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By W. A. Kracht

The McGill Bubble Size Analyzer, with the original image-capturing device (digital video camera), has a proven record for measuring bubble size distributions that are relatively narrow, such as in mechanical cells with frother. However, some problems arise when dealing with bubble size distributions characterized by a bi-modal shape and wide range of sizes such as found in some flotation columns. To measure wide bubble size distributions it is necessary to increase both the resolution to image the small bubbles and the viewing area to include the large bubbles. This can be done using a digital still camera: digital still cameras can have higher resolution than the digital video cameras currently used and with the proper lens the viewing area may be increased without resolution loss. The digital still camera approach was used to measure bubble size distributions in flotation columns at different operations in Chile. A comparison with typical bubble size distributions generated with mechanical cells is presented.

Jan 1, 2007

By Zhigao Xu, Ruan Chi, Zhenyue Zhang, Yaoyang Ruan, Zhengyan He

Thorium is frequently the main radioactive element in rare earth ores and is a resource that can potentially substitute for uranium. Thorium must be separated from rare earths in order to obtain products with low radioactivity. There are abundant resources of thorium in the rare earth ores in China, especially in Baiyunebo mixed ores. As an associated element coexisting in rare earth ores, thorium is, or can be, separated from rare earth concentrate, iron concentrate, as well as from waste water and slag to achieve recovery of thorium. The methods of separation include ion exchange resin, liquid-liquid extraction, and liquid-solid extraction. TBP extraction has been the main method applied to separate thorium by domestic and foreign scholars. This paper presents a comparison of different processes for the separation of thorium from rare earth ores, especially Baiyunebo mixed ores, single bastnaesite and monazite ore, and provides suggestions for the future recovery of thorium resources.

Jan 1, 2014

By Neda Zangeneh

Production efficiency from low permeability gas shales require techniques to optimize hydraulic fracture completions. One completion strategy involves the simultaneous or near simultaneous hydraulic fracturing of multiple horizontal wells to maximize the fracture network area and stimulated reservoir volume. However, changes to the in-situ stress field caused by an earlier hydrofrac on subsequent hydraulic fractures are not accounted for in traditional hydrofrac design calculations. Presented here are the results from a set of transient, coupled hydro-mechanical simulations of a rock mass containing two wellbores using the discontinuum-based distinct-element method. The results demonstrate the influence of stress-shadows generated by a hydraulic fracture on the development of subsequent hydrofracs from an adjacent well. It is shown here that these interactions have the potential to change the size and effectiveness of the hydraulic fracture stimulation by changing the extent of the hydraulic fracture around the secondary well.

Jun 1, 2012

By L. Tang

A seismic monitoring system was installed in 2005 at Dongguashan Copper Mine, the deepest metal mine in China. Based on the seismic events monitored in situ, the possibility of rockburst prediction and prevention is investigated in this paper. The characteristics of space-timeintensity of mining-induced seismicity and the seismic response to mining are studied in detail using the seismic data in Dongguashan Mine. A conceptual model and a criterion of assessment of hazard seismic nucleation are proposed for Dongguashan Mine. In this model, the mine seismic stiffness method is adopted for rockburst prediction within the framework of the unstable failure theory. To analyze rock failure cases in Donggauashan Mine, the rate of the ratio of stiffness of rock in nucleation area to its surrounding area is proposed as a criterion for rockburst prediction.

May 1, 2009

By T. Krumins, L. Zunti, R. Frischmuth

Titanium and titanium alloys are commonly selected for pressure oxidation autoclave vent piping and pressure control valve components, as well as autoclave internals, in high-temperature operations. In a vent application, titanium ignition risk is reduced by limiting oxygen concentration, and preventing high gas velocity gas impingement on surfaces. Oxygen concentration is dependent on the autoclave pressure and temperature conditions and therefore titanium ignition risk is dependent on standard operating procedures, and process control interlocks and permissive conditions. It is not uncommon for standard controls to be deficient during atypical operating conditions, or for operations to deviate from the operating procedures, increasing the potential for titanium ignition incident. Titanium ignition risk caused by elevated oxygen concentration in autoclave vent systems can be reduced with the introduction of an online autoclave overpressure calculation and the configuration of associated interlocks and permissive conditions.

