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By D. V. Dorling, J. T. Bowker, J. A. Gianetto

Over the last few years, interest in the development and construction of large diameter, high pressure pipelines from the Mackenzie Delta in northern Canada and Alaska's North Slope has steadily increased as a result of the projected decline in recoverable natural gas from existing reserves in western Canada. The success of such enormous pipeline projects, which will require utilization of a strain-based design approach, is largely based on successful application of high strength line pipe steels, such as X80 and X100. To fully realize the economic benefits of high strength steels, welding processes and procedures must be developed to ensure that the requirements for high strength and good low temperature toughness are confidently obtainable in field girth welds used in the construction of such pipelines. This study aims to provide a better understanding of the factors that control weld metal strength and toughness for a series of mechanized X100 girth welds produced using a range of narrow-gap gas-metal arc welding procedures. The attainment of high yield strength (> 810 MPa) is considered to be an important target to ensure overmatching strength relative to the longitudinal property distribution of X100 line pipe steel. Some factors that have been considered in this evaluation include influences of gas-metal arc welding process variants (single and multi-wire) and changes in welding procedure specifications, including joint preparation. Key components of this work relate to the reliable measurement of weld metal strength variation through-thickness and as a function of position around the circumference of a given girth weld.

Jan 1, 2005

This paper describes the results of a laboratory study on the upgrading of Algoma siderite by the amine flotation of silica and silicate gangue. The experiments indicate that a virtually complete removal of silica is possible in a rougher flotation con-ducted in tap water at natural pH, without prior desliming of the ore. Grinding considerably finer than the apparent liberation size is essential for maximum silica rejection. A cationic collector, Aeromine 3037, gave best results when used in combination with a modifier. Of the several modifiers tested, a Dutch potato dextrin, Dextrin 4356, was found to be the most effective. Both iron recovery and the grade of the final iron product are enhanced by floating the pyrite contained in the ore prior to the amine flotation of the silica, and by scalping the magnetics from the silica concentrate. F OR over twenty years, the Algoma Ore Properties Division of The Algoma Steel

Jan 1, 1963

By H. Watari

In 1998, a voluntary agreement was reached between the European Commission and the European Car Manufacturers Association (ACEA) to reduce average carbon dioxide emissions of new cars to 25% below 1995 levels by 2008, Agreements have also been reached between the European Commission and the Japanese Automobile Manufacturers Association (JAMA) and the Korean Automobile Manufacturers Association (KAMA), However, the target average of carbon dioxide emissions of less than 140g/km in 2008 is a very challenging goal, Therefore, total product weight reduction is an objective for many manufacturers, This can be achieved utilizing materials possessing high strength and low weight, One material that has recently attracted interest is magnesium alloys, The magnesium alloys are expected to play an important role as next-generation materials, which have possibilities of contributing to lighten the total product weight when magnesium products can be used to replace aluminum and mild steel products.

Jan 1, 2005

By M. M. Holgate

"Porosity neutron deflection scales can be derived more easily by cumulative correlation than by the conventional method of plotting corresponding points on a graph. The micro-log can be used as a porosity datum for the neutron log by transforming the permeability cut-off it shows to a porosity cut-off by a permeability-porosity function obtained from core analysis. Porosity footage values calculated in this manner from the neutron log are within 20 per cent of core analysis values."

