Search Documents

By F. T. Rabbitts

Introduction When the investigation of radioactive ores began at the Mines Branch about five years ago it was at once evident that improved chemical methods for the determination of uranium were essential. The published methods available were time-consuming and insensitive and were lacking in accuracy and precision. It was desirable to obtain methods which would be rapid, sensitive, and accurate. They should also allow for the possible presence of any interfering elements and should be adaptable to routine analysis by technicians. Chemical methods are necessary to provide standard analysed samples for counting and to check analyses by counter methods. Moreover, counter methods cannot be used, and only chemical methods are suitable, when the sample is not in equilibrium, as with weathered minerals and leach residues. As leaching processes are improved, more sensitive chemical methods are required for the increasingly lower content of uranium in the leached residues. When the leaching process reaches the plant stage, speed of analysis becomes more important, without sacrificing accuracy. The purpose of this paper is to describe briefly .the methods used at the Mines Branch for the chemical analysis of uranium in ores. These methods represent the results of investigations by a number of groups in the United Kingdom, the United States, and Canada.

Jan 1, 1952

By V. Vorontsov

Catalysts Mo-Ni-S were prepared by combining MoS2 and NiS in weight ratios 1:1, 1:2, 1:4 and 2:1, each of which was admixed with 5%wt Ag and 5%wt YSZ to increase three-phase boundary surface area of the electrode. For comparison catalysts comprising Co-Mo-S in weight ratio of 1:1 of CoS to MoS2 admixed with 5%wt Ag and YSZ and pre-sulfided NiMoO4 were made. The catalysts were examined for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cells (SOFC) at 850°C temperature. The catalyst prepared from 1:1 (wt. %) NiS:MoS2 demonstrated highest performance. Current density up to 1,330 mA/cm2 and power density up to 300 mW/cm2 were achieved using pure H25 gas, which are the highest among the reported H2S-powered fuel cells ever published in the literature. Anode materials of different NiS:MoS2 ratios have been characterized by means of X-ray diffraction (XRD), simultaneous TG/DSC analysis and Neutron Activation Analysis (NAA). TG/DSC and NAA results show that addition of NiS and Ag increases fuel cell performance due to improved structure/integrity of the anode. It has also been demonstrated that MoS2 is a suitable anode material in H2S-powered SOFC, with high activity towards H25 oxidation and thermally and chemically stable up to 850°C.

Jan 1, 2005

By Ainul Akhtar, Steve Cockcroft, Jixiang Xu, Daan Maijer, Lu Yao

"Nitrogen rich Ti-N inclusions are one of the more difficult inclusions to remove during liquid metal refining of titanium. If present in the final component, they can significantly decrease the mechanical performance of titanium and its alloys in applications involving cyclic loading. Understanding the kinetics of dissolution of Ti-N particles during consolidation/melting of titanium can help us better operate and design the melting processes to minimize their occurrence in Premium Quality Titanium production. A numerical model based on finite difference method has been developed to calculate the dissolution of a spherical Ti-N particles in molten titanium. Analytical solutions were used to verify the finite difference code for calculation of concentration profile and the dissolution of spherical solids. Taking into account the limitations in these approaches for the different cases examined, the invariant field approximation showed good agreement with the results from the numerical analysis. Evolution of the size of a spherical Ti-N particle during dissolution was predicted by the numerical model and the particle dissolves in 163 s.INTRODUCTION Properties like low density, high specific strength and excellent corrosion resistance make titanium attractive for a variety of applications. Key characteristics in the processing of titanium and its alloys include its high sensitivity to impurities, especially atmospheric oxygen and nitrogen and its high reactivity in the molten state. Nitrogen rich inclusions Ti-N, also known as Type ? or hard alpha defects, usually have substantially higher hardness and lower ductility than the surrounding material. Because they can act as fatigue initiation sites, Ti-N inclusions can significantly decrease the mechanical performance of titanium and its alloys in applications involving cyclic loading, even in minor amounts (tenth of a percent) (Lampman, 1990; Moiseyev, 2005; Lütjering & Williams, 2007). Ti-N encompasses as a broad range of nitrogen contents from a few wt% up to stoichiometric TiN. The liquidus temperature of Ti-N titanium increases substantially with increasing nitrogen content. Consequently, depending on the concentration of nitrogen, the melting point of Ti-N inclusions can be above bulk liquid metal temperatures during melt processing. Thus, removal of Ti-N defects hinges on dissolution and not melting."