Jan 1, 2014

By S. Minamiguchi

Grain refinement is effective to enhance strength and ductility of metallic materials. However this advantage has not been utilized fully for magnesium alloys in industry because microstructure control through thermomechanical treatment is difficult owing to their poor deformability. The authors proposed a high-speed heavy-reduction rolling for production of Mg alloy sheets. It was found that the deformability is significantly improved at high speed and that the thickness can be reduced 60% by one-pass operation even at room temperature without fracture at the rolling speed higher than 1000 m/min. In this study, commercial AZ31B sheets were rolled at 2000 m/min between room temperature and 350°C, and quenched immediately after the rolling. The sheets rolled at 200°C show the finest recrystallized microstructure with the mean grain size of 2.2 Rm. They show outstanding mechanical properties with the tensile strength of 293 MPa, and the elongation of 25%. It is concluded that high-speed rolling is very advantageous for grain refinement and improvement in mechanical properties as well as deformability and productivity.

Jan 1, 2006

By Jr. Wilkinson

Suncor Energy currently mines approximately nine hundred thousand tonnes of ore and waste per day at its open pit operations in the Athabasca Oilsands near Fort McMurray, Alberta. Modeling these deposits for planning purposes is particularly challenging given the characteristics associated with the deposit - stratigraphic deposition coupled with gradational grade distribution. The identification of ore and waste is a combination of bitumen cutoff grade, minimum mining thickness and separable waste thickness subject to criteria established by provincial regulatory agencies. Suncor along with Mincom Inc. have collaborated on this project to derive a methodology, automated by computer software, to streamline the ore and waste identification process. This paper explains the methodology and programs created to identify ore and waste in use at Suncor Energy and how this identification is used to categorize reserves and to generate mine design surfaces.

Apr 1, 2005

The article presents an outline of methods and certain results of laboratory tests, underground tests and model tests, aimed at assessing performance of a powered shield support on the floor of low strength parameters. The tests were conducted within the framework of GEOSOFT project co financed by Research Fund for Coal and Steel (RFCR-CT-2010-00001). The described research works were conducted by Central Mining Institute (Glówny Instytut Górnictwa), Janina coal mine and Becker-Warkop

Aug 1, 2013

By Frands Jensen, Erik Eriksson

"Haldor Topsoe’s Wet gas Sulfuric Acid (WSA) technology has been proven in a number of industries converting sulfurous gasses to concentrated sulfuric acid. In the metallurgical sector plants have been delivered handling SO2 gasses from copper, zinc, molybdenum, and lead ore. WSA has high energy efficiency and allows autothermal operation from feed gas strengths as low as 3.0% (volume). Recent variants of the WSA process have been developed that allow very high SO2 conversion efficiencies of over 99.9%. This paper describes the technology, its advantages and industrial achievements.The WSA technology is well suited for production of concentrated sulfuric acid of commercial quality from the sulfur dioxide (SO2) gas that inevitably emerges from the metallurgical processes. Some of the features that make the WSA technology attractive for this application are:- High SO2 conversion rates (up to 99.99%)- High energy efficiency leading to a low autothermal point (~ 3% SO2)- No need for gas cooling and drying to produce concentrated sulfuric acid- No production of waste- Very low cooling water consumptionThis paper describes the WSA process principles and highlights features that make this process attractive for handling SO2 gases."

