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By Robert B. Parsons

"During hard times, the focus on tax issues makes a slight change in direction. Mining companies contemplate the tax treatment of transactions and circumstances which are the product of a difficult financial environment. Some of these issues are discussed in this month's edition of Tax Notes.Every industrial sector in Canada is undergoing a major restructuring of some form, and the mining industry is not an exception. The longest recession since the Great Depression continues to affect the economy. Mining firms seek to bring their debt/equity ratios into line, and try to replenish depleted retained earnings by selling assets. This month, Tax Notes briefly examines some of the tax issues which are generally encountered during the course of such a restructuring process.Debt SettlementOne question which commonly arises during hard times concerns the tax treatment of a "" gain "" realized by a debtor on the settlement of a debt. Consider, for example, a simple situation where a creditor wants to protect itself from further losses, and makes a deal with the mining company to accept a cash payment of $8 million in full settlement of a $10 million loan. In financial terms, the debtor has made a $2 million gain on the settlement of the debt. What is the tax treatment of that gain?The Income Tax Act (the Act) contains provisions in section 80 of the Act and in section 5400 of the Income Tax Regulations which deal specifically with this question. First of all, it is noted that the $2 million gain is not brought directly into income for tax purposes. However, as indicated below, the gain could affect the debtor's income indirectly to the extent that certain of the debtor's tax pools must be reduced by the amount of the gain."

Jan 1, 1993

By H. Langlois

"Included in the Mines Gaspe mining complex located at Murdochville, Quebec, is a copper smelter which comprises a reverberator furnace, two Peirce-Smith converters, an anode furance, and a sulphuric acid plant.The 50% smelter capacity available is supple mentedby custom concentrates for treatment. As these concentrates can be varied and extremely complex many modifications and improvements have been brought about to optimize and make the process more flexible since its inauguration in 1955.IntroductionThe copper smelter of the Mines Gaspe mining complex is located in Murdochville, a small municipality in the heart of the Gaspe peninsula, 90 km northwest of the town of Gaspe .This metallurgical installation has a daily smelting capacity of 650 tonnes of concentrate and an output of 250 tonnes of copper and 900 tonnes of sulphuric acid. Its main components are: a reverberatory furnace, two Peirce-Smith converters, one rotary anode furnace and one acid plant. The gases, which are produced by the converters, are treated at the acid plant then combined with gases from the reverberatory furnace before being vented through a 152 metre high stack .From the beginning of its operation until the present day (1991), the smelter has treated 7 million tonnes of concentrate and 100 thousand tonnes of scrap for a production of 1.8 million tonnes of copper and 2.2 million tonnes of sulphuric acid."

Jan 1, 1993

By L. Jiang

The evolution of twinning in an AM30 Mg alloy was examined by uniaxial tension and compression testing at temperatures from ambient to 250°C and a strain rate of 0.1/s. The samples were cut along the extrusion direction from extruded AM30 Mg alloy tubes. Specimens deformed to various strain levels were examined by optical microscopy and electron backscattered diffraction (EBSD) techniques. The results indicate that the initial extrusion texture plays an important role in the formation of different types of twins and that the twinning behavior also depends on the strain path. Contraction and double twinning are the dominant twinning mechanisms in uniaxial tension, while extension twinning prevails in uniaxial compression. The different twinning behaviors are shown to be responsible for the sharply contrasting strain hardening characteristics of the experimental flow curves.