Jan 1, 1960

By Ki-Bok Min, Bona Park

"In spite of the applications of DEM models to emulate the elastic modulus, Poisson’s ratio and strengths of isotropic rock in laboratory scale, extensions to anisotropic rock and larger engineering scale still have many challenges to overcome such as robust verification and validation against observed field case. In this study, a discrete element modeling was performed in order to represent a transversely isotropic rock such as shale, and the upscaled model was applied to foundation and borehole problems using PFC2D. The applicability of the upscaled rock mass model was verified by an analytical solution. The DEM modeling of stress redistribution induced by an applied surface line load compares well with Boussinesq’s isotropic solution and anisotropic solution given by Bray. The borehole model with a circular opening under biaxial stress was compared with both isotropic and anisotropic solutions resulting in good agreement. The abilities of DEM model to investigate the micromechanisms accounting for complex macroscopic behaviors and to predict the macroscopic behavior are discussed.The results demonstrate that DEM modeling has the potential to be applied to anisotropic rock mechanics problems on larger engineering scales such as wellbore stability problems especially in shale formations. Furthermore, the effect of anisotropy modeled through this study may be able to explain failure behavior of anisotropic rock encountered frequently in real cases.INTRODUCTIONAnisotropy is prevalent in various types of rocks, especially in shale that contain a set of parallel bedding planes. These weak planes in various forms are sources of large deformation and low shear strength and contribute significantly to the anisotropic behavior of rocks (Amadei, 1996; Cho et al., 2012; Kim et al., 2012). As elastic and strength behavior of anisotropic rock is substantially different from that of isotropic rock, proper consideration of anisotropy is of great importance. There is extensive of experimental evidence showing the anisotropy of shale. Niandou et al. (Niandou et al., 1997) analyzed the plastic deformation and failure mechanisms of Tournemire shale were highly dependent on the orientation of bedding planes. Cho et al. (Cho et al., 2012) presented various deformations and strengths of Boryeong shale obtained from laboratory experiments. Fjaer and Nes (Fjaer and Nes, 2013) performed uniaxial and triaxial compressive strength tests using Mancos shale, and they observed that the shear sliding along the planes of weakness before the occurrence of a major failure can reduce the strength of anisotropic rock. The recent research has demonstrated that the anisotropy of rock is an important consideration in rock engineering."

Jan 1, 2015

Arguably the SMC Test® has become the most popular laboratory hardness test in the world with over 17,000 tests having been completed to date, covering over 650 different ore bodies. It is now routinely used in design, optimisation and orebody profiling projects. The test is unique in that from relatively small amounts of drill core it simultaneously provides parameters that are used in simulation modelling of AG/SAG and crushing circuits as well as work indices that are used in power-based equations for predicting the specific energies of AG/SAG/Crushing and HPGR circuits. The very large data base that has been accumulated has provided the opportunity to study the differences in variability from deposit to deposit. This paper describes and discusses the trends that have become apparent from the study of this data base. Recommendations for appropriate selection of sample numbers are also made which are based on these trends.

Jan 1, 2012

By Mari Yamamoto

Controlled thermolysis of gold(I) complex, [Au(C13H27COO)(PPh3)], at 180 °C for 5 h under an N2 atmosphere affords the new type of monodispersed spherical gold nanoparticles capped by myristate and a small amount of PPh3 ligands (average diameter 23±1.5 nm), in spite of no use of solvent, reducing agent and stabilizer. Much attention has been paid to the preparation and structure determination of transition metal nanoparticles, because of their widespread use in technological applications.1 In general, the chemical reduction of metal salts and organometallic complexes2 by the use of reducing agent is carried out to prepare gold nanoparticles. In some cases, a large amount of solvent and stabilizers such as surfactants,3 polymers4 and ligands5 are used to prevent agglomeration of particles and control the particle size. For instance, Brust et al. reported a two-phase reduction of AuCl4 - by NaBH4 in the presence of dodecanethiol as stabilizer to prepare gold nanoparticles.6 On the other hand, O?Brien et al. recently reported an one-phase preparation of gold nanoparticles by the reduction of AuCl4 - by NaBH4 in the mixture of tri-n-octylphosphine oxide and octadecylamine which act as both solvent and stabilizer, but this procedure also needs reducing agent.7