Jan 1, 2017

By A. Pawelczyk, D. Hreniak, E. Zych, W. Strek, K. Grabas, A. Ostrowski

"Nowadays recycling became an important rare earth elements (REE) source, which allows to reduce their demand for extraction from natural deposits. At present, the used fluorescent lamps and old type TV or computer monitors kinescopes are selectively collected and undergo processing in the system of recycling. It has been estimated, that utilization of such waste would be sufficient to cover the REE demand for the next 5-8 years. In the developed process, the luminophores were separated from the electronic and electronic waste materials, and processed by hydrometallurgical methods to obtain concentrated REE in form of oxides. INTRODUCTIONInternational Union of Pure and Applied Chemistry (IUPAC) defines the rare earths as a set of seventeen chemical elements, specifically the fifteen lanthanides plus scandium and yttrium. They are considered the most important indicators of the developed technologies and techniques. Rare earths are used, amongst others, for the production of magnetic and superconducting materials, ceramics, lighting, catalytic converters, advanced electronics and alloys. The demand for RE continually increases, similarly to many other primary raw materials. Globalization, the growing demand for limited resources of raw materials, the policy of the countries controlling the raw material market and the economic crisis became a spur for new programs of socio-economic development of the European Union (EU), with particular regard to EU safety for commodities in intermediary as well as long-term horizons (COM 2008), COM 2011).EU countries import most of metallic and chemical raw materials important for their economy. In 2008 a detailed program named Raw Material Initiative was announced. The increase in demand for most raw materials having special importance for the development of technology, and access to of raw materials security of supply affect the future economies of the UE member states and other developed countries."

Jan 1, 2012

By Engineering Staff

In 1958, the Iron Ore Company of Canada decided to proceed with the Carol Project. The ore deposits in the area are part of the highly metamorphosed southern zone of the Labrador Trough. They lie along the shore of W a bush lake, in the western part of Newfoundland-Labrador, 190 miles north of Sept-Iles. The project is designed to mine, by open-pit methods, 17,200,000 long tons of crude ore, grading 37 per cent iron, per year. This ore will be beneficiated to produce 7,000,000 long tons of concentrate, grading 66 per cent iron, of which 5,500,000 long tons will be pelletized. Production is scheduled to commence this summer. Initially, ore will be taken from 45-foot benches in the Smallwood mine, using jet-piercing production drills and large-scale blasting with "slurry" explosives. Four 13-yard electric shovels will muck the broken ore into 100-ton trailer trucks. The trailers will be hauled to two 2,000-ton loading pockets, which feed the ore into 100-ton railcars. Four ore trains, each comprised

Jan 1, 1962

By J. B. McKay

It is the purpose of this paper to present an initial report on the construction and operation of the Fluo-Solid roaster at the property of Campbell Red Lake Mines, Ltd., Balmertown, Ontario. The roaster prepares for subsequent cyanidation the bulk flotation concentrate obtained from four hundred tons per day of gold ore. The mill flow-sheet 'includes jigging and amalgamation; flotation; cyanidation of flotation tailing; and roasting followed by cyanidaition of flotation concentrate plus amalgamation tailing. Overall mill recovery for the year 1950 was 90.2 per cent. Recovery possible by straight cyanidation of this ore would not exceed 80 per cent. The ore contains considerable arsenopyrite and pyrrhotite as well as pyrite, with lesser quantities of nickel, zinc, and copper minerals. The mineralization is for the most part extremely fine. The roaster first went into operation on August 7th, 1949, and at the end of 1950 it had roasted 10,916 tons of concentrate. The average recovery of gold from calcine during that period was 94.86 per cent in the primary stage of calcine cyanidation. The average assay of calcine residue from primary cyanidation for the entire period was 0.37 oz. per ton. Both laboratory tests and plant metallurgical balance calculations indicate a further recovery of approximately 10 per cent of this 0.37 oz. when the calcine residue is again cyanided, in the flotation tailing cyanidation circuit.