Jan 1, 2006

By China University of Mining and Technology, P. Zhang, C. Zhou, C. Duan

"Recovering pyrite from the gangue with high sulfur content is of great significance for both economic development and environment protection in China. Due to the global water shortage and high cost in wet separation processes, it is urgent to explore more efficient energy and water conservation method in mineral processing field. This study has proposed an innovative method based on density difference for fine pyrite enrichment by vibration fluidized bed. In this study, the total sulfur content (TSC) of the gangue sample is 19.18%, and the pyrite is disseminated with fine granularity in the gangue which should be crushed for dissociation. The combination and dissociation experiment of -6mm gangue shows that the dominant density of -6+3mm, -3+1mm and -1+0.5mm comminuted material is +2.9g/cm3. Based on the analysis of characteristic, the effects of various factors on the separation performance were experimental studied. The results show that gas velocity, vibration intensity and bed height all have the significant effects. With the increases of superficial gas velocity, vibration intensity and bed height, the separation performance all presents a decreasing tendency. Additionally, the TSC of -6+3mm, -3+1mm and -1+0.5mm materials are respectively up to 37.94% , 35.43% and 30.61% at the optimum conditions, which are the 1.72?1.90 and 2.29 times as much as the TSC of raw material, respectively. This study demonstrates the vibrated fluidized bed can recovery pyrite from the gangue effectively.INTRODUCTIONWith the increasing mining and separation of coal, the yield of gangue has a further growth tendency, which has become one of the largest reserves of industrial waste (Querol et al., 2008). However, many harmful elements, such as S?NOx and Hg, is existed in the gangue leading the serious damage to the soil and environment (Hao, Yun, Zhanyuan, Sen, & Song, 2013). In addition, the economic would be suffered from the loss resulting in the occupied of arable land caused by the accumulation of gangue (Yeheyis, Shang, & Yanful, 2009; Zhou, Liu, Yan, Fang, & Wang, 2012). Therefore, the government has put forward the policies of ""green mining"" in China (Xing & Gao, 2009; R. Zhang, Ai, Zhou, Ju, & Zhang, 2015; Zheng, Du, Li, Qiu, & Yang, 2015). Among different research areas of coal utilization, extracting the useful minerals has become one of hot topics (Ledin & Pedersen, 1996; P. Patra & Natarajan, 2003; Partha Patra & Natarajan, 2004). At present, many researchers has devoted to the desulfurization of coal all over the world. As result, the sulfur element, which is mainly existed in the presence of pyrite, would transferred in the tailings, namely the gangue. Meanwhile, the pyrite is important raw materials to produce rubber, paper, textile and match. Consequently, recovering the pyrite from the gangue is not only suitable to the requirement of ""green mining"", but it could turn the waste into the treasure having the important significance."

Jan 1, 2016

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Several studies conducted recently have shown that molybdenite flotation from Cu-Mo ores is adversely impacted in sea water at pH >~ 10.0 irrespective of the pH modifier; under the same conditions Cu sulfide flotation is relatively unaffected. This has been attributed to the presence of Mg2+ ions and their hydrolysis products in the sea water which adsorb and precipitate on molybdenite surfaces as Mg(OH)2. However, why and how Mg(OH)2 impacts only molybdenite flotation in the complex flotation pulps containing a multitude of minerals is not understood. The work presented in this paper probes the interface and interphase regions near the edge and basal planes of natural molybdenite (MoS2) in aqueous solutions and flotation pulps, particularly in the presence of copper ore pulp and added Mg2+. Differences in interaction of metal ions and their hydrolysis products (Mg2+, Mg(OH)+) were measured on the two faces of this anisotropic mineral. How those differences relate to molybdenite floatability and the impact of aqueous solution chemistry are discussed.INTRODUCTIONWater resource management is an important sustainability challenge in mineral processing. In view of the shortage of fresh water in many parts of the world, mineral processing plants are evaluating alternative sources. Seawater flotation has received much attention recently and there have been several important studies reported in the literature, particularly for the processing of Cu-Mo ores (S. Castro, 2012; S. Castro, Rioseco & Laskowski, 2012; S. Castro et al., 2012; Laskowski & Castro, 2012; Ramos, Castro & Laskowski, 2013; S. Castro & Laskowski, 2013; Laskowski, Castro & Ramos, 2013; Nagaraj & Farinato, 2014; S. Castro, Uribe, & Laskowski, 2014; Veki, 2013). The main conclusions from these studies on Cu-Mo ores in seawater at elevated pH were: a) flotation recovery of Cu sulfides is either unaffected or only marginally reduced, b) molybdenite recovery is adversely affected in seawater at pH values necessary for rejecting pyrite (i.e. pH > 10 to 10.8 depending upon particular system), and c) the precipitation of Mg2+ in seawater as Mg(OH)2 is responsible for the adverse effect on Mo flotation. In order to further investigate the individual effects of Mg2+ and Ca2+ on molybdenite depression in Cu-Mo ore flotation, Nagaraj & Farinato (2014) conducted flotation tests wherein individual metal ions were spiked into tap water during grinding of Cu-Mo ores. They showed the strong adverse effect of Mg2+ addition on Mo recovery and, to a lesser extent, on Cu recovery when pH > 9.5. Under similar conditions, Ca2+ had virtually no effect on either Cu or Mo sulfide flotation. Figure 1 below shows the previous results for Cu- Mo ores in tap water and the effect of addition of Ca2+ and Mg2+ ions. Note that in seawater the adverse effect of Mg2+ on Cu recovery was much smaller than that in tap water (Nagaraj & Farinato, 2014; Figure 4a and 4b and Table 4 therein)."