Oct 1, 2003

By Yuki Tsunazawa, Shuji Owada, Sho Fukui, Chiharu Tokoro

"Since the amount of e-waste has been rapidly increasing all over the world, there is a desire to develop the effective recycling process. E-waste has various kinds of electronic components with valuable and/or hazardous materials. Recycling of them is an important subject from the viewpoint of both the recovery of valuable materials and waste treatment. In common with all mineral processing, the comminution of e-waste is a key process because the liberation states after comminution determine the overall efficiency of metal recovery. Since some of useful critical metals are concentrated in a specific component, a special and selective grinding is expected to be effective. However, the knowledge about the mechanism and the effectiveness of the selective grinding is still limited and unclear.To better comprehend the mechanism, in this study, the investigation of comminution process using the particle-based simulation was conducted. Especially, this study focused on the comminution performance of printed circuit boards (PCBs), which are major components of e-waste. The behavior of PCBs and airflow in a drum typed agitation mill having flexible chains was simulated by the discrete element method (DEM) coupled with computational fluid dynamics (CFD). To model the shape of PCBs, the particle based rigid body model was introduced into the DEM. Since this model could not directly simulate the breakage phenomena, collision energy was calculated to qualitatively evaluate the comminution performance. In addition, the simulation results were compared with the experimental comminution tests using simulant PCBs where some capacitors were solder-mounted. These results indicated that comminution performance was affected by the rotation speed of the agitator. It was also demonstrated that the comminution performance was qualitatively evaluated using the particle-based simulation and this particle-based simulation made it possible to investigate the mechanism of e-waste comminution."

Jan 1, 2016

By M. I. Kalashnikova, Y. M. Shneerson, M. V. Keskinova

Interaction between mattes having various compositions and solutions with a wide range of free acid and non-ferrous metals concentration have been studied in terms of chemistry, mechanism and kinetics. The solution acidity and oxidizers to reducers ratio in the matte-solution-gas phase system have been demonstrated to be the major factors determining the process behaviour. It was found that the types of copper and nickel secondary sulphides resulted from nonferrous metals precipitation from solution, depend on of the solution and initial matte composition. Based on these studies, technologies of matte leaching and nonferrous metal precipitation in the form of rich sulphide concentrates are developed.

Jan 1, 2004

By Kuwauchi. Y., M. Barati

Recycling of dust using a rotary hearth furnace (RHF) has gained considerable attention in the past two decades for the sustainable production of steel with less environmental impact. In order to further promote the recycling of electric arc furnace dust and carbonaceous wastes using the RHF process, a mathematical model was developed to predict the reaction behaviour of dust-reductant composites. The reduction kinetics of zinc and iron oxides as well as the volatilization behaviour of volatile matter in the reluctant were considered. The modeling approach and some preliminary results are presented in this article.

Jan 1, 2011

By Robert B. Parsons

"There is a widespread concern that certain of Finance Minister Michael Wilson's Tax Reform proposals will likely lead to a significant decline in flow through funding after 1988. This does not bode well for the junior exploration sector, which relies heavily on flow-through to finance exploration programs. The exploration industry is actively pursuing various solutions to the problems posed by Tax Reform, in order to ensure that flow-through has a future.IntroductionWhile the proposals contained in Finance Minister Michael Wilson's Tax Reform White Paper may not be as far-reaching as some people had expected, nevertheless the combination of the existing tax rules and proposed new rules offers sufficient complexity to keep pencils sharpened for many months. After having had an opportunity to study Tax Reform since June 18, 1987, the sharpened pencils are suggesting that the White Paper is not without its shortcomings and pitfalls. Insofar as the mineral exploration industry is affected, there is widespread concern that adoption of certain Tax Reform proposals could spell near disaster for mineral exploration in Canada. More specifically, there seems to be a consensus among the industry, as well as some federal and provincial government officials, that the announced phase-out of the ""mining exploration depletion allowance"" (MEDA) would reduce the appeal of flow-through shares to the point where only a fraction of exploration funding would be financed in the future by flow-through."

