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By Rolf Andreas Lauten, Yanhong Wang, Yongjun Peng

"In mineral flotation, bentonite as a kind of clay mineral imposes deleterious effects on the flotation of valuable minerals, possibly through its ability to increase the pulp viscosity. A higher viscosity lowers the amount of froth and affects the bubble-particle collision frequency. A previous study found that adding gypsum to a bentonite-ore mixture lowered the viscosity, possibly by inhibiting the formation of interconnected network structures. In this study, sulfate as an anion with different types of cations, Na+, K+, Mg2+ and Ca2+ were used to reduce bentonite viscosity and to improve flotation performance. It was found that at the same concentration, MgSO4 was the most effective salt in reducing bentonite suspension viscosity, while CaSO4 was not as effective likely due to the lower solubility of CaSO4. Na2SO4 and K2SO4 reduced bentonite suspension viscosity at high concentration. Flotation kinetics of ore blended with bentonite was increased with increasing the electrolytes concentration, which generally correlated with the reduction of bentonite viscosity. Meanwhile, significant discrepancies were found between flotation results and rheological measurements in the presence of monovalent ions. It is indicated that the morphology of bentonite aggregates in electrolytes solution is likely to influence the hydrodynamics in the froth zone.INTRODUCTIONClay is present in many ore bodies as a gangue mineral. Presence of clay presents several challenges in the processing of valuable minerals. They are soft compared to valuable minerals, which means that during grinding of the ore, clay particles are likely to obtain a smaller particle size than the valuable mineral. Often clay particles may be within the colloidal size domain (<20 µm). The smaller size increases the probability of entrainment in the concentrate. Another challenge is their anisotropic charge distribution, where depending upon the pH, edges (E) and faces (F) carry charges of opposite sign. This facilitates formation of aggregation structures that may impede percolation of bubbles through a froth, but also increase the viscosity more than expected from the mere change in volume fraction. In addition to lowering the froth mobility, a high slurry viscosity will have implications for the gas dispersion in the flotation column as it affects the dispersion of the suspended particles, and it modifies the bubble-particle collision rate and attachment efficiency (Bakker, Meyer, & Deglon, 2009; Shabalala, Harris, Leal Filho, & Deglon, 2011). A pragmatic approach to this problem is to blend high clay ore with ore of lower clay content, reducing the overall clay concentration. Alternatively, one may lower the solids content of the flotation slurry to counteract the viscosity-building properties of clay. While feasible, this approach has the disadvantage of increasing required flotation volume, and it also affects the properties of the froth. Thus, there are currently limited options in lowering the impact of clays and their tendencies to increase viscosity in flotation slurries."

Jan 1, 2016

By D. Pawelus, J. Butra, R. Debkowski, M. Szpak

Impact of horizontal stresses on stability of underground workings in mines is a very important issue in underground mining. Identification of the initial state of stress in the rock-mass should be one of the main actions taken into account while designing and carrying out the mining activity in underground mines. The paper presents the tests on three dimensional stress pattern in Polish copper mines, owned by KGHM Polska Miedz S.A. Group, carried out in 2012. The research program covered 7 measuring stands in two mines; their average depth was about 1000 m. The main aim was to identify the values and directions of horizontal stresses in order to optimize the extraction and to improve the safety. The overcoring method with the use of CSIRO HI type probe was applied. The paper also describes the measuring technique which was developed for the purpose of specific mining and geological conditions of KGHM mines, taking into consideration the natural hazards encountered there as well as technical and operational capabilities with regard to drilling equipment. The experience gained during the underground measurements and the issue of making such measurements in underground copper mines in Poland are presented in the paper. The stress patterns obtained during the underground measurements are of application importance for the process of designing the spacing of mine workings and improving their stability and mine support selection.