Jan 1, 1951

By Marcelle A. Hauseux

"The Turgeon Lake granite lies 5 miles north of Baie Johan Beetz, Quebec, at the eastern margin of the Grenville Province. The rocks are classed as granites, granulites, quartzites, biotite schists and gneisses, and amphibolites. The granite's uraniferous character is manifested by phosphuranylite, uraninite, and metamict .zircons associated with magnetite. Field anomalies occur in irregular pods, conformable with the tectonic foliation, in bands roughly paralleling sedimentary bedding. Associated features diagnostic of uraniferous granite are smoky quartz, brick-red feldspar, magnetite and a coarse to pegmatitic grain size. The granite is chemically and physically heterogeneous. Metasediment-granite contacts are diffuse or sharp, and usually conformable to bedding. The regional foliations within all rock types are coherent, and sedimentary structures are often preserved within both metasediments and granite. Autometasomatism probably was a strong granitization agent.A uranium reconcentration into fold-axial zones from original sediments which have been highly granitized during at least two phases of folding is suggested from the available data."

Jan 1, 1977

By Xueyuan Nie, Xuezhi Zhang, Henry Hu, Shen Xinwei, Jimi Tjong, Li Fang

With the demand for weight reduction in vehicles and airplanes, researchers have shown great interested in casting wrought aluminum alloy 7075 because of its potential advantages such as high strength-to-density ratio and stress-reduction capabilities. It is therefore essential to conduct a fundamental investigation on solidification behavior and grain microstructure of alloy 7075. In this study, a commercially-available wrought aluminum alloy 7075 was used to study the solidification behavior of alloy 7075. A thermal analysis was performed based on the cooling curve and its corresponding first and second derivative curves. The nucleation of the primary a-Al phase and eutectic phases were analyzed. The comparison between the microstructures of the wrought and cast 7075 alloys shows that coarse microstructure and porosity are present in the cast alloy. The techniques for grain refinement in casting, such as the addition of the nucleating particles and applied pressure, should be employed to reduce the dendrite arm spacing and the porosity.

Jan 1, 2015

By William E. Roscoe

"Valuation methods are well established for mineral properties with production or imminent production, and include discounted cash flow and comparable transactions. Valuation methods for non-producing mineral properties, however, are more subjective. Non-producing mineral properties include those at various stages of exploration, properties at the prefeasibility or feasibility stage, properties with currently uneconomic mineral resources, and past-producers. Different valuation methods may be appropriate for different types of mineral properties.Income approach methods such as discounted cash flow and option pricing are generally not applicable to properties at the exploration stage. The market approach is generally appropriate to all types of mineral properties, although it is difficult to find good comparables because of the unique nature of mineral properties and the small number of transactions. Cost approach methods, such as appraised value and geoscience factor, are commonly used for exploration stage properties.Canadian standards and guidelines for valuation of mineral properties are in the process of being finalized by a Special Committee of the Canadian Institute of Mining, Metallurgy and Petroleum (CIMVal Committee). The CIMVal Standards are intended to be consistent with National Instrument 43-101, which sets regulatory standards of disclosure for mineral projects, and with International Valuation Standards. The intent of the CIMVal Standards and Guidelines is that mineral property valuation be carried out by appropriately qualified individuals and that all relevant information be disclosed."

Jan 1, 2003

By B. Courtaud, L. Donati, V. Weigel

As a growing mining company, ERAMET is looking for new positions in the strategic metals market. In this context, the Gabonese Maboumine pyrochlore deposit is currently being studied for the recovery of niobium, tantalum, rare earths and uranium. This ore shows mineralogical and chemical characteristics that make it challenging to process by existing practices, from both technical and economic points of view. ERAMET has developed since 2008 an innovative hydrometallurgical process, which has been successfully operated at a pilot plant scale (more than 35 weeks in continuous). The upstream part of the process aims to dissolve valuable elements in sulphuric acid. The first step is dedicated to dissolve the ore matrix, leaving the pyrochlore unleached. The second step consists in chemically breaking down pyrochlores in order to form soluble species of the valuable elements. After dissolution, the valuable elements are separated into different flows: niobium and tantalum are recovered and transformed as commercial ferroniobium on one side, and rare earths and uranium remain in the solution to be recovered in the downstream part of the process. The main goal of this paper is to discuss the upstream part of the process, which has given successful results.

Jan 1, 2014

By J. E. Gebhardt, D. McBride, M. Cross

Heap leach processes can encounter diverse flow conditions, such as infiltration into dry ore material, drainage, perched water tables and heterogeneous materials, leading to large variations in permeability and the creation of preferential flow pathways. Climate and meteorological conditions, such as precipitation, evaporation, and temperature, can also have a significant effect on the hydrodynamics of the heap. Nonuniform and adverse flow behavior within the heap contributes to reducing the leaching efficiency of the heap leading to lower metal recoveries. The variability of flow within the heap can result in solute transport problems, which limit the leach reaction kinetics. Therefore, understanding the flow and transport phenomena within the heap is critical in its design and optimization. A comprehensive heap leach model, developed within a computational fluid dynamics (CFD) framework, employs robust algorithms to solve diverse variably saturated flow conditions. The model allows for a wide array of complex thermo-fluid physics to be represented and captures suites of very complex reactions that are closely coupled with thermal conditions and key microbial populations. Employing a three-dimensional heterogeneous ‘test’ heap, a number of flow conditions are investigated and the sensitivity of metal recovery is discussed.