Jan 1, 1987

By Iain Sommerville, Hugh Mountford, Dawid D. Smith, Claude Dube, Brett Hixson

JW Aluminum use lean and Six Sigma techniques to continuously improve their target of reliable, repeatable and reproducible (3R) manufacturing. Six Sigma’s second stage gate, known as "Measure" involves identification and qualifying appropriate measuring systems. Metal quality (inclusions) are known in the industry to be an important element in 3R casting. The measurement of inclusions at JW Aluminum historically depended on outside vendors. In order to establish real time inclusion measurement ability within JW Aluminum, inclusion measurement systems in the marketplace were investigated. The qualification of a MetalVision MV20/20 ultrasonic inclusion analyzer are discussed as well as the subsequent application of the system in melting and casting improvement projects.

Jan 1, 2015

By R. Prioul, J. Kear, D. Chuprakov, A. P. Bunger

"Hydraulic fracture (HF) growth through naturally fractured rocks challenges the development of accurate predictive HF models. The authors present laboratory experiments differentiating behaviours associated with orthogonal and oblique intersections between HFs and natural fractures (NFs). HFs were created in sandstone and crystalline (gabbro) rock specimens, impinging orthogonally or obliquely on an unbonded machined frictional interface. Ultrasound monitoring was used to observe the rate of propagation through the interface. A contrast was observed between direct and offset crossing for orthogonal and oblique intersection, respectively. The stresses required to promote crossing depended on the intersection angle between HFs and NFs.RÉSUMÉ La propagation des fractures hydrauliques (FH) dans les roches naturellement fracturées pose un défi pour le développement de modèles prédictifs. Nous présentons des essais en laboratoire qui différencient les comportements associés aux intersections orthogonales et obliques entre les FH et les fractures naturelles. Des FH ont été créées dans des spécimens de grès et de roches cristallines (gabbro), heurtés de manière orthogonale ou oblique sur une interface machinée, non liée, de frottement. Un suivi par ultrasons a servi à observer le taux de propagation à travers l’interface. Un contraste a été observé entre un croisement direct et un croisement indirect des intersections respectivement orthogonales et obliques. Les contraintes requises pour promouvoir le croisement variaient selon l’angle d’intersection entre les FH et les fractures naturelles."

Jan 1, 2016

By G. Titichoca

Modification of the blasting process considers that any increase in the energy consumption generates greater benefits if done in the later stages (associated with a larger decrease in energy consumption). Therefore, although the blasting cost is doubled, generating a greater proportion of fines in addition to a weaker ore (because with greater loads and appropriate distribution of explosives a greater number of internal cracks is generated), the reduction of the unit cost that occurs in the grinding stages (SAG and ball mills) generates a positive balance in the overall size reduction process. Codelco Chile, Division Andina, has developed an extensive experimental plan to evaluate the concept of blasting modification applying greater energy. This was implemented in two stages, each including a specific mine sector: La Union and Don Luis. This paper reviews the experience of implementing such blasting modifications at the La Union mine and its impact on the design concepts and the operation of the SAG mill plant

Jan 1, 2007

By William D. Swank, Prabhat K. Tripathy, Tedd E. Lister, Eric S. Peterson, Delon C. Haggerd

More than half of the primary neodymium, produced directly from ores, is being used to manufacture neo magnets. Neodymium, being a critical element in supply, has attracted considerable interest worldwide to recover this metal from a variety of waste streams. From among different recycling processes, hydriding-dehydriding can prove to be highly effective in recycling discarded neo magnets present in consumer electronics. In the present study, manually removed magnets from discarded Hard Disk Drives (HDDs) were subjected to the hydriding-dehydriding process in order to evaluate the resultant products for the re-fabrication of the magnets. The paper describes the effect of experimental parameters on both the hydriding and dehydriding processes as applied to different magnet chemistries.