Jan 1, 2015

By F. Habashi

Lead is an ancient metal, has been produced to-date from its ores exclusively by pyrometallurgical route. The process suffers from high operating cost and excessive pollution problems. Extensive research has been going on since the beginning of the twentieth century to find a non-polluting process for its production and a solution for its complex refining scheme. It has been assumed correctly that the hydrometallurgical route should be the most promising. Pilot plants have been constructed and operated for a reasonable periods, but no process has proved to be satisfactory. As a result, a number of smelters and refineries have been shut down. The present review analyses the situation and suggests that the best route to treat lead sulfide concentrates is by leaching with fluoroboric acid, HBF4, containing ferric fluoroborate, Fe(BF4)3, and electrolyzing the solution in a diaphragm cell - - a process recently invented by Italian metallurgists. In this process, any silver present in the concentrate remains in the residue together with elemental sulfur and can be recovered by known methods.

Jan 1, 2008

By Ralph W. Edie

"IntroductionTHIS PAPER presents some analyses of diabases from a number of metallogenic provinces in Canada and the United States. It is intended as a contribution to the literature on the genesis of mineral deposits associated with diabase.As it has been in the past, opinion today on the origin of the cobaltnickel- native silver and associated pitchblende type of deposit is sharply divided. Some geologists hold that this type of deposit is in some way genetically related to intrusive diabase; others are of the opinion that the deposits are related to granite. The controversy, like others of a similar nature, probably will not be settled satisfactorily for many years to come, •but in the meantime it is recognized that, with respect to most deposits of the type referred to, altogether too few facts are known for accurate conclusions on genesis to be drawn. To contribute in a small way to factual data on this whole .problem, the writer analyzed diabase from several districts in Canada in which deposits of the aforementioned type occur. For comparative purposes, the copper, cobalt, and nickel content of diabase from Cornwall, Pennsylvania, and of norite from the Sudbury basin of Ontario, was also determined.Insofar as is known, none of the analytical work undertaken had been previously carried out."

Jan 1, 1953

By Mahmood Alemrajabi, Ake Rasmuson, Kerstin Forsberg, Kivanc Korkmaz

"In the present study, the recovery of rare earth elements (REE) in the nitrophosphate process of fertilizer production is investigated. The apatite has been recovered from iron ore tailings by flotation. After digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REEs are recovered by precipitation. Optimum conditions in these steps have been determined in a previous study. The precipitate mainly consists of CaHPO4.2H2O and REE phosphates.In the present study, selective dissolution and re-precipitation have been studied in order to obtain a precipitate that is more concentrated in REEs. The precipitate was selectively dissolved in nitric and phosphoric acid at different acidities (pH 6 to 0) with the liquid /solid ratio of 100 mL/g. It is shown that most of the CaHPO4.2H2O and other calcium containing compounds will be dissolved at pH 2 while the REE phosphates are not dissolved above a pH of approximately 2. Thus, by partial dissolution of the REE precipitate at pH 2.5 most of the solid calcium phosphates will be dissolved and the remaining solid phase, which is more concentrated in REEs, can be filtered off as a fairly concentrated REE solid mass and the liquor can be recycled back to recover more P nutrients. Alternatively, the REE enriched precipitate was dissolved completely in nitric acid and re-precipitated again by addition of ammonium hydroxide to pH 1.2. A chemical equilibrium software, MEDUSA (Puigdomenech, 2013) has been used to evaluate the experimental results and to estimate the optimum conditions for selectively dissolving the precipitate."

Jan 1, 2016

By Nathan Deisman

Coupled reservoir geomechanical simulations have become a key component of caprock integrity assessments for SAGD operations. This work demonstrates the differences of stress evolution when considering coupled versus uncoupled reservoir simulation. Coupled simulation involves the use of a reservoir and a geomechanical simulator with feedback to each simulator to update reservoir or geomechanical variable (permeability, porosity, relative permeability, pressure, temperature, saturations). Uncoupled simulation only passes the pressure and temperature to the geomechanical simulation with no reservoir simulator updating. Therefore, it is possible to complete uncoupled simulations exclusively with no knowledge of geomechanical flow property evolution. However, it is important to understand the differences between the stress evolution in each model for caprock integrity analysis. A single geological model was selected and parametric analysis was completed while varying the geomechanical the production injection pressures (1600 kPa, 1900 kPa, 2200 kPa) for a reservoir with an initial pressure at the injector of 1300 kPa. The results of the six uncoupled and coupled models are compared through the changes in mean stress, shear stress, and strength with focus on geomechanical assessment of caprock integrity.