Jan 1, 2014

By G. M. Castillo

Newmont?s Phoenix mine started production in March of 2006. Due to the extreme hardness of the ore, the mill has struggled to meet throughput projections. Grinding studies showed that optimizing the existing circuit would not achieve budgeted throughput. These studies also showed that the pebble crusher was being underutilized due to the inability of the SAG mill to break the rock. The concept was developed to supplement the feed to the existing pebble crusher with a secondary crusher. Models of this process looked favorable so a portable crusher was installed to test the process. The temporary crusher was successful at increasing the throughput by 7% and based on the operating data, plans are currently being developed to install a permanent secondary crushing system in front of the SAG mill. This paper will review the results from the test crusher and the flow sheet for the permanent secondary crusher.

Jan 1, 2012

By F. G. Vetsch, F. A. Ronaghan

"Introduction1N THE FALL of 1951, Peace River Allied Fort St. John No. 1 well was drilled in Lsd. 1, Section 9 Township 83, Range 18, West of the 6th Meridian, on the flats of the north side of Peace river, six miles southeast of the village of Fort St. John, B.C. During this operation, non-commercial shows gas in three zones and of oil in one zone were obtained during the drill-stem tests. Further geological study indicated that this well was on the southeastern edge of the Fort St. St. John structure.Pacific Fort St. John No. 4, drilled shortly afterwards, obtained possible commercial gas flows on drill-stem test in five zones and thus encouraged development of what has become Canada's largest multizone gas field.In general, the productive horizons in this area possess fair per-meabilities and high porosities, a combination which provides for high reserves and moderate productivities. Development to date has therefore stressed experimental techniques in drilling and completion practice to provide high deliverability wells.Data and information of a specific nature apply, in all cases, to the pools in the Fort St. John structure."

Jan 1, 1954

By J. S. Fox

"Pyroclastic rocks are useful guides to volcanic centers due to the tendency of their fragments to increase in size and volume toward the source vent. The felsic rocks of these centers can be the prime hosts of base metal deposits in the Precambrian Shield; their sub-volcanic equivalents are often the focus of porphyry copper mineralization in the Cordillera. Quantitative mapping of pyroclastic rocks has not yet developed into a routine prospecting tool in Canada, however, possibly due to the cumbersome nature of existing manual techniques and their limitation to structurally simple terrains.A rapid pyroclastic mapping method has been developed whereby the field geologist acquires only a down-plunge outcrop photograph, a record of the fragmental deformation ellipsoid and a record of some descriptive features from each station. Mean fragment size and volume percent are obtained later in the laboratory from a photo-enlargement: by means of a digital analyzer. A computer program uses the strain parameters to 'undeform' the field measurements and obtains genetic information from the descriptive data. Results can be superimposed on a geologic map, with values for each station being represented by a dot of a specified diameter corresponding to the size or volume percentile range to which the value belongs.Control traverses were run over the pyroclastic rocks surrounding the Anderson Lake mine and the Flin Flon South main shaft in northern Manitoba. In both locations, the mapping has delineated regular increasing trends in mean size and volume per cent toward the head frame."