Jan 1, 2014

The Buzwagi Project is owned by Barrick Gold Corporation and located in the Lake Victoria Goldfields of central Tanzania in the District of Kahama in the Region of Shinyanga. The property is 6 km Southeast of the town of Kahama, 3 km South and adjacent to the road between Nzega and Burundi. The Buzwagi property is 97 km South of Barrick?s Bulyanhulu Mine. There is access to the rail line which connects from Isaka to the Indian Ocean coastal ports of Dares Salaam and Tanga. The Feasibility Study and permitting were started in early 2006. Project Execution commenced in August 2007. Process Plant commissioning started in January 2009 and the first gold pour is scheduled for Q2 2009. The reserve has been established as 3.3M oz of gold plus 177M lbs of copper. The project has been developed to include a 30Mtpa Open Pit Mine and 4.4 Mtpa Process Plant. Over an expected 15 year mine life, Buzwagi is anticipated to produce approximately 3.02M oz of gold and 220,000 tonnes of copper concentrate. Infrastructure associated with the project includes a 107 km 220kV power line, site accommodation, water harvest and extensive security facilities. The project is expected to be built on budget and on time during a period of extreme market volatility. This paper reviews the initiatives taken to achieve community support, control cost escalation, maintain schedule and manage logistic challenges, plus ensure security and safety of all workers.

May 1, 2009

Stellite-6 coatings were formulated on two Ni-base superalloys, namely Superni 75 and Superni 600, by a shrouded plasma-spray process, and the oxidation behaviour of these coatings has been investigated in air and in an aggressive environment of Na2SO4- 60%V2O5. Accelerated oxidation tests were conducted in a silicon-carbide tube furnace under cyclic conditions at an elevated temperature of 900°C for 50 cycles. Each cycle consisted of 1 h heating and 20 min cooling in air. A thermogravimetric technique was used to approximate the oxidation kinetics. The corrosion scales were characterised by XRD, SEM/EDAX and EPMA analysis. It has been observed that the coatings nearly followed the parabolic rate law of oxidation. Overall weight gain conceived in air was just 51% of that in the aggressive environment in the case of coated Superni 75, whereas in case of coated Superni 600, the cumulative weight gain in air was found to be one-third of that in the Na2SO4-60% V2O5 atmosphere. Furthermore, the coating showed very good adherence to both of the substrates during the course of air oxidation, whereas some superficial cracks were observed near the edges of the specimens during the molten salt induced oxidation. XRD analysis revealed the presence of phase-like CoO, CoCr2O4 and Cr2O3 in the oxide scales, which are reported be protective against high-temperature oxidation. The XRD results were further supported by SEM/EDAX and EPMA.

Jan 1, 2005

By Z. X. Cui, X. D. Ma, L. Contreras, X. Jiang

The bath smelting process is one of the key techniques applied in the current copper smelting production, which includes bottom-blown and side-blown furnaces differently from the direction of gas injection. Liquid matte and slag form the bath in the smelting furnace. To better understand the fluid dynamic of the bath and further optimise the operational efficiencies in the smelting furnace, physical simulation of the bath in the horizontal cylindrical reactor was investigated. The mixing behaviour and wave motion of the bath in the bottom-blown and side-blown furnaces have been studied systematically. The mixing time is reduced with increasing gas flowrate and height of the lower layer, while it increases significantly with increasing the height of the upper layer. The wave motion in the furnaces can be suppressed with the presence of the upper layer, but the bath with a lower density generates higher wave amplitude. Overall, in comparison to bottom-blown mixing, side-blown mixing shows better mixing efficiency and lower wave amplitude. In addition, the plume eye and splash phenomena occurred in the bottom-blown furnace have also been studied. INTRODUCTION The bath smelting process is one of the principal techniques used in the current copper making industry. The bath smelting techniques have some advantages of high smelting efficiencies, low capital costs, low energy consumptions and reduced dust generations. From the direction of gas injection, the bath smelting techniques can be classified into five general types: (1) top-submerged blown, e.g. Ausmelt and Isasmelt; (2) top-suspended blown, such as Mitsubishi smelting; (3) top direct-to-copper smelting, such as Outokumpu smelting; (4) submerged side-blown, such as Noranda and Teniente smelting; (5) bottom-blown, such as Dongying Fangyuan bottom-blown copper smelting furnace (Schlesinger et al., 2002; Zhao, Cui, & Wang, 2013; Perez-Tello et al., 2018). In many metallurgical processes involving bath smelting situations, the objectives of agitation are to accelerate the bath homogenization inside the bath which makes a significant contribution to process efficiency and product quality. Extensive mixing studies have been performed for ladle refining and tundish associated to steelmaking processes through water physical models. Mixing time is the parameter used to quantify the efficiency of mixing in the liquid bath and the first empirical equation predicting mixing time was proposed by Nakanishi, Fujii and Szekely (1975). Later on, more systematic studies have been carried out on ladle mixing and researchers realized that the geometry of the vessel could also have a significant impact on mixing (Khajaviand & Barati, 2010). However, the investigations using ladles which are vertical cylindrical vessels, cannot be directly used in the study of mixing behaviour in horizontal cylindrical reactors. Understanding the fluid dynamics inside horizontal cylindrical bath smelter is useful from the industrial perspective. Recently fluid dynamics of horizontal cylindrical smelter related to copper smelting have been studied by the authors’ group (Shui et al., 2015a, 2015b, 2018a; 2018b; Xu et al., 2018, 2019).