Jun 1, 2012

By B. Lafrance, C. J. Beaumont-Smith, L. R. Jones

"Abstract - The Burnt Timber gold deposit is located in the Paleoproterozoic Lynn Lake greenstone belt of the Trans-Hudson Orogen, Manitoba. The deposit occurs along the Johnson shear zone, and is hosted by enriched and depleted tholeiitic volcanic arc basalts cut by feldspar porphyry dikes. The Johnson shear zone is a regional, belt-parallel structure characterized by the intensification of the regional S2 foliation. At the Burnt Timber deposit, S2 is folded by centimeter- to meter-scale, Z-shaped, F3 chevron folds that have an axial planar S3 crenulation cleavage. Within the 20 to 30 m-wide core zone of the shear zone, S2 and F3 are transposed parallel to S3 and the volcanic rocks are strongly sheared parallel to S3. The presence of a steeply plunging stretching lineation, together with dextral shear sense indicators along both S2 and S3 on horizontal surfaces, suggest that the Johnson shear zone is a dextral transpression zone. Gold was introduced in pyritic, biotitic, and carbonatized mafic volcanic rocks along the core of the shear zone. Mylonitic mafic volcanic rocks contain localized high-grade zones (=10 g/t Au) that differ from wider carbonatized, low-grade zones (<3 g/t Au) by the presence of deformed gold-bearing quartz-pyrite veins. High-grade zones are also associated with swarms of quartz-pyrite veins that cut across sericitized and carbonatized feldspar porphyry dikes, which acted as brittle, competent bodies during shearing. Gold deposition in the high-grade zones was controlled by the channeling of hydrothermal fluid along the core of the shear zone during shearing of the volcanic rocks, and brittle fracturing of the porphyry dikes. Sommaire - Le gîte aurifère de Burnt Timber est situé dans la ceinture de roches vertes Paléoprotérozoïque de Lynn Lake dans l’orogène Trans-Hudsonien, au Manitoba. Ce gîte est situé le long de la zone de cisaillement de Johnson et est encaissé dans des basaltes tholéiitiques d’arc enrichis et appauvris recoupés par des dykes porphyriques. La zone de cisaillement de Johnson est une structure régionale parallèle à la ceinture de Lynn Lake caractérisée par une intensité accrue de la foliation régionale S2. Au gîte de Burnt Timber, S2 est affectée par un plissement F3 en chevrons en Z d’échelle centimétrique à métrique associé à un clivage de crénulation de plan axial S3. Dans la zone centrale de 20 à 30 m de largeur au sein de la zone de cisaillement, S2 et F3 sont transposés parallèlement à S3 et les roches volcaniques sont fortement cisaillées le long de S3. La présence conjointe d’une linéation d’étirement à forte plongée et d’indicateurs cinématiques dextres sur les surfaces horizontales S2 et S3 suggère que la zone de cisaillement de Johnson est une zone transpressive dextre. L’or a été mis en place dans des volcanites mafiques altérées en pyrite, en biotite, et en carbonate au coeur de la zone de cisaillement. Les roches volcaniques mylonitiques présentent des zones aurifères locales à haute teneur (=10 g/t Au) qui diffèrent des zones à basse teneur (<3 g/t Au) par la présence de veines de quartz et de pyrite aurifère. Des zones à haute teneur associées à des essaims de veinules de quartz et de pyrite sont aussi notées dans des dykes porphyriques à plagioclase altérés en séricite et en carbonates; ces dykes se sont comportés comme des corps compétents durant le cisaillement. La déposition de l’or dans le zones à haute teneur a été contrôlée par la circulation du fluide hydrothermal au coeur de la zone de cisaillement durant la déformation des roches volcaniques et la fracturation des dykes porphyriques."