Jan 1, 2016

By B. R. Casement

"Managing safety on the basis of after-the-fact reaction to accidents, can never be more than partially successful. Injuries will occur as long as the underlying potential for them still exists. Unless unsafe actions and conditions are systematically decreased, no program can have more than a short-term success.The pro-active Bullmoose loss control process, instead, focusses on heightening awareness of work habits, to prevent incidents by reducing their potential.Any safety program will be doomed to failure if the development of safe work habits depends on the safety supervisor or a safety committee. At Bullmoose the focus is on the critical actions out of which losses emerge. The successful application of performance-related feedback is achieved by taking safety, health, and environmental concerns into consideration on every level, and, by doing the right thing in every job done.What is an Exceptional Loss Control Program?If an accident in an organization creates a flurry of interest, resulting in ""cracking down"" on violations for a short period of time then an ""exceptional"" loss control program exists. Unfortunately, exceptional here does not refer to the effectiveness of quality of the program but to the fact that the organization is managing loss control by exception. The degree of management attention in an ""exceptional"" safety program varies over a period of time, remaining low as long as the rate of losses stays within management's acceptable control limit (Fig. I). When the losses rise above this, management becomes motivated to begin ""exceptional"" efforts to manage losses. When the rate falls again to within the accepted limit, efforts to control losses take a back seat.Such a strategy guarantees that losses will be tolerated or ignored as long as the actual rate is below the acceptable limit. Simply to lower the limit would not reduce losses, but would result in an increased number of flurries of management attention to loss control. This ""on-again, off-again"" style of management teaches supervisors and others that basic loss control is not as important as are statistics."

Jan 1, 1993

By Vern Evans

Saskatchewan has historically been recognized for farming, but in 1943 while drilling for oil, potash was discovered. The initial attempt to gain access to the potash beds was unsuccessful, however, subsequent attempts were successful and today there are ten operating potash mines in Saskatchewan. In this paper we will provide a brief overview of the historical and current Potash industry in Saskatchewan.

May 1, 2011

By Lin Li, Ahmad Ghahremaninezhad

"In this paper, the electrochemical behavior of ferric and ferrous couple on the pyrite surface was studied by application of the chronoamperometry technique in an acidic solution at room temperatures and atmospheric pressure. The effects of the pyrite origin, ferric and ferrous ions concentration on the electron transfer kinetics of Fe3+/Fe2+ reaction were probed. Tafel behavior of all the test conditions were developed. The results showed that the ferric-ferrous reaction on pyrite electrodes with different origins have a common mechanism, despite different reaction kinetics. The exchange current densities of the redox reaction have the same magnitude of about 10-5 A·cm-2, which is far lower than the value reported for the gold and platinum electrodes, but larger than that of the chalcopyrite electrode. The cathodic transfer coefficients are between 0.4 and 0.5, while the anodic transfer coefficients appear unusual with the lowest value being 0.23. It was also demonstrated that an increase of one order of magnitude of iron concentration has no clear effect on the exchange current density and cathodic transfer coefficients of Fe3+/Fe2+ redox reaction.INTRODUCTIONPyrite, FeS2, is mostly considered as a gangue mineral which frequently coexists with valuable minerals and metals, such as gold, copper and nickel. Its separation from valuable minerals can be a costly process (Chandra & Gerson, 2010). In refractory gold ores, the fine gold particles are locked inside the pyrite structure. Oxidative leaching of pyrite is a hydrometallurgical method to destroy the structure of pyrite and expose the fine gold particles to the cyanide solution in the downstream cyanidation circuit. Pyrite oxidative leaching can be achieved by oxidation of pyrite via oxygen and ferric ion(McKibben & Barnes, 1986). In fact, pyrite oxidation by oxygen and ferric is a significant source of acid mine drainage(AMD), which adversely causes serious environmental problems(V. P. Evangelou, 1995).The pyrite oxidation mechanism is accomplished in three consecutive steps: (i) pyrite is oxidized by oxygen and ferrous ion formation (Eq. 1); (ii) ferrous oxidation by oxygen and ferric ion formation (Eq. 2); (iii) pyrite oxidation by means of ferric ions (Eq. 3). Hence, both oxygen and ferric participate in the pyrite oxidation process (Moses & Herman, 1991):"