Jan 1, 2019

By M. Barati

A collaborative research between University of Toronto and Hatch was conducted to understand and optimize the process conditions pertaining to a novel steelmaking technology. In this technology, known as CRISP, direct reduced iron is continuously melted and refined in a stationary electric arc furnace. The major challenge against continuous operation of the electric furnace was identified to be minimizing the corrosion of the refractory in order to achieve uninterrupted operation for a minimum of one year. Theoretical analysis and bench scale experiments together with two pilot runs resulted in defining an operating window for slag chemistry that would minimize chemical attack to the refractory while satisfying the oxidizing conditions required for sufficient decarburization. An analysis of the process in terms of energy consumption and emission of greenhouse gases revealed that it is superior to the current batch DRI-based steelmaking technologies.

Jan 1, 2011

By S. Esfahani, M. Barati, Y. Kauwachi

"Heat recovery from slag has gained attention due to its high potential in lowering energy intensity of metal extraction processes. A direct method to recover the thermal energy of slag is to use countercurrent air flow that extracts the heat from falling droplets. Often, the solidified slag is aimed to be used as a substitute for Portland cement, thus high cooling rates are required to form an amorphous slag with sufficiently strong hydaulicity. Rapid cooling however involves using large gas flow rates that in turn lower the thermal efficiency of the process. This article presents a mathematical model that was developed to determine the optimum conditions in the heat recovery process and to investigate the effect of the air flow and granule diameter on the cooling rate of the droplets as well as the thermal efficiency of the heat recovery system. INTRODUCTIONMetallurgical slags are the largest by-product of high temperature materials refining and extraction processes. The total amount of metallurgical slag produced in the year 2008 has been estimated at up to 422 million tonnes containing up to 222 TWh/y (Barati and Esfahani, 2011) of thermal energy. Over the past four decades attempts have been made to recover this substantial amount of energy as heat, electricity, or fuel, while none of the proposed method has been commercialized yet.During slow cooling the slag tends to crystallize the constituents (CaO, SiO2, Al2O3, etc.) into a hard, heavy solid. In the past, over 90% (Bengt, 1983) of the molten waste was discharged onto heaps and allowed to cool slowly, then crushed and used in road construction or land filling or as coarse aggregate for concrete. However, later it was found if cooled rapidly, the slag can be used as a substitute for Portland cement. As a result, processes such as wet granulation were created in which molten slag is fragmented with water, forming amorphous (glassy) phases. Despite its effectiveness in producing a suitable material, heat would not be recovered through this process. Thus, dry granulation was introduced in 1930’s and was developed further in 1970 – 1980’s."

Jan 1, 2012