Jan 1, 2006

By E. O. Magnusson

THE orebodies of the Preston East Dome mine show a considerable variation in size,? shape, dip, and ground condition. They vary from small and large irregular masses being mined by shrinkage, cut-and-fill, and square set-and-fill mining methods to narrow veins being mined by open stoping. Standardization of mining operations has necessarily been difficult. This considerable variation in mining condition prompted the development of a bonus system which would give more equitable bonus payments through-out the mine than those obtained by the usually accepted methods of calculating mine bonus. PRINCIPLES ON WHICH THE SYSTEM IS BASED Under an incentive bonus system, performance (efficiency) and a price per unit of work done are inter-related. It is in the application of this? principle to working conditions .in the Preston East Dome mine that the system to be described differs from the standard methods of calculating mine bonus. It was found that the method of paying a fixed price per unit of work done, under the &apos;contract&apos; system, gave satisfactory results in development, less satisfactory results in timbering, and results which were not satisfactory in stoping. Under the fixed price system, bonus payments, in timbering and stoping particularly, were very erratic and did not necessarily represent fair payment for the work done. A fixed price in development is satisfactory because the work done, and the conditions under which the work is done, are uniform. The drilling and blasting cycle is completed in one shift, the size of heading is con-trolled, and a minimum number of holes are required in order to obtain a satisfactory break. The performance possible under these conditions has been found to be confined to a fairly narrow range. By performance in development is meant the efficiency of the working crew as expressed in terms of the two variables of feet of advance per round and pounds of ex-plosives consumed per foot of advance. A change in rock formation, how-ever, may alter to a marked degree the performance possible, quite independent of the skill and energy of the working crew. The changes in working conditions that affect development performance from the standpoint of bonus calculation are usually easily apparent and are satisfactorily met by establishing several fixed prices.

Jan 1, 1944

By Rodgers Peale

The Waite mine, as it is locally termed, is situated in the Rouyn district, in the townships of Duprat and Dufresnoy, Quebec, and lies about 340 miles north of Toronto. Due to the impetus given prospecting in the Rouyn district by the discovery, some years ago, of copper-gold ore on the Horne claims, many exploration parties were put into the field. Early in 1925, J. H. C. Waite, C. H. Ackerman, and T. Montgomery staked the claims which now comprise the mine beating their names. Trenching and diamond drilling soon disclosed an ore-body of commercial size and grade, and by the end of 1928 a shaft had been sunk 300 feet and the mine was producing 150 tons of direct-smelting copper ore a day. In the summer of 1925, Dr. H. C. Cooke, of the Geological Survey, made a reconnaissance survey of the property (1), and since that time work of the same nature has been done by several others. MacGregor has published some interesting data on the Amulet mine (2). Using as a background a summer&apos;s work on the Horne claims at Noranda, the writer spent the summer of 1929 at the Waite.

Jan 1, 1931

By V. A. G. Preto, W. H. White, J. E. Harakal

Potassium-argon age dating performed recently on intrusive rocks from Copper Mountain indicates that the satellite Smelter Lakes and Voigt stocks have radio-metric ages which are indistinguishable from that of the Copper Mountain stock, as determined by Sinclair and White (1967). The complex of intrusive rocks known as the Lost Horse Intrusions also yields essentially the same radiometric age, as do biotite-sulphide-pegmatite veins on Copper Mountain.

Jan 1, 1971

By F. Khomamizadeh

In this study the effect of solidification rate, T6 and T7 heat treatments on thermal fatigue resistance of A319 aluminum was investigated. Increasing of the solidification rate improved the thermal fatigue resistance of the alloy by refinement of the microstructure. The most sensible areas for thermal fatigue crack growth were the eutectic zones, T6 and T7 heat treatments improved the thermal fatigue resistance of the alloy by enhancing of the matrix resistance against the crack propagation. The slight reduction of the thermal fatigue resistance after T7 heat treatment is attributed to coarsening of the precipitates which reduces the matrix resistance.