Jan 1, 2016

By Chun-Sheng Liao, Chun-Hua Yan, Sheng Wu, Fu-Xiang Cheng

"INTRODUCTIONChina is providing more than 90% of the rare earth products consumed in the whole world. Acidic extractants are commonly used in the extraction separation of rare earths. Saponification of the acidic extractants by basic substances is usually necessary for the purpose of increasing and stabilizing their extraction capacity, and meanwhile inorganic acids are required for both scrubbing and stripping. Thus acids and bases are the main consumed chemicals, and the resulting salts are the main pollutants generated by rare earth separation processes. Currently, due to increasing environmental concerns in China, rare earth solvent extraction separation techniques are being developed to reduce both consumption and emission of chemicals, which is driving the developments on both theories and processes for solvent extraction separations.In the 1970s Prof. Xu et al. developed the Theory of Countercurrent Extraction (Xu, Li, & Yian, 1985). In recent years, the development of novel processes for rare earth separation has moved beyond the earlier theory. One rare earth separation process, the so-called hyperlink process, has been developed in the past decade and proven in industrial practice to dramatically reduce both the consumption and emission of chemicals during multi-component solvent extraction separations, and therefore is now widely used in the Chinese rare earth separation industry (Liao, Wu, Cheng, Wang, Liu, Zhang, & Yan, 2013). The present article will give a brief review of the development of the theory of the hyperlink processes, and the hyperlink separation flowsheets for typical rare earth mines in China designed using the theory.HYPERLINK PROCESSES (LIAO et al., 2013)A flowsheet of multiple-component separation consists of a couple of separation units. The units of a conventional flowsheet separately consume chemicals for saponification and scrubbing and discharge wastewater with resulting salts. In contrast, the separation units in a hyperlink process are hyperlinked and thereby the chemical demands of the whole flowsheet are decreased. For a feed containing t components of A1, A2, …, and At, it has been proved in theory that the separation mode of (AtAt-1…A2)/(At-1At-2…A1) is preferred in a single separation unit. The hyperlinking between separation units can have two forms. The link between two units locating at a same separation level, such as between (A4A3)/(A3A2) and (A3A2)/(A2A1), is known as horizontal hyperlinking. The link between two units located on different levels, such as between (A4A3A2)/(A3A2A1) and (A3A2)/(A2A1), is known as vertical hyperlinking. Both the hyperlinking forms have been proven to save chemical usage and consequently to lower the pollution emissions in industrial practices as well as in theory."

