gold anomalies in the study area, which in a few cases, are associated with base metal anomalies. The vertical position of gold anomalies in Matheson and older ti1ls varies from directly on bedrock to several meters above the bedrock surface and can provide information of relative ice transport distances."

Jan 1, 1994

By M. Kaya, A. R. Laplante

"Since the beginning of eighties the use of flotation columns has surged in Canada and abroad; the metallurgical superiority of columns over mechanical cells is in great part due to froth washing, which ensures higher gangue rejection and selectivity. Can wash water, which has proven so beneficial, be used in mechanical cells? Although froth washing technology was widely implemented in Soviet plants for bi tuminuous coal, and alusite, powellite, scheelite, molybdenite, etc. more than 25 years, it has been neglected in the western world. Published data suggest 10 to 15~ increases in grade and/or recovery with wash water in mechanical cells (Klassen and Mokrousov, 1963). There are at least three wash water plant applications in Zaire, Chile, and Canada, but little, if any, published information is available. This research work, which is the first extensive fundamental study related to froth washing in mechanical cells, attempts to answer the questions of how, how much, and where should wash water be added.This project was undertaken in three stages:1. Bench-scale laboratory tests with a 6.5 L Denver cell at McGill using a silica flour and a slime reject from Niobec (St.Honor6).2. Pilot-plant scale tests with a 65 L Denver cell at McGill using the silica flour and a complex Cu-Ni sulphide ore from the Strathcona mill of Falconbridge.3. Plant-scale tests with a bank of 2800 L Denver cells at Falconbridge Ltd. for complex Cu-Ni sulphide ore and Eastmaque Gold Mines Ltd. for Au tailing reclaimation."

Jan 1, 1989

By Sadan Kelebek, Gerhard W. Heinrich, Peter F. Wells, Peter J. Whittaker

"Based on plant mineralogical data & circuit modelling, a pilot plant campaign was conducted at Strathcona Mill to identify options for improving the performance and operating flexibility of the copper-nickel separation circuits. Emphasis was given to options for combined treatment of the two feed streams (primary nickel ore rougher concentrate and copper ore circuit concentrate) to obtain more flexibility in the use of existing column flotation capacities. The pilot test results demonstrated that circuits which incorporated preconcentration prior to column flotation gave the best metallurgical results. Maximum column carrying rates were also related to the preconcentration. Predictions that increased circulating loads from the column scavengers would improve copper-nickel separation performance were confirmed.IntroductionThe copper-nickel separation circuits at Falconbridge's Strathcona Mill produce a high grade (>30% Cu) copper concentrate most of which is treated at the Falconbridge Kidd Creek smelter near Timmins. The remaining nickel concentrate which still contains approximately 20% of the feed copper is combined with other lower grade nickel/copper concentrates and shipped to the Falconbridge nickel smelter. The separation is required because of the limited capacity for copper processing in and downstream from the nickel smelter. Since no nickel is recovered at present in the Kidd smelter, the challenge is to minimize the nickel content of the copper concentrate.At present there are two independent separation circuits treating the rougher concentrates from the copper and nickel circuits as shown in Figure I. The minerals treated are mainly chalcopyrite and pentlandite but there is up to 25% of the copper present as cubanite in the copper ore. The circuits were kept separate because the flotation rates and froth characteristics were very different, probably because of the presence of cubanite and the large difference in the concentrate grades feeding the circuits."

Jan 1, 1995

By M. Leijd, K. S. Forrester, M. Saxon, M. Oczlon

This paper provides an introduction to wet high intensity magnetic separation (WHIMS) and its successful application to the beneficiation of rare earth element (REE) enriched eudialyte. The analysis includes an in-depth reporting of the deportment of key elements as well as a statistical interpretation of the relative importance of operational parameters including magnetic field intensity, flow velocity, and matrix loading density. Conclusions are drawn on the relative success of the technology, potential areas for process improvement, and the research direction that continues to be investigated. Three original equipment manufacturer (OEM) technologies were subjected to a series of screening and characterization tests to identify the optimal operating parameter set to magnetically beneficiate eudialyte from Norra Kärr, Sweden. Upon the completion of the characterization test it was apparent that the Metso HGMS technology was superior with respect to REE recovery and gangue rejection for the Norra Kärr composite. The Metso HGMS was then subjected to a series of verification tests to confirm the repeatability and reproducibility of the system.