Jan 1, 2005

By R. B. Kaunda

One fundamental requirement for surface and underground rock engineering is the ability to characterise the rock mass. An accurate characterisation of the rock mass allows rock engineers to optimize designs safely and economically. A number of classification systems have been developed in the past 50 years to help characterise rock masses such as RMR, Q system, Rmi, and several others. The challenge in developing rock characterisation schemes is often practicality, i.e. creating systems with relatively simple inputs for the everyday practitioner. A second challenge is the degree of subjectivity often inherent in commonly used classification systems. These challenges are especially exacerbated in weak rock or densely jointed rock masses. This paper introduces a new approach to characterise densely jointed rock mass using artificial neural networks and principal component analysis, based on principles commonly used in the geotechnical engineering of rock fills and waste rock dumps. Thirteen input parameters are dimensionally compressed using principal component analysis. Using a global database with more than 100 case histories, an artificial neural network is developed to conduct the rock mass characterisation. The advantage of this approach is less subjectivity as commonly used engineering (quantitative) terms are put to use. A further advantage is that given that the method is site-data dependent, it allows for ‘fine tuning’ of the model for a specific site.

Jan 1, 2015

By J. Stachulak

In recent years more emphasis has been placed on the control of nitrogen dioxide (NO2) emissions from mining diesel equipment. Worldwide, diesel engine regulations to control emission and protect the environment are also driving the development of the diesel engine technology to reduce oxides of nitrogen NOx (Nitric oxide, NO + NO2). NOx are toxic gases produced in mines during the operation of diesel equipment. Most of the diesel equipment used in underground operations are equipped with Diesel Oxidization Catalysts (DOCs) designed to reduce carbon monoxide (CO) and hydrocarbons (HC). The effects of DOCs on NO2 production from diesel powered equipment is not well understood. DOCs do not alter NOx concentration, but may promote the oxidization of engine exhaust NO to the more toxic NO2, thus increasing the undesirable NO2 exposure of workers in the mine environment. In 2012, the ACGIH reduced the NO2 TLV concentration value from 3 ppm to 0.2 ppm. Vale and CanmetMINING have been involved in several research projects to reduce diesel emissions exposure to workers. One aspect of the current program is to determine the effects of in-use DOCs on NO2 production. Several in-use DOCs taken from mining equipment were selected for testing in the laboratory using ISO 8178-C1 and mine LHD transient test cycles. The paper presents the laboratory test results and effects of DOCs on NO2 production. The results indicate significant reductions in CO concentration, by over 77%, while increases in NO2 varied from 46% to 315% based on the ISO 8178-C1 8-mode steady state test cycle. The mine LHD transient test cycle showed the same pattern, although the magnitude of CO reduction was less. Consequently, it is recommended the use of only those DOCs that have been properly evaluated and shown not to significantly increase NO2 emission in the environment be used on mine equipment.

Aug 1, 2013

By H. L. Cheng, C. H. B. Leitch, C. T. Hood, A. J. Sinclair

"Epithermal Zn-Pb-Cu-Ag-Au quartz-carbonate-barite veins at the Silver Queen mine near Owen Lake, west-central British Columbia, are hosted by Late Cretaceous Tip Top Hill andesitic volcanic rocks. The veins form a rectilinear northwest-northeast pattern that differs slightly from regional structural trends. The main northwest-trending veins are oriented very close to the trend of regional northwest faults, but the crossing veins tend to be more east-north-easterly (070 degrees)compared to a regional north-easterly trend (040 degrees). The character of the veins suggests they are extensional features formed by dextral slip related to Paleogene oblique subduction, or intrusion of magma at depth, or both.In detailed exploration at the mine, the veins cannot be modelled as simple tabular sheet-like bodies. Instead, they are complex structures that divide and rejoin, forming multiple veins or stringers, or are found in shear zones as replacement features with quartzsericite- clay-carbonate-pyrite alteration haloes of variable width that make definition of vein margins and correlation from hole to hole ambiguous. In addition, individual veins within each of the main structures have en echelon characterboth along strike and down dip.Geological and assay data must be carefully studied to define the margins of these complex veins before any estimation of ore reserves may be made. Where multiple veins occur in a section, ore/gangue mineralogy, assays, character of wallrock alteration, and thickness of vein and mineralized hangingwall, median and footwall zones must be used to evaluate continuity of mineralized structures. Well-defined sections are projected into areas of increasing complexity. Once the vein boundaries are defined, metal concentrations, important metal ratios(Au/Ag, Pb/Zn, Cu/Zn), and true thicknesses of the vein provide the basic data for reliable ore reserve estimation."