Jan 1, 2016

By Nirmal Weerasekara, Jochen Franke, Malcolm Powell, John Favier

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By J. L. Bowlby

TWO years ago, at the annual meeting of this Society, the writer presented a paper dealing with various aspects of the water problems existing in the Cape Breton coal-mining area. Much of that paper was of a theoretical nature, in that an attempt was made to get at the fundamental principles underlying the problems, in order to establish a sort of background against which future results could be laid. Up to that time, only Central power plant in Glace Bay had been under observation, and, since the work had been in progress only a year, it was recognized that there were strong possibilities that certain variations in procedure might have to be introduced as w; became better acquainted with our problem. We were by no means certain that we had covered all the facts of the case. The present paper will therefore be of the nature of a progress report, rather than a formal contribution to the Society. Subjects of a theoretical or academic nature will be avoided as far as possible, attention being confined chiefly to the results obtained during the past two years. In looking over the work with low-pressure boilers, there are certain general conclusions that can apparently be safely drawn. Wherever possible, proper operating conditions will be expressed in terms of appropriate units. Absence of corrosion in boilers where the alkalinity has been maintained within the pH range 11.0 to 11.4 forces one to the conclusion that these are safe working limits. Previous experience had shown that corrosion would occur if the alkalinity were much reduced. Higher alkalinities are un-necessary, more expensive, and are said to introduce the possibility of pitting. We made no attempt to obtain quantitative data in respect to pitting. It is said to occur at pH 12.0. Consequently, conditions of alkalinity were main-tained well below this figure. In the above paragraph, the pH range 11.0 to 11.4 applies to boiler waters which have received the lime and soda treatment. The general practice, when this treatment is employed, is to use 1.0 lb. lime to 7.0 lb. washing soda. At Central power plant, soda-ash is at present substituted for washing soda, the equivalent proportions being kept the same. But not all the plants are on the lime and soda treatment. At Waterford Lake, a 1: 1 mixture of soda-ash and trisodium phosphate is satisfactorily employed, and in Sydney Mines and at No. 3 power plant in Sydney, good results are being obtained at a somewhat greater cost with a commercial phosphate treatment.

Jan 1, 1936

By A. Khodadadi, M. Abdolahi, P. Taimory

Cyanide is used by the mining and chemical industries in tremendous quantities without attention being given to its hazardous properties. The use of cyanide compounds in mining is one of the most important environmental issues for the mining industry due to the acutely toxic properties of many cyanide compounds to humans and aquatic life. Cyanide tends to react readily with most other chemical elements, producing a wide variety of toxic, cyanide-related compounds and because cyanide is carbon based an organic compound it reacts readily with other carbon-based matter, including living organisms. This research is aimed at investigating a feasible and economical technique for the removal of cyanide from tailing wastewater of Muteh gold mine. In this research, removal from Muteh factory's waste water, was achieved at Tarbiat Modares University's mineral processing laboratory through the oxidation of cyanide by calcium hypochlorite. Cyanide oxidizes and changes to cyanide (CNO-) which is 1000 times less environmentally hazards than cyanide. Cyanide titration was accomplished using Rhodanine solution and silver Nitrate. Cyanide concentration in the wastewater, was 270 mg/L. Cyanide removal was achieved at an optimum pH of 12.3. However, at higher temperatures, cyanide removal was complete at this pH level. Optimum Dosage for complete removal of cyanide using calcium hypochlorite was 1.43g/L.

Jan 1, 2005

By Hani S. Mitri

Strainbursts in brittle rock are common to deep underground mines. The state of stress at the boundary of mine openings is dictated by a biaxial stress/loading condition. This paper reports the results of a series of biaxial compression tests carried out on 100 mm cubic samples of norite rock, under different horizontal-to-vertical stress ratios. The results indicate that the biaxial compressive strength is considerably higher than the uniaxial one. It is found that the norite sample behaviour under biaxial loading mirrors field behaviour where shearing and progressive spalling of the opening boundary are observed prior to strainbursting. Sample failure is initiated by rock spalling at the sample free faces, i.e. in the plane of biaxial loading. Finally, it?s the out-of-plane shear failure mechanism that causes the sample to collapse. Shear failure takes place violently and abruptly and is accompanied with considerable audible noise.

Apr 1, 2005

By Ronald C. Schimmel

In 2006, the Corus IJmuiden pellet plant produced approximately 4.6 mln tonnes of pellets. Corus IJmuiden is about to increase its pig iron production to 6.4 mln tonne HM per annum. The burden of the Corus IJmuiden blast furnaces consists of approximately 50% high basicity sinter and 50% acid pellets, both produced in-house. To enable an increased iron production, the capacity of the pellet plant needs to be raised to 5.0 mln tonne per annum. The capacity is increased by modifications to the plant layout, which were implemented during the 2006 cold maintenance stop. In addition, the composition of the ore blends is optimised to gain productivity.