Jan 1, 2014

By S. Nakamura, K. Fujiwara, S. Hirosawa, S. Tsukamoto, Y. Koshino, Y. Aruga

"In this study, hardness test, differential scanning calorimetry(DSC)and transmission electron micros copy were carried out to investigate the age-hardening behavior of Al-Mg-Si alloy with a Mg+Si concentration of 1.5mass%, and a Mg/Si ratio of 1.0. Pre-aging treatment was conducted for the solution-treated and then water-quenched specimen at 100, 80, 60, 40, 20 (natural aging), 0 and -20°C for 20min or 5h, followed by artificial aging at 170°C for 20min. It was found that when pre-aging time is prolonged from 20min to 5h, the bake-hardening response is deteriorated irrespective of the pre-aging temperature. In particular, the specimens subjected to pre-aging at 20-40°C for 5 h hardly increased the hardness with the subsequent artificial aging. From the results of DSC measurement, it was suggested that as pre-aging temperature is lowered, the amount of solute clusters formed during pre-aging, i.e. Mg-Si clusters and Si-rich clusters, is decreased, but the ratio of Si-rich clusters is increased, resulting in the deteriorated bake-hardening response.INTRODUCTIONIn recent years, Al-Mg-Si alloys have been widely used forautomotive body panels due to their excellent characteristics such as high strength-to-weight ratio and good formability. Their strength is increased not only by artificial aging during paint-bake treatment; i.e. “bake-hardening”, but also when kept at room temperature(RT);i.e. “natural aging”, in association with the suppressed bake-hardening response. Such a “negative effect of two-step aging” has been a serious problem because Al-Mg-Si alloy coils are unavoidably maintained at RT in the manufacturing process of body panels; e.g. shipping and storage. However, it was reported that pre-aging above 70°C before the two-step aging can restore the bake-hardening response, and such an improvement is related to the formation of solute clusters(Sato, 2006; Abidet al., 2010; Takaki et al., 2014; Zandbergen et al., 2015). From the comprehensive analysis by three-dimensional atom probe (Aruga et al., 2014 and 2015), it is believed that Mg-Si clusters formed during pre-aging transform into the strengtheningß"" phase, whereas Si-rich clusters formed during pre-aging act as a detrimental precursor of ß""phase. In this study, it was aimed to investigate the effect of pre-aging conditions, especially pre-aging temperature and time, on the formation of solute clusters during pre-aging, in order to elucidate the mechanism of the age-hardening behavior of an Al-Mg-Si alloy."

Jan 1, 2018

By J. Shibata, K. Manabe, A. Fuji, N. Matsunaga, D. Murakami, Yamaguchi University, T. Suzuki

"Spent hydrodesulphurization (HDS) catalyst contains rare metals such as cobalt, nickel (Ni), molybdenum (Mo), and vanadium (V). The overall objective of this project is to develop a hydrometallurgical process that provides a degree of high recovery and selectivity of these rare metals from spent HDS catalyst. As a part of this project, this study focused on (i) development of a solvent extraction-precipitation stripping process for separation of Mo and V from solutions and (ii) optimization of grinding conditions of alkaline leaching residue for selective Ni sulfuric acid leaching against aluminum (Al). Experimental results showed that effective separation between Mo and V can be achieved by the two-stage process; solvent extraction of Mo and V with TOA (tri-n-octylamine) and precipitation stripping of V with ammonium salt at pH above 8.0. Regarding grinding conditions of alkaline leaching residue for selective Ni leaching against Al, it was found that Ni leaching efficiencies increased by providing higher grinding intensity, while the Al leaching efficiency increased and then decreased with increasing grinding intensity.INTRODUCTIONHydrodesulphurisation (HDS) catalysts account for about one third of the total worldwide catalyst consumption and are extensively used for sulphur removal in petroleum refineries (Zeng & Cheng, 2009). Fresh HDS catalysts generally contain molybdenum (Mo) and nickel (Ni) on an alumina carrier, but various elements included in the crude oil such as sulphur, carbon, silica, arsenic, cobalt, and vanadium (V) deactivates HDS catalysts during HDS reactions. As a result, spent HDS catalysts contain high concentration of rare metals. For example, regarding to Mo and V, it has been reported in the literature that the concentrations of Mo and V in the general spend HDS catalysts are generally 10-30% and 1-12%, respectively (Zeng & Cheng, 2009), which makes it economically viable to recover these rare metals (Biswas et al., 1986).Among a number of processes proposed for the recycling of rare metals from spent HDS catalysts, alkaline leaching is often used for selective Mo and V leaching (Zeng & Cheng, 2009). However, the process which provides a high degree of separation between Mo and V from a leaching solution had not been developed. Therefore, the first objective of this study was set to develop a solvent extraction-precipitation stripping process for the separation of Mo and V from solutions. More specifically, using artificial aqueous solutions of Mo and V, a series of experiments was performed to optimize the extraction pH, stripping agent, and the stripping pH."