Jan 1, 1977

By Erwin L. Zodrow

"IntroductionThrough an extensive coal sampling project in the Sydney coalfield of Nova Scotia during 1981 - 1984 involving a majority of the mineable coals (Zodrow, 1985, Fig. 1), a sizeable inventory on trace, minor and major metals was established. In this paper, results of studying the inventory are summarized, concentrating mainly on the relationship that exists between metal variations and thickness of coal channel samples (i.e. trends) and on explaining the trends in geochemical and sedimentological terms. As an over-all conclusion the Everglades peat of Florida is proposed as a modern-day analogue to Upper Carboniferous peat swamp development that took place in the Sydney Basin.Data InventoryFor this study 17 channel samples were cut , 8 cm to 14 cm channel width and 8 cm to 10 cm depth, from 10 successive coals which in stratigraphically descending order are as follows: Point Aconi (3), overrider Lloyd Cove (2), Lloyd Cove (2), Stubbart (2), Harbour (4), Backpit (I), Phalen (,I), Shoemaker (1) and McAulay (I), where bracketed values signify the number of channel samples cut from a seam (Zodrow, 1985, Fig. I). Each channel sample was subdivided by 15 em incremental length yielding a total sample size of 137 for analysis. By appropriate modern techniques these samples were analyzed to determine concentration levels for 32 chemical elements and ash content, the average results of which are presented in Table 1.Tests were also made for Pd, Pt, Ga, Nb, Cd, Cs, Sm and W but their concentration levels in many instances hovered on the lower detection limits that were used and on this accounts are excluded from discussion. Ashing, when necessary for the determination of concentration levels, was done for 12 hours at a temperature not exceeding 450°C. Concentration levels for the elements are reported in reference to whole-coal or whole-coal equivalents and discussed on this basis. In the course of the analyses, lower detection limits received careful attention."

Jan 1, 1986

By B. F. Osborne

"A new sensor cannot be considered in isolation from the process in which it is utilized. This paper, describing an on-stream particle size analyzer, therefore gives considerable emphasis to the slurry handling techniques employed to ensure that the instrument is presented with a representative sample. A new sampler is described, which continuously abstracts a small, representative sample from a closed pipeline containing a flowing slurry. This sample is then diluted, thoroughly mixed and pumped to a head tank, from where a continuous stream is fed at a constant rate to the size analyzer. Data are presented to show that particle size segregation is minimal throughout this sampling and sample preparation. A continuous particle size analyzer based on a separation principle is described, and the basic parameters of size distributions, and how they relate to this particular instrument, are considered. Typical results are given. An electronic system is presented which accepts the basic sensor outputs, and converts these to a particle size signal suitable for process control. Finally, the use of an inplant computer to process the sensor signals to obtain a particle size signal is briefly considered."

Jan 1, 1972

By L. Yuan, J. H. Rowland, R. A. Thomas, D. Bahrami, G. P. Cole

"The past several decades have seen a steady increase in the use of atmospheric monitoring systems (AMS) in underground mines as sensor technology has advanced and costs for this technology have decreased. The AMS is a reliable tool for early mine fire warning by detecting gaseous products of combustion in underground mines. During a mine fire emergency, mine decision makers rely heavily on the prompt and accurate knowledge of the ventilation and fire situation in the mine, such as fire location, fire size, and the spread of smoke to make effective and efficient decisions on firefighting strategies and miner evacuation. Meanwhile, a prediction of the potential for fire development at a later time, such as whether the currently designated mine escapeways will be contaminated by smoke and toxic gases with the progress of the fire, is critical for effective decision-making to save lives that are in danger. The AMS monitoring data, including carbon monoxide (CO) concentration, airflow rate, smoke, etc., can provide information as to whether the smoke has reached the locations where AMS sensors are installed and if a mine-wide smoke spread has occurred. The National Institute for Occupational Safety and Health (NIOSH) has undertaken a task to integrate real-time AMS monitoring data with the mine fire simulation program, MFIRE, to simulate and predict the spread of smoke and toxic gas in a ventilation network based on the real-time AMS data. This paper reports the developed real-time method for characterizing the size and location of an underground mine fire and for predicting the spread of contaminants throughout the mine ventilation network using sensor data from the AMS.INTRODUCTIONNIOSH conducts research to develop workplace solutions to improve detection of and reduce the risk of hazardous conditions in underground mines. The advancement of senor technology and the increasing demand for real-time mine parameters monitoring have led to extended applications of atmospheric monitoring systems (AMS) in underground mines worldwide. In the United States, AMS is primarily used for early mine fire warning by detecting carbon monoxide (CO) in fire hazard areas, such as belt entries. Mine fires can grow rapidly, and time is the critical element. Prompt detection, timely and accurate warnings to those miners potentially affected, and a proficient response by underground miners can have a tremendous impact on the social and economic consequence of a small underground mine fire (Conti et al., 2005). The early detection of a mine fire could gain time for the first responders to put out the fire before it develops into a disaster. An AMS system with CO sensors has especially played an important role in the early detection of mine fires. The continuous monitoring of an underground mine atmosphere with an AMS could generate a large amount of data in a mine fire event. However, the current application of AMS is mainly limited to sending out an alarm when monitored CO concentration exceeds a certain level. An opportunity arises as to whether these data can be further used in fire emergency response. In order to make effective decisions on firefighting strategies, mine workers’ seeking refuges, evacuation and escape, and the timing on when to send rescuers, decision makers need accurate and timely knowledge of the ventilation and fire situation in the mine. Information about the fire intensity, where in the mine the smoke and toxic gases have spread, and whether designated mine escapeways have been compromised by smoke and toxic gases from the fire would greatly increase the effectiveness of these decisions. However, the monitored AMS data only provides atmospheric conditions in the vicinity of sensor locations. What is concluded from the monitored AMS data highly depends on the decision makers’ capability and experience. Predictive insight into fire growth and smoke transport would greatly help decision makers during a fire emergency."