May 1, 2007

By Robert B. Parsons

"It is generally acknowledged that Canadian and foreign-based mining companies are spending relatively fewer dollars in Canada and more dollars abroad than was the case not many years ago. It is common to see the Canadian tax system being fingered as one of the causes in this shift in direction. However, if one takes the time to peel away the surface of our tax system, and to probe a little deeper into its substance, it will be found that the Canadian taxation of mining is generally quite competitive. IntroductionCross-border shopping in the mining industry? - Absolutely! Economics 100 teaches that dollars are votes in the capitalist system, and mining companies are going to cast their limited number of votes where they can achieve the highest return at the least risk. The Canadian consumer knows that taxes are a major factor in cross-border shopping, and mining company executives know that the same tenet holds true in their industry. Unfortunately, mining operations are subject to such a bewildering array of tax rules that making an intelligent decision is not always an easy matter.Statutory Tax RatesConsider, for example, the ""statutory"" tax rates shown in Table 1. (Statutory tax rate in this table refers to the simple sum of federal and provincial tax rates on profits as specified in the tax legislation.) Looking only at the total statutory tax rates (such as 66070 for Manitoba) , one might quickly observe that the Canadian mining industry is subject to a truly onerous tax regime, especially as compared to the United States where statutory tax rates can be in the 34% range."

Jan 1, 1992

By Robert B. Parsons

"This article is based on a paper presented by Jim Scott at the 1988 annual convention of the Prospectors and Developers Association of Canada. The paper suggests a number of factors that might be taken into account in negotiating royalty terms.IntroductionRoyal ties are a part of mining life in Canada. They are used by many kinds of individuals in many kind s of situations. Prospectors commonly take royalty interests back when they transfer claims to development companies. Mining companies disposing of undeveloped (or sometimes even developed) properties are often paid at least in part by royalties. Royalties are even used by institutional investors with no other connection with the resource industry.Such different royalty holders have different investment goals, different cash flow requirements, and different risk / return preferences. These differences have given rise to a number of different royalty type s. These types range from the simplest cents-per-ton royalty (where the operator pays a royalty at a fixed rate per ton milled) to net smelter return or ""NSR"" royalties (where the royalty is based on a percentage of the operator's NSR) all the way to net profit interest or ""NPI"" royalties (where the royalty is based on the operator's bottom-line net profit),The fundamental difference between the many royalty types is in the risk/ return relationship. The cents-per-ton royalty, for example, is relatively risk-free. Of the many economic factors which affect a mine, the only one which will affect the royalty holder is the amount of ore physically milled. On the other hand, the potential for significant gains under a cents-per-ton royalty is also very limited. The royalty holder will not share in any increases in the market price of the end product or any cost reductions achieved by the producer."

Jan 1, 1988

By Robert B. Parsons

"This article is based on a paper presented by Jim Scott at the 1988 annual convention of the Prospectors and Developers Association of Canada. The paper suggests a number of factors that might be taken into account in negotiating royalty terms.IntroductionRoyal ties are a part of mining life in Canada. They are used by many kinds of individuals in many kind s of situations. Prospectors commonly take royalty interests back when they transfer claims to development companies. Mining companies disposing of undeveloped (or sometimes even developed) properties are often paid at least in part by royalties. Royalties are even used by institutional investors with no other connection with the resource industry.Such different royalty holders have different investment goals, different cash flow requirements, and different risk / return preferences. These differences have given rise to a number of different royalty types. These types range from the simplest cents-per-ton royalty (where the operator pays a royalty at a fixed rate per ton milled) to net smelter return or ""NSR"" royalties (where the royalty is based on a percentage of the operator's NSR) all the way to net profit interest or ""NPI"" royalties (where the royalty is based on the operator's bottom-line net profit),The fundamental difference between the many royalty types is in the risk / return relationship. The cents-per-ton royalty, for example, is relatively risk-free. Of the many economic factors which affect a mine, the only one which will affect the royalty holder is the amount of ore physically milled. On the other hand, the potential for significant gains under a cents-per-ton royalty is also very limited. The royalty holder will not share in any increases in the market price of the end product or any cost reductions achieved by the producer."