Jan 1, 2016

By B. McFadzean, J. Taguta

In order to recover minerals by flotation, the sub-processes of collector adsorption onto the valuable minerals followed by bubble-particle attachment should occur efficiently. This paper investigates both of these sub-processes for various thiol collectors and their mixtures onto base metal sulfide minerals. The aim of the work was to investigate whether there is a correlation between the strength of the collector interaction with the mineral and the subsequent bubble-particle attachment. The collector-mineral affinity was measured experimentally using an isothermal titration calorimeter in order to determine the molar enthalpy of adsorption for each collector-mineral system. The bubble-particle attachment was measured using a microflotation device which essentially determines the hydrophobicity of the mineral. Sodium ethyl xanthate (SEX) and sodium diethyl dithiocarbamate (DTC) and mixtures thereof were used as collectors with either single minerals or binary mixtures of pyrite and chalcopyrite, respectively. The adsorption enthalpies of the collectors were interpreted with reference to the chemical structure of the collector molecule and showed that the greater the positive inductive effect of the collector, which may be qualitatively related to their pKa, the greater their affinity for the mineral surface. In the microflotation studies, recoveries were strongly related to the alkyl chain length but there was no correlation between the enthalpies of adsorption and the flotation recoveries. When mixtures of collectors were used there was clear evidence of synergistic effects and in the case of DTC/xanthate mixtures it is possible that this synergism is related to a DTC promoted oxidation of xanthate to dixanthogen. When mixtures of pyrite and chalcopyrite were used the flotation recovery and enthalpy of adsorption of SEX onto the individual pyrite particles in the mixture increased substantially compared to the case of pyrite alone. Mechanisms are proposed to interpret these important observations.

Jan 1, 2016

By Miguel A. Cuba

Trends in the mean and/or variance are a longstanding challenge in mineral resource modeling. Geologic modeling and/or grade domaining are often employed to account for heterogeneities in mineral grades; however, this is only practical up to a certain point since the number of data available for reliable model construction can be severely reduced. In such cases, trends remain present in certain geologic/grade domains and directly impact the modeling methodology; the trend must either be handled explicitly or a suitable approach is adopted to implicitly account for it. This is highly dependent on understanding the source of the trend. We propose an approach that detects the source of non-stationarity, which is based on quantifying the impact of non-stationarity in the mean and the variance via the semivariogram. By expanding the methodof- moments approximation of the semivariogram, we decompose the experimental semivariogram is into three terms: 1) trend in mean component, 2) trend in variance component and 3) stationary component. We can then assess the source of trend by calculating the contribution of each component at every lag. Two cases are presented to illustrate this tool. Firstly, a synthetic reference model is simulated and different trend patterns are added; the influence of these patterns in the experimental semivariogram calculation are analyzed and discussed. Secondly, a real dataset is considered where the impact due to the presence of trends in the mean and variance are assessed. The results of this paper reveal the semivariogram to be a tremendously powerful tool in determining the source of the trend. This insight may be useful in the selection of a suitable modeling approach for resource estimation.

Oct 1, 2009

By André Desbiens, Frédéric Flament, Lionel Ryan

"In December 1991, the GRAHM (Groupe de Recherche sur Jes Applications de L'informatique a L'industrie Minerale), of Laval University started a KBAC (Knowledge Based Automatic Control) grinding project with Falconbridge Ltd. The project was shifted to the Kidd Creek concentrator in the summer of 1992, with the first phase involving the collection of data by GRAHM and Falconbridge personnel for the construction and tuning of a dynamic simulator. This grinding circuit dynamic simulator known as DYNAFRAG was used to assess various control strategies, with a PID-based strategy being selected for ease of installation on a Foxboro II A DCS.The ""B"" primary grinding circuit was chosen for the initial strategy development, which is one of three parallel divisions. The KBAC project was successfully completed in November 1994, with subsequent modifications being implemented by Kidd Creek staff.This paper summarizes, the current control strategy, the project costs, and the realized benefits. Some of the problems which were encountered with the initial installation, and the subsequent modifications are also dealt with in this paper.2.0 IntroductionIn the summer of 1992, the GRAHM of Laval University and Falconbridge Ltd. started a project to design a control strategy for the ""B"" grinding circuit at the Kidd Creek Division. Between 1992 and 1994 several papers have been written to describe the control objectives, the methodology followed, and some initial results (Flament, 1994A, 1994B). Since then, however, the control objectives changed, and several improvements were made to the circuit. In particular, maximizing tonnage was no longer a priority, a variable speed drive pump was installed on the cyclone feed, the ball mill power was lowered, and the geometry of the cyclones changed. As a consequence, the control strategy was revised. Table 1 summarizes the historical developments on the ""B"" division grinding control."