Jan 1, 2014

By M. Roy, Y. Roux, R. McIvor

"La Compagnie Minière Québec Cartier at Port Cartier. Quebec, utilizes six parallel wet grinding open circuit ball mills to grind iron ore concentrate for the pellet making process. In an attempt to improve grinding efficiency, a mix of 605 25 mm (1 in.) and 405 38 mm (1 ½ in.) grinding balls was charged to mill D while the opposite mix was used in all the other mills. Because media costs were higher for mill D, it was necessary to find out if the smaller balls provided a net economic benefit. Therefore, a test program was undertaken to determine the relative efficiency of the charge in mill D compared to the other grinding mills. Mill F was chosen for comparative efficiency measurements.The first problem was to choose a suitable definition of grinding efficiency. In management&apos;s view, previous attempts to quantify milling performance using population balance modelling were ineffective because they were unable to relate breakage rate functions to grinding circuit economical in any meaningful way. Work index analysis was also not favoured because of a number of complicating effects, including the fineness of the feed and product streams and open circuit grinding.It was decided to adopt a recent innovative approach which had been successfully applied to closed-circuit ball milling. For ""functional performance analysis of ball milling"" (McIvor et al., 1990; McIvor et al., 1991), a size criterion is first chosen to define ""fines·&apos; and ~&apos;coarse particles"". In this case 45 microns (325 mesh) was chosen to distinguish fines from coarse material. The relative grinding efficiency of each ball mill environment would then be ~e cumulative grinding (disappearance) rate of coarse (plus 45 nucrons) material per kilowatt hour of energy applied to the coarse material in the mill, divided by the grindability (measured in the laboratory) of the coarse material in the mill feed.Because the disappearance rate of coarse particles is also the production rate of fines, the following equation can be written for the efficiency of the mill environment, Effe, as defined above:"

Jan 1, 1994

By I Wilkomirsky, F. Parada, R. Parra, E. Balladares

"The neutral roasting of As bearing copper concentrates is confirmed well established and promising option for the treatment of this type of complex concentrate. The AS elimination by volatilization allows subsequent treatment of the calcines produced in a conventional pyrometallurgical process, by blending this product with standard concentrates.Several tests were performed using the fluidized bed pilot plant at the University of Concepción with different types of concentrates. Calcines, fines from two hot cyclones and flue dust from the ESP were collected. These materials were characterized using QEMSCAN® and the results used for the development of a mass and energy balance which took into consideration the specific chemical transformations that occurred in the reactor.A physico-chemical/kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite. The mechanism involves solid-gas reactions between chalcocite, pyrrhotite and gaseous sulfur that without the mineralogical characterization would not have been possible to propose"

Jan 1, 2014

By X. Cao, X. -G. Chen, K. Liu

Due to the detrimental effect of platelet iron-rich intermetallics on mechanical properties (particularly ductility) in cast alloys, it has been essential to transform these phases into Chinese script morphology. In the present work, the effects of Mn and/or Si addition and cooling rate on the phase transformation of the iron-rich intermetallics in 206 cast alloys with different Fe contents ranging from 0.15 % to 0.5 % were systematically investigated. The results obtained showed that platelet ß-Fe and Al3(FeMn), Chinese script a-Fe, Alm(FeMn) and Al6(FeMn) can be observed in the 206 cast alloys, depending on the Fe, Mn and Si contents as well as the cooling rate. It was found that the addition of either Mn or Si favors the formation of Chinese script iron-rich intermetallics but inhibits the precipitation of the platelet phases. In addition, the combined addition of both Mn and Si has a synergistic effect on the phase transformation. Furthermore, there exists a critical cooling rate to effectively suppress the formation of platelet iron-rich intermetallics for a given alloy. The threshold cooling rate decreases with increasing Fe, Mn and Si contents. Casting process maps are established to correlate the intermetallics precipitated with alloy chemistry and cooling rate for 206 cast alloys containing various Fe levels.