Jan 1, 1989

By Baisheng Nie

The process of gas diffusion through coal particles and the mathematical physical model under the third kind boundary condition was determined to obtain the rules of gas diffusion through coal particles of different sizes. The analytical solution of the equation was obtained by the Method of Mathematical Physics. The parameters of analytical solutions and the implications of parameters were analyzed. The Biot criterion (Bi) and the Fourier criterion (F0) of mass transfer can represent and reflect the features of gas diffusion field of coal particles. Moreover, the measurement method of gas diffusion coefficient and surface mass transfer coefficient is introduced and an example of measurement is given. The achievement can provide the support to prevent disasters related to methane in coal mines.

Aug 1, 2013

By G. Stokreef, B. R. Davis, M. Kadiyski, T. LeBel, Alvear Montenegro, R. Parra, V. Montenegro

A drop tower and methodology were developed to study the impact of mineralogy on the flash combustion behaviour of copper concentrates. Reaction shaft conditions of a flash furnace were simulated using a drop tower reactor and different molar ratios of oxygen gas to sulphur in the feed. Five feeds were tested in the drop tower including pure minerals chalcopyrite and pyrite as well as two mineralogically distinct copper concentrates and a blend of the two. The behaviour of each of these five feeds were evaluated through analysis of the solid combustion products for elemental sulphur, mineralogy and particle size. Desulphurization curves for each of the feeds were produced. It is thought that the desulphurization behaviour of pure minerals can be used to estimate the behaviour of a concentrate and that a blending recipe could be developed, which can optimize the chemical and mineralogical inputs to the flash furnace and guide operations on the optimum furnace conditions. Overall, the drop tower has proven to be a useful tool for studying flash combustion processes. Experimental results suggest that mineralogy has a significant impact on the conditions required for the production of matte with consistent grade. This finding is especially significant for custom smelters, which may see several different blends in a day. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process that is used to produce copper matte from copper sulphide concentrates. Dried concentrate(s), silica flux, and secondary materials are blended to a target chemical composition, typically given by the Cu/S ratio, before processing. This fine, dried feed is dispersed throughout the heated furnace reaction shaft with an O2-enriched reaction gas. The particles heat up in the shaft of the furnace, ignite and undergo reactions that pre-oxidize the iron sulphide and some of the impurities in the feed. Oxidation reactions in the shaft of the furnace desulphurize the feed and produce an SO2-containing off gas. The reacted particles fall into the furnace settler and separate into a Cu-rich matte and an iron-silicate slag, while the SO2-containing off gas is carried out of the furnace for heat and dust recovery, as well as H2SO4 production. Some concerns during operation of the furnace are dusting, over or under oxidation of the feed, and a stable flame.

Jan 1, 2019

By M. C. Villeneuve, P. A. Siratovich

We present an integrated analysis of laboratory-based thermally induced fracturing and results of numerical models to give insight to the role of thermal shock fracture on geothermal reservoir rocks. Thermal stimulation is a reservoir permeability enhancement technique applied to commercial geothermal reservoir rocks to enhance fluid injection capabilities for spent power plant working fluids. The process is well known to enhance permeability but the thermodynamic and physical constraints of the process are less certain. In an attempt to constrain the interaction and the ideal conditions that lead to permeability enhancement, experimental procedures were carried out to mimic the conditions that a reservoir rock would experience during a thermal stimulation using temperature differentials ranging from 50-300°C. Samples underwent such thermal gradients under controlled laboratory conditions and were characterized for the changes to permeability, porosity, ultrasonic velocities, dynamic elastic moduli and petrological changes. The thermal stimulation was simulated in a FLAC2D thermal numerical model to investigate the nature of the thermally induced changes in the sample. The development of this model also allows us to investigate the relationship between geological characteristics and the ability to thermally stimulate any type of rock. The results indicate that numerical thermal shocking experiments are corroborated by laboratory-based results. The implication of this study is that the refined numerical models present an insight to the conditions and constraints under which thermal stimulation can prove to enhance permeability that could not be gained through purely laboratory-based studies.

Jan 1, 2015