Jan 1, 1996

By Ken Musgrave

"What Most Effective Management Does?It must satisfy the demands, of three groups of people: owners, employees and the public.OwnersOwners want profitable operations that will pay them a return on their investment, plus operations managed for long life. Many owners are also concerned with employee's well being and their company's public image.EmployeesJob security and a good income are probably still the most important demands, however, as time goes by, employees are also demanding more involvement in safety issues, working conditions, and even how work is done.The PublicThe public requires acceptable environmental standards, as well as enjoying the prosperity supplied by a successful operation.How are Mines Managed?Most mines are managed very traditionally. The basic credo is that the managers make the decisions, and the hourly, and junior salaried employees do what they are told. Clearly this is the extreme case, epitomized by the long service shift boss who might say ""It took twenty-years to become a shift boss, and no miner is going to tell me what to do"" .There are some exceptions, two notable ones being Campbell-Chibougamau, and T.G.S. (now Kidd Creek Mines) which, in very different circumstances, decided on a more participative style.Campbell-Chibougamau, having closed down due to unprofitable operations, reopened, using a team structure with working leaders, and a system for sharing gains against cost targets with employees. Although the system has some problems, and development miners are bonused conventionally, this has been a basically successful program.Texasgulf Sulphur, a company with a history of non-union operations, and a participative management style, made a corporate decision to operate their Kidd Creek Mine in the same way. The orebody was rich enough to allow them the luxury to do this, but they have never had a strike, so perhaps they have more than saved the cost of the benefits and salaries they needed to pay. They also reward employees with a stock distribution scheme based on service and earnings."

Jan 1, 1985

This paper generalizes open stopes into elliptical cross sections and applies the results of calculations based on the mathematical theory of elasticity to indicate stress distribution on the boundaries of such stopes. These show both compressive and tensile stresses and provide an ex-planation for the development of excessive dilution in shrinkage toping. Introduction T HE stress pattern around shrinkage stopes is identical with that around other stopes under the same physical conditions. However, a shrinkage stope ends as an unsupported open stope, and the method i limited to the stress range within which the rock is generally self-supporting. If it is acceptable to generalize the outline of a shrinkage stope into an elliptical cross section, then the graphs of Geldart & Udd (1) (see also Panek (2) and Denkhaus (3)) provide a good base for approximating the stress distribution as mining progresses. However, with failure conditions in the walls, the axis ratio, as cut

Jan 1, 1964

By J. G. Pharoah

Over the last two decades a variety of models for solid oxide fuel cells (SOFCs) have emerged ranging from one dimensional (1-D) to 3-D models, from steady-state to transient models; single- and half-cell and entire stack models. A majority of these models have focused either on the transport processes or on the chemical/electrochemical processes. The approach taken by our research group is to develop a comprehensive SOFC model framework based on the considerations of detailed electrochemical reaction mechanism and by accounting for complex transport processes occurring in the porous media at the micro-scale level. In this paper, we review the state-of-the-art in SOFC modeling and identify the existing gaps that need to be filled in.