Jan 1, 1991

By E. A. Roux

As the first mine-to-metal zinc operation utilising atmospheric leaching, solvent extraction and electrowinning, Skorpion Zinc faces unique challenges and opportunities. One of these challenges is found in the solvent extraction circuit, in which di-ethylhexyl phosphoric acid (D2EHPA) is used as the organic extractant. Although D2EHPA is an excellent extractant for zinc, it suffers from the co-extraction of ferric iron, which is produced during leaching and by the corrosion of the grinding media. This situation is partially mitigated by iron precipitation in the neutralisation step prior to solvent extraction. Unfortunately, some ferric iron still reports to the solvent extraction process. This leads to a slow build up of iron in the organic phase. Chemical stripping is used to maintain the Fe concentration at an acceptable level. In this paper, the efficiency of the iron removal process is discussed.

Jan 1, 2006

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25&apos; C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By C. S. Chen, Y. J. Luo, M. W. Gao, B. Li, Z. F. Zhang

"To obtain large-sized billets with fine grains and homogeneous elements distribution, uniform direct chill (UDC) casting process, based on annular electromagnetic stirring coupling with intercooling, was employed to produce 7055 alloy billets with a size of F584 mm in this study. The results indicated that there were the coupled effects of annular electromagnetic stirring and intercooling on grain refinement and element homogenization, and also the billets produced by the UDC casting process showed excellent hot workability in comparison to the normal direct chill casting process.INTRODUCTION The high solute 7055 aluminium alloy has a wonderful combination of high specific strength and hardness, good resistance to stress corrosion cracking and high fracture toughness, which is very useful in aerospace application (Yan et al., 2013; Mondal & Mukhopadhyay, 2005). The production of large-sized 7055 alloy billets with high quality is the basic condition for the subsequent application of 7055 alloy to the aircraft. Inhomogeneous microstructures and performances of 7055 billets result from the high alloying element content and the inhomogeneous cooling condition in different regions of billets during the conventional direct chill casting (Paramatmuni et al., 2004; Lalpoor et al., 2011), which will bring bad influence to processing property, functional performance and utilization rate of materials. To alleviate segregation and obtain fine and uniform grains, some effective treatment methods were proposed including electromagnetic stirring (EMS) (Vives, 1989), ultrasonic vibrating (Zhang et al., 2011) and melt conditioning (Fan et al., 2013), on the melt to obtain fine and uniform grains. However, these methods could not effectively decrease the large temperature difference between central and periphery parts of the billet, because the solidification mainly depends on outside cooling including mould cooling and water spraying cooling. To change the heat extraction pattern of the billet functioned solely from the outer surface, based on annular electromagnetic stirring (A-EMS) invented by Xu et al. (2010), Luo et al. (2017) proposed uniform direct chill (UDC) casting coupling A-EMS with intercooling in the direct chill (DC) casting process. An in-mold cooler was inserted to the melt sump, and thus the alloy melt temperature and concentration at solidification front become more uniform."