Jan 1, 2014

By R. A. D. Pattrick, D. A. Polya, D. J. Marsh, J. -J. Bao

"The utility of high-density stream sediment and stream water sampling to the exploration for silver deposits was investigated by the study of the epithermal Ag-Au base-metal prospect at Lagalochan in western Scotland. The geology of Lagalochan is dominated by a calc-alkaline Caledonian intrusive complex emplaced into Dalradian Supergroup rocks (Harris et al., 1988a). The complex consists of subvolcanic porphyrytic rocks associated with intense hydrothermal alteration and brecciation. Early Cu-Ag-Mo-rich mineralization is found in the core of the complex with later Pb-Zn-Ag-Au-As-Sb-rich mineralization toward the margins (op. cit.).Stream sediment sample analysis spatially resolved the Cu-rich and Ag-rich mineralization. Ag and Cu anomalies relative to local background values were found in all size fractions analyzed (-125µm, +125 µm, +180 µm, +250 µm) but the more pronounced anomalies were found in the -125 µm fraction. The coarser fractions generally revealed more erratic but longer dispersion trails. The separation of Cu-rich and Ag-rich mineralization is also apparent in the distribution of relatively high dissolved Cu and Ag in stream waters, particular when expressed relative to the solute load as Cu/TDS and Ag/TDS.The mineralization at Lagalochan is indicated by Ag, Cu and Pb stream sediment and water concentrations that are anomalous with respect to local backgrounds, but are difficult to distinguish from regional backgrounds. This emphasizes the further potential of high-density stream water sampling,in particular, as a viable geochemical exploration tool on a sub-regional scale for epithermal depositsin relatively unpolluted upland terranes."

Jan 1, 1995

By R. A. D. Pattrick, D. A. Polya, D. J. Marsh, J. -J. Bao

"Abstract-The utility of high-density stream sediment and stream water sampling to the exploration for silver deposits was investigated by the study of the epithermal Ag-Au base-metal prospect at Lagalochan in western Scotland. The geology of Lagalochan is dominated by a calc-alkaline Caledonian intrusive complex emplaced into Dalradian Supergroup rocks (Harris et al., 1988a). The complex consists of subvolcanic porphyrytic rocks associated with intense hydrothermal alteration and brecciation. Early Cu-Ag-Mo-rich mineralization is found in the core of the complex with later Pb-Zn-Ag-Au-As-Sb-rich mineralization toward the margins (op. cit.).Stream sediment sample analysis spatially resolved the Cu-rich and Ag-rich mineralization. Ag and Cu anomalies relative to local background values were found in all size fractions analyzed (-125 µm, +125 µm, +180 µm, +250 µm) but the more pronounced anomalies were found in the -125 µm fraction. The coarser fractions generally revealed more erratic but longer dispersion trails. The separation of Cu-rich and Ag-rich mineralization is also apparent in the distribution of relatively high dissolved Cu and Ag in stream waters, particular when expressed relative to the solute load as Cu/TDS and Ag/TDS.The mineralization at Lagalochan is indicated by Ag, Cu and Pb stream sediment and water concentrations that are anomalous with respect to local backgrounds, but are difficult to distinguish from regional backgrounds. This emphasizes the further potential of high-density stream water sampling, in particular, as a viable geochemical exploration tool on a sub-regional scale for epithermal deposits in relatively unpolluted upland terranes."

Jan 1, 1995