Jan 1, 2005

By James F. Archibald

Testing has been accomplished to substantiate recent laboratory trials which have demonstrated that thin liner membranes, applied to rock core samples, can significantly enhance the structural performance of such rock materials. A range of Canadian polymer liner materials (MineguardTM, RockguardTM and RockWebTM) have been tested side-by-side to evaluate strength and other physical property improvements generated for two highly homogeneous, though differently sourced, granodioritic rock materials. Tests were conducted on physically similar core materials, utilizing 104 to 113 samples of each respective rock type. For both rock sample populations, cores were coated using linings at thicknesses varying between 1 and 7.3 mm, typical of the application range currently used underground by mines contemplating use of such membrane agents. Results of rock failure tests, following application of passive lining covers upon the very large sample populations of each rock type, have indicated that noticeable strength improvement and enhancement of post-yield failure characteristics can be developed by the entire range of spray-on liner materials evaluated. It is shown that all of the tested liner agent materials currently available can and do act to positively reinforce rock support capabilities of modeled core pillars. Where liner materials can be effectively placed underground, it is anticipated that they may provide similar benefit and be successfully used in partial replacement for either screen or shotcrete to provide advantageous area support for rock.

May 1, 2001

By Francisca San Martin, Tomas Vargas, Willy Kracht

"In Cu-Mo deposits it is usual to find considerable amounts of pyrite (FeS2). When processing this kind of ore by flotation, pyrite is rejected using lime to increase the pH to alkaline conditions (pH ~10.5). In the case of using seawater without pre-processing, i.e., raw seawater, the lime consumption increases dramatically and the recovery of molybdenite drops due to the precipitation of magnesium hydroxide on its surface. In order to avoid these negative effects, alternative ways of depressing pyrite should be considered.The current work introduces the use of Acidithiobacillus ferrooxidans, bacteria commonly used in bioleaching, as an alternative to depress pyrite in seawater flotation. The paper presents the results of biodepression in three systems: fresh water, water with added sodium chloride at 35 g/L (which corresponds to the salt concentration in seawater ) and seawater. The results show that it is possible to bio-depress pyrite with A. ferrooxidans in natural seawater pH (7.8-8.2). A similar behaviour is observed when running the experiments in fresh water, and in water with sodium chloride added.INTRODUCTIONWater is a scarce but essential resource for human development. The main reason for this scarcity is that, although 70% of the earth's surface is covered with water, only 3% of the total is fresh water and an important part of this water is frozen, so that only 1% of fresh surface water can be used for human activities. In Chile, most of the mining activity is concentrated in the north of the country, located in the Atacama Desert, considered the world's driest desert. That is why some mining companies have chosen to use seawater in their processes. For example, Esperanza (Antofagasta Minerals), and Sierra Gorda (KGHM International) use raw seawater in their flotation processes."

Jan 1, 2016

By Brian Penney

"The Iron Ore Company of Canada (IOCC} has mined and processed an iron deposit in Western Labrador along the Labrador-Quebec border since the early 1960' s. Current capacity is approximately 19 million tonnes of concentrate, 70% of which is converted to pellets at these facilities.The ore deposits are located in hills rising 150 to 300 meters above the adjacent lakes, and most of them are covered by very little overburden. The iron minerals are mainly specular hematite and magnetite hosted in a quartz formation. Crude ore averages 40% Fe that is concentrated to 65.5% Fe. IOCC is an extensive operation extending from Labrador City NF to Sept-Iles Quebec. It consists of open pit mining, concentrating, pelletizing, railway, and dock loading facilities.The Concentrator liberates iron from the silica by crushing and grinding the ore to -14 mesh (-1190 microns}. Ground ore is concentrated in spirals and filtered for transportation. Spiral tailings are treated in a Magnetic Recovery Plant (Mag Plant} that recovers lost magnetite. Mag Plant tailings are treated in a Hematite Spiral Plant (Hem Plant} that scavenges fine iron remaining in this stream.This report deals with ongoing iron recovery initiatives within the ConcentratorIron Losses in the ConcentratorIron recovery at IOCC is approximately 70.5%. This compares with recoveries that range from 65% to 86% for other iron mines in our area. Other world large iron ore producers dig and ship concentrate quality ore directly out of the ground and have an effective recovery of 100%. With increasing costs for labour, equipment, and supplies an increase in iron recovery is required to keep the operation viable.More than 90% of our iron concentrate is produced by gravity separation using spirals. The physical characteristics of the iron minerals that most effect recovery are mineral grain size and degree of liberation. We divide ground ore into three size categories -coarse, intermediate, and fines. A brief description of each size fraction follows:"

Jan 1, 1996