Jan 1, 2019

By James Kear, Romain Prioul, Robert G. Jeffrey, Andrew P. Bunger, Dimitry Chuprakov

"Unconventional gas and geothermal reservoirs are typically naturally fractured and therefore the challenging problem of hydraulic fracture (HF) growth through naturally fractured rocks is an important issue especially for the development of accurate predictive HF models. This paper presents results from laboratory experiments in which HFs have been created in both sandstone and crystalline (gabbronorite) rock specimens such that they impinge either orthogonally or at an oblique angle on an unbonded, machined frictional interface. Depending on the conditions of each experiment, the fractures either cross or are blunted at the interface. The growth behavior was ascertained for these experiments based on a synthesis of the injection pressure record, active ultrasound monitoring, and direct post-experiment inspection of fractured specimens. From these experiments we observe: 1) A contrast between direct crossing and crossing with an offset for orthogonal and oblique intersection, respectively, 2) Apparent independence of crossing/blunting behavior on the friction coefficient for orthogonal intersection, 3) Dependence of the stresses required to promote crossing on the intersection angle between the HF and NF, 4) Existence of cases in which the hydraulic fracture crosses but then essentially ceases propagation such that all fluid is diverted to the interface. INTRODUCTIONHydraulic fracturing is a vital technology used to increase the productivity of oil, gas, and geothermal wells. Predicting hydraulic fracture (HF) growth is, in turn, critical to design of hydraulic fractures that grow to the desired length, accept the desired amount of proppant, and remain contained in the reservoir without unwanted height growth into surrounding layers (e.g. Economides and Nolte, 2000). The importance of HF modeling has prompted 6 decades of research during which simulators have become more efficient, more accurate, and have addressed a growing range of complexities (see review of e.g. Adachi et al., 2007).One of these complexities is the interaction between HFs and mechanical discontinuities such as natural fractures (NFs). Efforts in this area have been mainly driven by development of unconventional (i.e. low permeability) oil and gas resources because essentially all viable low permeability reservoirs, including shale gas/oil reservoirs, are naturally fractured to some degree (King, 2010). One of the most important questions for developing effective HF stimulation strategies in these reservoirs is whether the hydraulic fracture(s) is/are expected to be single-stranded or whether interaction with the NFs will lead to network-like growth. The basic building block for numerical simulators that can address this question (such as Kresse et al., 2013 and Weng et al., 2014) is whether an HF that intersects an NF will cross the NF or whether its growth will be captured by the NF so that additional fluid injection pressurizes the NF but does not generate ongoing growth of a new HF. These scenarios, including subcategories such as crossing with an offset, have been recognized for several decades (Daneshy, 1974; Warpinski and Teufel, 1987, and as recently reviewed and expanded by Chuprakov et al., 2013)."

Jan 1, 2015

By G. Morin, F. Chiesa, B. Duchesne

The Quality index is a useful tool allowing to assess the metallurgical quality of aluminium AlSiMg foundry alloys (A356/357). Its value is calculated from the ultimate tensile strength and elongation; it increases with the metallurgical quality of the casting, i.e. with finer dendrites, lower microporosity and inclusion count and lower iron content. This Quality index does not depend on the degree of temper applied during the heat treatment (aging time and temperature). After defining the Quality index, it will be explained how it can be predicted from the knowledge of the local solidification conditions obtained from modelling. The paper will then present four case studies of castings for which the prediction of the Quality index by modelling was made. These case studies from different authors will involve the three most common casting processes used for producing high integrity aluminium castings, namely: sand casting, permanent mould casting and investment casting (lost wax). In all cases, the accuracy of the prediction will be assessed by comparing the predicted Quality index distributions to the experimental values based on the published measured values of the local tensile properties.

Jan 1, 2006

By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005