Jan 1, 2018

By Pizhi Zhao, Yingdong Li, Hailong Cao, Yingjuan Feng

"Three types of anodic films (unsealed, hot water sealed and agent sealed) were prepared to study the effects of anodizing pores structure on the adhesive bonding performance of AA5754 automotive sheets. The morphology of the anodic films was examined by using scanning electron microscope (SEM) and the composition was examined by glow discharge optical emission spectroscopy (GDOES). The adhesive bonding strength and durability in corrosive environment were investigated by using single lap shear test and salt spray corrosion test (SST), respectively. The results showed that the pores structure could significantly influence the adhesive bonding performance. The unsealed sample showed porous structure and provided high bonding strength, however, the durability was poor in corrosive environment. The hot water sealed sample showed fine and loose hydrated alumin a structure on the surface and provided high durability in corrosive environment, but the bonding strength was low. In contrast, the agent sealed sample provided both high bonding strength and durability in corrosive environment.INTRODUCTIONAdhesively bonded aluminum joints by using adhesives have been widely used for the realization of lightweight design in industrial applications like automotive and aerospace industry[1, 2]. Durable bonds which are capable of taking structural loads can be created due to a careful consideration of the way in which the joint is formed, the type of adhesive and the appropriate treatment of the adherend surfaces prior to bonding[3-6]. Experiences demonstrate that the surface treatment is the most critical step which could not be disregarded, since it is essential to achieve long-term service capability [7].In structural applications, a bonded assembly is expected to maintain a significant load and may be combined with exposure to harsh environmental conditions in its service life. For this purpose, the pretreatment for structural bonding of aluminum alloy must provide not only strong tensile strength and durability but also good corrosion resistance. Chromic acid anodizing (CAA) process provides an anodized layer which has good corrosion resistance while also exhibiting useful adhesion characteristics as well as lacquer coating retaining characteristics[8].However, the use of Cr (VI) is unadvised from a health and environmental point of view since it is toxic and carcinogenic, and this process is gradually limited even prohibited. Boeing's phosphoric acid anodizing(PAA) process provides a more open pore structure allowing penetration of high molecular primers/adhesives[8]and PAA process is the most widely used pre-surface treatment suitable for adhesive bonding between aluminum alloy components. Rahimi et al. demonstrated that nanostructure can be produced by PAA process and is affected by the time of pretreatment and anodizing parameters [9]. Xu et al.investigated the influence of surface energy and roughness on adhesive bonding through PAAprocess and provided improved adhesion performance under certain anodizing parameter[10]. However, PAA process is normally not recommended for a major concern of deterioration of the mechanical performance of the joints as a result of exposure to a wet and corrosive environment. Sulfuric acid anodizing(SAA)process, recently, has been widely used for corrosion protection and good base coating for the adhesion of lacquers in aerospace manufacturing[11]. The good performance is explained by properties such as the porous morphology and high adsorptive power of the oxide film, the chemical and electrical inertness of the anodized layer. Moreover, modified sulfuric acid could also used for adhesive bonding. Lunder et al. found that anodizing in hot sulfuric acid is promising as a simple, very rapid and environmentally friendly pre-treatment for adhesive bonding[12].Saeedikhani et al. studied the process of phosphoric/boric/sulfuric acids anodizing and found it was is a promising pre-treatment for adhesive bon"

Jan 1, 2018

By Vic Briccardi

Energy Management Challenges The Holistic Standard to Energy Management Energy Management Information System (EMIS) "Best Practices?: Energy Management Maturity Curve De Beers Canada Profile & Mine Locations Significant ROI Driven by Real-Time Energy Visibility Mining Energy KPI?s Summary: What Does EMIS Deliver? Q&A Session

May 1, 2013

By W. A. Lang

"IntroductionCARBONIZATION, gasification, and chemical utilization of coal are interrelated topics, which makes it difficult to review one without indicating its connection with the others. Hence, in Progress in Coal Technology, Series No. 5: Carbonization, reference was made to gaseous products recovered in the carbonization of coal, and .to a number of chemicals made from the tars, light oils, and ammoniacal liquors which are by-products of coal carbonization.In this, the sixth paper in the review series, prime consideration will be given to the complete gasification of coal to give a fuel for domestic industrial, or power purposes and a synthesis gas suitable for the manufacture of gasoline, Diesel oil, and chemicals. The hydrogenation of coal, an alternative source of liquid fuels and of chemicals, will be reviewed, as will be a number of processes for •the recovery of chemical products from coal by extraction and chemical treatment."

Jan 1, 1952